• Title/Summary/Keyword: hybrid green composites

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Mechanical Properties of Cellulose-filled Epoxy Hybrid Composites Reinforced with Alkali-treated Hemp Fiber (염기 처리 대마 섬유로 강화된 셀룰로오스 충전 에폭시 하이브리드 복합재의 기계적 물성)

  • Anand, P.;Anbumalar, V.
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.46-55
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    • 2015
  • There is a limit for deforestation in order to keep the environmental cycle undisturbed. The heart of the paper is to replace the wood to a maximum extent to obtain a sustainable environment. This research aims at new natural composites in which treated hemp fiber used as reinforcement, synthetic cellulose used as particulate to improve the adhesion between matrix - fiber interface and Epoxy LY556 acted as matrix fabricated by hand layup technique. The density, water absorption, tensile properties, impact strength, hardness, flexural properties and compressive properties have been evaluated under ASTM standards and compare the results with existing materials such as wood, aluminium, etc., The composite hemp fiber reinforced polymer (HFRP) could be exploited as an effective replacement for wood and it would be suitable for automotive applications by comparing results.

Novel green composite material manufactured by extrusion process from recycled polypropylene matrix reinforced with eucalyptus fibres and granite powder

  • Romulo Maziero;Washington M. Cavalcanti;Bruno D. Castro;Claudia V. Campo, Rubio;Luciano M.G. Vieira;Tulio H. Panzera;Juan C. Campos Rubio
    • Advances in materials Research
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    • v.12 no.2
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    • pp.119-131
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    • 2023
  • The development of sustainable composites materials, from recycled polymeric materials and waste from the wood industry and stone processing, allows reducing the volume of these by-products, minimizing impacts on health and the environment. Nowadays, Polypropylene (PP) is the most recycled polymer in industry, while the furniture industry has increasingly used timber felled from sustainable forest plantations as a eucalypt. The powder tailing from the ornamental stone extraction and processing industry is commonly disposed of in the environment without previous treatment. Thus, the technological option for the development of composite materials presents itself as a sustainable alternative for processing and manufacturing industries, enabling the development of new materials with special technical features. The results showed that powder granite particles may be incorporated into the polypropylene matrix associated with short eucalyptus fibres forming green hybrid composites with potential application in structural engineering, such as transport and civil construction industries.

Behaviour of FRP composite columns: Review and analysis of the section forms

  • Rong, Chong;Shi, Qingxuan;Zhao, Hongchao
    • Advances in concrete construction
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    • v.9 no.2
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    • pp.125-137
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    • 2020
  • As confining materials for concrete, steel and fibre-reinforced polymer (FRP) composites have important applications in both the seismic retrofit of existing reinforced concrete columns and in the new construction of composite structures. We present a comprehensive review of the axial stress-strain behaviour of the FRP-confined concrete column. Next, the mechanical performance of the hybrid FRP-confined concrete-steel composite columns are comprehensively reviewed. Furthermore, the results of FRP-confined concrete column experiments and FRP-confined circular concrete-filled steel tube experiments are presented to study the interaction relationship between various material sections. Finally, the combinations of material sections are discussed. Based on these observations, recommendations regarding future research directions for composite columns are also outlined.

Intelligent prediction of engineered cementitious composites with limestone calcined clay cement (LC3-ECC) compressive strength based on novel machine learning techniques

  • Enming Li;Ning Zhang;Bin Xi;Vivian WY Tam;Jiajia Wang;Jian Zhou
    • Computers and Concrete
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    • v.32 no.6
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    • pp.577-594
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    • 2023
  • Engineered cementitious composites with calcined clay limestone cement (LC3-ECC) as a kind of green, low-carbon and high toughness concrete, has recently received significant investigation. However, the complicated relationship between potential influential factors and LC3-ECC compressive strength makes the prediction of LC3-ECC compressive strength difficult. Regarding this, the machine learning-based prediction models for the compressive strength of LC3-ECC concrete is firstly proposed and developed. Models combine three novel meta-heuristic algorithms (golden jackal optimization algorithm, butterfly optimization algorithm and whale optimization algorithm) with support vector regression (SVR) to improve the accuracy of prediction. A new dataset about LC3-ECC compressive strength was integrated based on 156 data from previous studies and used to develop the SVR-based models. Thirteen potential factors affecting the compressive strength of LC3-ECC were comprehensively considered in the model. The results show all hybrid SVR prediction models can reach the Coefficient of determination (R2) above 0.95 for the testing set and 0.97 for the training set. Radar and Taylor plots also show better overall prediction performance of the hybrid SVR models than several traditional machine learning techniques, which confirms the superiority of the three proposed methods. The successful development of this predictive model can provide scientific guidance for LC3-ECC materials and further apply to such low-carbon, sustainable cement-based materials.

Synthesis and Characterization of Silica/Polystyrene Composite Nanoparticles by in situ Miniemulsion Polymerization (In situ 미니에멀젼중합에 의한 실리카/폴리스타이렌 복합체 나노입자의 합성과 특성)

  • Patole, Archana S.;Patole, S.P.;Song, Mi-Hyang;Yoon, Joo-Young;Kim, Jin-Hwan;Kim, Tae-Ho
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.34-40
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    • 2009
  • New coupling agent or surface modified agent (9-decenoic acid) was used to enhance the compatibility between silica and polystyrene in silica/polystyrene hybrid nanocomposite, synthesized by in situ miniemulsion polymerization. Composites contain well dispersed nanosize silica particles. Related tests and analyses confirmed the success of synthesis. Functionalization of silica by 9-decenoic acid and silica on the polystyrene was confirmed by FTIR. TGA showed presence and amount of silica in final latex. The glass transition temperature of the hybrid nanocomposite was increased with the silica amount. SEM and TEM analysis showed the spherical morphology of PS and composite with an average diameter of 55 nm. The presence of silica within composite was confirmed by EDS attached to the existing TEM.

Synthesis and Characterization of Mica Coated with Zinc Oxide Nanoparticles (산화 아연 나노 입자로 도포된 마이카의 합성 및 특성 규명)

  • Kil, Hyun Suk;Kim, Young Ho;Park, Minyoung;Rhee, Seog Woo
    • Applied Chemistry for Engineering
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    • v.23 no.3
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    • pp.271-278
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    • 2012
  • In this work, we have prepared the nanocomposite by the reaction of mica and zinc oxide, and investigated the application of nanocomposite to UV protecting creams. Mica treated with 3-aminopropyltrimethoxysilane (APTMS) reacted with 1,4-phenylenediisothiocyanate (PDC) to give -N=C=S functionalized surface, which was further reacted with zinc oxides coated with APTMS to give mica-zinc oxide nanocomposites. The composites were characterized by EA, EDS, TGA, SEM, zeta potential measurement, powder XRD, and DRS UV/Vis analyses. Finally, we measured transmittances of ultraviolet protection creams manufactured by using mica composite covered with zinc oxides in the range of 280~400 nm. The nanocomposites developed in this work might be applicable as inorganic hybrid materials for UV protecting creams.

A Study on Bonding Process for Improvement of Adhesion Properties Between CFRP-Metal Dual Materials (CFRP/금속간 접합력 강화를 위한 접합공정 연구)

  • Kwon, Dong-Jun;Park, Sung-Min;Park, Joung-Man;Kwon, Il-Jun
    • Composites Research
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    • v.30 no.6
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    • pp.416-421
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    • 2017
  • The structural adhesive have been manufactured for improvement of bonding process between CFRP and metal. The optimal condition for bonding process were investigated by evaluating the lap shear strength with amount of adhesive and curing time and the surface treatment of the CFRP. To confirm proper adhesion conditions, the fracture sections between CFRP and metal was observed using reflection microscope. Not only the improvement of the adhesion condition was important, but surface treatment on CFRP was also important. The optimal curing temperature was at $180^{\circ}C$ for 20 minutes. The improvement for adhesive property was confirmed After surface treatment on CFRP. The optimal amount of structural adhesive for bonding between CFRP and metal was $1.5{\times}10^{-3}g/mm^2$. Through the optimization of bonding process, the improvement of mechanical property over 10% is confirmed in comparison with existing adhesive.

Investigation of Compressive Strength and Foaming Characteristics of Acid Anhydride Epoxy Foam by Foaming Agent (발포제에 따른 산무수물계 에폭시 폼의 압축강도 및 포밍특성 분석)

  • Kwon, Dong-Jun;Kim, Jong-Hyun;Park, Sung-Min;Kwon, Il-Jun;Park, Joung-Man
    • Composites Research
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    • v.31 no.4
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    • pp.133-138
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    • 2018
  • Polymer foams were used to fill the void in the structure in addition to flame retardant and heat insulation. Polymer foams such as polyurethane, polyisocyanurate, poly(vinyl chloride), polyethylene terephthalate were used to weight lighting materials. In this study, epoxy foam was used to improve mechanical properties of polymer foam. Acid anhydride type hardener reacts with polyol. Using this phenomenon, if blowing agent was added into epoxy resin using acid anhydride type hardener, formation and compressive properties of epoxy foam was studied. Formation of polymer foam was compared with type of blowing agent and concentration of blowing agent via compressive test. As these results, optimized condition of epoxy foam was found and epoxy foam had better compressive property than other polymer foam.

Novel Bi2S3/TiO2 Heterogeneous Catalyst: Photocatalytic Mechanism for Decolorization of Texbrite Dye and Evaluation of Oxygen Species

  • Zhu, Lei;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.56-62
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    • 2016
  • A heterogeneous $Bi_2S_3/TiO_2$ composite catalyst was synthesized via a green ultrasonic-assisted method and characterized by XRD, SEM, EDX, TEM analysis. The results clearly show that the $TiO_2$ particles were homogenously coated with $Bi_2S_3$ particles, indicating that $Bi_2S_3$ particle agglomeration was effectively inhibited after the introduction of anatase $TiO_2$. The Texbrite BA-L (TBA) degradation rate constant for $Bi_2S_3/TiO_2$ composites reached $8.27{\times}10^{-3}min^{-1}$ under visible light, much higher than the corresponding value of $1.04{\times}10^{-3}min^{-1}$ for $TiO_2$. The quantities of generated hydroxyl radicals can be analyzed by DPCI degradation, which shows that under visible light irradiation, more electron-hole pairs can be generated. Finally, the possible mechanism for the generation of reactive oxygen species under visible-light irradiation was proposed as well. Our result shows the significant potential of $Bi_2S_3$-semiconductor-based $TiO_2$ hybrid materials as catalysts under visible light for the degradation of industry dye effluent substances.