• Title/Summary/Keyword: hydrated cement paste

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Carbonation Properties of Recycled Cement Mortar made of Cementitious Powder from Concrete Waste (폐콘크리트 미분말을 이용한 재생시멘트 모르터의 중성화 특성)

  • Kim Jin-Yang;Park Cha-Won;Ahn Jae-Cheol;Kang Byeung-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.61-64
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    • 2005
  • Recently, there have been many studies about recycling cementitious powder from concrete waste(hereinafter referred to as waste powder), generated after recycle aggregate production. Previous studies showed that when the heating process of waste powder at $700^{\circ}C,\;Ca(OH)_2$ in paste is dehydrated making possible the restoration of hydraulic properties. Recycled cement with hydraulic properties restored is thought to be re-hydrated through the mechanism of hydration, which is almost similar in Portland cement. This clearly suggests that the hydrate of recycled cement is alkali in type. Like in general concrete, if recycled cement is used as a structural material, resistance performance against carbonation or neutralization by $CaCO_3$ in air probably would be most influential to the life of steel-reinforced concrete structure. Thus the purpose of this study is to make an experimental review on chemical properties of recycled cement, manufactured with concrete waste as base material, and investigate the durability of concrete using recycled cement through evaluating the cement s performance of resistance to carbonation in accordance with its accelerating age. Based on its results, further, the study seeks to provide basic information about ways of utilizing recycled cement.

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Carbonation Properties of Recycled Cement Mortar made of Cementitious Powder from Concrete Waste (폐콘크리트 미분말을 이용한 재생시멘트 모르터의 중성화 특성)

  • Park, Cha-Won;Ahn, Jae-Cheol;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.6 no.4 s.22
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    • pp.61-68
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    • 2006
  • Recently, there have been many studies about recycling cementitious powder from concrete waste(hereinafter referred to as waste powder), generated after recycle aggregate production. Previous studies showed that when the heating process of waste powder at $700^{\circ}C,\;Ca(OH)_2$ in paste is dehydrated making possible the restoration of hydraulic properties. Recycled cement with hydraulic properties restored is thought to be re-hydrated through the mechanism of hydration, which is almost similar in Portland cement. This clearly suggests that the hydrate of recycled cement is alkali in type. Like in general concrete, if recycled cement is used as a structural material, resistance performance against carbonation or neutralization by $CaCO_3$ in air probably would be most influential to the life of steel-reinforced concrete structure. Thus the purpose of this study is to make an experimental review on chemical properties of recycled cement, manufactured with concrete waste as base material, and investigate the durability of concrete using recycled cement through evaluating the cement's performance of resistance to carbonation in accordance with its accelerating age. Based on its results, further, the study seeks to provide basic information about ways of utilizing recycled cement.

An Experimental Study on the Fluidity Properties of High Flowing Concrete Affected by Size and Volume Ratio of Coarse Aggregate (조골재 크기 및 용적비에 의한 고유동콘크리트의 각종 유동특성에 관한 실험적 연구)

  • 최세진;김완영;김진만;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10a
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    • pp.258-261
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    • 1998
  • Aggregate is cheaper than cement and confers considerable technical advantages on concrete, which has a higher volume stability and better durability than hydrated cement paste alone. and coarse aggregate is the largest particle size out of concrete and is much affect on the fruidity, compaction and non-segregation ability of high flowing concrete. As the compaction, fillingability and shrinkage of high flowing concrete, the volume ratio of coarse aggregate is prescribed by Japanese Architectural Standard Specificateon (JASS 5) : from 0.500 to 0.500㎥/㎥. It is the aim of this study to compare and analysis the fruidity, fillingability and non-segregation of high flosing concrete according to the volume ratio of coarse aggregate of concrete(G/Glim).

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The Inhibition Effect of Alkali-Silica Reaction in Concrete by Pozzolanic Effect of Metakaolin (메타카오린의 포조란 효과에 의한 콘크리트 내 알칼리-실리카 반응 억제 효과)

  • Lee Hyomin;Jun Ssang-Sun;Hwang Jin-Yeon;Jin Chi-Sub;Yoon Jihae;Ok Soo Seok
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.277-288
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    • 2004
  • Alkali-silica reaction (ASR) is a chemical reaction between alkalies in cement and chemically unstable aggregates and causes expansion and cracking of concrete. In the Present study, we studied the effects of metakaolin, which is a newly introduced mineral admixture showing excellent pozzolainc reaction property, on the inhibition of ASR. We prepared mortar-bars of various replacement ratios of metakaolin and conducted alkali-silica reactivity test (ASTM C 1260), compressive strength test and flow test. We also carefully analyzed the mineralogical changes in hydrate cement paste by XRD qualitative analysis. The admixing of metakaolin caused quick pozzolanic reaction and hydration reaction that resulted in a rapid decrease in portlandite content of hydrated cement paste. The expansion by ASR was reduced effectively as metakaolin replaced cement greater than 15%. This resulted in that the amounts of available portlandite decreased to less than 10% in cement paste. It is considered that the inhibition of ASR expansion by admixing of metakaolin was resulted by the combined processes that the formation of deleterious alkali-calcium-silicate gel was inhibited and the penetration of alkali solution into concrete was retarded due to the formation of denser, more homogeneous cement paste caused by pozzolanic effect. Higher early strength (7 days) than normal concrete was developed when the replacement ratios of metakaolin were greater than 15%. And also, late strength (28 days) was far higher than normal concrete for the all the replacement ratios of metakaolin. The development patterns of mechanical strength for metakaolin admixed concretes reflect the rapid pozzolanic reaction and hydration properties of metakaolin.

The Effects of Self-Healing for Ternary Blended Cement in Tap-water and Sea-water (삼성분계 시멘트의 해수와 담수에서의 자기치유 효과)

  • Kim, Tae-Wan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.6
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    • pp.10-19
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    • 2016
  • The objective of this study is to investigate the self-healing properties of ternary blended cement(TBC) paste made with OPC, GGBFS and FA. The influence of OPC-GGBFS-FA on the self-healing ability of ternary blended cement paste was researched by ultrasonic pulse velocity(UPV) measurement. The TBC paste with GGBFS-FA replacement ratios of 20%, 40% and 60% were prepared having a constant water-cementitious materials ratios os 0.5. The research focuses on behavior after 28days(after loading). Four-point bending tests are used to pre-cracked the prismatic specimens at 28days. For specimens (uncracked and cracked) submerged in tap-water and sea-water until 60days. According to the experimental results, the TBC paste system has self-healing ability increased when the fraction of GGBFS increased. Because GGBFS and FA continues to hydrate after 28days, it is likely that hydrated products from GGBFS and FA may modify microstructures, seal these cracks. From these results, it is clear that the crack in all samples experience self-healing and that this occurs mostly in the first 30days of submerging. Futhermore, most of the healing for both specimens of submerged in sea-water and tap-water occurred during the first 30days. Sea-water submerged specimens healed cracks as fast as those in tap-water. Differences in healing effects of submerged in sea-water and tap-water may be attributed to the presence of specific sea-water ions. Therefore, self-healing effects considered age-effects was more strong effect occurred mostly in the first 30days, and then gradually weaken.

Fundamental Study on the Strength Development of Cement Paste using Hardening Accelerator and High-Early-Strength Cement (경화촉진제와 조강시멘트를 사용한 시멘트 페이스트의 강도발현에 대한 기초적 연구)

  • Min, Tae-Beom;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.4
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    • pp.407-415
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    • 2013
  • The purpose of this research is to verify the performance of hardening accelerator in cement paste through mechanical performance evaluation and micro structure analysis on hardening accelerator for development of super high early strength concrete. The research results showed that hardening accelerator produced $Ca(OH)_2$ when hydrated with cement, enhancing the degree of saturation of Ca ion by using differential thermal analysis. Moreover, porosity was reduced rapidly as capillary pores were filled by hydration products of $C_3S$. According to the experiment using hydration measurement testing, when 1% and 3% of accelerator were mixed, hydration rate increased toward the second peak point compared to high early strength cement, before the first peak point disappeared. It turned out that adding accelerator accelerated the hydration rate of cement, especially $C_3S$. The shape of C-S-H is shown depending on the amounts of accelerator added and the production and age of $Ca(OH)_2$ by using SEM to observes hydration products. Therefore, it's evident that hardening accelerator used in this research increases amounts of $Ca(OH)_2$ and accelerates $C_3S$, it is effective for the strength development on early age.

Recycling Technology Trend of Waste Concrete Powder for Carbon Neutrality in the Cement Industry (시멘트 산업 탄소중립을 위한 폐콘크리트 미분말의 재활용 기술 동향)

  • Sang-Chul, Shin;Jin-Man, Kim;Geon-Woo, Kim;In-Gyu, Kang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.465-474
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    • 2022
  • Research on the recycling of waste concrete has been conducted mainly focusing on the production of high-quality recycled ag g reg ate, and as a result, standards and specifications for recycled ag g reg ate have been established. However, in the case of waste concrete powder, although a lot of research on its utilization has been conducted in Korea, an innovative technology leading to commercialization has not yet been announced. Recently, research on technology using waste concrete powder as a raw material for clinker or cement has been actively conducted in major overseas advanced countries. This study investigated the overseas cases with regard to high value-added recycling technology and commercialization trend of waste concrete powder for carbon neutrality in cement and concrete industries. A number of studies have reported that it is essential to completely separate the aggregate and hydrated cement paste fraction for recycling of waste concrete powder. Also in major foreig n countries such as EU and USA, commercialization and standardization of using waste concrete powder as a raw material for clinker or a additive for cement are now in progress beyond the R&D stage. Therefore, Research and standardization for recycling of waste concrete powder should be urgently carried out from the perspective of carbon neutrality in Korea.

Segmentation of Natural Fine Aggregates in Micro-CT Microstructures of Recycled Aggregates Using Unet-VGG16 (Unet-VGG16 모델을 활용한 순환골재 마이크로-CT 미세구조의 천연골재 분할)

  • Sung-Wook Hong;Deokgi Mun;Se-Yun Kim;Tong-Seok Han
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.37 no.2
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    • pp.143-149
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    • 2024
  • Segmentation of material phases through image analysis is essential for analyzing the microstructure of materials. Micro-CT images exhibit variations in grayscale values depending on the phases constituting the material. Phase segmentation is generally achieved by comparing the grayscale values in the images. In the case of waste concrete used as a recycled aggregate, it is challenging to distinguish between hydrated cement paste and natural aggregates, as these components exhibit similar grayscale values in micro-CT images. In this study, we propose a method for automatically separating the aggregates in concrete, in micro-CT images. Utilizing the Unet-VGG16 deep-learning network, we introduce a technique for segmenting the 2D aggregate images and stacking them to obtain 3D aggregate images. Image filtering is employed to separate aggregate particles from the selected 3D aggregate images. The performance of aggregate segmentation is validated through accuracy, precision, recall, and F1-score assessments.

A study on the application of waste concrete powder as a material for construction (건설용 재료로써 폐콘크리트 미분말의 활용성 연구)

  • Kim, Yong-Jic;Choi, Yun-Wang;Kim, Sang-Chel;Kim, Young-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.88-94
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    • 2012
  • This study is conducted to utilize waste concrete powder made as a by-product manufacturing high quality recycled aggregate. The blaine fineness of the used waste concrete powder was 928 and $1,360cm^2/g$. As the main characteristic of waste concrete powder, it showed an angular type similar to cement, but hydrated products were attached on the surface of particles. In addition, the size of the particles of waste concrete powder was larger than OPC and in terms of chemical components it had higher $SiO_2$ contents. The viscosity of the paste that mixed waste concrete power decreased by 62% at the most, compared to the paste that only used OPC, and the final set time was delayed about two hours. As composition rates of waste concrete powder increased, the flow value decreased by 30% at the most according to the comparison with mortar that only used OPC, and sorptivity coefficients increased by 70%. The compressive strength of mortar decreased by 73% at the most as composition rates of waste concrete powder increased. According to the test results, it is desirable to use waste concrete powder by combining OPC appropriately(below 15%).

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