• Proceedings of the KSR Conference
• /
• 2008.06a
• /
• pp.755-764
• /
• 2008

When the high speed train (KTX) departs from station in the high-speed line, sometimes on board signal disappears, which causes a hindrance of the operation punctuality, therefore, we have a research objective to verify the causes of hindrance and to find an improvement plan. In the process of research, when train left, we applied sand on the rail to improve adhesive power, whose sand has an effect on the ATC(Automatic Train Control) signal wave. We detected & analyzed signal waves which came from detecting device by changing operation condition in accordance with sand material

• Bulletin of the Korean Chemical Society
• /
• v.30 no.10
• /
• pp.2217-2222
• /
• 2009

The transition structures for the epoxidations of ethylene and the disproportionations by the dioxiranes of phosphines, phosphites and sulfides were studied with density function theory methods using the Becke3LYP functional and 6-311+G(2d,p) basis set. When the dioxiranes have methyl substituents rather than hydrogen substituents, the reaction barriers ($E_{TS}$) become higher in their epoxidations of ethylene by the steric hindrance, but become lower in their disproportionations of phosphines, phosphites and sulfides, which indicates that the nature of the dioxiranes seems to be electrophilic and in their disproportionations the reaction barriers are effected both by the electrophilicity and the steric hindrance. The steric factors in the disproportionations were calculated and more bulky substituents at dioxiranes may be necessary to retard the disproportionation and to enhance the epoxidation.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.63 no.6
• /
• pp.834-840
• /
• 2014

When the high speed train (KTX) departs from station in the high-speed line, intermittent on-board signal disappearance causes a hindrance of the operation punctuality. Therefore, we have a research objective to verify the causes of hindrance and to find an improvement plan. process of research, when train leaves the station, we applied sand on the rail to improve adhesive power, that sand has an effect on the ATC(Automatic Train Control) signal wave. We detected & analyzed signal waves which is came from detecting device by changing operation condition in accordance with sand material overage detection to be achieved.

• Structural Engineering and Mechanics
• /
• v.29 no.1
• /
• pp.1-16
• /
• 2008

Tunnels are generally constructed below the ground water table, which produces a long-term interaction between the tunnel lining and the surrounding geo-materials. Thus, in conjunction with tunnel design, the presence of water may require a number of considerations such as: leakage and water load. It has been reported that deterioration of a drainage system of tunnels is one of the main factors governing the long-term hydraulic and structural lining-ground interaction. Therefore, the design procedure of an underwater tunnel should address any detrimental effects associated with this interaction. In this paper an attempt to identify the coupled structural and hydraulic interaction between the lining and the ground was made using a numerical method. A main concern was given to local hindrance of flow into tunnels. Six cases of local deterioration of a drainage system were considered to investigate the effects of deterioration on tunnels. It is revealed that hindrance of flow increased pore-water pressure on the deteriorated areas, and caused detrimental effects on the lining structures. The analysis results were compared with those from fully permeable and impermeable linings.

• Bulletin of the Korean Chemical Society
• /
• v.21 no.6
• /
• pp.613-617
• /
• 2000

p-(2-Vinyloxyethoxy)benzylidenemalononitrile (4a), methyl p-(2-vinyloxyethoxy)benzylidenecyanoacetate (4b), 3,5-dimethoxy-4-(2'-vinyloxyethoxy)benzylidenemalononitrile (5a), methyl 3,5-dimethoxy-4-(2'-vinyloxy-ethoxy) benzylidenecyanoacetate (5 b), o-(2 -vinyloxyethoxy)benzylidenemalononitrile (6a), methyl o-(2-viny-Ioxyethoxy) benzylidenecyanoacetate (6b), 1,3-di-(2',2'-dicyanovinyl)-5-methyl-2-(2'-vinyloxyetioxy)benzene (7a), l,3-di-(2'-carbomethoxy-2'-cyanovinyl)-5-methyl-2-(2'-vinyloxyethoxy)benzene (7b), 2,3,4-tri-(2'-viny-Ioxyethoxy) benzylidenemalononitrile (8a), methyl 2,3,4-tri-(2'-vinyloxyethoxy)benzylidenecyanoacetate (8b), 2,4,6-tri-(2'-vinyloxyethoxy)benzylidenemalononitrile (9a), and methyl 2,4,6-tri-(2'-vinyloxyethoxy)benzyl-idenecyanoacetate(9b) were prepared by the condensation of the corresponding benzaldehyde 1-3 with malononitrile or methyl cyanoacetate, respectively. Vinyl ether monomers 4, 6, and 8 polymerized readily with radical initiators to yield crosslinked polymers 10, 12, and 14. However, compounds 5, 7, and 9 were inert to radical initiators due to the steric hindrance. The resulting polymers 10, 12, and 14 were not soluble in common solvents showing a thermal stability up to $300^{\circ}C$.

• Archives of Plastic Surgery
• /
• v.48 no.6
• /
• pp.717-719
• /
• 2021

• Archives of Pharmacal Research
• /
• v.23 no.1
• /
• pp.22-25
• /
• 2000

Formation of glutathione (GSH) conjugates with 2- or 6-(1-hydroxymethyl)- and 2-(1-hydroxyethyl)-DMNQ derivatives (DMNQ, 5,8-dimethoxy-1,4-naphthoquone was carried out in phosphate buffer (pH 7.4), in the presence of glutathione-S-transferase (GST), in rat liver S-9 fraction and by perfusion, and the rates of conjugates formation were compared and correlated to cytotoxicity. The GSH conjugates of 6-(1-hydroxyalkyl)-DMNQ derivatives were formed faster than 2-(1-hydroxyalkyl)-DMNQ derivatives under all of the media, implying that steric hindrance was the cause of lowering the rate of conjugate formation of 2-substituted derivatives. For both isomers, addition of GST did not improve the reaction rate, compared with that in buffer, while the reaction in the S-9 fraction and the perfusate was accelerated to a great extent. The catalytic effect of the S-9 fraction and the perfusate contain an effective system relaxing the steric hindrance of 2-(1-hydroxyalkyl)-DMNQ derivatives. Furthermore, a good correlation between the formation of the GSH conjugates and the cytotoxic activity of both naphthazarin isomers suggests that the steric hindrance is a cause of lowering the cytotoxicity of 2-isomers.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.5
• /
• pp.1547-1550
• /
• 2012

Second-order rate constants ($k_N$) have been measured spectrophotometrically for the reactions of benzyl 2-pyridyl carbonate $\mathbf{3}$ and $t$-butyl 2-pyridyl carbonate $\mathbf{3}$ with a series of alicyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. Substrate $\mathbf{4}$ is much less reactive than $\mathbf{3}$ and the steric hindrance exerted by the bulky $t$-Bu group in $\mathbf{4}$ has been attributed to its decreased reactivity. The Br${\o}$nsted-type plots for the reactions of $\mathbf{3}$ and $\mathbf{4}$ are linear with ${\beta}_{nuc}=0.57$ and 0.45, respectively. Thus, the reactions have been concluded to proceed through a concerted mechanism, although the current reactions were expected to proceed through a stepwise mechanism with a zwitterionic tetrahedral intermediate $T^{\pm}$. It has been proposed that the rate of leaving-group expulsion is accelerated by the intramolecular H-bonding interaction in $T^{\pm}$ and the "push" provided by the RO group through the resonance interaction. Thus, the enhanced nucleofugality forces the reactions to proceed through a concerted mechanism. The reactivity-selectivity principle (RSP) is not applicable to the current reaction systems, since the reaction of the less reactive $\mathbf{4}$ results in a smaller ${\beta}_{nuc}$ than that of the more reactive $\mathbf{3}$. Steric hindrance exerted by the bulky $t$-Bu group in $\mathbf{4}$ has been suggested to be responsible for the failure of the RSP.

• Hwankyungkyoyuk
• /
• v.15 no.2
• /
• pp.86-99
• /
• 2002

The purpose of this study is to make clear the management of Environmental Education in Elementary school in Korea. To accomplish this purpose, The research for the actual condition of management of Environmental Education according to school, grade, and class was progressed. The researcher was analyzed Hindrance Factors of Sound Environmental Education in School and presented some suggestion on the basis of above-mentioned findings. On one side, the method of research is a case study on qualitative based way. A case study was conducted with it's focus on public elementary school in Seoul. As for major research methods, observation by participating in school field and in-depth interview were respectively employed; subsidiary methods included literature study. The findings of this study are as belows: First, Environmental Education was not managed practically with specific way in school. Second, Environmental Education by direct and actual outdoor experience was unusual. Third, most of class school work about Environmental Education was focused on not only the type of prescription after the environmental problem but also, the treatment of articles in newspaper and TV. Forth, educational compulsion such as “you have to do that.” was mainly used as Environmental guidance for sound attitude in school without clear reasons. In the last analysis, hindrance factors of sound management for environmental education in elementary schools were ‘passive adjustment’, ‘discriminative reception’, ‘absence of information resource’. these factors came from atmosphere of negligence environmental education in schools. Therefore, all of teachers have to affirmative belief and attitude as personal dimension and all of elementary schools improve environmental education system.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.8
• /
• pp.2325-2329
• /
• 2013

Second-order rate constants $k_N$ have been measured for reactions of benzyl 2-pyridyl thionocarbonate (4b) and t-butyl 2-pyridyl thionocarbonate (5b) with a series of cyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. The $k_N$ values for the reactions of 4b and 5b have been compared with those reported previously for the corresponding reactions of benzyl 2-pyridyl carbonate (4a) and t-butyl 2-pyridyl carbonate (5a) to investigate the effect of changing the electrophilic center from C=O to C=S on reactivity and reaction mechanism. The thiono compound 4b is more reactive than its oxygen analogue 4a. The Br${\o}$nsted-type plots for the reactions of 4a and 4b are linear with ${\beta}_{nuc}=0.57$ and 0.37, respectively. The reactions of 4a were previously reported to proceed through a concerted mechanism, while those of 4b in this study have been concluded to proceed through a stepwise mechanism with formation of an intermediate being the rate-determining step on the basis of the ${\beta}_{nuc}$ value of 0.37. Enhanced polarizability upon changing the C=O in 4a by C=S has been suggested to be responsible for the reactivity order and the contrasting reaction mechanisms. In contrast, the reactivity of 5a and 5b is similar, but they are much less reactive than 4a and 4b. Furthermore, the reactions of 5a and 5b have been concluded to proceed through the same mechanism (i.e., a concerted mechanism) on the basis of linear Bronsted-type plots with ${\beta}_{nuc}=0.45$ or 0.47. It has been concluded that the strong steric hindrance exerted by the t-Bu in 5a and 5b causes a decrease in their reactivity and forces the reactions to proceed through a concerted mechanism.