• Journal of the Korea Concrete Institute
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• v.23 no.2
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• pp.225-233
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• 2011

The volume change in concrete takes place with changes in temperature and water content immediately after concrete casting. In the early age stage, the thermal and drying shrinkages can cause cracks that are very crucial to the durability of concrete. It was reported that when the cement with lightly-burnt MgO powder was used, the shrinkage of concrete can be reduced. This study investigates fundamental properties of cement composites with lightly burnt MgO powder by performing various experiments. The stability test results verified that MgO powder in cement composites does not cause any abnormal expansion. Also, the hydrate product analysis results obtained from MgO cement paste showed that MgO powder reduces the shrinkage at the longterm ages. In addition, the cement composites containing the proper amount of MgO powder could improve compressive strength. Finally, the shrinkage reduction from using MgO powder can be optimized by increasing MgO replacement level and curing temperature.

• Polymer(Korea)
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• v.37 no.3
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• pp.362-372
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• 2013

During extruder processing to manufacture cellulose fiber and film using cellulose-NMMO pre-dope produced by a new method, it seems to occur the changes of molecular weight and ${\alpha}$-cellulose content of cellulose upon thermal and mechanical degradation. In an extruder making cellulose solutions from the pre-dope obtained by high-speed mixer, the changes of cellulose molecular weight and ${\alpha}$-cellulose content resulted with the variations of processing temperature, concentration of cellulose, and residence time. The molecular weight and ${\alpha}$-cellulose content of cellulose decreased with decreasing cellulose concentration and increasing processing temperature. At 15% concentration and short residence time region, the change of ${\alpha}$-cellulose content was so high due to high-shear with an increase in temperature. From these processing conditions, the variations of ${\alpha}$-cellulose content and molecular weight showed different behaviors, and these processing conditions for making cellulose solution were found to be important factors.

• The Korean Journal of Physiology
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• v.17 no.1
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• pp.29-35
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• 1983

The most popular way to get the animal to be co-operative for the animal experimentation is by using some kinds of general anesthetic agents. One of the most important point to take care of is, however, whether the agent(s) to be used is hinder the experimentation itself. There have been many contradictory reports of the general anesthetic agents on the renal function. Moreover, little information on the changes of the renal function by anesthesia has been available. We have done experiments to clarify and compare the effects of anesthesia induced by several general anesthetic agents on renal function in unanesthetized rabbits. Nembutal anesthesia(30 mg/kg, iv.) caused a decrease in free-water clearance, and increase in sodium and chloride excretion without significance. Thiopental anesthesia$(20{\sim}30\;mg/kg,\;iv.)$ suppressed all renal parameters tested. Chloralose(50 mg/kg, iv.) and chloral hydrate(75 mg/kg, iv.) did not change renal functions except for glomerular filtration rate, which parameter was suppressed only for a short period just after agent administration. Urethane(1 g/kg), administered by the route of either subcutaneously or intraperitoneally, suppressed renal functions lasted for the duration of experimental anesthesia. The above data suggest that it is very important to chose an appropriate anesthetic agents for a given experiment, especially experiment involved with renal function, and to interprete the data obtained from the anesthetized animal model for the expected results.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.127-134
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• 2021

A hydrophobic emulsion consisting of PMHS and PVA was mixed into a cement mortar to observe changes in cement hydrate and microstructure, and to experimentally evaluate compressive strength and flexural strength. The hydrophobic emulsion was added with metakaolin and PVA fibers, and the stirring speed and sequence were adjusted to prepare a shell-concept hydrophobic emulsion. It was then mixed when mixing mortar to enhance filling of the internal pores and change of the hydrates. It was observed that the mortar mixed with a hydrophobic emulsion was filled with micropores and a coating film was formed on the surface of the hydrates by the emulsion. It was analyzed that the total pore area and porosity of the mortar mixed with the emulsion decreased from 30% to 60% compared to OPC, excluding the 50MK variable, which was extremely reduced and the median pore diameter decreased in some variables. It was also found that the compressive strength of the mortar mixed with emulsion 1% was increased up to 20%, but the strength of the mortar specimen mixed with 2% decreased to 50%.

• Journal of Korean Society on Water Environment
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• v.27 no.1
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• pp.110-114
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• 2011

In this paper, in order to eliminate Limnoperna fortunei inhabiting the water conduction pipeline, prechlorination at the intake station was employed to improve the degradation of water quality due to the high pH of raw water taken at the downstream of Paldang Dam, algal growth, etc.. With the prechlorination concentration of 1.0mg/L at the intake station, the pH in the water well at the treatment plant decreased by 0.4, and with 1.5mg/L, by 0.6. Also, it eliminated Chlorophyll-a by about 95%, and the population of algae by about 49%. Such disinfection by-products (DBPs) as Trihalomathanes (THMs), Haloacetic Acids (HAAs), and Chloral Hydrate (CH) were under the quality standard for potable water, showing no change by the prechlorination, while raising the prechlorination rate from 1.0 up to 1.5mg/L, the DBPs in the water well increased by 1.5 to 3.1 times. As a consequence of testing Kyungan Stream, a branch stream flowing into Lake Paldang, the prechlorination (0.57mg/L, 1.14mg/L, 1.71mg/L) had no effect of eliminating the taste and odor compounds and total organic carbon (TOC) which is the DBPs precursor. As for the efficiency of Geosmin elimination by the rates of prechlorination and powder activated carbonation (PAC), it was found that the higher the concentration of PAC was (30ppm>20ppm>10ppm), the higher the efficiency was; the higher the rate of prechlorination was, the lower the efficiency by PAC was. Therefore, when taste and odor occur from raw water, suspending prechlorination at the intake or lowering the rate was proved to be more effective in eliminating the taste and odor compounds by PAC.

• Journal of Powder Materials
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• v.29 no.3
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• pp.247-251
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• 2022

This study demonstrates the effect of the compaction pressure on the microstructure and properties of pressureless-sintered W bodies. W powders are synthesized by ultrasonic spray pyrolysis and hydrogen reduction using ammonium metatungstate hydrate as a precursor. Microstructural investigation reveals that a spherical powder in the form of agglomerated nanosized W particles is successfully synthesized. The W powder synthesized by ultrasonic spray pyrolysis exhibits a relative density of approximately 94% regardless of the compaction pressure, whereas the commercial powder exhibits a relative density of 64% under the same sintering conditions. This change in the relative density of the sintered compact can be explained by the difference in the sizes of the raw powder and the densities of the compacted green body. The grain size increases as the compaction pressure increases, and the sintered compact uniaxially pressed to 50 MPa and then isostatically pressed to 300 MPa exhibits a size of 0.71 m. The Vickers hardness of the sintered W exhibits a high value of 4.7 GPa, mainly due to grain refinement.

• Geomechanics and Engineering
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• v.36 no.6
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• pp.589-599
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• 2024

Dispersion occurs when clay soil disperses under specific conditions and is rapidly washed away. While there are numerous methods for rectifying it, they are neither cost nor time-effective. The current study used metakaolin and zeolite to improve heavily dispersive clay soil either separately or in combination at 0%, 2%, 4%, 6%, and 8% of the soil weight. After 7 days of curing, the samples were tested to determine the extent of change in the dispersion potential, as well as the improvement of the geotechnical properties of the soil. The results indicated that the addition of 2% zeolite with 6% to 8% metakaolin decreased the dispersion potential considerably. Double hydrometry test findings revealed that the dispersion potential decreased by almost 70% and entered the non-dispersive group; the crumb test also revealed this. Atterberg limits testing indicated a decrease in the plasticity index which reduced the flexibility of the samples. The greatest decrease in PI (67.5%) was achieved with the addition of 8% zeolite plus 8% metakaolin to the soil. The results of density tests revealed that a decrease in the optimal moisture content increased the maximum dry density of soil. This increase in density was a response to the high reactivity of metakaolin with calcium hydroxide and the formation of calcium hydroxide hydrate gel. This eventually caused an increase in the unconfined compressive strength, the greatest increase in strength of about 1.8-fold was observed with a combination of 2% zeolite and 6% metakaolin compared to the unmodified sample.

• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.613-621
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• 2007

Due to the increasing significance of durability, much researches on carbonation, one of the major deterioration phenomena are carried out. However, conventional researches based on fully hardened concrete are focused on prediction of carbonation depth and they sometimes cause errors. In contrast with steel members, behaviors in early-aged concrete such as porosity and hydrates (calcium hydroxide) are very important and may be changed under carbonation process. Because transportation of deteriorating factors is mainly dependent on porosity and saturation, it is desirable to consider these changes in behaviors in early-aged concrete under carbonation for reasonable analysis of durability in long term exposure or combined deterioration. As for porosity, unless the decrease in $CO_2$ diffusion due to change in porosity is considered, the results from the prediction is overestimated. The carbonation depth and characteristics of pore water are mainly determined by amount of calcium hydroxide, and bound chloride content in carbonated concrete is also affected. So Analysis based on test for hydration and porosity is recently carried out for evaluation of carbonation characteristics. In this study, changes in porosity and hydrate $(Ca(OH)_2)$ under carbonation process are performed through the tests. Mercury Intrusion Porosimetry (MIP) for changed porosity, Thermogravimetric Analysis (TGA) for amount of $(Ca(OH)_2)$ are carried out respectively and analysis technique for porosity and hydrates under carbonation is developed utilizing modeling for behavior in early-aged concrete such as multi component hydration heat model (MCHHM) and micro pore structure formation model (MPSFM). The results from developed technique is in reasonable agreement with experimental data, respectively and they are evaluated to be used for analysis of chloride behavior in carbonated concrete.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.415-424
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• 2017

The purpose of this study is to investigate the effect of sulfate (${SO_4}^{2-}$) and magnesium ($Mg^{2+}$) ions on sulfate resistance of Alkali-activated materials using Fly ash and Ground granulated blast furnace slag (GGBFS). In this research, 30%, 50% and 100% of GGBFS was replaced by sodium silicate modules ($Ms(SiO_2/Na_2O)$, molar ratio, 1.0, 1.5 and 2.0). In order to investigate the effects of $Mg^{2+}$ and ${SO_4}^{2-}$, compression strength, weight change, lengh expansion of the samples were measured in 10% sodium sulfate ($Na_2SO_4$), 10%, 5% and 2.5% magnesium sulfate ($MgSO_4$), 10% magnesium nitrate ($Mg(NO_3)_2$), 10% [magnesium chloride ($MgCl_2$) + sodium sulfate ($Na_2SO_4$)] and 10% [magnesium nitrate $(Mg(NO_3)_2$ + sodium sulfate ($Na_2SO_4$)] solution, respectively and X-ray diffraction analysis was conducted after each experiment. As a result, when $Mg^{2+}$ and ${SO_4}^{2-}$ coexist, degradation of compressive strength and expansion of the sample were caused by sulfate erosion. It was found that the reaction of $Mg^{2+}$ with Calcium Silicate Hydrate (C-S-H) occurred and $Ca^{2+}$ was produced. Then the Gypsum ($CaSO_4{\cdot}2H_2O$) was formed due to reaction between $Ca^{2+}$ and ${SO_4}^{2-}$, and also Magnesium hydroxide ($Mg(OH)_2$, Brucite) was produced by the reaction between $Mg^{2+}$ and $OH^-$.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.95-102
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• 2012

The serious issue of tall building is to ensure the fire resistance of high strength concrete. Therefore, Solving methods are required to control the explosive spalling. The fire resistant finishing method is installed by applying a fire resistant material as a light-weight material to structural steel and concrete surface. This method can reduce the temperature increase of the reinforcement embedded in structural steel and concrete at high temperature due to the installation thickness control. This study is interested in identifying the effectiveness of light-weight fire protection material compounds including the inorganic admixture such as fly ash, meta-kaolin and light-weight aggregate as the fire resistant finishing materials through the analysis of fire resistance and components properties at high temperature. Also, this paper is concerned with change in microstructure and dehydration of the light-weight fire protection materials at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of SEM and XRD. The study results show that the light-weight fire resistant finishing material composed of fly ash, meta-kaolin and light-weight aggregate has the thermal stability of the slight decrease of compressive strength at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate. Developed light-weight fire protection materials showed good stability in high Temperatures. Thus, the results indicate that it is possible to fireproof panels, fire protection of materials.