• 제목/요약/키워드: hydrated lime

검색결과 64건 처리시간 0.052초

동해 폐탄광 일대 산성 광산폐수의 중화처리 (Neutralization Processes of Acid Mine Drainage (AMD) from the Abandoned Donghae Coal Mine)

  • 김정엽;전효택;오대균
    • 대한지하수환경학회지
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    • 제2권1호
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    • pp.38-47
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    • 1995
  • 이 연구에서는 삼척탄전 내에 위치하는 폐탄광인 동해탄광을 대상으로 산성 광산폐수의 중화 처리를 위한 각종 기초자료를 제시하고자 하였다. 산성 광산폐수의 측정시기에 따른 변화양상을 관찰한 결과 갈 수기에는 각종 잠재적 유독성 원소들의 함량이 증가하며, pH가 하락하여 수질이 악화되는 경향을 보였다. 공업용 소석회는 처리효율 및 경제성을 고려할 경우 산성 광산폐수의 처리를 위한 최적의 중화제로 판단되며, 평형 모델링 결과 중화처리과정에서 Fe는 FeOOH의 형태로, Al은 Al(OH)$_3$, 의 형태로 침전되는 것으로 추정된다. GIS를 이용하여 동해탄광일대 산성 광산폐수 처리시설의 위치를 제시하였으며 수문학적 자료를 이용하여 최대강우량 및 첨두유량을 계산하였다.

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CuO/3Al$_2$O$_3$ㆍ2SiO$_2$, 촉매담지 세라믹 캔들필터를 이용한 먼지/NOx/SOx/HCl 제거기술

  • 문수호;홍민선;이재춘;이동섭
    • 에너지공학
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    • 제13권2호
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    • pp.133-143
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    • 2004
  • Simultaneous removal technology of particulate/NOx/SOx/HCl using CuO/3Al$_2$O$_3$ㆍ2SiO$_2$catalyst impregnated ceramic candle filters is an advanced air pollution process and provides significantly to reduce hazardous gases emitted from coal-fired power plant. This process uses a high-temperature catalytic filter for integrating SOx and HCl reduction through injection an alkali sorbent (such as hydrated lime or sodium bicarbonate), NOx removal through ammonia injection and selective catalytic reduction (SCR), and particulate collection on the catalytic filter surface. The advantages of the process include : compact integration of the emission control technologies into a single component; easy handling of dry sorbent and by-product; and improved SCR catalytic life due to lowered SOx, HCl and particulate levels. CuO/3Al$_2$O$_3$ㆍ2SiO$_2$ catalyst impregnated ceramic candle filters showed a possibility of simultaneous treatment from results which have ascertained high removal efficiency at various combined gases conditions, and in pilot plant test for 3 months, NO conversion was showed 90% over.

복토의 pH 및 칼슘이 양송이의 균사생장 및 수량에 미치는 영향 (Effect of pH of Casing Soil and Calcium on Mycelial Growth and Yield of Agaricus bisporus (Lge.) Sing)

  • 박원목;김동수;박용환;곽병화
    • 한국응용곤충학회지
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    • 제10권1호
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    • pp.59-62
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    • 1971
  • 양송이를 재배할 때 복토의 최적 pH와 칼슘원의 효과를 구명코저 본 시험을 실시하였다. 양송이 복토의 최적 pH는 7.5이었다. 중성내지 약알카리성토양에서 칼슘의 촉진적 효과가 뚜렷하였다. 즉, 복토에 첨가되는 수산화칼슘 및 탄산칼슘의 효과는 pH교정뿐만 아니라 칼슘의 생장촉진효과도 중요하다고 본다.

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가압성형 방법에 의한 발포유리의 제조공정 (Production Process of Foamed Glass by Compressive Shaping)

  • 이철태
    • 공업화학
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    • 제24권3호
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    • pp.239-246
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    • 2013
  • 기존의 발포유리 제조공정의 원리는 원료유리분말을 거푸집에 담아 발포소성시키며, 발포소성 후에 발포체를 거푸집과 분리 후에 서냉 열처리를 하는 것이다. 이러한 이유로 기존의 발포유리 제조공정은 연속생산이 불가능하다. 본 연구에서는, 발포유리의 연속생산공정을 개발하기 위해서 거푸집을 사용하지 않는 대신, 원료유리분말을 가압성형하여 먼저 성형체를 만들고, 이 성형체를 발포시켜 발포유리를 생산하는 새로운 발포유리제조공정의 가능성을 타진하였다. 수화된 소다석회 유리분말을 사용하고 유리의 발포에 가장 핵심적인 발포제를 달리한 가압성형체를 발포소성시키는 실험 결과를 통해서, 거푸집을 사용하지 않고서도 발포유리의 연속생산공정이 가능할 수 있음을 확인하였다.

보일링 시험을 통한 아스팔트 혼합물의 수분민감성 평가 (Evaluation of Moisture Susceptibility of Asphalt Mixtures Using Boiling Water Test)

  • 김준;박대욱;보비에트하이;김혁중;박준상
    • 한국도로학회논문집
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    • 제17권1호
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    • pp.77-82
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    • 2015
  • PURPOSES : The purpose of this paper is to evaluate the moisture susceptibility of asphalt mixtures containing developed liquid anti-stripping agents using the boiling water test as a screening test. METHODS : The boiling water test was used to evaluate the moisture susceptibility of asphalt mixtures containing different anti-stripping agents. The tensile strength ratio was calculated to compare the moisture susceptibility of the asphalt mixtures after indirect strength tests were performed. Additionally, image analysis techniques were used to calculate and analyze the quantity of stripped area in the asphalt mixtures. RESULTS : In general, the asphalt mixtures containing anti-stripping agents showed a higher resistance of anti-stripping based on the boiling water test and tensile strength ratio. CONCLUSIONS : The boiling water test can be used to differentiate the resistance of moisture susceptibility of asphalt mixtures, except for asphalt mixtures containing hydrated lime. The boiling water test can be used as a screening test for asphalt mixtures before conducting time consuming and expensive indirect tensile strength tests.

재유화형분말수지를 혼입한 재생콘크리트의 강도 특성 (Strength Properties of Recycled Concrete Containing Water-redispersible Copolymer Powder)

  • 김인수;성찬용
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2005년도 학술발표논문집
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    • pp.128-134
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    • 2005
  • This study was performed to evaluate the strength and durability properties of recycled concrete containing water - redispersible copolymer powder(WRP) and blast furnace slag powder(BSP) [RCWS]. Material used were cemente, recycled coarse aggregare, natural fine aggregate, water-redispersible copolymer powder, blast-furnace slag powder. Especially, Water-redispersible powder was used for blending with Inorganic binders such as cemente, gypsum and hydrated lime etc. First of all, Mixed ratio method of RCWS made Two Type. One was called type-1 which used to BSP content 5% and WRP(Water-redispersible powder) content 0%, 1%, 2%, 3%, 4%, 5%, 6%. respectively. Another was called Type-2 which used to BSP(blast furnace slag powder)content 10% and WRP(Water-redispersible powder) content 0%, 1%, 2%, 3%, 4%, 5%, 6%. respectively. According to the experimental results of (RCWS), Incase Type-2 at curing age 28days, Compressive strength, pulse velocity and dynamic modulous of elasticity were shown higher than Type-1 and The more WRP content increasing($0%{\sim}6%$) was the lower Compressive strength, Pulse velocity and Dynamic modulous of elasticity. Water absorption ratio was in the range of $3.85%\;{\sim}\;3.23%$, it was almost equal to Type-1, 2 but Increasing the WRP content($0%{\sim}6%$), The water absorption ratio is decreased.

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Effect of Cassava Hay and Rice Bran Oil Supplementation on Rumen Fermentation, Milk Yield and Milk Composition in Lactating Dairy Cows

  • Lunsin, R.;Wanapat, Metha;Rowlinson, P.
    • Asian-Australasian Journal of Animal Sciences
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    • 제25권10호
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    • pp.1364-1373
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    • 2012
  • Four crossbred (75% Holstein Friesian) lactating dairy cows, with an average live weight of $418{\pm}5$ kg and $36{\pm}10$ d in milk were randomly assigned according to a $2{\times}2$ factorial arrangement in a $4{\times}4$ Latin square design to evaluate the effects of cassava hay (CH) and rice bran oil (RBO) on feed intake, nutrient digestibility, ruminal fermentation, milk yield, and milk composition. Factor A was non-supplementation or supplementation with CH in the concentrate. Factor B was supplementation with RBO at 0% or 4% in the concentrate mixture. The four dietary treatments were (T1) control (Concentrate with non-CH plus 0% RBO; C), (T2) Concentrate with CH plus 0% RBO (CH), (T3) Concentrate with non-CH plus 4% RBO (RBO), and (T4) Concentrate with CH plus 4% RBO (CHRBO). The cows were offered concentrate, at a ratio of concentrate to milk production of 1:2, and urea-lime treated rice straw was fed ad libitum. Urea-lime treated rice straw involved 2.5 g urea and 2.5 g $Ca(OH)_2$ (purchased as hydrated lime) in 100 ml water, the relevant volume of solution was sprayed onto a 100 g air-dry (91% DM) straw, and then covering the stack with a plastic sheet for a minimum of 10 d before feeding directly to animals. The CH based concentrate resulted in significantly higher roughage intake and total DM intake expressed as a percentage of BW (p<0.05). Ruminal pH, $NH_3$-N, BUN and total VFA did not differ among treatments, while RBO supplementation increased propionate, but decreased acetate concentration (p<0.05). Furthermore, the population of total ruminal bacteria was significantly lower on the RBO diet (p<0.05). In contrast, the total ruminal bacteria and cellulolytic bacteria on the CH diet were higher than on the other treatments. Supplementation with CH increased (p<0.05) F. succinogens and R. flavefaciens populations, whereas the populations of B. fibrisolvens and M. elsdenii were increased on the RBO diet. In addition, supplementation with CH and RBO had no effect on milk production and composition in dairy cows, while fatty acid composition of milk was influenced by RBO supplementation, and resulted in significantly lower (p<0.05) concentrations of both short-chain and medium-chain FA, and increased (p<0.05) the proportion of long-chain FA in milk fat, as well as significantly increased cis-9, trans-11 CLA and total CLA. In conclusion, RBO or CH exhibited specific effects on DMI, rumen fermentation, microbial population, milk yield and composition in lactating dairy cows, which were not interactions between CH and RBO in the diets. Feeding lactating dairy cows with RBO could improve fatty acid in milk fat by increasing cis-9, trans-11 CLA.

박리방지제의 첨가에 따른 아스팔트 혼합물의 수분민감성 평가 (Evaluation of Moisture Susceptibility on Asphalt Mixtures mixing Anti-Stripping Agent)

  • 양성린;황성도;김영민;정규동
    • 한국도로학회논문집
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    • 제10권4호
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    • pp.41-52
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    • 2008
  • 본 연구는 박리방지 첨가제를 혼입한 아스팔트 혼합물의 수분민감성에 대한 특성 평가 방안을 제시하고자, 기존의 수침 시험을 개선한 3가지 종류($H_c$, $V_s$, F-T)의 수침 방법을 통하여 생석회, 소석회, 1종의 액상 박리방지 첨가제를 혼입한 각 아스팔트 혼합물에 대한 수분민감성의 거동 특성을 분석하였다. 실험방법은 AASHTO TP-9에 규정된 간접인장시험(Indirect Tensile Test, IDT)을 통한 크리프시험 (Creep Test), 회복탄성계수시험(Resilient Modulus Test) 및 강도시험(Strength Test)을 수행하였다. 분석방법으로는 미국 플로리다 대학의 Roque에 의해 제안된 에너지비(Energy Ratio, ER) 개념을 사용하여 박리방지제의 사용에 따른 효과 및 수분민감도 특성을 평가하였다(Roque, 2004). 시험결과, 수분처리 방법 에 따른 아스팔트 흔합물의 물성 변화뿐만 아니라 박리 방지 첨가제에 따른 물성 변화가 현저하게 나타났다. 또한 누적 수분 손상에 의해 발생되는 균열에 대한 저항성이 각 첨가제 및 수분처리 방법에 따라 변화됨을 나타내었다. 이를 토대로 Energy Ratio를 분석한 결과 약 $10{\sim}30%$ 정도의 균열 저항성 변화가 나타났다.

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Hybrid neutralization and membrane process for fluoride removal from an industrial effluent

  • Meftah, Nouha;Ezzeddine, Abdessalem;Bedoui, Ahmed;Hannachi, Ahmed
    • Membrane and Water Treatment
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    • 제11권4호
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    • pp.303-312
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    • 2020
  • This study aims to investigate at a laboratory scale fluorides removal from an industrial wastewater having excessive F- concentration through a hybrid process combining neutralization and membrane separation. For the membrane separation operation, both Reverse Osmosis (RO) and Nanofiltration (NF) were investigated and confronted. The optimized neutralization step with hydrated lime allowed reaching fluoride removal rates of 99.1± 0.4 %. To simulate continuous process, consecutive batch treatments with full recirculation of membrane process brines were conducted. Despite the relatively high super saturations with respect to CaF2, no membrane cloaking was observed. The RO polishing treatment allowed decreasing the permeate fluoride concentration to 0.9± 0.3 mg/L with a fluoride rejection rate of 93± 2% at the optimal transmembrane pressure of around 100 psi. When NF membrane was used to treat neutralization filtrate, the permeate fluoride concentration dropped to 1.1± 0.4 mg/L with a fluoride rejection rate of 88± 5% at the optimal pressure of around 80 psi. Thus, with respect to RO, NF allowed roughly 20% decrease of the driving pressure at the expense of only 5% drop of rejection rate. Both NF and RO permeates at optimal operating transmembrane pressures respect environmental regulations for reject streams discharge into the environment.

Enhancement of the Characteristics of Cement Matrix by the Accelerated Carbonation Reaction of Portlandite with Supercritical Carbon Dioxide

  • Kim, In-Tae;Kim, Hwan-Young;Park, Geun-Il;Yoo, Jae-Hyung;Kim, Joon-Hyung;Seo, Yong-Chil
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.586-591
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    • 2001
  • This research investigated the feasibility of the accelerated carbonation of cement waste forms with carbon dioxide in a supercritical state. Hydraulic cement has been used as a main solidification matrix for the immobilization of radioactive and/or hazardous wastes. As a result of the hydration reaction for major compounds of portland cement, portlandite (Ca(OH)$_2$) is present in the hydrated cement waste form. The chemical durability of a cement form is expected to increase by converting portlandite to the less soluble calcite (CaCO$_3$). For a faster reaction of portlandite with carbon dioxide, SCCD (supercritical carbon dioxide) rather than gaseous $CO_2$, in ambient pressure is used. The cement forms fabricated with an addition of slated lime or Na-bentonite were cured under ambient conditions for 28days and then treated with SCCD in an autoclave maintained at 34$^{\circ}C$ and 80atm. After SCCD treatment, the physicochemical properties of cement matrices were analyzed to evaluate the effectiveness of accelerated carbonation reaction. Conversion of parts of portlandite to calcite by the carbonation reaction with SCCD was verified by XRD (X-ray diffraction) analysis and the composition of portlandite and calcite was estimated using thermogravimetric (TG) data. After SCCD treatment, tile cement density slightly increased by about 1.5% regardless of the SCCD treatment time. The leaching behavior of cement, tested in accordance with an ISO leach test method at 7$0^{\circ}C$ for over 300 days, showed a proportional relationship to the square root of the leaching time, so the major leaching mechanism of cement matrix was diffusion controlled. The cumulative fraction leached (CFL) of calcium decreased by more than 50% after SCCD treatment. It might be concluded that the enhancement of the characteristics of a cement matrix by an accelerated carbonation reaction with SCCD is possible to some extent.

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