• Title/Summary/Keyword: hole transport

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Thickness and Angle Dependent Microcavity Properties in Top-Emission Organic Light-Emitting Diodes (상부 발광 유기 발광 소자에서 두께와 시야각에 따른 마이크로 캐비티 특성)

  • Lee, Won-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.1
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    • pp.32-35
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    • 2011
  • Top-emission device has a merit of high aperture ratio and narrow emission spectrum compared to that of bottom-emission one. Emission spectra of top-emission organic light-emitting diodes depending on a layer thickness and view angle were analyzed using a theory of microcavity. Device structure was manufactured to be Al (100 nm)/TPD/$Alq_3$/LiF (0.5 nm)/Al (2 nm)/Ag (30 nm). N,N'-diphenyl-N,N'- di (m-tolyl)-benzidine (TPD) and tris (8-hydroxyquinoline) aluminium (Alq3) were used as a hole-transport layer and emission layer, respectively. And a thickness of TPD and Alq3 layer was varied in a range of 40 nm~70 nm and 60 nm~110 nm, respectively. Angle-dependent emission spectrum out of the device was measured with a device fixed on a rotating plate. Since the top-emission device has a property of microcavity, it was observed that the emission spectrum shift to a longer wavelength region as the organic layer thickness increases, and to a shorter wavelength region as the view angle increases. Layer thickness and view-angle dependent emission spectra of the device were analyzed in terms of microcavity theory. A reflectivity of semitransparent cathode and optical path length were deduced.

Influence of Electrode and Thickness of Organic Layer to the Emission Spectra in Microcavity Organic Light Emitting Diodes (마이크로캐비티 OLED의 전극과 유기물층 두께가 발광 스펙트럼에 미치는 영향)

  • Kim, Chang-Kyo;Han, Ga-Ram;Kim, Il-Yeong;Hong, Chin-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.11
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    • pp.1183-1189
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    • 2012
  • Organic light-emitting diodes (OLEDs) using microcavity effect have attracted great attention because they can reduce the width of emission spectra from organic materials, and enhance brightness from the same material. We demonstrate the simulation results of the radiation properties from top-emitting organic light-emitting diodes (TE-OLEDs) with microcavity structures based on the general electromagnetic theory. Organic materials such as N,N'-di (naphthalene-1-yl)-N,N'-diphenylbenzidine (NPB) as a hole transport layer and tris (8-hydroxyquinoline) ($Alq_3$) as emitting and electron transporting layer are used to form the OLEDs. The organic materials were sandwiched between anode such as Ni or Au and cathode such as Al, Ag, or Al:Ag. The devices were characterized with electroluminescence phenomenon. We confirmed that the simulation results are consistent with experimental results.

GEOMETRICAL EFFECTS ON THERMAL-HYDRAULIC PERFORMANCE OF A MULTIPLE JET IMPINGEMENT COOLING SYSTEM IN A DIVERTOR OF NUCLEAR FUSION REACTOR (핵융합로 디버터 다중충돌제트 냉각시스템의 형상변화가 열수력학적 특성에 미치는 영향)

  • Jung, H.Y.;Kim, K.Y.
    • Journal of computational fluids engineering
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    • v.22 no.1
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    • pp.26-36
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    • 2017
  • A numerical study has been performed to evaluate thermal-hydraulic performance of a finger type cooling module with multiple-jet impingement in a divertor of nuclear fusion reactor. To analyze conjugate heat transfer in both solid and fluid domains, numerical analysis of the flow using three-dimensional Reynolds-averaged Navier-Stokes equations has been performed with shear stress transport turbulence model. The computational domain for the cooling module consisted of a single fluid domain and three solid domains; tile, thimble, and cartridge. The numerical results for the temperature variation on the tile were validated in comparison with experimental data under the same conditions. A parametric study was performed with four geometric parameters, i.e., angles between x-axis and centerlines of hole 1, 2, 3 and 4. The results indicate that the heat transfer rate was increased by 2.7% and 0.7% by the angle ${\theta}_1$ and angle ${\theta}_2$, respectively, and that the pressure drop was decreased by up to 1.8% by the angle ${\theta}_3$.

Electrical Characteristics on the Variation of Deposition Rate in Organic Layer of OLEDS (정공수송층 및 발광층의 증착속도에 따른 OLEDS의 전기적 특성에 관한 연구)

  • Yang, Jae-Hoon;Lee, Young-Hwan;Kim, Weong-Jong;Kim, Keui-Yeul;Yeon, Kyu-Ho;Kim, Tae-Wan;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.275-276
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    • 2005
  • Organic Light Emitting Diodes(OLEDs) are attractive as alternative display components because of their relative merits of being self-emitting, having large intrinsic viewing angle and fast switching speed. But because of their relatively short history of development, much remains to be studied in terms of their basic device physics and design, manufacturing techniques, stability and so on. We invested electrical properties of N,N-diphenyl-N,N bis (3-methyphenyl)-1,1'-biphenyl-4,4'-diamine(TPD) and tris-8-hydroxyquinoline aluminum($Alq_3$) when their thicknesses were changed variedly from 3:7 to 7:3 of their thickness ratios. And we also studied properties of OLEDs depend on their deposition rate between 0.05$\sim$0.2 [nm/s].

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Energy Transfer and Emission Properties of Organic Electroluminescent Device According to Polymer/Dye Mixing Ratio (고분자/저분자 발광재료의 혼합비에 따른 유기 전계발광 소자의 에너지 전달 및 발광특성)

  • Kim, Ju-Seung;Seo, Bu-Wan;Gu, Hal-Bon;Lee, Kyung-Sup;Park, Bok-Kee
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.997-999
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    • 1999
  • We fabricated white light-emitting organic electroluminescent device which have a mixed single emitting layer containing poly(N-vinylcarbazole)[PVK], tris(8-hydroxyquinoline)aluminum[Alq3] and poly(3-hexylthiophene)[P3HT] and investigated the emission properties of it. We expect to obtain a blue light from PVK, green light from Alq3 and red light from P3HT The fabricated device emits white light over 18V with slight orange light. We think that the energy transfer in a mixed layer occurred from PVK to $Alq_3$ and P3HT resulted in decreasing the blue light intensity from PVK. With mixing of N, N'-diphenyl-N, N'-(3-methylphenyl)-[1,1'-biphenyl]-4, 4'-diamine[TPD], hole transport material, to the emitting layer, the luminance intensity of device was increased 50 times than that of the device which not contain TPD. We find that the efficiency of the white light electroluminescent device can be improved by injecting electron more effectively and blue light need to improve the color purity of white light.

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P3HT:PCBM-based on Polymer Photovoltaic Cells with PEDOT:PSS-pentacene as a Hole Conducting Layer

  • Kim, Hyun-Soo;Hwang, Jong-Won;Park, Su-Jin;Chae, Hyun-Hee;Choe, Young-Son
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.313-313
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    • 2010
  • The performance of polymer photovoltaic cells based on blends of poly(3-hexylyhiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) is strongly influenced by blend composition and thickness. Polymer photovoltaic cells based on bulk-heterojunction have been fabricated with a structure of ITO/poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)-pentacene/poly (3-hexylthiophene) (P3HT):phenyl-C61-butyric acid methyl ester (PCBM)/Al. We have prepared PEDOT:PSS by dissolving pentacene in N-methylpyrrolidine (NMP) and mixing with PEDOT:PSS. Pentacene was added a maximum concentration of approximately 5.5mg to the PEDOT:PSS solution and sonicated for 10 min. Active layer (P3HT:PCBM) (1:1) was strongly influenced by PEDOT:PSS-pentacene. We have investigated the performance of photovoltaic device with different concentration of P3HT:PCBM (1:1) 2.0wt%, 2.2wt%, 2.4wt% and 2.6wt%, respectively. The photocurrent and power conversion efficiency (PCE) showed a maximum between 2.0wt% and 2.2wt% concentration of P3HT:PCBM. This implied that both morphology and electron transport properties of the layer influenced the performance of the present photovoltaic cells. As the concentration of P3HT:PCBM blends as an active layer was increased, the power conversion efficiency was decreased. P3HT:PCBM layer and PEDOT:PSS-pentacene layer were characterized by work function, UV-visible absorption, atomic force microscopy (AFM), X-ray diffraction (XRD) and scanning electron microscope (SEM).

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Electrochemical properties of metal salts polymer electrolyte for DSSC (금속염을 이용한 염료감응 태양전지의 고체전해질의 전기화학적 특성)

  • Zhao, Xing Guan;Jin, En Mei;Gu, Hal-Bon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.55.1-55.1
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    • 2011
  • Dye-sensitized solar cell(DSSC) have been considered one of the promising alternatives to conventional solar cells, because of their low cost, easy fabrication and relatively high energy conversion efficiency. However, although the cell offers reasonable efficiency at least 11%, the use of a liquid electrolyte placed technological challenges for achieving the desired durability and operational stability of the cell. In order to prevent or reduce electrolyte leakage considerable efforts have been made, such as p-type semiconductor or organic hole-transport material that better mechanical properties and simple fabrication processes. In this work, we synthesized solid-state electrolyte containing LiI and KI metal salt with starting materials of poly ethylene oxide to substitute liquid electrolyte enhance the ionic conductivity and solar conversion efficiency. Li+ leads to faster diffusion and higher efficiency and K+ leading to higher ionic conductivity. The efficiency of poly ethylene oxide/LiI system electrolyte is 1.47% and poly ethylene oxide/potassium electrolyte is 1.21%. An efficiency of 3.24% is achieved using solid-state electrolyte containing LiI and KI concentrations. The increased solar conversion efficiency is attributed to decreased crystallinity in the polymer that leads to enhanced charge transfer.

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Health hazards occurred in the underground storing places of ginger roots (생강 저장굴에서 발생한 건강 피해)

  • Lim, Hyun-Sul;Kim, Heon;Bae, Geun-Ryang;Kim, Doo-Hie
    • Journal of agricultural medicine and community health
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    • v.23 no.2
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    • pp.251-258
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    • 1998
  • Ginger has been cultivated for thousands of years. It is very popular in the food industry as an additive to ginger ale, candies, pastries and cakes. The root has a strong, sweet scent. It contains protein, fat, carbohydrates, ash, calcium, potassium, vitamin A. thiamine, riboflavin, niacin and ascorbic acid. In korea, farmers keep ginger roots into underground holes from the harvest time to the seedtime. They dig 6 meters under the ground and preserve the cultivated ginger roots. This study was conducted to evaluate the health hazards occurred in the underground storing places of ginger roots. Authors reviewed the accidents occurred in those places, therefore transported by the public emergency system in Seo-cheon city from Jan, 1 1996 to Dec, 31 1997. We could confirm 8 persons on transport records. Among them, 5 persons were due to poisoning, 3 persons were due to injuries. We would like to suggest that poisoning could be induced by hypoxia and injuries occurred from a fall into the underground hole. These should be prevented by the health education for farmers. And further investigations are needed to understand their magnitude and the pathogenic mechanisms.

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Wet-Chemically Prepared NiO Layers as Hole Transport Layer in the Inverted Organic Solar Cell

  • Lim, Dong-Chan;Kim, Young-Tae;Shim, Won-Hyun;Jang, A-Young;Lim, Jae-Hong;Kim, Yang-Do;Jeong, Yong-Soo;Kim, Young-Dok;Lee, Kyu-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.1067-1070
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    • 2011
  • We have demonstrated that solution-based fabrication of NiO films as HTL can be used for the construction of IOSCs. Type of solvent of NiO-solution, and annealing procedure of the active layers were optimized for obtaining a PCE of 3% of IOSC. The photovoltaic performance of NiO-based device is comparable to that of the same type of solar cell using PEDT:PSS instead of NiO. These solution-based processes can be a promising method for a mass production OSCs under ambient condition.

Characteristic of organic electroluminescent devices with 8-hydroxyquinoline Zinc($Znq_2$) as green-emitting material (녹색 발광 재료인 8-hydroxyquinoline Zinc($Znq_2$)를 이용한 유기 발광소자의 특성)

  • 박수길;정승준;정평진;정은실;류부형;박대희;이성구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.193-196
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    • 1999
  • Organic electroluminescent devices have attracted a great deal of attention due to thier potential application to full-color flat-panel displays. The 8-hydroxyquinollne Zinc(Znq$_2$) were synthesized successfully from zinc chloride(ZnCl$_2$) and zinc acetate(Zn(C$_2$H$_3$O$_3$)$_2$) as green omitting material. A double-layer ELD consist of an emitting layer of B-hydroxyquinoline Zinc(Znq$_2$) and a hole-transport layer of tai-phenylene diamine(TPD) derivatives sandwiched between an Aluminium(Al) and Indium-Tin-Oxide(ITO) electrodes omitted green light resulting from Znq$_2$. The electroluminescent devices (ELD) exhibited a maximum luminance of 1000cd/$\textrm{cm}^2$ at a driving voltage of 8V and a driving current density of 0.4mA/$\textrm{cm}^2$.

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