• Journal of Soil and Groundwater Environment
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• v.8 no.2
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• pp.62-69
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• 2003

The aim of research is the evaluation of the $Cr^{6+}$ emission features of the liquid injection through emission experiments in varying conditions, based on a field-mixing ratio. The results showed that the content of $Cr^{6+}$ content in cement measured had an Ordinary Potland Cement (OPC) of 25.3 mg/kg, which constitute the largest portion among the other materials. Likewise, the emission experiment of homo-gel and sand-gel generally satisfied the standard of KSLT (Korea Standard Leaching Test) in waste of 1.5 mg/L, but in case of the standard of KSLT in soil the emission of OPC $Cr^{6+}$ of 4.85 mg/kg. These conditions is a little exceeded the criteria in the ‘Ga’ area in terms of Korea Soil Environmental Preservation Law. In addition, results generated by the mock-up injection facilities revealed that $Cr^{6+}$ emission increased as Water/Cement and injection pressure increased. At injection pressure higher than 4 kg/㎤, $Cr^{6+}$ emission exceeded the water preservation standard of 0.5 mg/L. Similarly, a pattern experiment of C $r^{6+}$ emission according to pH was conducted, in order to evaluate the $Cr^{6+}$ emission features of grout materials in leachate below pH 5 such as pH 4 acid rain or landfill. Results show that $Cr^{6+}$ emission dramatically increased in high acidic or basic state. It indicates that $Cr^{6+}$ emission will probably increase in an environment where grout materials are injected. On the other hand, concentration of leachate was determined in areas where grout materials are used. The results show that the concentration of emission in an ultra purity condition does not manifest intensity, and is affected in the OPC>MC>SC order. It means that the pollutants or $Cr^{6+}$ emission increases with decreasing concentration. As such, $Cr^{6+}$ emission will probably exceed the countermeasure criteria according to the types of gout materials. Similarly, high pressure or injection will cause increased $Cr^{6+}$ emission. Therefore, the selection of materials or mixing ratio should be considered in general as well as according to specific industries, based on the strength and pH of $Cr^{6+}$ emission.

• Journal of the Korea Institute of Building Construction
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• v.15 no.1
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• pp.1-7
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• 2015

The objective of this study is to develop a high-performance foamed concrete made with a new mixture proportioning as an alternative of autoclaved lightweight concrete (ALC) block. For the early-strength gain of the foamed concrete under an atmospheric curing condition, the binders and chemical agents were specially contrived as follows: 3% anhydrous gypsum was added to ordinary portland cement (OPC) in which $3CaO{\cdot}SiO_2$ content was controlled to be above 60%; and the content of polyethylene glycol alkylether in a polycarboxylate-based water-reducing agent was modified to be 28%. Using these binders and chemical agents, 11 mixes were prepared with the parameters of W/B ratio (30% to 20% in a interval of 2.5%) and unit binder content ($400kg/m^3$ to $650kg/m^3$ in a interval of $50kg/m^3$). The quality and availability of the mixed foamed concrete were examined according to the minimum requirements specified in the KS for ALC block and existed conventional foamed concrete. The measured properties satisfied the minimum requirement of KS for ALC block and proved that the developed high-performance foamed concrete had considerable potential for practical application.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.313-323
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• 1998

Fluidity retention of concrete used high range water reducing AE agent(HWAE) is varied according to main component, dosage amount and dosing method of HWAE. The type and substitution ratio of mineral admixture also have influence on the fluidity retention of concrete used HWAE. In this study, for the purpose of improving the fluidity retention in concrete used HWAE. 3 types of HWAE and ground granulated blast furnace slag(SG) are used in cement paste, mortar and concrete varing dosage amount and dosing time of HWAE and substitution ratio of SG respectively. According to using the HWAE of naphthalene sulfonates and SG, the fluidity retention of mortar and concrete is improved remarkably. And after 30 min, dosing method of HWAE is very effective in improving the fluidity retension and strength of concrete regardless of type of HWAE.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.12
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• pp.165-172
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• 2019

The aim of the research is to evaluate the influence of various replacing ratios of supplementary cementitious materials(SCMs) such as fly ash(FA), blast furnace slag(BS), and both FA and BS on general properties including segregation resistance as a powder based high fluidity concrete of normal strength grade with water-to-cement ratio 0.40. Specifically, by replacing the SCMs with low density powders, it was assessed that the decreased segregation resistance due to the decreased viscosity by J-ring test. As a result of the experiment, from the general test, the mixtures with SCMs showed increased segregation resistance by increased viscosity as the references, while some segregation was shown from J-ring test due to the decreased density of fresh state mixture related with the capacity of delivering coarse aggregate.

• Tunnel and Underground Space
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• v.31 no.6
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• pp.428-439
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• 2021

A spray-on membrane is a material composed of a polymer, and is a spray-type material that is expected to be able to replace materials such as existing shotcrete or sheet membrane for support or waterproofing purposes. In the previous studies, it is expected that the thickness of the support material such as shotcrete can be reduced if the spray-on membrane is additionally installed on the existing cement-based support materials. In this study, a three-point bending test was performed by a spray-on membrane on the high-performance shotcrete on the outside, and comparison was made between the case where high-performance shotcrete and a spray-on membrane were installed. As a result of comparing the values calculated through the standard test and the real-size bending test, there was no significant difference in terms of flexural strength, but it was found that there was a difference in flexural toughness.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.2
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• pp.185-191
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• 2017

The objective of this paper is to investigate the effect of waste refractory powder(WRP) and desulfurization gypsum(FGD) as activators on the flow properties and the strength development of high volume blast furnace slag mortar incorporating illite(BSM) having adsorption and deodorization. To fabricate the BSMs with 60% of W/B, blast furnace slag are incorporated with 45% and 65%, respectively. WRP and FGD are substituted from 5 to 10%. Test results indicate that the flow is decreased with increase of WRP and FGD, while increase of WRP and FGD enhance the compressive strength due to accelerated reaction of blast furnace slag, The use of illite results in a decrease of compressive strength. pH has increasing tendency until 7days, while it has reduction. In this paper, optimal dosages of WRP and FGD are believed to be around 5% each.

• Journal of the Korea Institute of Building Construction
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• v.17 no.4
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• pp.341-348
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• 2017

The performance degradation of concrete pavement by winter deicer is very serious in Korea, and its maintenance and rehabilitation brings a high expense. Therefore, a suitable method for rehabilitation of such concrete pavement and repair material of proper performance are required. In this study, the properties of compressive strength, ability to resist chloride ion penetration, and properties of dry shrinkage of magnesium phosphate ceramics were assessed to evaluate its applicability as a repair material for concrete pavement in Korea. As a result, the mortar flow showed a normal level of 190 mm, but the viscosity was high and the self-flow ability was poor. The setting time was 12 minutes, leading very rapid-hardening, and thus a prompt work was required. The compressive strength of mortar was 38.4MPa in 2 hours, 73.8MPa in 24 hours, and 111.0MPa in 28 days, showing a significant level. As a result of the test to chloride ion penetration resistance, mortar showed 143 Coulombs, and concrete showed 172.6 Coulombs, which fell under very low level. The drying shrinkage of MPC concrete in 40 days was below $60{\times}10-6$, and comparing with normal cement concrete, it showed the level below 1/10 of other concrete to secure an excellent volume stability. As above, magnesium phosphate ceramics has excellent strength performance, chloride ion penetration resistance, and volume stability, and this in the future shall be used in construction under the consideration of working time or workability, requiring further improvement for such performance.

• Journal of the Korea Concrete Institute
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• v.18 no.4 s.94
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• pp.449-458
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• 2006

The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the cement. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_2\;and\;Al_2O_3$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^-$ through alkali activators. Alkali activators were used for supplying it with additional $OH^-$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also, according to scanning electron microscopy and X-Ray diffraction, the main reaction product in the alkali activated fly ash mortar is Zeolite of $Na_6-(AlO_2)_6-(SiO_2)_{10}-12H_2O$ type.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.3
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• pp.307-315
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• 2016

The aim of this research is analyzing the fundamental properties and autogenous shrinkage reducing performance of 70 and 100MPa grade high performance concrete including emusified refined cooking oil(ERCO) under the mock-up conditions. As a results of experiment, the mixture contained 0.5% of ERCO showed slightly decreased slump flow while the slump was increased and segregation resistance performance was improved as 2.5 of EIS. For air content, all mixtures satisfied target air content with increased unit weight and delayed setting time with ERCO addition. In the case of compressive strength, when ERCO was added 0.5%, the result of approximately 5 to 10% of increased compressive strength was observed. For the autogenous shrinkage, ERCO contributed on 20-30% of shrinkage reducing performance comparing to Plain mixture without ERCO. It is considered that capillary pore filling action of soap particles occurred by the reaction of ERCO in cement paste between fatty aicd and calcium hydroxide contributed the shrinkage reducing performance. Based on these mock-up test results, application of the high performance concrete mixture with ERCO on CFT actual structure was decided.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.95-102
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• 2015

In this paper, the effects of sodium hydroxide (NaOH) and aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) dosage on strength properties were investigated. For evaluating the property related to the dosage of alkali activator, sodium hydroxide (NaOH) of 4% (N1 series) and 8% (N2 series) was added to 1~5% (K1~K5) dosage of aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) and 1% (C1) and 2% (C2) dosage of calcium oxide (CaO). W/B ratio was 0.5 and binder/ fine aggregate ratio was 0.5, respectively. Test result clearly showed that the compressive strength development of alkali-activated slag cement (AASC) mortars were significantly dependent on the dosage of NaOH and $AlK(SO_4)_2{\cdot}12H_2O$. The result of XRD analysis indicated that the main hydration product of $NaOH+AlK (SO_4)_2{\cdot}12H_2O$ activated slag was ettringite and CSH. But at early ages, ettringite and sulfate coated the surface of unhydrated slag grains and inhibited the hydration reaction of slag in high dosage of $NaOH+AlK(SO_4)_2{\cdot}12H_2O$. The $SO_4{^{-2}}$ ions from $AlK(SO_4)_2{\cdot}12H_2O$ reacts with CaO in blast furnace slag or added CaO to form gypsum ($CaSO_4{\cdot}2H_2O$), which reacts with CaO and $Al_2O_3$ to from ettringite in $NaOH+AlK(SO_4)_2{\cdot}12H_2O$ activated slag cement system. Therefore, blast furnace slag can be activated by $NaOH+AlK(SO_4)_2{\cdot}12H_2O$.