• 제목/요약/키워드: hybrid type materials

검색결과 261건 처리시간 0.032초

CdSe Nanocrystal Quantum Dots Based Hybrid Heterojunction Solar Cell

  • Jeong, So-Myung;Eom, S.;Park, H.;Lee, Soo-Hyoung;Han, Chang-Soo;Jeong, So-Hee
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.93-93
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    • 2010
  • Semiconductor nanocrystal quantum dots (NQDs) have recently attracted considerable interest for use in photovoltaics. Band gaps of NQDs can be tuned over a considerable range by varying the particle size thereby allowing enhance absorption of solar spectrum. NQDs, synthesized using colloidal routes, are solution processable and promise for a large-area fabrication. Recent advancements in multiple-exciton generation in NQD solutions have afforded possible efficiency improvements. Various architectures have attempted to utilize the NQDs in photovoltaics, such as NQD-sensitized solar cell, NQD-bulk-heterojuction solar cell and etc. Here we have fabricated CdSe NQDs with the band gap of 1.8 eV to 2.1 eV on thin-layers of p-type organic crystallites (1.61 eV) to realize a donor-acceptor type heterojuction solar cell. Simple structure as it was, we could control the interface of electrode-p-layer, and n-p-layer and monitor the following efficiency changes. Specifically, surface molecules adsorbed on the NQDs were critical to enhance the carrier transfer among the n-layer where we could verify by measuring the photo-response from the NQD layers only. Further modifying the annealing temperature after the deposition of NQDs on p-layers allowed higher conversion efficiencies in the device.

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리튬이차전지용 양극재 개발 동향 (The Research and Development Trend of Cathode Materials in Lithium Ion Battery)

  • 박홍규
    • 전기화학회지
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    • 제11권3호
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    • pp.197-210
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    • 2008
  • 리튬이차전지용 양극재는 전지 성능발전과 더불어 다양하게 발전되어 왔다. 처음으로 채용된 $LiCoO_2$는 초기의 부족한 성능을 도핑이나 표면개질이라는 기술을 채용하여 지속적인 발전을 거듭하면서 최근 4.3V에 가까운 충전전압에서도 적용 가능하게 되었다. 한편으로 응용기기가 복잡해지면서 요구되는 특성도 한층 강화되었다. 높은 작동전압 뿐만 아니라 고용량이 요구되면서 새로운 재료에 대한 연구개발이 시작되었고, 그 중에서도 ${LiNi}_{1-x}{M_xO_2}$, $Li[Ni_{x}Mn_{y}Co_{z}]O_{2}$, $Li[{Ni}_{1/2}{Mn}_{1/2}]O_{2}$등 다양한 재료들이 개발되기에 이르렀다. 최근에는 고유가에 따라 전기자동차용 개발이활발해지면서 고안전성의 새로운 재료가 필요하게 되었고, 이러한 요구에 수렴하여 ${LiMn_2}{O_4}$, $LiFePO_4$와 같은 안전성이 매우 우수한 재료가 개발되었다. 향 후 양극재 부분은 이외에도 다양한 상들이 고용량과 동시에 안전성이 뛰어난 고용체를 이루고 있는 복합체 양극재를 비롯하여 다양한 재료들이 개발될 것으로 여겨진다.

Carrier Transport of Quantum Dot LED with Low-Work Function PEIE Polymer

  • Lee, Kyu Seung;Son, Dong Ick;Son, Suyeon;Shin, Dong Heon;Bae, Sukang;Choi, Won Kook
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.432.2-432.2
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    • 2014
  • Recently, colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been extensively studied and developed for the future of optoelectronic applications. In the work, we fabricate an inverted CdSe/ZnS quantum dot (QD) based light-emitting diodes (QDLED)[1]. In order to reduce work function of indium tin oxide (ITO) electrode for inverted structure, a very thin (<10 nm) polyethylenimine ethoxylated (PEIE) is used as surface modifier[2] instead of conventional metal oxide electron injection layer. The PEIE layer substantially reduces the work function of ITO electrodes which is estimated to be 3.08 eV by ultraviolet photoemission spectroscopy (UPS). From transmission electron microscopy (TEM) study, CdSe/ZnS QDs are uniformly distributed and formed by a monolayer on PEIE layer. In this inverted QD LED, two kinds of hybrid organic materials, [poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo)(F8BT) + poly(N,N'-bis (4-butylphenyl)-N,N'-bis(phenyl)benzidine (poly-TPD)] and [4,4'-N,N'-dicarbazole-biphenyl (CBP) + poly-TPD], were adopted as hole transport layer having high highest occupied molecular orbital (HOMO) level for improving hole transport ability. At a low-operating voltage of 8 V, the device emits orange and red spectral radiation with high brightness up to 2450 and 1420 cd/m2, and luminance efficacy of 1.4 cd/A and 0.89 cd/A, respectively, at 7 V applied bias. Also, the carrier transport mechanisms for the QD LEDs are described by using several models to fit the experimental I-V data.

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자동차 부품용 무도장 메탈릭 플라스틱 소재 개발 (Development of Paint-free Metallic Plastic Material for Automotive Parts)

  • 최민진;조정민;최영호;최민호;이춘수;성한기;이경실;박기훈;황세종
    • Korean Chemical Engineering Research
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    • 제60권2호
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    • pp.295-299
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    • 2022
  • 본 논문에서는 범퍼 스키드 플레이트 및 아웃사이드미러 하우징 부품에 적용되는 polypropylene (PP)와 acrylonitrile styrene acrylate (ASA) 소재를 활용하여 무도장 메탈릭 소재 구현에 대해 연구하였다. 금속 효과를 극대화하기 위해 알루미늄 입자의 종류, 크기, 함량을 최적화하였고 웰드 라인을 은폐하기 위해 종횡비가 상이한 하이브리드 알루미늄 입자를 사용하였다. 또한 부품 표면에 발생되는 플로우 마크를 개선하기 위해 유동성을 제어하였으며 사출 해석을 수행하였다.

CO 검지용 후막형 ZnO와 $SnO_2$ 가스센서의 비교 (A comparison between thick-film ZnO and $SnO_2$ gas sensors for CO gas detection)

  • 김봉희;이승환;강희복;성영권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1991년도 하계학술대회 논문집
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    • pp.209-212
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    • 1991
  • Recently, oxide semiconductor gas sensors consisted of n-type semiconductor materials such as $SnO_2$, ZnO and $Fe_2O_3$ have been widely used to detect reducing gases. The advantage of thick-film technology include the possibility of mass-production and automation, that of integrating the sensing element in a hybrid circuit and that of fuctional trimming of the sensor and/or the circuit. which would enable really interchangeable transducers to be prepared. In this paper, we made ZnO and $SnO_2$ gas sensors and investigated the sensitivity to CO gas. Therefore, we compared a ZnO gas sensor with a $SnO_2$ gas sensor.

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The Influence of Resin Mixture Ratio for the Use of Prepreg on the Fatigue Behavior Properties in FRMLs

  • Song, Sam-Hong;Kim, Cheol-Woong
    • International Journal of Precision Engineering and Manufacturing
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    • 제1권1호
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    • pp.33-41
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    • 2000
  • Fiber reinforced metal laminates(FRMLs) were new type of hybrid materials. FRMLs consist of high strength metals(Al 5052-H34) and laminated fiber with structural adhesive bond. The effect of resin mixture ratios on the fatigue crack propagation behavior and mechanical properties of aramid fiber reinforced aluminum composites was investigated. The epoxy, diglycidylether of bisphenol A(DGEBA), was cured with methylene dianiline(MDA) with or without an accelerator(K-54). Eight kinds of resin mixture ratio were used for the experiment ; five kinds of FRMLs(1)(mixture of epoxy and curing agent) and three kinds of FRMLs(2)mixture of epoxy, curing agent and accelerator). The characteristic of fatigue crack propagation behavior and mechanical properties FRMLs(2) shows more effecting than that of FRMLs(1).

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Generation of Si-O-C Bond without Si-$CH_3$ Bond in Hybrid Type SiOC Film

  • Oh, Teresa
    • 반도체디스플레이기술학회지
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    • 제7권3호
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    • pp.1-4
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    • 2008
  • The chemical shift of SiOC film was observed according to the flow rate ratio. SiOC film had the broad main band of $880\sim1190cm^{-1}$ and the sharp Si-$CH_3$ bond at $1252cm^{-1}$, and the peak position of the main bond in the infrared spectra moved to high frequency according to the increasing of an BTMSM flow rate. So the increment of the alkyl group induced the C-H bond condensation in the film, and shows the blueshift in the infrared spectra. In the case of P5000 system of Applied Materials Corporation, the strong bond of Si-CH3 bond in precursor does not enough to dissociated and ionized, because low plasma energy due to the capactive coupled CVD. Therefore, there was the sharp peak of Si-$CH_3$ bond at $1252cm^{-1}$.

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새만금 방조제 내측사면의 식생환경 조사 (A Study for the Environment of Vegetation to the Inside Slope of Sea Dike)

  • 유전용;강병윤;김현태;최경영;양영철;권태영
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2003년도 학술발표논문집
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    • pp.315-318
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    • 2003
  • A study was performed to examine the soil environment, vegetation type to the inside slope of sea dike. The soil pH was about 8.5, electric conductivity was $4.59dSm^{-1}$, soil strength was 12.1mm, organic matter was 0.21%. The vascular plants of the inside slope of sea dike were consisted of 101 taxa such as 26 families, 80 genera, 93 species, 8 varieties, 1 hybrid. The life cycle of the plants was annual 38.6%, biennial 14.8%, perennial 46.5%. As it compared with consistency ratio in the flora of korea, the distribution of annual, biennial appeared highly. From this examine, it appears that the environment need soil improvement using water holding materials and organic supplements.

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ICT 기반 공작기계 전망 (ICT Based Prospects of Machine Tool)

  • 박홍석;송준엽
    • 대한기계학회논문집 C: 기술과 교육
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    • 제5권1호
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    • pp.63-67
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    • 2017
  • 한국 기계공업에서 공작기계는 예나 지금이나 기계기술발전을 견인하고 있다는 사실을 누구도 부인하지 못한다. 이에 따라 항상 첨단기술을 응용하여 새롭게 변신 하에 왔다. 본 논문은 공작기계의 발전 과정을 소개한 ICT 기술이 어떻게 적용되었는지 기술한다. 이를 위한 어떤 요소기술이 요구되는지를 보여준다. 미래 비전 또한 제시되었다.

TTX 구동차 설계안의 충돌압괴특성 분석 (Crush Analysis of a TTX M-Car Design)

  • 정현승;권태수;구정서;조태민
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2004년도 추계학술대회 논문집
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    • pp.616-621
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    • 2004
  • In this paper, the crush characteristics of a tilting train express (TTX) M-car design are evaluated with a head-on collision scenario. Its body shell is divided into three parts - front end, middle section, and rear end. For each part, crush-force relation is evaluated numerically through 3-dimensional shell element analysis with LS-DYNA. TTX's embody structure is a hybrid type structure made of steel and composite materials. Composite sandwich panels are modeled as layered shells whose layers have different material properties. And a damage material model is used to consider the effect of stiffness degradation during deformation. The crush characteristics obtained from these calculations will be used as material modeling data of full-rake collision analyses.

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