• Title/Summary/Keyword: high temperature state

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A Study on a Palladium-Silicon Garbide Schottky Diode as a Hydrogen Gas Sensor (Pd-SiC 쇼트키 다이오드의 수소 가스 감지 특성)

  • Lee, Joo-Hun;Lee, Young-Hwan;Kim, Chang-Kyo;Cho, Nam-Ihn
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.858-860
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    • 1998
  • A Pd-SiC Schottky diode for detection of hydrogen gas operating at high temperature was fabricated. Hydrogen-sensing behaviors of Pd-SiC Schottky diode have been analyzed as a function of hydrogen concentration and temperature by I-V and ${\Delta}I$-t methods under steady-state and transient conditions. The effect of hydrogen adsorption on the barrier height was investigated. Analysis of the steady-state kinetics using I-V method confirmed that the atomistic hydrogen adsorption process is responsible for the barrier height change in the diode.

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Description and Discussion of the Current State of the Knowledge about the Leidenfrost Phenomenon (Leidenfrost 현상에 관한 최근 기술현황분석)

  • Moon Ki Chung;Young Whan LEE
    • Nuclear Engineering and Technology
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    • v.14 no.4
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    • pp.204-218
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    • 1982
  • The purpose of this report is to describe and discuss the current state of the knowledge about the Leidenfrost phenomenon which is a heavily studied subject in the field of boiling heat transfer. The strong interest is due to reactor safety considerations since it is desirable to obtain a better understanding of the physical mechanisms involved in the rewetting of high temperature surface after a loss of coolant accident. Brief survey of the theoretical and experimental results from available open literatures indicates that considerable discrepancy exists in the prediction of the Leidenfrost temperature at the elevated pressures and more investigations are needed in this area.

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리튬이차전지용 Polyacenic Semiconductor Material의 전기화학적 특성

  • ;;N. Oyama
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.407-410
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    • 1998
  • During the past decade, substantial research effort has been directed into the development of rechargeable lithium batteries. Although some improvements in cycle life and efficiency have been achieved, the reversibility of the lithium electrode remains as a significant problem in aprotic solvent based electrolyte. The major problems limiting cycle life are short circuits resulting from growth of lithium dendrites, and macroscopic shape changes during the recharge process. As an anode material of lithium rechargeable battery, amorphous carbon materials have been studied extensively because of their high electrochemical performance. The polyacene materials prepared from phenol refine at relatively low temperature(550∼750$^{\circ}C$) show a highly Li-doped state up C$_2$Li state without liberation of Li cluster. So it has largely layered distance 4${\AA}$. The Li storage mechanism as well as the large hysterisis observed in the voltage-capacity profile of the amorphous carbone materials are still the subjects of controversy. We prepared each polyacene material various temperature and investigated electrochemical property. The mole ratio of [H]/[C] is 0.027∼0.015 range.

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Nonactivaed adsorption of $CH_3_Cl$ on Si(100)-2$\times$1 studied by LEED, AES and semiempirical method.

  • Lee, Junyoung;Kim, Sehun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.157-157
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    • 2000
  • The adsorption processes of methyl chloride on Si(100)-2$\times$1 have been studied by low energy electron diffraction (LEED), Auger electron spectroscopy (AES) and semiempirical PM3 calculations. The dissociative adsorption of the methyl chloride on Si(100) takes place without breaking of the silicon dimer with high efficiency. For adsorption at the room temperature, the existence of a precursor state is confirmed by the behavior of the sticking probability depending on the coverage and temperature. From AES measurements, the determined activation barrier of adsorption ($\Delta$ Hads) is -28.4 kj/mol. This results indicate that the dissociative process is nonactivated. The optimized precursor state of CH3Cl on the Si(100)-2$\times$1 surface was determined by PM3 calculations based on a cluster model.

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PEO/PPC based Composite Solid Electrolyte for Room Temperature Operable All Solid-State Batteries (상온에서 작동되는 전고체전지 용 PEO/PPC 기반의 복합 고체 전해질)

  • Shin, Sohyeon;Kim, Sunghoon;Cho, Younghyun;Ahn, Wook
    • Journal of the Korean Electrochemical Society
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    • v.25 no.3
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    • pp.105-112
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    • 2022
  • For the commercialization of all-solid-state batteries, it is essential to develop a solid electrolyte that can be operable at room temperature, and it is necessary to manufacture all-solid-state batteries by adopting materials with high ionic conductivity. Therefore, in order to increase the ionic conductivity of the existing oxide-based solid, Li7La3Zr2O12 (LLZO) doped with heterogeneous elements was used as a filler material (Al and Nb-LLZO). An electrolyte with garnet-type inorganic filler doped was prepared. The binary metal element and the polymer mixture of poly(ethylene oxide)/poly(propylene carbonate) (PEO/PPC) (1:1) are uniformly manufactured at a ratio of 1:2.4, The electrochemical performance was tested at room temperature and 60 ℃ to verify room temperature operability of the all-solid-state battery. The prepared composite electrolyte shows improved ionic conductivity derived from co-doping of the binary elements, and the PPC helps to improve the ionic conductivity, thereby increasing the capacity of all-solid-state batteries at room temperature as well as 60 ℃. It was confirmed that the capacity retention rate was improved.

Enhance photoelectric efficiency of PV by optical-thermal management of nanofilm reflector

  • Liang, Huaxu;Wang, Baisheng;Su, Ronghua;Zhang, Ao;Wang, Fuqiang;Shuai, Yong
    • Advances in nano research
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    • v.13 no.5
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    • pp.475-485
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    • 2022
  • Crystalline silicon photovoltaic cells have advantages of zero pollution, large scale and high reliability. A major challenge is that sunlight wavelength with photon energy lower than semiconductor band gap is converted into heat and increase its temperature and reduce its conversion efficiency. Traditional cooling PV method is using water flowing below the modules to cool down PV temperature. In this paper, the idea is proposed to reduce the temperature of the module and improve the energy conversion efficiency of the module through the modulation of the solar spectrum. A spectrally selective nanofilm reflector located directly on the surface of PV is designed, which can reflect sunlight wavelength with low photon energy, and even enhance absorption of sunlight wavelength with high photon energy. The results indicate that nanofilm reflector can reduce spectral reflectivity integral from 9.0% to 6.93% in 400~1100 nm wavelength range, and improve spectral reflectivity integral from 23.1% to 78.34% in long wavelength range. The nanofilm reflector can reduce temperature of PV by 4.51℃ and relatively improved energy conversion efficiency of PV by 1.25% when solar irradiance is 1000 W/m2. Furthermore, the nanofilm reflector is insensitive in sunlight's angle and polarization state, and be suitable for high irradiance environment.

SOME CHARACTERISTICS OF THE CERAMIC SUPERCONDUCTORS PHYSICS PROERTIES AND CHEMICAL ASPECTS

  • Escudero, Roberto
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1992.05a
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    • pp.17-17
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    • 1992
  • The ceramic high transition temperature superconducting materials present many interesting characteristics that will be analysed from two points of view: physical behavior, and chemical aspects. From the first point of view, these materials display an enormous variety of different physical properties. At low doping levels the normal state shows antiferromagnetism and insulating behavior. At intermediate doping levels, an anomalous metallic state appears and, the optimum Tc in the superconducting state is generated. With increasing doping a normal metallic state develops and superconductivity starts to disappear. Many of the physical phenomena that describe the overall behavior when doping levels are changed will be discussed. From the poing of view of the chemical aspects. we well discuss some of the problems involved in the methods of preparation with particular emphasis on defects, crystal structures, critical currrents, and applications in technology.

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On the route towards Si-based full color LED microdisplays for NTE applications

  • Smirnov, A.;Labunov, V.;Lazarouk, S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.727-731
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    • 2005
  • Design and manufacturing process of a full color LED microdislay fabricated by standard CMOS technology and containing an array of aluminum / nanostructured porous silicon reverse biased light emitting Schottky diodes will be discussed. Being of a solid state construction, this microdisplays are cost-effective, thin and light in weight due to very simple device architecture. Its benefits include also super high resolution, wide viewing angles, fast response time and wide operating temperature range. The advantages of full integration of an LED-array and driving circuitry onto a Si-chip will be also discussed.

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High-temperature Drying of Southern Pine Lumber by Green sorting (건조전(乾燥前) 선별(選別)에 의한 Southern pine재(材)의 고온건조(高溫乾燥))

  • So, Won-Tek;Taylor, Fred W.
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.2
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    • pp.51-60
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    • 1992
  • This study was performed to investigate the effect of green sorting before drying on the high-temperature drying characteristics of southern yellow pine dimension lumber(2"${\times}$6"${\times}$12'). To test the advantages of weight sorting, green lumber was seperated into heavy(above 55 1b), medium(50-55 1b), and light(below 50 1b)weight classes. Pieces in each weight class were subgrouped into high(above 35%) and low(below 30%) latewood groups. Groups were dried and seperated by a standard commercial high-temperature schedule; dry bulb temperature $245^{\circ}$ F, wet bulb temperature $180^{\circ}$ F, and air velocity 1200fpm. The results obtained were as follows; 1. There was a highly significant correlation between annual rings per inch(X) and percent-latewood(Y). The regression equation was Y=24, 5047+1.3272X. 2. There were highly significant correlations between either annual rings per inch($X_1$) or percent-latewood($X_2$) a.d specific gravity in green wood(Y). Their regression equations were Y=0.4260+0.0081$X_1$ and Y=0.3749+0.0029$X_2$, respectively. 3. Heavier weight charges dried more slowly than lighter weight charges. 4. Board-to-board variation in green or dry moisture content was less for all seperate weight classes than for unseperated control charges. 5. Lower latewood pieces had higher initial moisture content than higher latewood pieces, and then drying time for lower late wood pieces was longer than higher latewood pieces.

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Studies on the fabrication and properties of $La_ 0.7Sr_0.3MnO_3$cathode contact prepared by glycine-nitrate process and solid state reaction method for the high efficient solid oxide fuel cells applications 0.3/Mn $O_{3}$ (고효율 고체산화물 연료전지 개발을 위한 자발 착화 연소 합성법과 고상반응법에 의한 $La_ 0.7Sr_0.3MnO_3$ 양극재료 제조 및 물성에 관한 연구)

  • Shin, Woong-Shun;Park, In-Sik;Kim, Sun-Jae;Park, Sung
    • Electrical & Electronic Materials
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    • v.10 no.2
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    • pp.141-149
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    • 1997
  • L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ powders were prepared by both GNP(Glycine-Nitrate Process) and solid state reaction method in various of calcination temperature(800-1000.deg. C) and time in air. Also, L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ cathode contacts on YSZ(Yttria-Stabilized Zirconia) substrate were prepared by screen printing and sintering method as a function of sintering temperature(1100-1450.deg. C) in air. Sintering behaviors have been investigated by SEM(Scanning Electron Microscope) and porosity measurement. Compositional and structural characterization were carried out by X-ray diffractometer and ICP AES(Inductively Coupled Plasma-Atomic Emission Spectrometry) analysis. Electrical characterization was carried out by the electrical conductivity with linear 4 point probe method. As the calcination period increased in solid state reaction method, L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ phase increased. Although L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ single phase was obtained only for 48hrs at 1000.deg. C, in GNP method it was easy to get single and ultra-fine L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ powders with submicron particle size at 650.deg. C for 30min. The particle size and thickness of L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ cathode contact by solid state reaction method did not change during the heat treatment, while those by GNP method showed good sintering characteristics because initial powder size fabricated from GNP method is smaller than that fabricated from solid state reaction method. Based on enthalpy change from thermodynamic data and ICP-AES analysis, it was suggested to make cathode contact in composition of (L $a_{0.7}$S $r_{0.3}$)$_{0.91}$ Mn $O_{3}$ which have little second phase (L $a_{2}$Z $r_{2}$ $O_{7}$) for high efficient solid oxide fuel cells applications. As (L $a_{0.7}$S $r_{0.3}$)$_{0.91}$Mn $O_{3}$ cathode contact on YSZ substrate was sintering at 1250.deg. C the temperature that liquid phase sintering did not occur. It was possible to obtain proper cathode contacts with electrical conductivity of 150(S/cm) and porosity content of 30-40%.m) and porosity content of 30-40%.

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