• 제목/요약/키워드: hydrated

검색결과 490건 처리시간 0.028초

소석회, 포틀랜드 시멘트, FeCl3·6H2O, NaOH를 이용한 비소 오염토양의 안정화 (Stabilization of As Contaminated Soils using a Combination of Hydrated Lime, Portland Cement, FeCl3·6H2O and NaOH)

  • 문덕현;오다연;이승제;박정훈
    • 한국환경농학회지
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    • 제29권1호
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    • pp.47-53
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    • 2010
  • 본 연구에서 비소로 오염된 토양에 함유된 비소를 안정화시키기 위하여 4종류의 안정화제를 이용 처리하여 다음과 같은 결론을 얻었다. 안정화 처리에 사용된 오염토는 약알칼리성을 띄고 있으며, 입도분포 결과 사토계열이였고 57.5%의 비소가 무정형 및 비결정형 철/알루미늄 수산화물형태로 존재했다. 안정화 실험 결과 소석회/포틀랜드시멘트 혼합 안정화처리가 모든 안정화 처리와 비교 했을 때 현저한 우의를 보였으며 총 함량 30%로 토양오염 우려기준 20 mg/kg('나'지역)을 통과 하였다. 소석회/$FeCl_3{\cdot}6H_2O$ 혼합 이용시 효율적인 비소 저감효과룹 기대할 수 없었으며 소석회/NaOH는 효과적이었으나 소석회/포틀랜드시멘트 보다는 효율성이 제한적 이였다. 소석회/포틀랜드시멘트 혼합 안정화 처리 후 연속추출결과는 처리 전 오염토와 비교했을 때 특이적 흡착과 잔류대의 증가를 보였다. 특히 25wt%+10wt% 처리 시료에서 잔류태의 증가는 2배가 넘어 (16%에서 35.7%) 매우 안정적인 비소 존재 형태를 보여 비소 용출농도 저감에 현저하게 기여한 것으로 판단된다.

석회 종류와 배합비 별 문화재 보수용 석회 모르타르의 초기거동특성과 수축특성 연구 (Initial Behavior and Shrinkage Properties of Lime Mortars for Restoration of Cultural Heritage According to the Mixing Ratio)

  • 남병직;노상균;김은경;안선아;강소영
    • 보존과학회지
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    • 제36권6호
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    • pp.456-474
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    • 2020
  • 본 연구는 문화재 보수에 사용되는 소괴 소석회, 분말 소석회, 시판 소석회를 대상으로 배합비에 따른 석회 모르타르의 유동성, 응결시간 및 수축율을 비교하였다. 유동성 시험 결과, 문화재 조적용 석회 모르타르의 최적 배합수 비율은 소괴 소석회 8~10%, 분말 소석회 10~18%, 시판 소석회 17~40%의 범위로 나타났다. 응결시간과 수축율 분석 결과, 문화재수리표준품셈에 기술된 전돌벽쌓기(습식) 대비 종결시간비는 시판 소석회(0.4) < 분말 소석회(5.6) < 소괴 소석회(5.7)의 순으로, 수축율비는 소괴 소석회(1.1) < 분말 소석회(1.2) < 시판 소석회(3.0)의 순으로 나타났다. 물리·화학적 특성 분석 결과, 소석회의 입자크기가 커질수록 최적 배합수 함량은 낮아졌고 응결시간은 지연되며 수축율은 감소하였다. 이와 같은 결과는 향후 건축문화재의 수리·복원 현장에 사용되는 석회 모르타르의 초기거동과 수축특성을 예측하는데 기여할 것으로 판단된다.

비파괴 충격파 시험을 통한 소석회 첨가 투수성 가열 아스팔트 혼합물의 수분민감성 평가 (Evaluation of Moisture Susceptibility of Porous Hot Mixed Asphalt Mixtures with Hydrated Lime using Non-destructive Impact Test)

  • 김도완;문성호
    • 한국도로학회논문집
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    • 제17권4호
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    • pp.77-87
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    • 2015
  • PURPOSES: It is theoretically well known all over the world, that porous hot mixed asphalt (HMA) with hydrated Lime improves moisture and rutting resistance, and reduces pothole occurrence frequency, as well as the life cycle cost (LCC). METHODS : Addictive in the two different formations of the liquid anti-stripping Agent and powder Hydrated-Lime was applied in this investigation in order to obtain relatively clear results according to their types and conditions. Firstly, the moisture conditions were set, and applied to the porous HMA mixtures with hydrated lime (anti-stripping agent). Next, it was followed by a non-destructive test with the application of three freeze-thaw cycles, which were individually carried out thrice to compare the results of the dynamic moduli. Lastly, the hydrated lime effect related to moisture sensibility to porous HMA has been verified through the analysis of the modulus results regarding the change rate of dynamic modulus per n-cycle. RESULTS: It is clear from this investigation, that the dynamic modulus is inversely proportional to the change in temperature, as the graph representing the rigidity of the thermorheologically simple (TRS) material showed gradual decline of the dynamic modulus with the increase in temperature. CONCLUSIONS: The porous HMA mixture with the anti-stripping agent (hydrated Lime) has been found to be more moisture resistant to freezing and thawing than the normal porous HMA mixture. It is clear that the hydrated lime helps the HMA mixture to improve its fatigue resistance.

편광을 통한 수화한 소행성 연구 (Study of Hydrated Asteroids via Polarimetry: Correlation between Polarimetric Properties and the Degree of Aqueous Alteration of Hydrated asteroids)

  • 김주연
    • 천문학회보
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    • 제46권1호
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    • pp.46.1-46.1
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    • 2021
  • Hydrated asteroids get widespread attention for the evolution of water in the Solar System, especially thanks to the recent successes of the Hayabusa2 and OSIRIS-REx space missions. The target asteroids of these missions are believed to be fragments that have experienced aqueous alteration in their parent bodies [3]. Although hydrated asteroids have been studied well via spectroscopy, focusing on the 0.7 um or the 2.7 um absorption bands [2, 3, 4], polarimetric properties of these asteroids have rarely been investigated. In this study, we conducted a polarimetric observation of 18 C-complex main-belt asteroids with the 1.6-m Pirka telescope at the Nayoro Observatory of Hokkaido University, Japan. We used a polarimetric imaging mode of the Multi-Spectral Imager (MSI) with the standard Rc-band filter (the central wavelength at 0.64 um) [5]. As a result, we found that all of these hydrated asteroids indicate deep negative branches of their polarimetric profiles. Accordingly, the hydrated asteroids have the polarization minima (Pmin), whose values are significantly lower than any other taxonomic types of asteroids (including C-group asteroids). Because Pmin depends on albedo, particle size, and porosity of the surface materials [1], we suspect that hydrated asteroids are distinctive from other asteroids in terms of these physical properties. In this presentation, we introduce our polarimetric observation and findings. We discuss why hydrated asteroids indicate such low Pmin values, comparing Pmin with spectral features at 0.7 um and 2.7 um based on the observation results.

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Mechanical Properties of Hydrated Cement Paste: Development of Structure-property Relationships

  • Ghebrab, Tewodros T.;Soroushian, Parviz
    • International Journal of Concrete Structures and Materials
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    • 제4권1호
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    • pp.37-43
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    • 2010
  • Theoretical models based on modern interpretations of the morphology and interactions of cement hydration products are developed for prediction of the mechanical properties of hydrated cement paste (hcp). The models are based on the emerging nanostructural vision of calcium silicate hydrate (C-S-H) morphology, and account for the intermolecular interactions between nano-scale calcium C-S-H particles. The models also incorporate the effects of capillary porosity and microcracking within hydrated cement paste. The intrinsic modulus of elasticity and tensile strength of hydrated cement paste are determined based on intermolecular interactions between C-S-H nano-particles. Modeling of fracture toughness indicates that frictional pull-out of the micro-scale calcium hydroxide (CH) platelets makes major contributions to the fracture energy of hcp. A tensile strength model was developed for hcp based on the linear elastic fracture mechanics theories. The predicted theoretical models are in reasonable agreements with empirical models developed based on the experimental performance of hcp.

폐광미-소석회 고화체의 동결융해 내구성에 관한 연구 (Durability of the Solidified Mine Tailing-Hydrated Lime Mixture Against Repeated Freezing and Thawing)

  • 민경원;이현철;김태풍
    • 산업기술연구
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    • 제28권B호
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    • pp.65-69
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    • 2008
  • The tailings piled in abandoned mines are well-known potential sources of soil contamination. Hydrated limes were applied as cementing materials to solidify heavy metal contaminated tailings for the purpose of reducing their toxicity and migration rates. The optimum mixing ratio of tailings, hydrated lime, and water was determined through a preliminary test. The mixtures of mine tailings and hydrated lime solidified through pozzolanic reaction were tested for their durability against repeated freezing and thawing processes. After repeated freezing and thawing, the uniaxial compressive strengths of all the solidified mixture specimens decreased in comparison with those before test but still higher than $3.5kgf/cm^2$, the standard recommended for land reclamation solids by EPA(Environmental Protection Agency), which suggested that hydrated lime be a potential material to treat the abandoned mine tailings for the environmental purpose.

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저발열 배합 및 수화발열량차 공법을 이용한 매스콘크리트의 온도제어 및 수화열해석 (Development and Application of Unit Table Form using Euro Form for High-rise Building Construction)

  • 조만기;김민호;장덕배;양성환;한민철;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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    • pp.25-26
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    • 2015
  • In this study, we test the 3 properties low hydrated heat as binder, and also utilized the hydrated heat disparity construction method to decrease the cracks of the mass concrete caused by hydrated heat. The result showed by using the two methods narrowly decreased the cracks. And we ensured that during the mass concrete pouring, the cracks caused by hydrated heat could be reduced by utilizing the new construction method.

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아스팔트 혼합물의 박리방지제의 종류 및 함량에 따른 박리저항성 분석 (Moisture Damage Evaluation of Asphalt Mixtures depending on the Types of Anti-Stripping Agent)

  • 최성호;김원재;르반푹;이현종;황성도
    • 한국도로학회논문집
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    • 제16권4호
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    • pp.45-50
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    • 2014
  • PURPOSES : The objective of this study is to analyze the performance of anti-stripping agent depending on its type and content to reduce pothole, an increasing pavement distress due to abnormal climate intensity. METHODS : In the past years, U.S and many countries in Europe use hydrated lime and liquid anti-stripping agent in asphalt mixtures. Hydrated lime or liquid anti-stripping agent is substituted for filler and binder, respectively, to improve the anti-stripping property of asphalt mixtures. To investigate this, indirect tensile strength test was performed and TSR values were compared for different content of hydrated lime and types of liquid anti-stripping agent in asphalt mixture. RESULTS : Test results indicate that hydrated lime remarkably increased the asphalt mixture performance on anti-stripping denoted by the increased in TSR values from 55% to 100%. Liquid anti-stripping agent also increased the value of TSR but not significant. In addition, depending on the types of aggregate, TSR values and effect of liquid anti-stripping were different. CONCLUSIONS : Using anti-stripping agents improve the anti-stripping property of asphalt mixture especially hydrated lime; however, more experiments should be conducted to improve the reliability about the effect of liquid anti-stripping agent.

Determination of the Proton Transfer Energies of Glycine and Alanine and the Influence of Water Molecules

  • 권오영;김수연;노경태
    • Bulletin of the Korean Chemical Society
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    • 제16권5호
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    • pp.410-416
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    • 1995
  • The proton transfer energies of gas phase glycine and alanine and those of hydrated glycine and alanine were calculated both with Hartree-Fock and $M{\Phi}ller-Plesset$ ab initio molecular orbital (MO) calculations with 6-31G** basis set. The transition states of the proton transfer of gas phase glycine was also investigated. For zwitterions, both for glycine and alanine, the water bound to -NH3+ site stabilize the complex more compared with the water bound to -CO2-. The proton transfer energy, ΔEpt, of glycine, alanine, mono-hydrated glycine, mono-hydrated alanine, di-hydrated glycine and di-hydrated alanine were obtained as 30.78 (MP2: 22.57), 31.43, 23.99 (MP2: 17.00), 24.98, 22.87, and 25.63 kcal/mol, respectively. The activation energy for proton transfer from neutral (Nt) glycine to zwitterion (Zw) glycine, Ea, was obtained as 16.13 kcal/mol and that for reverse process, Ear, was obtained as 0.85 kcal/mol. Since the transition state of the proton transfer of gas phase glycine locate near the glycine zwitterion on the potential energy surface and the shape of the potential well of the zwitterion is shallow, the zwitterion easily changed to neutral glycine through the proton transfer.

Improved controllability of a fully dehydrated Selemion actuator

  • Tamagawa, Hirohisa;Nogata, Fumio
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2004년도 ICCAS
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    • pp.96-100
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    • 2004
  • Ion exchange polymer membrane in the dehydrated state was found to exhibit bending upon a small applied voltage, although the investigations on the hydrated ion exchange polymer membrane bending behavior have been performed quite intensively for more than a decade for the purpose of producing a practical polymer actuator. Our investigation on the dehydrated ion exchange polymer membrane has revealed that its bending direction is perfectly controllable by the polarity control of applied voltage and the degree of its bending curvature is also almost completely determined by the control of duration time of voltage application on it, while the hydrated ion exchange polymer membranes lack of such properties. Furthermore the longevity of dehydrated ion exchange polymer membrane sustaining such a highly controllable properties has been found quite longer than that of the hydrated ion exchange polymer membrane.

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