• Title/Summary/Keyword: homogeneous mixture

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Frictional Pressure Drop of a Capillary Tube Flow of Pure HFC Refrigerants and Their Mixtures (HFC 순수냉매 및 혼합냉매의 모세관내에서 마찰에 의한 압력강하)

  • Chang, S.D.;Ro, S.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.4
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    • pp.589-599
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    • 1995
  • The frictional pressure drop of a capillary tube flow is experimentally investigated for pure refrigerants such as R32, R125, and R134a and refrigerant mixtures such as R32/R134a(30/70 by mass percent), R32/R125(60/40), R125/R134a(30/70), and R32/R125/R134a(23/25/52). The binary interaction parameters for the calculation of viscosities of refrigerant mixtures are found based upon the data in the open literature. Several homogeneous flow models predicting the viscosity of two-phase region are compared to select the best model. Cicchitti's equation is known to be the most adequate for the prediction of the viscosity for refrigerant mixtures, which is used in the analysis of adiabatic capillary flows. A model for the prediction of the frictional pressure drop of single and two-phase flow is developed for refrigerant mixtures in this study. This model may be used to design and analyze the performance of a capillary tube in the refrigerating system.

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A Study on the Auto-ignition Combustion Characteristics of CH4-Air Pre-mixtures in Constant Volume Combustion Chamber (정적연소기를 이용한 메탄-공기 예혼합기의 자발화 연소특성에 관한 연구)

  • Lee, Jin-Soo;Lee, Hae-Chul;Cha, Kyung-Ok;Jung, Dong-Soo
    • Journal of ILASS-Korea
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    • v.10 no.2
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    • pp.41-47
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    • 2005
  • Exhaust gas emissions from internal combustion engines are one of the major sources of air pollution. And. it is extremely difficult to increase gasoline engine efficiency and to reduce NOx and PM(particulate matter) simultaneously in diesel combustion. This paper offers some basic concepts to overcome the above problems. To solve the problems, a recommended technique is CAI(controlled auto-ignition) combustion. In this paper. internal EGR(exhaust gas recirculation) effect is suggested to realize CAI combustion. An experimental study was carried out to achieve CAI combustion using homogeneous premixed gas mixture in the constant volume combustion chamber(CVCC). A flame trap was used to simulate internal EGR effect and to increase flame propagation speed in the CVCC. Flame propagation photos and pressure signals were acquired to verify internal EGR effect. Flame trap creates high speed burned gas jet. It achieves higher flame propagation speed due to the effect of geometry and burned gas jet.

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Mixing and Combustion Characteristics of a CNG and Air according to Fuel Supply Conditions in a DI Engine (직분식 엔진에서 연료공급 조건에 따른 CNG와 공기의 혼합 및 연소특성)

  • Kang, Jeong-Ho;Park, Jong-Sang;Yeom, Jeong-Kuk;Chung, Sung-Sik;Ha, Jong-Yul
    • Journal of ILASS-Korea
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    • v.13 no.1
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    • pp.1-8
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    • 2008
  • It was investigated how fuel injection timing - early injection and later injection - in conjunction with throttle open rate effect the fuel-air mixing characteristics, Engine power, combustion stability and emission characteristics on a DI CNG spark Engine and control system that had been modified and designed according to the author's original idea. It was verified that the combustion characteristics were changed according to fuel injection timings and Engine conditions determined by different throttle open rates and rpm. It was found that the combustion characteristics greatly improved at the complete open throttle rate with an early injection timing and at the part throttle rate with a late injection timing. Combustion duration was governed by flame propagation duration in a late injection timing and by an early flame development duration in an early injection timing. As the result, we discovered that combustion duration is shortened, lean limit is improved, air-fuel mixing conditions controlled, and emissions reduced through control of fuel injection timing according to change of the throttle open rate.

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Pepsin Action on the New Synthetic Peptides 1. Pepsin action on benzyloxycarbonyl-glycyl-L-tyrosyl-L-phenylalanyl-glycine and its ethyl ester (새로운 합성 펩티드에 대한 펩신 작용 1. Benzyloxycarbonyl-glycyl-L-tyrosyl-L-phenylalanyl-glycine 과 그의 에틸에스테르에 대한 펩신 작용)

  • Yoon, Joo-Ok;Shin, Hong-Dae
    • Journal of the Korean Chemical Society
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    • v.13 no.3
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    • pp.233-240
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    • 1969
  • The synthesis is described of new pepsin substrates of benzyloxycarbonyl-glycyl-L-tyrosyl-L-phenylalanyl-glycine ethyl ester and benzyloxycarbonyl-glycyl-L-tyrosyl-L-phenylalanyl-glycine for studies on the specificity of pepsin, and thin layer chromatographic examination of the peptides prepared showed the new substrates are homogeneous and also, same examination of the incubation mixtures showed that two synthetic substrates are cleaved by pepsin at the L-tyrosyl-L-phenylalanyl bond and hydrolysis of these substrates by pepsin is achieved without transpeptidation. It is found that synthetic peptides are moderately soluble with the amount of the substrate up to a concentration of 0.7 mM in aqueous sodium citrate buffers (0.04 M) in the pH range 1.8-4.0, thus obviating the necessity for the adding of an organic solvent in the assay mixture. The kinetic parameters for synthetic substrates are tabulated in the following table. The data in the table indicate that the susceptibility of synthetic peptides to peptic hydrolysis are relatively large and the change of the carboxyl-terminal group of synthetic substrate from glycine ethyl ester to glycine causes a small decrease in the susceptibility of the L-tyrosyl-L-phenylalanyl bond.

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Shell Powder Coating on the Surface of Concrete by Geopolymer Cement (지오폴리머 시멘트를 이용한 콘크리트 표면의 패각 분말 코팅)

  • Kim, Gab-Joong;Han, Hyun-Geun;Seo, Dong-Seok;Lee, Jong-Kook
    • Korean Journal of Materials Research
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    • v.20 no.1
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    • pp.1-6
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    • 2010
  • Geopolymer materials are attractive as inorganic binders due to their superior mechanical and eco-friendly properties. In the current study, geopolymer-based cement was prepared using aluminosilicate minerals from fly-ash with KOH as an alkaline-activator and $Na_2SiO_3$ as liquid glass. Then, calcium carbonate powder from a clam shell was mixed with the geopolymer and the mixture was coated on a concrete surface to provide points of attachment for environmental organisms to grow on the geopolymers. We investigated the effect of the shell powder grain size on the microstructure and bonding property of the geopolymers. A homogeneous geopolymer layer coated well on the concrete surface via aluminosilicate bonding, but the adhesiveness of the shell powder on the geopolymer cement was dependent on the grain size of the shell powder. Superior adhesive characteristics were shown in the shell powder of large grain size due to the deep penetration into the geopolymer by their large weight. This kind of coating can be applied to the adhesiveness of eco-materials on the surface of seaside or riverside blocks.

An Investigation of Effects of Fuel Stratification and Cooled EGR on DME HCCI Engine's Operating Ranges by Numerical Analysis (농도성층화와 Cooled EGR이 DME HCCI 엔진의 운전영역에 미치는 영향에 관한 수치해석)

  • Jeong, Dong-Won;Amarbayar, D.;Lim, Ock-Taeck
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.2
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    • pp.129-135
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    • 2010
  • Homogeneous charge compression ignition (HCCI) engines have the potential to provide both diesel-like efficiency and very low emissions of nitrogen oxide (NOx) and particulate matter(PM). However, several technical issues still must be resolved before HCCI can see application. Among these, steep pressure-rise rate which leads to narrow operating range of HCCI engine continues to be a major issue. This work investigates the combination of two methods to mitigate the excessive pressure-rise rates at high power output, namely fuel stratification and Cooled exhaust-gas recirculation (Cooled EGR), after identifying the each effects to pressure-rise rate. When applying the fuel stratification to simulation, total fuelling width of 0.15 at BDC is set as a equivalent ratio difference based on the previous research. In order to simulate the effects of cooled EGR, $CO_2$ mole fraction in pre-mixture is changed ranging from 0 to 30%. DME which has a characteristic of two-stage ignition is used as a fuel.

An Experimental Study on the Combustion and Emission Characteristics of the Early Injection in a Gasoline Direct Injection Engine Using Controlled Auto Ignition Combustion Method (CAI 연소 방법을 이용한 직분식 가솔린 엔진내의 조기 분사시 연소 및 배기 특성에 관한 실험적 연구)

  • Choi Young-Jong;Lee Ki-Hyung;Lee Chang-Hee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.5 s.248
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    • pp.457-464
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    • 2006
  • Controlled auto ignition (CAI) combustion, also known as HCCI (homogeneous charge compression ignition), offers the potential to simultaneously improve fuel economy and reduce emission. CAI-combustion was achieved in a single cylinder gasoline DI engine, with a cylinder running in a CAI mode. Standard components were used the camshafts which had been modified in order to restrict the gas exchange process. The effects of air-fuel ratio, residual EGR rate and injection timing such as early injection and late injection on the attainable CAI combustion region were investigated. The effect that injection timings on factor such as start of combustion, combustion duration and heat release rate was also investigated. From results early injection caused the mixture to ignite earlier and burn more quickly due to the exothermic reaction during the recompression and gave rise to good mixing of the fuel-air.

Effects of Additive and Preheat on the Partially Premixed $CH_4-Air$ Counter Flow Flames Considering Non-gray Gas Radiation

  • Park Won-Hee;Chang Hee-Chul;Kim Tae-Kuk
    • Journal of Mechanical Science and Technology
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    • v.20 no.2
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    • pp.242-250
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    • 2006
  • Detailed structures of the counterflow flames formed for different inlet fluid temperatures and different amount of additives are studied numerically. The detailed chemical reactions are modeled by using the CHEMKIN-II code. The discrete ordinates method and the narrow band based WSGGM with a gray gas regrouping technique (WSGGM-RG) are applied for modeling the radiative transfer through non-homogeneous and non-isothermal combustion gas mixtures generated by the counterflow flames. The results compared with those obtained by using the SNB model show that the WSGGM-RG is very successful in modeling the counterflow flames with non-gray gas mixture. The numerical results also show that the addition of $CO_2\;or\;H_2O$ to the oxidant lowers the peak temperature and the NO concentration in flame. But preheat of fuel or oxidant raises the flame temperature and the NO production rates. $O_2$ enrichment also causes to raise the temperature distribution and the NO production in flame. And it is found that the $O_2$ enrichment and the fuel preheat were the major parameters in affecting the flame width.

Synthesis and Characterization of Rutile TiO2 Powder by the Sulfuric Acid Method (황산법을 이용한 루틸형 TiO2 분말의 제조 및 특성 평가)

  • Choi, Soon Ok;Cho, Jee Hee;Kim, Won Yong;Lim, Sung Hwan
    • Korean Journal of Metals and Materials
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    • v.50 no.7
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    • pp.523-530
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    • 2012
  • We investigated the experimental method that uses the homogeneous precipitation method to prepare mica flakes-coated rutile-type titania pearlescent pigment with urea as a precipitant. $TiO_2$ particles exhibit a high reflection of lights and optical properties with chemical stabilities, so they are appropriate for coating on luminescent pigments (mica). The coating principle of mi ca coated titania with various thicknesses was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and tested by spectrophotometer. Mica with a particle size in the range of $40-60{\mu}m$ was suspended in water, and metal sulphates and urea were added to the mixture, which was heated to boiling. The change in pH was continuously followed. The metal oxide and crystal structure were affected by the conditions of $TiOSO_4$ concentration and reaction time with a sintering temperature the range of $800-1100^{\circ}C$.

Utilization of PTE and LDPE Plastic Waste and Building Material Waste as Bricks

  • Intan, Syarifah Keumala;Santosa, Sandra
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.603-608
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    • 2019
  • Plastic waste is becoming a problem in various countries because of the difficulty of natural decomposition. One type is PET plastic(Polyethylene Terephthalate), which is often used as a bottle for soft drink packaging, and LDPE(Low Density Polyethylene), which is also widely used as a food or beverage packaging material. The use of these two types of plastic continuously, without good recycling, will have a negative impact on the environment. Building material waste is also becoming a serious environmental problem. This study aims to provide a solution to the problem of the above plastic waste and building material waste by making them into a mixture to be used as bricks. Research is carried out by mixing both materials, namely plastic heated at a temperature of $180-220^{\circ}C$ and building material waste that had been crushed and sized to 30-40 mesh with homogeneous stirring. The ratios of PET and LDPE plastic to building material waste are 9 : 1, 8 : 2, 7 : 3, 6 : 4 and 5 : 5. After heating and printing, density, water absorption and compressive strength tests are carried out. Addition of PET and LDPE plastic can increase compressive strength, and reduce water absorption, porosity and density. A maximum compressive strength of 10.5 MPa is obtained at the ratio of 6 : 4.