• Title/Summary/Keyword: hole transport

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Improved Efficiency and Lifetime for Organic Light-Emitting Devices Based on Mixed-Hole Transporting Layer (혼합된 정공 수송 층을 이용한 유기발광소자의 효율 및 수명 개선)

  • Seo, Ji-Hyun;Park, Jung-Hyun;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.67-68
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    • 2006
  • Organic light-emitting devices (OLEDs) with the high efficiency and long lifetime are of growing interest in next-generation displays. Among the factors influencing OLEDs properties, one of unstable factor is $Alq_3$ cationic species caused by the excess holes resided in $Alq_3$ layer. Therefore, we suppressed the accumulation of excess holes by using the mixed-hole transporting layer (MHTL) of NPB and CBP in multilayer green OLEDs. The devices with MHTL showed improved characteristics in the luminance efficiency and lifetime. More characteristics and the carrier transport mechanism will be discussed.

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Fabrication of $TiO_2$ Blocking Layers for CuSCN Based Dye-Sensitized Solar Cells by Atomic Layer Deposition Method

  • Baek, Jang-Mi;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.310.2-310.2
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    • 2013
  • For enhancement of dye-sensitized solar cell performance, TiO2 blocking layer has been used to prevent recombination between electron and hole at the conducting oxide and electrolyte interface. In solid state dye-sensitized solar cells, it is necessary to fabricate pin-hole free TiO2 blocking layer. In this work, we deposited the TiO2 blocking layer on conducting oxide by atomic layer deposition and compared the efficiency. To compare the efficiency, we fabricate solid state dye-sensitized solar cell with using CuSCN as hole transport material. We see the efficiency improve with 40nm TiO2 blocking layer and the TiO2 blocking layer morphology was characterized by SEM. Also, we used this blocking layer in TiO2/Sb2S3/ CuSCN solar cell.

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Effect of Microstructure of Quantum Dot Layer on Electroluminescent Properties of Quantum Dot Light Emitting Devices (양자점 층의 미세구조 형상이 양자점 LED 전계 발광 특성에 미치는 효과)

  • Yoon, Sung-Lyong;Jeon, Minhyon;Lee, Jeon-Kook
    • Korean Journal of Materials Research
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    • v.23 no.8
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    • pp.430-434
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    • 2013
  • Quantum dots(QDs) with their tunable luminescence properties are uniquely suited for use as lumophores in light emitting device. We investigate the microstructural effect on the electroluminescence(EL). Here we report the use of inorganic semiconductors as robust charge transport layers, and demonstrate devices with light emission. We chose mechanically smooth and compositionally amorphous films to prevent electrical shorts. We grew semiconducting oxide films with low free-carrier concentrations to minimize quenching of the QD EL. The hole transport layer(HTL) and electron transport layer(ETL) were chosen to have carrier concentrations and energy-band offsets similar to the QDs so that electron and hole injection into the QD layer was balanced. For the ETL and the HTL, we selected a 40-nm-thick $ZnSnO_x$ with a resistivity of $10{\Omega}{\cdot}cm$, which show bright and uniform emission at a 10 V applied bias. Light emitting uniformity was improved by reducing the rpm of QD spin coating.At a QD concentration of 15.0 mg/mL, we observed bright and uniform electroluminescence at a 12 V applied bias. The significant decrease in QD luminescence can be attributed to the non-uniform QD layers. This suggests that we should control the interface between QD layers and charge transport layers to improve the electroluminescence.

Polymer Electrolytes and their Application to Solar Cells and Separation Membranes (촉진수송 및 태양전지용 분리막)

  • 강용수
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.03a
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    • pp.13-35
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    • 2004
  • Metal Complexes in Macromolecules Applications of Polymer Electrolyte Membranes Facilitated Transport in Solid State Roles of Electrolytes in Solar Cells - Electrolytes :ㆍI- and $I_3$-conductor ㆍelectron barrier or hole conductor ㆍelectrochemical redox reaction media ㆍinterfacial contactor for dye, $TiO_2$ and electrode ㆍmechanical separator (omitted)

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A Study on the Correlation between Leak Hole Size, Leak Rate, and the Influence Range for Hydrochloric Acid Transport Vehicles (염산 운송차량의 누출공 크기와 누출률 및 영향범위간 상관관계 연구)

  • Jeon, Byeong-Han;Kim, Hyun-Sub
    • Journal of Environmental Health Sciences
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    • v.47 no.2
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    • pp.175-181
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    • 2021
  • Objectives: The correlation between the size of a leak hole, the volume of the leakage, and the range of influence was investigated for a hydrochloric acid tank-lorry. Methods: For the case of a tank-lorry chemical accident, KORA (Korea Off-site Risk Assessment Supporting Tool) was used to predict the leak rate and the range of influence according to the size of the leak hole. The correlation was studied using R. Results: As a result of analyzing the leak rate change according to the leak hole size in a 35% hydrochloric acid tank-lorry, as the size of the leak hole increased from 1 to 100 mm, the leak rate increased from 0.008 to 83.94 kg/sec, following the power function. As a result of calculating the range of influence under conditions ranging from 1 to 100 mm in size and 10 to 60 minutes of leakage time, it was found that the range spanned from a minimum of 5.4 m to a maximum of 307.9 m. As a result of multiple regression analysis using R, the quadratic function model best explained the correlation between the size of the leak hole, the leak time, and the range of influence with an adjected coefficient of determination of 0.97 and a root mean square error of 22.33. Conclusion: If a correlation database for the size of a leak hole is accumulated for various substances and under various conditions, the amount of leakage and the range of influence can easily be calculated, facilitating field response activities.

A Study on the Film-cooling Characteristics of Gas Turbine Blade with Various Area Ratios and Ejection Angles of the Double Jet Holes (이중분사 홀의 면적비와 분사각 변화에 따른 가스터빈 막냉각 특성 연구)

  • Cho, Moon-Young;Lee, Jong-Chul;Kim, Youn-Jea
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.3
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    • pp.59-64
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    • 2014
  • The kidney vortex is the important factor adversely influencing film cooling effectiveness. In general, double jet film-cooling hole is designed to overcome the kidney vortex by generating anti-kidney vortices. In this study, the film cooling characteristics and the effectiveness of the double jet film cooling hole were numerically investigated with various area ratios of the first($A_1$) and second($A_2$) cooling hole($A_1/A_2$=0.8, 1.0, 1.25) and lateral ejection angle(${\alpha}$ = $30^{\circ}$, $45^{\circ}$, $60^{\circ}$) as the design parameters. The effects of lateral distance between the first and second row holes are investigated. Numerical study was performed by using ANSYS CFX with the shear stress transport(SST) turbulence model. The film cooling effectiveness and temperature distribution were graphically depicted with various flow and geometrical conditions.

A Study on the Bottom-Emitting Characteristics of Blue OLED with 7-Layer Laminated Structure (7층 적층구조 배면발광 청색 OLED의 발광 특성 연구)

  • Gyu Cheol Choi;Duck-Youl Kim;SangMok Chang
    • Clean Technology
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    • v.29 no.4
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    • pp.244-248
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    • 2023
  • Recently, displays play an important role in quickly delivering a lot of information. Research is underway to reproduce various colors close to natural colors. In particular, research is being conducted on the light emitting structure of displays as a method of expressing accurate and rich colors. Due to the advancement of technology and the miniaturization of devices, the need for small but high visibility displays with high efficiency in energy consumption continues to increase. Efforts are being made in various ways to improve OLED efficiency, such as improving carrier injection, structuring devices that can efficiently recombine electrons and holes in a numerical balance, and developing materials with high luminous efficiency. In this study, the electrical and optical properties of the seven-layer stacked structure rear-light emitting blue OLED device were analyzed. 4,4'-Bis(carazol-9-yl)biphenyl:Ir(difppy)2(pic), a blue light emitting material that is easy to manufacture and can be highly efficient and brightened, was used. OLED device manufacturing was performed via the in-situ method in a high vacuum state of 5×10-8 Torr or less using a Sunicel Plus 200 system. The experiment was conducted with a seven-layer structure in which an electron or hole blocking layer (EBL or HBL) was added to a five-layer structure in which an electron or hole injection layer (EIL or HIL) or an electron or hole transport layer (ETL or HTL) was added. Analysis of the electrical and optical properties showed that the device that prevented color diffusion by inserting an EBL layer and a HBL layer showed excellent color purity. The results of this study are expected to greatly contribute to the R&D foundation and practical use of blue OLED display devices.