• 한국재료학회지
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• 제16권12호
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• pp.754-760
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• 2006

Mercaptoundecanoic acid (MUA) has been used to enhance the dispersity of Au nanoparticles in organic solvent and the affinity between the Au nanoparticles surface and titanium dioxide shell in the synthesis of $Au/TiO_2$ core-shell composite nanoparticles. The dispersity of the MUA-coated Au nanoparticles in ethanol aqueous solution with different concentration of $H_2O$ was investigated by UV-Vis. absorption spectrum and the coating amount of MUA was varied from 0.02 mM to 1.0 mM. The MUA-coated Au nanoparticles were highly dispersed in pure $H_2O$ in the wide range of the coating amount of MUA. On the contrary, the MUAcoated Au nanoparticles showed an enhanced stability in the ethanol/$H_2O$=8/2 mixed solution only when the coating amount of MUA was 0.05 mM, and in the ethanol/$H_2O$=7/3 mixed solution when the coating amount of MUA was in the range from 0.02 mM to 0.17 mM. From this systematic study, it can be inferred that the stability and the dispersibility of Au nanoparticles in organic solvents are highly sensitive towards the amount of MUA coating.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.110-112
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• 2006

Membrane electrode assembly (MEA) for polymer electrolyte fuel cell (PEFC) are commonly prepared in the research laboratory by spraying, screen-printing and brushing catalyst slurry onto membrane or other support material like carbon paper or polyimide film in a batch style. These hand applications of the catalyst slurry are painstaking process with respect to precision of catalyst loading and reproducibility. It has been generally mentioned that the adoption of continuous process is very helpful to develop the reliable product. In the present work, we report the results of using continuous type coater with doctor-blade to coat catalyst slurry for preparing the MEA catalyst layers In a faster and highly reproducible fashion. We show that while expectedly faster than batch style, the machine coater requires the use of slurry of appropriate composition and a properly selected transfer decal material in order to achieve superior MEA plat lnw loading reproducibility. To make highly viscous catalyst slurry that is imperative for using coater, we use 40wt.% Nafion solution and minimize the content of organic solvent. And the choice of proper high surface area catalyst is important in the viewpoint of making well-dispersed slurry. After catalyst coating onto the support material, we transferred the catalyst layer to both sides of Nafion membrane by hot-pressing In this case, the degree of transfer was Influenced by hot-pressing condition including temperature, pressure, and time. To compare the transferring ability, we compared so many films and detaching papers. And among the support, polyethylene terephthalate(PET) film shows the prominent result.

• KIEAE Journal
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• 제8권5호
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• pp.55-60
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• 2008

The purpose of this study is to increase the use of Hwangto and examine the strength according to what it is compounded with. Hwangto-concrete containing Hwanto without cement nor organic chemical products were compared to the traditional cement concrete through some durability experiments. We expect to gain more knowledge on the potentials of Hwangto-concrete as an architectural source. 1) As Hwangto binder amount rises, the value of slump increases too. The reason is that the increase of the quantity of cement causes the increase of the amount of material and the decrease of the amount of aggregate. 2) When the mixed component into Hwangto-concrete remains at 2%, the compress strength is generally dispersed high along the per unit fission, in case the amount of which is at $400(g/m^3)$. The highest compress strength is 39MPa. It means that it can be applied to common structures and we need to conduct a basic property test to ensure the strength and fluidness. 3) Hwangto-concrete is expected to be highly used in the ocean structure and chemical industry because it has better resistance to sulfuric acid and to hydrochloric acid than the cement-concrete has. The result of this study is as follows. It is expected that Hwangto-concrete will be widely applied and further research on its durability and tests for its basic substantial characteristics based on future component added to it.

• 공업화학
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• 제4권3호
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• pp.522-529
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• 1993

인산형 연료전지용 전극촉매로 많이 사용되고 있는 고가의 백금촉매의 이용가치를 높이기 위하여 촉매 담지시 백금촉매의 미립화가 매우 중요하다. 따라서 카본블랙상에 고분산화된 촉매의 제조를 위하여, 고전적 함침법, pressing & soaking법, 무전해 도금법 및 콜로이드법의 여러 가지 촉매담지방법에 관하여 연구하였다. 그리고 각 촉매담지방법에 대하여 카본블랙상 백금촉매의 담지수율 및 백금촉매 입자크기를 비교하였다. 담지수율은 DCP로 확인하였으며 입자의 크기는 XRD 및 TEM으로 관찰하였다. 결과 콜로이드방법이 백금촉매를 $30{\AA}$ 이하로 미립화할 수 있는 가장 우수한 촉매담지 방법이었으며 카본 담체에 대한 백금촉매의 담지수율은 99% 이상이었다.

• 대한기계학회논문집B
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• 제24권2호
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• pp.270-279
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• 2000

Recently, according to increase in the requirement of electric power, a thermoelectric power plant equipped with pulverized coal combustion system is highly valued, because coal has abundant deposits and a low price compared with others. For efficient use of coal fuel, most of plant makers are studying to improve combustion performance and flame stability, and reduce pollutants emission. One of these studies is how to control the profile of particle injection and velocity dependant on coal nozzle configuration. Basically, nozzle which has mixed flow of gas and particle is required to have the balanced coal concentration at exit, but it is very difficult to obtain that by itself without help of other device. In this study, coal distribution and pressure drop in gas-solid flow are calculated by numerical method in nozzle with various shapes of venturi diffuser as a means to get even coal particle distribution. The tentative correlations of pressure drop and exit coal distribution are deduced as function of the height, length and reducing angle of venturi from the calculated results. When coal hurner nozzle is designed, these equations are very useful to optimize the shape of venturi which minimize uneven particle distribution and pressure drop within coal nozzle.

• 대한세포병리학회지
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• 제9권1호
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• pp.117-121
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• 1998

Cytologic features of a poorly differentiated "insular" carcinoma of the thyroid are presented. In fine needle aspiration cytology, the aspirates were highly cellular and tumor cells were arranged in loose cluster or singly dispersed on focally necrotic background. Occasional microfollicles were evident. The tumor cells had poorly defined, scanty cytoplasm and most of the nuclei were fairly uniform with coarse chromatin pattern. A few large pleomorphic cells were also noted. The cytologic findings of the present case were correlated well with the histologic findings, which showed typical insular pattern and the presence of uniform cells with occasional pleomorphism.

• 소성∙가공
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• 제29권1호
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• pp.37-43
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• 2020

Increasing the critical current density of superconducting wire is one of the difficult challenges in the field of superconductivity. It is well known that the higher volume fraction of uniformly dispersed α-Ti is able to enhance the critical current density of superconducting material NbTi because α-Ti serves as a flux pinning center. The volume fraction of α-Ti highly depends on the grain size of NbTi because α-Ti precipitates at the grain boundaries or triple points. For this purpose, we investigated the effect of initial microstructures of NbTi obtained from hot rolling in various temperature conditions on the critical current density. In addition, subsequent heat treatment was assigned to precipitate α-Ti and groove rolling/cold drawing was adopted to produce a wire with a diameter of about 1.0 mm. It was observed that the band structure was formed after hot rolling at 500~600℃. It was also found that the volume fraction of α-Ti after hot rolling at 500~600℃ was higher and it led to the highest critical current density.

• 센서학회지
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• 제26권3호
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• pp.204-208
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• 2017

Highly uniform and well-dispersed Zeolitic Imidazolate Framework-7 (ZIF-7) particles were prepared by the precipitation of $Zn^{2+}$ using benzimidazole, which were converted into ZnO nanoparticles by heat treatment at $500^{\circ}C$ for 24 h. The ZIF-7 derived ZnO nanoparticles showed abundant mesopores, high surface area, and good dispersion. The gas sensing characteristics toward 5 ppm acetone, ethanol, trimethylamine, ammonia, p-xylene, toluene, benzene, and carbon monoxide and carbon dioxide were investigated at $350-450^{\circ}C$. ZIF-7 derived ZnO nanoparticles exhibited high response to 5 ppm acetone ($R_a/R_g=57.6$; $R_a$: resistance under exposure to the air, Rg: resistance under exposure to the gas) at $450^{\circ}C$ and negligible cross-responses to other interference gases (trimethylamine, ammonia, p-xylene, toluene, benzene, carbon monoxide, carbon dioxide) and relatively low responses to ethanol. ZIF derived synthesis of metal oxide nanoparticles can be used to design high performance acetone sensors.

• 한국진공학회지
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• 제7권3호
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• pp.261-266
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• 1998

공정 플라즈마내에서 입자의 거동은 하전되는 입자의 극성과 하전량에 따르게 된다. 따라서 본 연구에서는 플라즈마내에서 입자의 거동을 이해하기 위한 기초 작업으로 입자의 하전 특성을 측정하였다. 본 연구에 사용된 단분산 입자는 직경 0.05$\mu\textrm{m}$, 0.07$\mu\textrm{m}$, 0.1$\mu\textrm{m}$, 0.2$\mu\textrm{m}$ 으로 이들 입자를 DC-공기 플라즈마내에 주입하여 이들의 하전량과 하전 극성 변화를 Faraday Cup을 이용하여 측정하였다. 본 실험에서 입자의 하전량과 하전 극성은 주입 입자 의 크기와 농도 및 플라즈마 발생조건 즉, 반응 압력, 전압 등에 영향을 받음을 알 수 있었 으며 입자 당 103~105의 평균 하전 수를 갖음이 관찰되었다.

• 폴리머
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• 제25권6호
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• pp.876-883
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• 2001

에톡시히드로퀴논과 브로모 테레프탈산을 사용하여 용액 중합법으로 네마틱 액정 상을 가지는 열방성 액정 고분자를 합성하였다. 합성된 헥사데실-몬모릴로나이트 (C$_{16}$-MMT)를 액정고분자의 용융 전이온도 이상에서 매트릭스 고분자에 대해 여러 wt%로 조성을 변화시키면서 나노복합재료를 만들었다. $C_{16}$-MMT가 액정 고분자에 대해 2 wt%만 첨가되어도 열적 성질이 크게 증가하였으며 이후로 $C_{16}$-MMT가 증가함에 따라 일정하게 증가하였다. 유기화 점토가 2에서 6 wt%까지 증가되어도 액정 상은 파괴되지 않고 그대로 유지되었다. X-ray 회절도의 결과, 첨가된 $C_{16}$-MMT의 일부는 TLCP에 잘 분산되었으나, 일부는 뭉쳐진 형태로 존재하였으며 첨가된 $C_{16}$-MMT의 상이 증가할수록 뭉침이 증가되었다. 합성된 나노복합재료의 열적 성질과 몰폴로지는 시차주사 열분석기(DSC), 열중량 분석기(TGA), 편광 현미경, 그리고 전자 현미경(SEM, TEM) 등을 이용하여 분석하였다.다.