• Title/Summary/Keyword: higher order solution

Search Result 1,048, Processing Time 0.028 seconds

An Analysis of the Application Technology of Heat Recovery System from Dyeing Wastewater (염색폐수 열회시스템 적용기술 분석)

  • 장기창;박성룡;이상남;라호상;박준택;함성원;박영태
    • Journal of Energy Engineering
    • /
    • v.10 no.3
    • /
    • pp.195-205
    • /
    • 2001
  • A great deal of energy is necessary with emission of lots of wastewater in dyeing and finishing process, but heat recovery from wastewater is not introduced since is technology is not developed yet. In order to obtain the method utilizing hot water produced by heat source, that is, dyeing wastewater it was investigated the characteristics of dyeing and finishing process and energy basic unit. Energy basic unit of polyester/cotton (T/C), polyester/rayon (T/R) and polyester dyeing process are higher than that of the other process. The average quantity of wastewater for each dyeing company is 20,470 ton/month, the average temperature of wastewater is about 41$^{\circ}C$. Because the SS solution of wastewater in polyester dyeing process is lower than that of the other process, the effect of corrosion in heat recovery system is low. Since the energy price for 1000 kcal produced by vapor compression heat pump is presumed to be 22.50 won, it is found to be very economic heat recovery system, and its payback is 2.09 years for the factory with LNG boiler.

  • PDF

Color Sensibility Factors for Yellowish and Reddish Natural Dyed Fabrics by 40s Middle-Aged Consumers (황색과 적색계열 천연염색 직물에 대한 사십대 중년층 소비자의 색채감성요인)

  • Yi, Eun-Jou;Choi, Jong-Myoung
    • Science of Emotion and Sensibility
    • /
    • v.12 no.1
    • /
    • pp.109-120
    • /
    • 2009
  • This study was carried out in order to investigate color sensation and sensibility for yellowish natural dye fabrics and reddish ones and to establish prediction models for color sensibility factors of them by color sensation and the related physical measurements focusing on 40s middle-aged people. Eight fabric stimuli which were dyed with a variety of yellowish or reddish natural dyes was subjectively evaluated in terms of color sensation and sensibility by 40s aged participants. As results, three color sensibility factors including 'Active', 'Characteristic', and 'Relax' were extracted and they were examined in respect of their relationships with color sensation and physical color properties. Color sensibility factor 'Active', the dominant factor for the naturally dyed fabrics was explained by $L^*$ and sensation 'Deep' in its predictive model and a yellowish fabric dyed with 300% solution of armur cork unmordanted was perceived the strongest in the factor. Factor 'Characteristic' was predicted by both $a^*$ and sensation 'Light' and reddish natural dye fabrics tended to be felt more strongly for it. Color sensation 'Strong' was the only predictor for factor 'Relax' in that naturally dyed fabrics with lower values for the sensation seemed to show higher 'Relax' factor and a reddish fabric dyed with safflower 125% was the highest for the color sensibility factor. These results could be utilized to design color-sensible natural dye fabrics for middle-aged people.

  • PDF

Synthesis of Polyamine Type Flocculant and Properties in Potable Water Treatment (Polyamine계 고분자 응집제의 합성 및 상수 처리 특성)

  • Park, Lee-Soon;Shin, June-Ho;Choi, Sang-June;Shin, Myung-Chul;Lee, Seok-Hun
    • Applied Chemistry for Engineering
    • /
    • v.9 no.4
    • /
    • pp.542-547
    • /
    • 1998
  • Polyamine type polymer flocculants were synthesized and their characterization, viscosity and flocculation studies were conducted. In order to increase the molecular weight of polyamine flocculant which was prepared by polycondensation reaction from dimethylamine and epichlorohydrin, a small amount of 1,6-hexanediamine was employed. The incorporation of 1,6-hexanediamine up to 5.5 mole % replacing corresponding part of dimethylamine gave a branched type polyamine sample with increased intrinsic viscosity ([${\eta}$]=0.46 in 1 wt % aqueous NaCl solution). The amount of 1,6-hexanediamine above 5.5 mole %, however, resulted in gelation during polymerization. Utilizing raw water from Maegok potable water treatment plant, it was found that the addition of polyamine flocculant at a concentration of 1 mg/L level could reduce the amount of polyaluminum chloride (PAC) inorganic flocculant by half (15 mg/L). It was also observed that the incoporation of polyamine flocculant at 1 mg/L level was effective in the higher pH raw water, while PAC inorganic flocculating agent alone was not effective.

  • PDF

Study on Mixing Condition of the Rubber Composite Containing Functionalized S-SBR, Silica and Silane : II. Effect of Mixing Temperature and Time (변성 S-SBR Silica-Silane 고무복합체의 배합조건에 대한 연구 : II. 배합온도와 시간의 영향)

  • Jang, Suk-Hee;Kim, Wook-Soo;Kang, Yong-Gu;Han, Min-Hyun;Chang, Sang-Mok
    • Elastomers and Composites
    • /
    • v.48 no.2
    • /
    • pp.103-113
    • /
    • 2013
  • The properties of the rubber composites containing a silane and silica were evaluated by changing the mixing time and temperature, in order to find the optimum mixing conditions. Characteristics of the compounds were evaluated after mixing at $120^{\circ}C$, $140^{\circ}C$, and $160^{\circ}C$ with various mixing time. With increasing of mixing time, mooney viscosity decreased while the bound rubber contents of the compounds increased. Viscosity rise by increased mixing time was bigger at low temperature and the higher the mixing temperature the faster in the formation of bound rubber. With lower mixing temperature of $120^{\circ}C$, cross-linking rate was almost constant. Dynamic viscoelastic properties and dispersity of the compound showed that dispersion of ingredients and reaction was not sufficient with the mixing time of less than 10min. On the contrary, with high temperature, it was obvious that good dynamic and physical properties could be obtained due to sufficient coupling reaction, however it was thought this high temperature is not optimum because of sensitive cross-linking rate and physical properties and excessive formation of bound rubber. Consequently, it was confirmed that the mixing condition of 10min at $140^{\circ}C$ was optimum for the silane coupling reaction and dispersion of functionalized S-SBR containing silica and silane.

Study on Mixing Condition of the Rubber Composite Containing Functionalized S-SBR, Silica and Silane : I. Effect of Mixing Temperature (변성 S-SBR Silica-Silane 고무복합체의 배합조건에 대한 연구 : I. 배합온도의 영향)

  • Jang, Suk-Hee;Kim, Wook-Soo;Kang, Yong-Gu;Han, Min-Hyun;Chang, Sang-Mok
    • Elastomers and Composites
    • /
    • v.48 no.2
    • /
    • pp.94-102
    • /
    • 2013
  • Characteristics of rubber mixture were evaluated in order to find the optimum mixing conditions of compounds containing silica and silane at various temperatures. With different mixing temperatures of 105, 120, 130, 140 and $160^{\circ}C$, the viscosity of the compound mixed at $105^{\circ}C$ showed a very high viscosity value. Compounds mixed the temperature range from at $120^{\circ}C$ to $140^{\circ}C$ showed lower viscosity than the compound mixed at $105^{\circ}C$. However, the difference was found to be small in those temperature ranges. On the contrary, at the mixing temperature of $160^{\circ}C$, the viscosity of compound increased again. Through the physical and dynamic observations, it was verified that at the mixing temperature below $120^{\circ}C$ only insufficient silica-silane reaction has been obtained. In addition, with the elevated mixing temperature of $160^{\circ}C$, Cross-linking occurred during mixing by the sulfur contained in coupling agent. In the temperature ranges from $120^{\circ}C$ to $140^{\circ}C$, because of the fast coupling reaction at higher temperature, it was thought to be more advantageous during reaction even though the trend of viscosity and dynamic mechanical property was not clear.

Phase Behavior of Simvastatin Drug in Mixtures of Dichloromethane and Supercritical Carbon Dioxide and Microparticle Formation of Simvastatin Drug Usins Supercritical Anti-Solvent Process (디클로로메탄과 초임계 이산화탄소의 혼합용매에서 Simvastatin 약물의 상거동과 초임계 역용매 공정을 이용한 Simvastatin 약물 미세입자의 제조)

  • Oh, Dong-Joon;Lee, Byung-Chul
    • Clean Technology
    • /
    • v.13 no.1 s.36
    • /
    • pp.34-45
    • /
    • 2007
  • Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dichloromethane and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing dichloromethane as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of dichloromethane and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the dichloromethane composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature. The second half of this work is focused on the particle formation of the simvastatin drug by a supercritical anti-solvent recrystallization process in a cylindrical high-pressure vessel equipped with an impeller. Microparticles of the simvastatin drug were prepared as functions of pressure (8 MPa to 12 MPa), temperature (303.15 K, 313,15 K), feed flow rate of carbon dioxide, and stirring speed (up to 3000 rpm), in order to observe the effect of those process parameters on the size and shape of the drug microparticles recrystallized.

  • PDF

The Improvement of Incompatible Sliding Contact Problem Using Mesh Refinement And Its Application to Railway Skewed Culvert Problem (요소 세분화를 이용한 비적합 미끄러지는 접촉문제의 개선과 철도 사각암거 문제에의 적용)

  • Choi, Chan-Yong;Yeo, In-Ho;Chung, Keun-Young;Lee, Gye-Hee
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.30 no.5
    • /
    • pp.435-444
    • /
    • 2017
  • The vehicle-track structure dynamic interaction analysis problem can be treated as sliding contact problem, and it is assumed that vehicle run at a constant speed over a rail modeled as beam elements. Unfortunately, Salome-Meca can not satisfy the compatibility condition for the beam master elements, which are consist of the elements with higher order polynomial shape function, in sliding contact problem. In this study, it is suggested to use more finer beam master element mesh as the remedy for incompatibility in sliding contact problem, and the accuracy of the solution is secured. For this, the effect of beam element mesh refinement consisting runway is analysed through simple examples, and the applicability to the dynamic interaction analysis is evaluated. Finally, the dynamic interaction analysis of railway skewed culvert transition problem is carried out to evaluate the effect of supporting stiffness due to backfill pattern changes and track irregularity due to uneven subgrade settlement.

The Solubility of Ozone in Deionized Water and its Cleaning Efficiency (초순수내에서의 오존의 용해도와 세정효과)

  • Han, Jeoung-Hoon;Park, Jin-Goo;Kwak, Young-Shin
    • Korean Journal of Materials Research
    • /
    • v.8 no.6
    • /
    • pp.532-537
    • /
    • 1998
  • The purpose of this study was to investigate the behavior of ozone in DI water and the reaction with wafers during the semiconductor wet cleaning process. The solubility of ozone in DI water was not only dependent on the temperature but also directly proportional to the input concentration of ozone. The lower the initial ozone concentration and the temperature, the longer the half-life time of ozone. The reaction order of ozone in DI water was calculated to be around 1.5. The redox potential reached a saturation value in 5min and slightly increased as the input ozone concentrations increased. The completely hydrophilic surface was created in Imin when HF etched silicon wafer was cleaned in ozonized DI water containing higher ozone concentrations than 2ppm. Spectroscopic ellipsometry measurements showed that the chemical oxide formed by ozonized DI water was measured to be thicker than that by piranha solution. The wafers contaminated with a non-ionic surfactant were more effectively cleaned in ozonized DI water than in piranha and ozonized piranha solutions.

  • PDF

Analysis of Activity Process of Gifted Students Shown in Field Trip Activity Emphasizing Open Inquiry (개방적 탐구를 강조한 탐방 활동에서 나타난 초등과학 영재학생들의 활동 과정 분석)

  • Lee, Kun-Hee;Kim, Sun-Ja;Park, Jong-Wook
    • Journal of Gifted/Talented Education
    • /
    • v.19 no.1
    • /
    • pp.1-23
    • /
    • 2009
  • Science field trip is a comprehensive learning activity in which students can solve problems by themselves, whose importance is emphasized in learning for the gifted. But because not much study has been done yet on this, and convergent activities such as solving too many problems or requesting given answers have generally been done, it has been criticized for not being enough to develop the abilities of gifted Students. Therefore, this study attempted to analyze the activity process of the gifted through field trip to which open inquiry is adapted so that the demands of the gifted can be met, and the abilities of the gifted can be brought out. The study focused on 18 gifted elementary science students at Institute of Science Gifted Education, Cheongju National University of Education, and in the field trip process of the students, analyzed the types of establishment of inquiry problems and inquiry process, and the behavioral characteristics of gifted science students shown during field trip activity through field trip proceedings, transcript contents, poster materials, questionnaires, etc. As a result, more inquiry problems were established after than before inquiry, and the level of inquiry problems was also higher after inquiry. The solution process for inquiry problems of the gifted science students were done in the following order: planning, inquiring, follow-up inquiring and consolidating. But it proceeded to open inquiry process, the next stage being decided according to circumstances. Also, in the inquiry that the students did, diverse factors were revealed such as basic and integrative inquiries, and especially, the students were competent in analyzing the results after transforming and interpreting them. And the analysis of the interaction among the students showed many behavioral traits of talented science students.

Methods of Recycling Soil Washing Wastewater for Volume Reduction (토양세척폐액 부피감소를 위한 재생방법 연구)

  • 김계남;원휘준;오원진
    • Journal of Soil and Groundwater Environment
    • /
    • v.8 no.1
    • /
    • pp.17-26
    • /
    • 2003
  • The sorption experiment of cobalt was performed after the TRIGA soil was intentionally contaminated with cobalt was found that the sorption equilibrium coeficiency of soil decontamination was high when the ratio of soil mass to the volume of citric acid becomes 1:5 The TRIGA soil contaminated with 0.01 M, 0.001 M, and 0.0001 M of cobalt solution were decontaiminated with 0.01 M citric acid. The cobalt concentrtion in the wastewater were measured to be correspondingly 36.0, 14.0, 1.5 ppm. The results of wastewater recycling experiment by chemical precipitation method revealed that corresponding cobalt removal efficiency were 97% 88%. It was shown that the removal efficiency decreases as the cobalt concentration in the wastewater decreases. During the decontamination experiment, a lot of NaOH had to be added, and the volume of final solid waste reached almost 10% of that of the contaminated soil. The result of wastewater recyling experiment by ion exchange resin meted rethod revealed that to more the strong acid resins are used, the higher the cobalt removal efficiency becomes and the cobalt removal efficiency becomes and the lower the pH of recycling wastewater become. In order to obtain more than 95% removal efficiency, more than 0.625 g of strong acid resin was necessary in each of 3 experiments. There was an unexpected problem that a lot of strong acid resin waste was produced which amounts to 9.2% (volume) of the contaminated soil.