• Title/Summary/Keyword: high-elasticity

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Rheology of hydrophobic-alkali-soluble-emulsions (HASE) and the effects of surfactants

  • Lau, A.K.M.;Tiu, C.;Kealy, T.;Tam, K.C.
    • Korea-Australia Rheology Journal
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    • v.14 no.1
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    • pp.1-9
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    • 2002
  • Steady and dynamic shear properties of two hydrophobically modified alkali soluble emulsions (HASE), NPJI and NPJ2, were experimentally investigated. At the same polymer concentration, NPJ1 is appreciably more viscous and elastic than NPJ2. The high hydrophobicity of NPJ1 allows hydrophobic associations and more junction sites to be created, leading to the formation of a network structure. Under shear deformation, NPJ1 exhibits shear-thinning behaviour as compared with Newtonian characteristics of NPJ2. NPJ1 and NPJ2 exhibit a very high and a low level of elasticity respectively over the frequency range tested. For NPJ1, a crossover frequency appears, which is shifted to lower frequencies and hence, longer relaxation times, as concentration increases. Three different surfactants anionic SDS, cationic CTAB, and non-ionic TX-100 were employed to examine the effects of surfactants on the rheology of HASE. Due to the different ionic behaviour of the surfactant, each type of surfactant imposed different electrostatic interactions on the two HASE polymers. In general, at low surfactant concentration, a gradual increase in viscosity is observed until a maximum is reached, beyond which a continuous reduction of viscosity ensues. Viscosity development is a combined result of HASE-surfactant interactions, accompanied by constant rearrangement of the hydrophobic associative junctions, and electrostatic interactions.

Evaluation on Displacement Property of Ceramic Belt by Using FEM (FEM을 이용한 세라믹벨트 변위특성 평가)

  • Yang, Sung-Mo;Yu, Hyo-Sun;Kang, Hee-Yong;Hwang, Young-Min;Song, Joon-Hyuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.4
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    • pp.119-124
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    • 2012
  • Ceramics are becoming one of the most important materials due to its good mechanical properties such as high strength, hardness, chemical safety, and high modulus of elasticity. Ceramics have been used widely as a material not only for construction, but also for vehicles, planes, and bones for the human body. Despite these advantages, ceramics have some limitations in actual use due to its brittle fracture characteristic. In order to develop ceramic belt in this study, the data regarding stiffness and strain is necessary. For this purpose, the sensitivities of maximum stress value and displacement are analyzed by applying the load change on ceramic belt with finite element method program.

A Study on the Mechanical Properties of Knit Fabric Using 3D Printing -Focused on PLA, TPU Filament- (3D프린팅을 이용한 편성물의 역학적 특성 연구 -PLA, TPU 필라멘트를 중심으로-)

  • Han, Yoojung;Kim, Jongjun
    • Journal of Fashion Business
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    • v.22 no.4
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    • pp.93-105
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    • 2018
  • Using FDM 3D printing, yarn shape and composition were modeled and 3D printed with PLA and TPU filaments currently used for apparel. Based on this, mechanical characteristics were measured to determine 3D printing yarn according to type of filaments in the 3D printed output and deformation and recovery characteristics due to differences in structure type. As a result of examining tensile and shear characteristics of PLA and TPU 3D printing compiles, TPU overall was measured with significantly lower stress than PLA. This is due to high elasticity of TPU's character, revealing that it has better flexibility than PLA. In addition, during deformation due to external forces, the more freedom between the head and foot parts of the loop, and the lower the force associated with each other, the more flexible it is. TPU revealed that it was easier to tension and recovery from tensile deformation than PLA, indicating potential for clothing materials using 3D printing. If high-molecular materials, such as PLA flexibility, it is likely to provide some flexibility through development of styles, including degree of freedom in modeling. Based on this, we provide basic data for developing 3D printing textures that can be satisfied with textile for apparel.

Engineering Properties of Lightweight Concrete Using Surlightweight Aggregate (초경량골재를 사용한 경량콘크리트의 공학적 특성)

  • 성찬용;김성완;민정기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.36 no.4
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    • pp.48-55
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    • 1994
  • This study was performed to evaluate the engineering properties of the lightweight concrete using surlightweight aggregate foaming agent and high performance agent. The following conclusions were drawn. 1. The unit weight of type A, B and C concrete was 0.912t/m$^3$, 1.592t/m$^3$ and 1.070t/m$^3$, respectively. Specially, the unit weight of type A concrete was decreased 42% than that of the type B concrete. 2. The highest engineering property was measured in the lightweight concrete using high performance agent Also, the ratio of tensile and bending strength to compresive streng-th of the lightweight concrete was higher than that of the normal cement concrete. 3. The dynamic modulus of elasticity of the lightweight concrete was in the range of 2.86 x 10 5~9.86 x 10 5 kg/cm$^2$ which was approximately 300% than that of the normal cement concrete. 4. The ultrasonic pulse velocity of the lightweight concrete was in the range 2047~3394 n/sec, which was smaller than that of the normal cement concrete.

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Mechanical properties and adiabatic temperature rise of low heat concrete using ternary blended cement

  • Kim, Si-Jun;Yang, Keun-Hyeok;Lee, Kyung-Ho;Yi, Seong-Tae
    • Computers and Concrete
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    • v.17 no.2
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    • pp.271-280
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    • 2016
  • This study examined the mechanical properties and adiabatic temperature rise of low-heat concrete developed based on ternary blended cement using ASTM type IV (LHC) cement, ground fly ash (GFA) and limestone powder (LSP). To enhance reactivity of fly ash, especially at an early age, the grassy membrane was scratched through the additional vibrator milling process. The targeted 28-day strength of concrete was selected to be 42 MPa for application to high-strength mass concrete including nuclear plant structures. The concrete mixes prepared were cured under the isothermal conditions of $5^{\circ}C$, $20^{\circ}C$, and $40^{\circ}C$. Most concrete specimens gained a relatively high strength exceeding 10 MPa at an early age, achieving the targeted 28-day strength. All concrete specimens had higher moduli of elasticity and rupture than the predictions using ACI 318-11 equations, regardless of the curing temperature. The peak temperature rise and the ascending rate of the adiabatic temperature curve measured from the prepared concrete mixes were lower by 12% and 32%, respectively, in average than those of the control specimen made using 80% ordinary Portland cement and 20% conventional fly ash.

Effect of basalt fibers on fracture energy and mechanical properties of HSC

  • Arslan, Mehmet E.
    • Computers and Concrete
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    • v.17 no.4
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    • pp.553-566
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    • 2016
  • Fracture energy is one of the key parameters reveal cracking resistance and fracture toughness of concrete. The main purpose of this study is to determine fracture behavior, mechanical properties and microstructural analysis of high strength basalt fiber reinforced concrete (HSFRC). For this purpose, three-point bending tests were performed on notched beams produced using HSFRCs with 12 mm and 24mm fiber length and 1, 2 and $3kg/m^3$ fiber content in order to determine the value of fracture energy. Fracture energies of the notched beam specimens were calculated by analyzing load versus crack mouth opining displacement curves by the help of RILEM proposal. The results show that the effects of basalt fiber content and fiber length on fracture energy are very significant. The splitting tensile and flexural strength of HSFRC increased with increasing fiber content whereas a slight drop in flexural strength was observed for the mixture with 24mm fiber length and $3kg/m^3$ fiber content. On the other hand, there was no significant effect of fiber addition on the compressive strength and modulus of elasticity of the mixtures. In addition, microstructural analysis of the three components; cement paste, aggregate and basalt fiber were performed based on the Scanning Electron Microscopy and Energy-Dispersive X-ray Spectroscopy examinations.

Properties of Friction Coefficient with Re-Ir Coating Surface (Re-Ir 코팅에 따른 표면 마찰 계수 특성 연구)

  • Lee, Ho-Shik;Cheon, Min-Woo;Park, Yong-Pil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.676-677
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    • 2011
  • Rhenium-Iridium(Re-Ir) thin films were deposited onto the tungsten carbide(WC) molding core by sputtering system. The Re-Ir thin films on tungsten carbide molding core were analyzed by scanning electron microscope(SEM) and surface roughness. The Re-Ir coating technique has been intensive efforts in the field of coating process because the coating technique and process have been their feature, like hardness, high elasticity, adrasion resistance and mechanical stability and also have been applied widely the industrial and biomedical areas. In this report, tungsten carbide(WC) molding core was manufactures using high performance precision machining and the efforts of Re-Ir coating on the surface roughness.

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THE QUALITY PROPERTIES FOR FLY ASH OF COMBINED HEAT POWER PLAINT AND MECHANANICAL PROPERTIES IN CONCRETE (열병합발전소 플라이애쉬 품질 및 콘크리트의 역학적 특성)

  • Lee, Sang-Soo;Back, Myung-Jong;Won, Cheol;Ahn, Jae-Hyen;Park, Chil-Lim
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.69-74
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    • 1995
  • The primary purpose of this study is to investigate reusal techniques of fly ash of combined heat power plant in the construction field, which may contribute to the saving of construction materials and conservating environment. Firstly chemical and physical characteristics of fly ash is analysed. And then, the usability of the concrete is tested by investigating the flowablility and stength development through parameters of various replacement ratios with respect to different mixing conditions. Finally, the durability and mechanical properties(elastic modulus) of the concrete is tested. As the result of the study, the following conclusions are derived : (1) the quantity of the CaO in the fly ash is relatively high based on the chemical analysis, (2)the compressive strength ratio of the mortar is satisfied with the specification, but the unit water ratio increased, (3)high strength concrete of more than 400kg/$\textrm{cm}^2$ can be developed in the ranges of FA 30%, W/B 40%, (5)the slump loss with the elapsed time due to the delivery is decreased as the replacement ratio of the fly ash is increased, (6)the modulus of the elasticity is matched withn the specification of the Architectural Institute of Korea.

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Geometrically nonlinear analysis of sandwich beams under low velocity impact: analytical and experimental investigation

  • Salami, Sattar Jedari;Dariushi, Soheil
    • Steel and Composite Structures
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    • v.27 no.3
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    • pp.273-283
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    • 2018
  • Nonlinear low velocity impact response of sandwich beam with laminated composite face sheets and soft core is studied based on Extended High Order Sandwich Panel Theory (EHSAPT). The face sheets follow the Third order shear deformation beam theory (TSDT) that has hitherto not reported in conventional EHSAPT. Besides, the two dimensional elasticity is used for the core. The nonlinear Von Karman type relations for strains of face sheets and the core are adopted. Contact force between the impactor and the beam is obtained using the modified Hertz law. The field equations are derived via the Ritz based applied to the total energy of the system. The solution is obtained in the time domain by implementing the well-known Runge-Kutta method. The effects of boundary conditions, core-to-face sheet thickness ratio, initial velocity of the impactor, the impactor mass and position of the impactor are studied in detail. It is found that each of these parameters have significant effect on the impact characteristics which should be considered. Finally, some low velocity impact tests have been carried out by Drop Hammer Testing Machine. The contact force histories predicted by EHSAPT are in good agreement with that obtained by experimental results.

Enhanced Cathode/Sulfide Electrolyte Interface Stability Using an Li2ZrO3 Coating for All-Solid-State Batteries

  • Lee, Jun Won;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.176-183
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    • 2018
  • In this study, a $Li_2ZrO_3$ coated $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ (NCA) cathode was applied to an all-solid-state cell employing a sulfide-based solid electrolyte. Sulfide-based solid electrolytes are preferable for all-solid-state cells because of their high ionic conductivity and good softness and elasticity. However, sulfides are very reactive with oxide cathodes, and this reduces the stability of the cathode/electrolyte interface of all-solid-state cells. $Li_2ZrO_3$ is expected to be a suitable coating material for the cathode because it can suppress the undesirable reactions at the cathode/sulfide electrolyte interface because of its good stability and high ionic conductivity. Cells employing $Li_2ZrO_3$ coated NCA showed superior capacity to those employing pristine NCA. Analysis by X-ray photoelectron spectroscopy and electron energy loss spectroscopy confirmed that the $Li_2ZrO_3$ coating layer suppresses the propagation of S and P into the cathode and the reaction between the cathode and the sulfide solid electrolyte. These results show that $Li_2ZrO_3$ coating is promising for reducing undesirable side reactions at the cathode/electrolyte interface of all-solid-state-cells.