• Journal of the Korean Ceramic Society
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• v.48 no.5
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• pp.384-389
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• 2011

Gas pressure sintering (GPS) of reaction bonded silicon nitride (RBSN) was performed using $Lu_2O_3-SiO_2$ additive and the properties were compared with those of specimens prepared using high purity $Si_3N_4$ powder. The relative density of RBSN and compacted $Si_3N_4$ powder were 68.9 and 47.1%, and total linear shrinkage after sintering at $1900^{\circ}C$ were 14.8 and 42.9%, respectively. High nitrogen partial pressure (5MPa) was required during sintering at $1900^{\circ}C$ in order to prevent the decomposition of the nitride and to promote the formation of SiC. The relative density and 4-point bending strength of RBSN and $Si_3N_4$ powder compact were 97.7%, 954MPa and 98.2%, 792MPa, respectively, after sintering at $1900^{\circ}C$. The sintered RBSN also showed high fracture toughness of 9.2MPam$^{1/2}$.

• Korean Journal of Materials Research
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• v.15 no.1
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• pp.19-24
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• 2005

For the good combination of high-temperature strength, toughness and creep property, $9-12\%$ chromium steels are often used for gas turbine compressors, steam turbine rotors, blade and casing. In this study, the correlation of microstructural evolution and mechanical properties was investigated fur the specimens heat-treated at 600, 650 and $700^{\circ}C$ for 1000, 3000 and 5000 hrs. The microstructure of as-received specimen was tempered martensite with a high dislocation density, small sub-grains and fine secondary phase such as $M_23C_6$. Aging for long-time at high temperature caused the growth of martensite lath and the decrease of dislocation density resulting in the decrease in strength. However, the evolution of secondary phases had influence on hardness, yield strength and impact property. In the group A specimen aged at $600^{\circ}C\;and\;650^{\circ}C$, Laves phase was observed. The Laves phase caused the increase of the hardness and the decrease of the impact property. In addition, the abrupt growth of secondary phases caused decrease of the impact property in both A and B group specimens.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.3
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• pp.598-607
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• 1992

The environment degradation of structural steel under high temperature is one of the key phenomena governing the availability and life of plant. This degradation resulted from the microstructural changes due to the long exposure at high temperature affect the mechanical properties such as creep strength and toughness. For instance, boiler tube materials usually tend to degrade, after long term operation, by precipitates, spherodizing, coarsening, and change in chemical composition of carbides. In this study, the material degradation under high temperature exposure was investigated by evaluating the carbide precipitation. The electrochemical polarization method was facilitated to investigate the precipitation and coarsening of carbides. It was shown by the modified electrochemical potentiokinetic reactivation (EPR) tests that the passivation of Mo-rich carbides did not occur even in the anodic peak current (Ip) which indicates the precipitation of Mo$_{6}$C was also observed. And it was assured that special electrolytic cell assembled in this research can be used for the detection of Mo$_{6}$C precipitation in the field.eld.

• Korean Journal of Metals and Materials
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• v.48 no.2
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• pp.122-132
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• 2010

Higher strength and fracture toughness of reactor pressure vessel steels can be obtained by changing the material specification from that of Mn-Mo-Ni low alloy steel (SA508 Gr.3) to Ni-Mo-Cr low alloy steel (SA508 Gr.4N). However, the operation temperature of the reactor pressure vessel is more than $300^{\circ}C$ and the reactor operates for over 40 years. Therefore, we need to have phase stability in the high temperature range in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel. It is very important to evaluate the temper embrittlement phenomena of SA508 Gr.4N for an RPV application. In this study, we have performed a Charpy impact test and tensile test of SA508 Gr.4N low alloy steel with changing impurity element contents such as Mn and P. And also, the mechanical properties of these low alloy steels after longterm heat treatment ($450^{\circ}C$, 2000hr) are evaluated. Further, evaluation of the temper embrittlement by fracture analysis was carried out. Temper embrittlement occurs in KL4-Ref and KL4-P, which show a decrease of the elongation and a shifting of the transition curve toward high temperature. The reason for the temper embrittlement is the grain boundary segregation of the impurity element P and the alloying element Ni. However, KL4-Ref shows temper embrittlement phenomena despite the same contents of P and Ni compared with SC-KL4. This result may be caused by the Mn contents. In addition, the behavior of embrittlement is not largely affected by the formation of $M_3P$ phosphide or the coarsening of Cr carbides.

• Korean Journal of Metals and Materials
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• v.46 no.10
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• pp.672-682
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• 2008

The resistance spot welding of TRIP590 steels was investigated to enhance understanding of weld fracture during tensile-shear strength (TSS) test. The main failure modes for spot welds of TRIP590 steels were nugget pullout and interfacial fracture. The peak load to cause a weld interfacial failure was found to be related to fracture toughness of the weld and the weld diameter. Although interfacial fracture occurred in the samples, the load carrying capacity of the weld was high and not significantly affected by the fracture mode. Substantial part of the weld exhibits the characteristic dimple (or elongated dimple) fractures on interfacial fractured surface, in spite of the high hardness values associated with the martensite microstructures. The high load-bearing ability of the weld is directly associated with the area of ductile fracture occurred in weld. Therefore, the judgment of the quality of resistance spot welds in TRIP590 steels, the load carrying capacity of the weld should be considered as an important factor than fracture mode.

• Journal of Powder Materials
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• v.28 no.4
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• pp.317-324
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• 2021

High-strength low-alloy (HSLA) steels show excellent toughness when trace amounts of transition elements are added. In steels, prior austenite grain size (PAGS), which is often determined by the number of added elements, is a critical factor in determining the mechanical properties of the material. In this study, we used two etching methods to measure and compare the PAGS of specimens with bainitic HSLA steels having different Nb contents These two methods were nital etching and picric acid etching. Both methods confirmed that the sample with high Nb content exhibited smaller PAGS than its low Nb counterpart because of Nb's ability to hinder austenite recrystallization at high temperatures. Although both etching approaches are beneficial to PAGS estimation, the picric acid etching method has the advantage of enabling observation of the interface containing Nb precipitate. By contrast, the nital etching method has the advantage of a very short etching time (5 s) in determining the PAGS, with the picric acid etching method being considerably longer (5 h).

• Tunnel and Underground Space
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• v.31 no.6
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• pp.428-439
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• 2021

A spray-on membrane is a material composed of a polymer, and is a spray-type material that is expected to be able to replace materials such as existing shotcrete or sheet membrane for support or waterproofing purposes. In the previous studies, it is expected that the thickness of the support material such as shotcrete can be reduced if the spray-on membrane is additionally installed on the existing cement-based support materials. In this study, a three-point bending test was performed by a spray-on membrane on the high-performance shotcrete on the outside, and comparison was made between the case where high-performance shotcrete and a spray-on membrane were installed. As a result of comparing the values calculated through the standard test and the real-size bending test, there was no significant difference in terms of flexural strength, but it was found that there was a difference in flexural toughness.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.6
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• pp.182-192
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• 2022

Brittle feature is one of the fracture behaviors of structure s and has a great influence on the seismic performance of structure materials. The load velocity acts as one of the main causes of brittle fracture, and in particular, in situations such as earthquakes, a high load velocity acts on buildings. However, most of the seismic performance evaluation of the domestic and external steel connections is conducted through static experiments. Therefore, there is a possibility that brittle fracture due to factors such as degradation of material toughness and reduction of maximum deformation rate due to high load velocity during an earthquake was not sufficiently considered in the existing seismic performance evaluation. This study conducts a static test at a low load velocity according to the existing experimental method and a dynamic test at a high load velocity using a shaking table, respectively. It compares and analyzes the fracture shape and structural performance according to the results of each experiment, and finally analyzes the effect of the load velocity size on the seismic performance of the connection.

• Applied Microscopy
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• v.52
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• pp.5.1-5.10
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• 2022

The use of Pipelines for long-distance transportation of crude oil, natural gas and similar applications is increasing and has pivotal importance in recent times. High specific strength plays a crucial role in improving transport efficiency through increased pressure and improved laying efficiency through reduced diameter and weight of line pipes. TRIP-based high-strength and high-ductility alloys comprise a mixture of ferrite, bainite, and retained austenite that provide excellent mechanical properties such as dimensional stability, fatigue strength, and impact toughness. This study performs microstructure analysis using both Nital etching and LePera etching methods. At the time of Nital etching, it is difficult to distinctly observe second phase. However, using LePera etching conditions it is possible to distinctly measure the M/A phase and ferrite matrix. The fraction measurement was done using OM and SEM images which give similar results for the average volume fraction of the phases. Although it is possible to distinguish the M/A phase from the SEM image of the sample subjected to LePera etching. However, using Nital etching is nearly impossible. Nital etching is good at specific phase analysis than LePera etching when using SEM images.

• Structural Engineering and Mechanics
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• v.89 no.6
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• pp.617-626
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• 2024

The study investigated the behavior of plain and fibered Ultra-High Performance Concrete (UHPC) beams under varying loading conditions using integrated analysis of the flexure and acoustic emission tests. The loading rate of testing is -0.25 -2 mm/min. It is observed that on increasing loading rate, flexural strength increases, and toughness decreases. The acoustic emission testing revealed that higher loading rates accelerate crack propagation. Fiber effect and matrix cracking are identified as significant contributors to the release of acoustic emission energy, with fiber rupture/failure and matrix cracking showing rate-dependent behavior. Crack classification analysis indicated that the rise angle (RA) value decreased under quasi-static loading. The average frequency (AF) value increased with the loading rate, but this trend reversed under rate-dependent conditions. K-means analysis identified distinct clusters of crack types with unique frequency and duration characteristics at different loading rates. Furthermore, the historic index and signal strength decreased with increasing loading rate after peak capacity, while the severity index increased in the post-peak zone, indicating more severe damage. The sudden rise in the historic index and cumulative signal strength indicates the possibility of several occurrences, such as the emergence of a significant crack, shifts in cracking modes, abrupt failure, or notable fiber debonding/pull-out. Moreover, there is a distinct rise in the number of AE knees corresponding to the increase in loading rate. The crack mapping from acoustic emission testing aligned with observed failure patterns, validating its use in structural health monitoring.