• Title/Summary/Keyword: high temperature state

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Nanoscale Characterization of a Heterostructure Interface Properties for High-Energy All-Solid-State Electrolytes (고에너지 전고체 전해질을 위한 나노스케일 이종구조 계면 특성)

  • Sung Won Hwang
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.1
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    • pp.28-32
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    • 2023
  • Recently, the use of stable lithium nanostructures as substrates and electrodes for secondary batteries can be a fundamental alternative to the development of next-generation system semiconductor devices. However, lithium structures pose safety concerns by severely limiting battery life due to the growth of Li dendrites during rapid charge/discharge cycles. Also, enabling long cyclability of high-voltage oxide cathodes is a persistent challenge for all-solid-state batteries, largely because of their poor interfacial stabilities against oxide solid electrolytes. For the development of next-generation system semiconductor devices, solid electrolyte nanostructures, which are used in high-density micro-energy storage devices and avoid the instability of liquid electrolytes, can be promising alternatives for next-generation batteries. Nevertheless, poor lithium ion conductivity and structural defects at room temperature have been pointed out as limitations. In this study, a low-dimensional Graphene Oxide (GO) structure was applied to demonstrate stable operation characteristics based on Li+ ion conductivity and excellent electrochemical performance. The low-dimensional structure of GO-based solid electrolytes can provide an important strategy for stable scalable solid-state power system semiconductor applications at room temperature. The device using uncoated bare NCA delivers a low capacity of 89 mA h g-1, while the cell using GO-coated NCA delivers a high capacity of 158 mA h g−1 and a low polarization. A full Li GO-based device was fabricated to demonstrate the practicality of the modified Li structure using the Li-GO heterointerface. This study promises that the lowdimensional structure of Li-GO can be an effective approach for the stabilization of solid-state power system semiconductor architectures.

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Development of High Temperature Creep Properties Evaluation Method using Miniature Specimen (미소시험편을 이용한 고온 크리프 특성 평가법 개발)

  • Yu, Hyo-Sun;Baek, Seung-Se;Lee, Song-In;Ha, Jeong-Soo
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.43-48
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    • 2000
  • In this study, a small punch creep(SP-Creep) test using miniaturized specimen$(10{\times}10{\times}0.5mm)$ has been described for the development of the newly semi-destructive creep test method for high temperature structural components such as headers and tubes of boiler turbine casino and rotor and reactor vessel. The SP-Creep testing technique has been applied to 2.25Cr-1Mo(STBA24) steel used widely as boiler tube material and the creep test temperature are varied at $550^{\circ}C{\sim}600^{\circ}C$. The overall deformations of SP-Creep curves are definitely depended with applied load and creep test temperature and show the creep behaviors of three steps like conventional uniaxial creep curves. The steady state creep rate${\delta}_{ss}$ of SP-Creep curve for miniaturized specimen increases with increasing creep temperature, but the exponential value with creep loading is decreased. The activation energy$(Q_{spc})$ during SP-Creep deformation with various test temperatures shows 605.7kJ/mol that is g.eater than 467.4kJ/mol reported in uniaxial creep test. This may be caused by the difference of stress states during creep deformation In two creep test. But from the experimental results, e.g. SP-Creep curve behaviors, the steady state creep rate${\delta}_{ss}$ with creep temperature, and the exponential value(n) with creep loading, it can be summarized that the SP-Creep test may be a useful test method to evaluate the creep properties of the heat resisting material.

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Effects of Surface Radiation on the Unsteady Natural Convection in a Rectangular Enclosure

  • Baek, Seung-Wook;Kim, Taig-Young
    • International Journal of Aeronautical and Space Sciences
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    • v.3 no.1
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    • pp.95-104
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    • 2002
  • Numerical solution of the full Navier-Stokes equation as well as the energy equation has been obtained for the unsteady natural convection in a rectangular enclosure. One side wall was maintained at very high temperature simulating fires. Especially the effect of surface radiation was taken into account. While the enclosed air was assumed to be transparent, the internal walls directly interacted one another through the surface radiation. Due to a significant temperature difference in the flow field, the equation of state was used instead of the Boussinesq approximation. It was found that the rapid heating of the adiabatic ceiling and floor by the incoming radiation from the hot wall made the evolution at thermo-fluid field highly unstable in the initial period. Therefore, the secondary cells brought about at the floor region greatly affected the heat transfer mechanism inside the enclosure. The heat transfer rate was augmented by the radiation, resulting in requiring less time for the flow to reach the steady state. At the steady state neglecting radiation two internal hydraulic jumps were clearly observed in upper/left as well as in lower/right comer. However, the hydraulic jump in the lower/right comer could not be observed for the case including radiation due to its high momentum flow over the bottom wall. Radiation resulted in a faster establishment of the steady state phenomena.

NUMERICAL STUDY OF DROPLET VAPORIZATION AND COMBUSTION AT HIGH PRESSURE AND HIGH TEMPERATURE

  • KOO J.-Y.;KO J.-B.
    • International Journal of Automotive Technology
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    • v.6 no.6
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    • pp.563-570
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    • 2005
  • A numerical study of high pressure and temperature droplet vaporization and combustion is conducted by formulating one dimensional evaporation model and single-step chemical reaction in the mixture of hydrocarbon fuel and air. The ambient pressure ranged from atmospheric conditions to the supercritical conditions. In order to account for the real gas effect on fluid p-v-T properties in high pressure conditions, the modified Soave-Redlich-Kwong state equation is used in the evaluation of thermophysical properties. Some computational results are compared with Sato's experimental data for the validation of calculations in case of vaporization. The comparison between predictions and experiments showed quite a good agreement. Droplet surface temperature increased with increasing pressure. Ignition time increased with increasing initial droplet diameter. Temporal or spatial distribution of mass fraction, mass diffusivity, Lewis number, thermal conductivity, and specific heat were presented.

A New Method of HTS Material Synthesis by Combination of MCA and SHS

  • Korobova, N.;Soh, Dea-Wha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1270-1273
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    • 2004
  • The combination of methane-chemical activation and Self-propagating High-temperature synthesis (SHS) has widened the possibilities for both methods. For YBCO systems the investigation showed that a short-term mechano-chemical activation of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors of YBCO composition with a grain size d < $1{\mu}m$ is developed. The specific feature of the technique is formation of the $YBa_2Cu_3O_{7-x}$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors (HTS) are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples investigated.

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Temperature Distributions of High Precision Spindle with Built -in Motor (모터내장형 주축의 온도분포해석에 관한 연구)

  • 김용길;김수태;박천홍;김춘배
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.04a
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    • pp.624-628
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    • 1996
  • Unsteady-state temperature distributions in the high precision spindle system with built-in motor are studied. For the analysis, three dimensional model is built for the high precision spindle. The three dimensional model includes the estimation on the amount of heat generation of bearing and built-in motor and the thermal characteristic values such as heat transfer coefficient. Temperature distributions are computed using the finite element method. Analysis results are compared with the measured data. Analysis shows that temperature distributions of high precision spindle system can be estimated resonably using the three dimensional model through the finite element method.

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Analysis on the Thermal Characteristics of Spindle of a High Precision Lathe (고정밀 선반 주축계의 열특성 해석)

  • 김용길
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.6 no.3
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    • pp.44-51
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    • 1997
  • Unsteady-state temperature distributions and thermal deformations of the spindle of a high precision lathe are studied in this paper. Three dimensional model is built for analysis, and the amount of heat generation of bearing and the thermal characteristic values including heat transfer coefficient are estimated. Temperature distributions and thermal deformations of a model are analyzed using the finite element method and the thermal boundary values. Numerical results are compared with the measured data. The results show that the thermal deformations and the temperature distributions of the dpindle of a high precision lathe can be reasonably estimated using the three dimensional model and the finite element method.

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Combination of MCA and SHS for Material Synthesis

  • Soh, Dea-Wha;N., Korobova
    • Journal of the Speleological Society of Korea
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    • no.78
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    • pp.1-8
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    • 2007
  • The combination of mechano-chemical activation (MCA)and Self-propagating High-temperature Synthesis (SHS) has widened the technical possibilities for both methods. For YBCO systems the investigation showed that a short-term MCA of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors (HTS) of YBCO composition with a grain size d <1m is developed using combination of MCA and SHS. The specific feature of the technique is formation of the $YBa_2Cu_3O_7-$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples.

Transient cooling experiments with a cooper block in a subcooled flow boiling system (과냉비등류에 있어서 동블록을 이용한 과도적 냉각실험)

  • 정대인;김경근;김명환
    • Journal of Advanced Marine Engineering and Technology
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    • v.11 no.1
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    • pp.72-79
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    • 1987
  • When the wall temperature is very high, a stable vapor film covers the heat transfer surface. The vapor film creates a strong thermal resistance when heat is transferred to the liquid though it. This phenomenon, called "film boiling" is very important in the heat treatment of metals, the design of cryogenic heat exchangers, and the emergency cooling of nuclear reactors. In the practical engineering problems of the transient cooling process of a high temperature wall, the wall temperature history, the variation of the heat transfer coefficients, and the wall superheat at the rewetting points, are the main areas of concern. These three areas are influenced in a complex fashion such factors as the initial wall temperature, the physical properties of both the wall and the coolant, the fluid temperature, and the flow state. Therefore many kinds of specialized experiments are necessary in the creation of precise thermal design. The object of this study is to investigate the heat transfer characteristics in the transient cooling process of a high temperature wall. The slow transient cooling experiment was carried out with a copper block of high thermal capacity. The block was 240 mm high and 79 mm O.D.. The coolant flowed throuogh the center of a 10 mm diameter channel in the copper block. In the copper block, three sheathed thermocouples were placed in a line perpendicular to the flow. These thermocouples were used to take measurements of the temperature histories of the copper block.

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Multiscale Simulation of Yield Strength in Reduced-Activation Ferritic/Martensitic Steel

  • Wang, Chenchong;Zhang, Chi;Yang, Zhigang;Zhao, Jijun
    • Nuclear Engineering and Technology
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    • v.49 no.3
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    • pp.569-575
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    • 2017
  • One of the important requirements for the application of reduced-activation ferritic/martensitic (RAFM) steel is to retain proper mechanical properties under irradiation and high-temperature conditions. To simulate the yield strength and stress-strain curve of steels during high-temperature and irradiation conditions, a multiscale simulation method consisting of both microstructure and strengthening simulations was established. The simulation results of microstructure parameters were added to a superposition strengthening model, which consisted of constitutive models of different strengthening methods. Based on the simulation results, the strength contribution for different strengthening methods at both room temperature and high-temperature conditions was analyzed. The simulation results of the yield strength in irradiation and high-temperature conditions were mainly consistent with the experimental results. The optimal application field of this multiscale model was 9Cr series (7-9 wt.%Cr) RAFM steels in a condition characterized by 0.1-5 dpa (or 0 dpa) and a temperature range of $25-500^{\circ}C$.