• 제목/요약/키워드: hybrid type materials

검색결과 261건 처리시간 0.06초

하이브리드 습식 공정을 통한 PVDF 섬유의 제조 및 특성에 관한 연구 (Characterization of the PVDF Fibers Fabricated by Hybrid Wet Spinning)

  • 정건;김성수
    • Composites Research
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    • 제29권4호
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    • pp.145-150
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    • 2016
  • Polyvinylidene fluoride (PVDF)는 압전성을 나타내는 대표적인 고분자로 1960년대부터 많은 연구가 진행되어 왔다. PVDF는 반결정의 고분자로써 5가지의 결정 구조(${\alpha}$, ${\beta}$, ${\gamma}$, ${\delta}$, 그리고 ${\varepsilon}$형)로 구성되어 있다. ${\alpha}$형과 ${\delta}$형 결정은 전기적으로 반응하지 않는 무극성 결정구조이나 ${\beta}$형, ${\gamma}$형 그리고 ${\varepsilon}$형은 전기적으로 반응하는 극성 결정구조이다. 그 중에서도 ${\beta}$형 결정구조는 트랜스 형 분자 쇄가 평행으로 충진 된 형태로서 PVDF 단위체가 갖는 영구 쌍극자가 모두 한 방향으로 배열되어 있는 구조이기 때문에 자발 분극이 커지게 되고 압전성을 나타내게 된다. 일반적으로 ${\beta}$형 결정구조는 연신을 통한 ${\alpha}$형 결정구조의 변환을 통하여 얻을 수 있고, 연신 후 후처리 공정을 통해 그 양을 증가시킬 수 있다. 습식방사로 제조된 PVDF 섬유는 응고욕에서 극성 용매의 확산 메커니즘에 의해 ${\beta}$형 결정구조가 형성되는 장점을 가지고 있지만 극성 용매가 빠져나감과 동시에 섬유 고화가 진행되기 때문에 용매의 확산 경로가 섬유 내부 기공으로 남게 되는 단점을 가지고 있다. 이 기공은 폴링(Poling) 공정에서 전기장에 의한 분극을 방해하여 그 효과를 감소시키는 역할을 한다. 또한, PVDF 섬유가 압전 특성을 필요로 하는 응용분야에 사용되기 위해서는 섬유 가공 후에 전극이 반드시 부착되어야 하는데 섬유 형태로 제조된 PVDF에 전극을 형성하기는 매우 어렵다. 본 연구에서는 압전성을 갖는 PVDF 섬유를 습식 방사와 건식 방사의 혼합 공정으로 제조하여 기공 문제를 해결하였고, 전극이 섬유 내부에 삽입된 Core/Shell 형태의 PVDF 섬유를 제조하여 까다로운 전극형성 문제를 해결하였다.

반응표면분석법을 이용한 영구자석의 형상 및 특성에 따른 매입형 영구자석 동기기의 최적 설계 (Optimal Design of Interior Permanent Magnet Synchronous Machines Consideration of Magnet BH Characteristic with Different Rotor Type using Response Surface Methodology)

  • 임영훈;장석명
    • 전기학회논문지
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    • 제62권8호
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    • pp.1080-1089
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    • 2013
  • Interior Permanent Magnet Synchronous Machines (IPMSMs) with rare earth magnet are widely used in electric vehicles and hybrid electric vehicles. IPMSMs having high efficiency, high torque, and a wide speed range are employed in propulsion system. And the rotor in an IPMSM is generally made of a rare earth magnet to achieve a large energy product and high torque. This paper discusses issues regarding design and performance of IPMSMs using different factors of BH magnetic characteristic. It is necessary to choose factors of magnetic material according to permanent magnet shape in rotor for high performance. Response Surface Methodology (RSM) is selected to obtain factors of magnetic material according to variety of rotor shapes. The RSM is a collection of mathematical and statistical techniques useful for the analysis of problems in which a response of interest in influenced by several variables and the objective is to optimize response. Therefore, it is necessary to analyze the torque characteristics of an IPMSM having magnet BH hysteresis curve with different rotor shape. Factors of residual flux density (Br) factor and intrinsic coercive force (Hc) are important parameters in RSM for rotor shape. The rotor shapes for IPMSMs having magnet BH characteristic were investigated using the RSM, and three shapes were analyzed in detail using FEA. The results lead to design consequence of IPMSMs in the various rare earth magnet materials.

Study on Electrical Properties of X-ray Sensor Based on CsI:Na-Selenium Film

  • Park Ji-Koon;Kang Sang-Sik;Lee Dong-Gil;Choi Jang-Yong;Kim Jae-Hyung;Nam Sang-Hee
    • Transactions on Electrical and Electronic Materials
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    • 제4권3호
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    • pp.10-14
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    • 2003
  • In this paper, we have introduced the x-ray detector built with a CsI:Na scintillation layer deposited on amorphous selenium. To determine the thickness of the CsI:Na layer, we have estimated the transmission spectra and the absorption of continuous x-rays in diagnostic range by using computer simulation (MCNP 4C). A x-ray detector with 65 ${\mu}m$-CsI:Na/30 ${\mu}m$-Se layer has been fabricated by a thermal evaporation technique. SEM and PL measurements have been performed. The dark current and x-ray sensitivity of the fabricated detector has been compared with that of the conventional a-Se detector with 100 ${\mu}m$ thickness. Experimental results show that both detectors exhibit a similar dark current, which was of a low value below $400 pA/cm^2$ at 10 V/${\mu}m$. However, the CsI:Na-Se detector indicates high x-ray sensitivity, roughly 1.3 times that of a conventional a-Se detector. Furthermore, a CsI:Na-Se detector with an aluminium reflective layer shows a 1.8 times higher x-ray sensitivity than an a-Se detector. The hybrid type detector proposed in this work exhibits a low dark current and high x-ray sensitivity, and, in particular, excellent linearity to the x-ray exposure dose.

Design and Construction of GINZA KABUKIZA

  • Kawamura, Hiroshi;Ishibashi, Yoji;Morofushi, Tsutomu;Saragai, Yasuyuki;Inubushi, Akira;Yasutomi, Ayako;Fuse, Naohiko;Yoshifuku, Manabu;Saitoh, Kouji
    • 국제초고층학회논문집
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    • 제5권3호
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    • pp.233-241
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    • 2016
  • This paper describes the structural solution for the design of a 29-story high-rise tower, which features a large office space above the Kabukiza Theatre. Kabuki is a type of Japanese traditional drama, and Kabukiza is the home building of Kabuki. GINZA KABUKIZA is the fifth generation of the Kabukiza Theatre, the first of which was built in 1889. In order to support 23 stories of office space above the theater - featuring a large void in plan - two 13-meter-deep mega-trusses, spanning 38.4 meters, are installed at the fifth floor of the building. Steelwork is used as a primary material for the structure above-ground, and a hybrid response control system using a buckling-restrained brace and oil damper is adopted in order to achieve a high seismic performance. This paper also describes the erection process of installing hydraulic jacks directly above the mega-truss at column bases, in order to keep the structure above the truss level during construction. The temple architecture of the previous Kabukiza is carefully restored by incorporating contemporary light-weight materials supported by steelwork.

Collapse Vulnerability and Fragility Analysis of Substandard RC Bridges Rehabilitated with Different Repair Jackets Under Post-mainshock Cascading Events

  • Fakharifar, Mostafa;Chen, Genda;Dalvand, Ahmad;Shamsabadi, Anoosh
    • International Journal of Concrete Structures and Materials
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    • 제9권3호
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    • pp.345-367
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    • 2015
  • Past earthquakes have signaled the increased collapse vulnerability of mainshock-damaged bridge piers and urgent need of repair interventions prior to subsequent cascading hazard events, such as aftershocks, triggered by the mainshock (MS). The overarching goal of this study is to quantify the collapse vulnerability of mainshock-damaged substandard RC bridge piers rehabilitated with different repair jackets (FRP, conventional thick steel and hybrid jacket) under aftershock (AS) attacks of various intensities. The efficacy of repair jackets on post-MS resilience of repaired bridges is quantified for a prototype two-span single-column bridge bent with lap-splice deficiency at column-footing interface. Extensive number of incremental dynamic time history analyses on numerical finite element bridge models with deteriorating properties under back-to-back MS-AS sequences were utilized to evaluate the efficacy of different repair jackets on the post-repair behavior of RC bridges subjected to AS attacks. Results indicate the dramatic impact of repair jacket application on post-MS resilience of damaged bridge piers-up to 45.5 % increase of structural collapse capacity-subjected to aftershocks of multiple intensities. Besides, the efficacy of repair jackets is found to be proportionate to the intensity of AS attacks. Moreover, the steel jacket exhibited to be the most vulnerable repair intervention compared to CFRP, irrespective of the seismic sequence (severe MS-severe or moderate AS) or earthquake type (near-fault or far-fault).

Repair bond strength of resin composite to bilayer dental ceramics

  • Ataol, Ayse Seda;Ergun, Gulfem
    • The Journal of Advanced Prosthodontics
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    • 제10권2호
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    • pp.101-112
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    • 2018
  • PURPOSE. The purpose of this study was to investigate the effect of various surface treatments (ST) on the shear bond strength of resin composite to three bilayer dental ceramics made by CAD/CAM and two veneering ceramics. MATERIALS AND METHODS. Three different bilayer dental ceramics and two different veneering ceramics were used (Group A: IPS e.max CAD+IPS e.max Ceram; Group B: IPS e.max ZirCAD+IPS e.max Ceram, Group C: Vita Suprinity+Vita VM11; Group D: IPS e.max Ceram; Group E: Vita VM11). All groups were divided into eight subgroups according to the ST. Then, all test specimens were repaired with a nano hybrid resin composite. Half of the test specimens were subjected to thermocycling procedure and the other half was stored in distilled water at $37^{\circ}C$. Shear bond strength tests for all test specimens were carried out with a universal testing machine. RESULTS. There were statistically significant differences among the tested surface treatments within the all tested fracture types (P<.005). HF etching showed higher bond strength values in Groups A, C, D, and E than the other tested ST. However, bonding durability of all the surface-treated groups were similar after thermocycling (P>.00125). CONCLUSION. This study revealed that HF etching for glass ceramics and sandblasting for zirconia ceramics were adequate for repair of all ceramic restorations. The effect of ceramic type exposed on the fracture area was not significant on the repair bond strength of resin composites to different ceramic types.

자체 감지능 및 작동기용 다기능 하이브리드 나노복합재료의 계면 특성 및 소수성 표면 연구 (Interfacial Evaluation and Hydrophobicity of Multifunctional Hybrid Nanocomposites for Self-sensing and Actuation)

  • 왕작가;공조엘;장정훈;김명수;박종만
    • Composites Research
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    • 제23권2호
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    • pp.24-30
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    • 2010
  • 니켈-나노분말/에폭시 복합재료의 계면 특성과 소수성을 자체-감지능과 작동기 측정을 위해 평가하였다. 경사형 시편을 사용하여 접촉 저항 및 저항도를 측정하였다. 자기장에서 복합재료의 작동성을 세가지 파형들, 즉, 싸인, 삼각, 그리고 사각파를 사용하여 평가하였다. 균일하지 않은 표면에 존재하는 소수성 영역 때문에 Ni-에폭시 나노복합재료의 어떤 부분은 초소수성보다는 다소 낮은 접촉각인 110도를 가졌다. 동적 접촉각은 정적 접촉각과 경향이 상호 일치함을 보였다. 니켈-나노분말의 고유의 금속성질 때문에 자체 감지를 확인하였으며, 또한 전자기장에 작동 반응을 잘 하였다. 니켈-나노분말/에폭시 복합재료의 최대 및 최적의 성능을 얻기 위해서, 레이져 변위 센서를 사용하여, 파형, 주파수, 그리고 전압의 함수로 작동기의 변위를 평가하였다. 니켈-나노분말/에폭시 복합재료의 작동은 적용된 주파수와 전압의 함수로써 증가하였다. 작동된 복합재료들의 연신율은 전압의 증가에 따라 삼각 혹은 사각파보다 싸인파에서 더욱 빨리 증가하였다.

한국산 쑥속(Artemisia L.) 산흰쑥절(sect. Absinthium)의 분류학적 재검토 (A taxonomic review of Artemisia sect. Absinthium in Korea)

  • 박명순;정규영
    • 식물분류학회지
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    • 제43권3호
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    • pp.188-195
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    • 2013
  • 한국산 쑥속(Artemisia L.) 산흰쑥절(sect. Absinthium)의 분류군들을 대상으로 기준표본과 원기재, 생체 및 표본에 근거하여 외부형태학적 형질과 학명을 재검토하였다. 쑥속 산흰쑥절에 포함되는 분류군의 생육지, 생육형, 지하부의 구조, 잎의 형태, 두상화서의 형태는 분류군을 식별하는데 유용한 형질로 관찰되었다. 국내에 분포하는 산흰쑥절은 산흰쑥(A. sieversiana), 비단쑥(A. lagocephala), 애기비쑥(A. fauriei)의 3분류군으로 정리되었으며, 이에 따른 분류군의 형질기재 및 도해를 제시하였다. 특히, 화탁에 털이 있는 애기비쑥은 화탁에 털이 없는 더위지기절(sect. Abrotanum)의 큰비쑥(A. fukudo)과 서해안의 갯벌에 혼생하며, 외부형태적으로 절간의 잡종으로 추정되는 개체들이 분포하였다.

현대 패션에 나타난 디지로그의 특징 (A Study on the Features of Digilog in Contemporary Fashion)

  • 유차향;서승희
    • 패션비즈니스
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    • 제21권5호
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    • pp.61-77
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    • 2017
  • Fashion companies are increasingly becoming aware of the importance of Digilog as a response strategy to an emotional stimulus, in order to win the hearts of consumers, because the Digilog provides a new type of emotional value. The features of Digilog found in modern fashion are characterized as follows: first, the "Fashion Image of Hybrid Nature" expresses nature in a new light or reinterprets existing expressions of nature, by using cutting-edge technology based on the psychological desire to return to, adapt with, and harmonize with nature. Second, the "Fashion Image of Nostalgia," which exhibits past forms of regressive fashion, is a fashion code that can be understood as a social trend. It has a digital exterior, with retro materials and old perfumes that reflect psychological comfort, as its expressive medium. Third, the "Lifestyle through the Technique of Interaction" is the sharing of information through consumer participation and delivery, or its interaction. Fourth, the "Fashion Design through the Technique of Customizing" allows consumers to actively participate in the design process. It reflects the consumer's desire to personally design fashion products. Fifth, the "Emotion Sharing through the Technique of Storytelling," which focuses on intangible values, is based on the sentiment of communication between the consumer and the brand, thereby satisfying the inner values as well as the aesthetic demands of consumers. This study confirmed that digital fashion, which uses digital technology based on analog sentiments, has opened up a new environment for fashion culture and has also widened the boundaries of fashion.

Hybrid complementary circuits based on organic/inorganic flexible thin film transistors with PVP/Al2O3 gate dielectrics

  • Kim, D.I.;Seol, Y.G.;Lee, N.E.;Woo, C.H.;Ahn, C.H.;Ch, H.K.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.479-479
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    • 2011
  • Flexible inverters based on complementary thin-film transistor (CTFTs) are important because they have low power consumption and other advantages over single type TFT inverters. In addition, integrated CTFTs in flexible electronic circuits on low-cost, large area and mechanically flexible substrates have potentials in various applications such as radio-frequency identification tags (RFIDs), sensors, and backplanes for flexible displays. In this work, we introduce flexible complementary inverters using pentacene and amorphous indium gallium zinc oxide (IGZO) for the p-channel and n-channel, respectively. The CTFTs were fabricated on polyimide (PI) substrate. Firstly, a thin poly-4-vinyl phenol (PVP) layer was spin coated on PI substrate to make a smooth surface with rms surface roughness of 0.3 nm, which was required to grow high quality IGZO layers. Then, Ni gate electrode was deposited on the PVP layer by e-beam evaporator. 400-nm-thick PVP and 20-nm-thick ALD Al2O3 dielectric was deposited in sequence as a double gate dielectric layer for high flexibility and low leakage current. Then, IGZO and pentacene semiconductor layers were deposited by rf sputter and thermal evaporator, respectively, using shadow masks. Finally, Al and Au source/drain electrodes of 70 nm were respectively deposited on each semiconductor layer using shadow masks by thermal evaporator. Basic electrical characteristics of individual transistors and the whole CTFTs were measured by a semiconductor parameter analyzer (HP4145B, Agilent Technologies) at room temperature in the dark. Performance of those devices then was measured under static and dynamic mechanical deformation. Effects of cyclic bending were also examined. The voltage transfer characteristics (Vout- Vin) and voltage gain (-dVout/dVin) of flexible inverter circuit were analyzed and the effects of mechanical bending will be discussed in detail.

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