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Thermal Durability of 4YSZ Thermal Barrier Coating Deposited by Electron Beam PVD (전자빔을 이용한 물리기상증착법으로 제조된 열차폐용 4 mol% YSZ 코팅의 내열특성)

  • Park, Chanyoung;Yang, Younghwan;Kim, Seongwon;Lee, Sungmin;Kim, Hyungtae;Lim, Daesoon;Jang, Byungkoog;Oh, Yoonsuk
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.460-466
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    • 2013
  • 4 mol% Yttria-stabilized zirconia (4YSZ) coatings with $200{\mu}m$ thick are fabricated by Electron Beam Physical Vapor Deposition (EB-PVD) for thermal barrier coating (TBC). $150{\mu}m$ of NiCrAlY based bond coat is prepared by conventional APS (Air Plasma Spray) method on the NiCrCoAl alloy substrate before deposition of top coating. 4 mol% YSZ top coating shows typical tetragonal phase and columnar structure due to vapor phase deposition process. The adhesion strength of coating is measured about 40 MPa. There is no delamination or cracking of coatings after thermal cyclic fatigue and shock test at $850^{\circ}C$.

The Textiles and the Performance Level in Developing the Pesticide Proof Clothing (기능성 농약방제복 개발을 위한 소재 및 성능에 관한 연구)

  • Hwang, Kyoung-Sook;Kim, Kyung-Ran;Lee, Kyung-Suk;Kim, Hyo-Cher;Kim, Kyung-Su;Baek, Yoon-Jeong
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.11
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    • pp.1611-1620
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    • 2007
  • The precaution to spray with agricultural chemicals is very important, in particular personal protective equipment against pesticide in order to protect farmers# pesticide poisoning. The Ministry of Agriculture and Forestry has proclaimed the announcement of pesticide proof clothing(PPC) in 1983, and revised it in 1987. The announcement had many performance items to achieve the high-quality protective clothing for pesticide including weight, density, force strength, dimensional change(in washing and drying), fastness(dyeing, washing, sweating and rubbing) and water resistance of clothes. Announcement of the PPC has better durability and penetration resistance function than former days, but the plenty of farmers didn#t wear it because of the intolerable heat. To increase wearing rates, the pesticide proof clothing must be estimated the water-vapour resistance. From the results, the developed PPC with polyester treated water-repellent showed the more excellent comfort than an existing PPC with nylon coated polyurethane. But the developed PPC appeared to have the low water-vapour resistance. Therefore, it is suggested that the property of pesticide penetration must be evaluated through the field test in the future study.

Study on Geometry Design of Lip-Seal for Automobile Wheel Bearing Considering Drag Torque and Sealing Performance (자동차용 횔베어링의 기동토크와 밀봉성을 고려한 립 씰의 형상 설계에 관한 연구)

  • Huh, Young-Min;Lee, Kwang-O;Sim, Tae-Yang;Kang, Sung-Soo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.4
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    • pp.10-16
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    • 2007
  • A rubber seal for wheel bearing which has been mainly applied to car wheel supporting device is required to have both high sealing performance and drag torque. Because of severe operational conditions like infiltration of mud or splashed water, the importance of rubber seal which is aimed for leakage prevention of grease and effective blocking of foreign substances has been increasing continuously. The sealing performance of this seal depends on several factors such as materials of seal, friction conditions of contact regions and geometry of seals and so on. We have focused on the effects of geometric characteristics such as the angle of main lip, interference between lip edge and inner metallic ring. In this study, the optimization of geometric variables was performed using the finite element analysis. For the sake of finite element analysis, uniaxial tensile tests were conducted and several constants for Mooney-Rivlin's equation were obtained. According to the results of this study, mock-up bearing was made. To verify this study, drag torque and mud spray test were preformed.

Selective NO2 Sensors Using MoS2-MoO2 Composite Yolk-shell Spheres

  • Jeong, Seong Yong;Choi, Seung Ho;Yoon, Ji-Wook;Won, Jong Min;Kang, Yun Chan;Park, Joon-Shik;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.24 no.3
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    • pp.151-154
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    • 2015
  • The gas sensing characteristic of $MoS_2-MoO_2$ composite yolk-shell spheres were investigated. $MoO_3$-carbon composite spheres were prepared by ultrasonic spray pyrolysis of aqueous droplets containing Mo-source and sucrose in nitrogen, which were converted into $MoO_3$ yolk-shell spheres by heat treatment at $400^{\circ}C$ in air. Subsequently, $MoS_2-MoO_2$ composite yolk-shell spheres were prepared by the partial sulfidation of $MoO_3$. The $MoS_2-MoO_2$ composite yolk-shell spheres showed relatively low and irreversible gas sensing characteristics at < $200^{\circ}C$. In contrast, the sensor showed high and reversible response (S=resistance ratio) to 5 ppm $NO_2$ (S=14.8) at $250^{\circ}C$ with low cross-responses (S=1.17-2.13) to other interference gases such as ethanol, CO, xylene, toluene, trimethylamine, $NH_3$, $H_2$, and HCHO. The $MoS_2-MoO_2$ composite yolk-shell spheres can be used as reliable sensors to detect $NO_2$ in a selective manner.

Control of Algal Blooms in Eutrophic Water Using Porous Dolomite Granules

  • Huh, Jae-Hoon;Choi, Young-Hoon;Lee, Shin Haeng;Cheong, Sun Hee;Ahn, Ji Whan
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.108-113
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    • 2017
  • The use of aluminum-based coagulants in water pretreatment is being carefully considered because aluminum exposure is a risk factor for the onset of Alzheimer's disease. Lightly burned-dolomite kiln dust (LB-DKD) was evaluated as an alternative coagulant because it contains high levels of the healthful minerals calcium and magnesium. An organic pore forming agent (OPFA) was incorporated to prepare porous granules after OPFA removal through a thermal decomposition process. A spray drying method was used to produce uniform and reproducible spherical granules with low density, since fine dolomite particles have irregular agglomeration behavior in the hydration reaction. The use of fine dolomite powder and different porosity granules led to a visible color change in raw algae (RA) containing water, from dark green to transparent colorlessness. Also, dolomite powders and granules exhibited a mean removal efficiency of 48.3% in total nitrogen (T-N), a gradual increase in the removal efficiency of total phosphorus (T-P) as granule porosity increased. We demonstrate that porous dolomite granules can improve the settling time and water quality in summer seasons for the emergent treatment of excessive algal blooms in eutrophic water.

The Effect of Changes in Polymerization Conditions of Orthodontic Acrylic Resin on Maximum Load (Orthodontic Acrylic Resin의 중합조건 변화가 최대하중에 미치는 영향)

  • Lee, Gyu Sun
    • Journal of Technologic Dentistry
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    • v.35 no.2
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    • pp.127-136
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    • 2013
  • Purpose: In order to find out the impact of changes in polymerization conditions of orthodontic acrylic resin on maximum load. Methods: While maintaining mixing ratio 3:1 of polymer and monomer in spray-on way in the production condition of polymerization temperature $25^{\circ}C$ or $37^{\circ}C$ for 10 minutes or 30 minutes of polymerization time by pressure $3kfg/cm^2$ or $6kfg/cm^2$ in the lab maintaining $25^{\circ}C$ of room temperature, the change in maximum load rise rate was tested by producing 5 acrylic resin specimens for orthodontics per group to meet the standards of $25mm{\times}2mm{\times}2mm$ and using INSTRON with the 3rd bar 2mm in diameter and parallel support bending device of $15{\pm}0.1mm$ as test equipment showing 30.00mm/min of crosshead speed, $50{\pm}16$ N/min of load ratio in the laboratory of $24^{\circ}C$ room temperature and as a result, the following results were obtained. Results: 1. When increasing pressure from $3kfg/cm^2$ to $6kfg/cm^2$, maximum load was lowered by -4.285%. 2. When increasing polymerization time from 10 minutes to 30 minutes, maximum load rose by 3.848%. 3. When increasing polymerization temperature from $27^{\circ}C$ to $37^{\circ}C$, maximum load rose by 5.854%. Conclusion: Considering the above test results that polymerization time and polymerization temperature when polymerizing acrylic resin for orthodontics according to changes in working conditions had an impact on the rate of rise of maximum load values but the rate of rise was lowered when increasing pressure from $3kfg/cm^2$ to $6kfg/cm^2$, we came to a conclusion that high pressure more than necessary does not affect the rate of rise of maximum load.

Adhesion Properties of Hot-Melt Pressure Sensitive Adhesives Based on Metallocene Polyolefin (메탈로센 폴리올레핀을 이용한 핫멜트 점착제의 제조 및 특성)

  • Shim, Jaeho;Sung, Ickkyeung;Lee, Jungjoon
    • Journal of Adhesion and Interface
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    • v.14 no.2
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    • pp.95-100
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    • 2013
  • In this study, a series of hot-melt pressure sensitive adhesives (HMPSAs) based on metallocene polyolefin (me-PO) were prepared to investigate their possibility of replacing the HMPSAs based on styrenic block copolymers (SBCs). In addition, to optimize the performance of HMPSAs based on me-PO, several tackifiers having different softening point and molecular weight were evaluated. To achieve the HMPSAs which can satisfy the Dahlquist Criterion, hot melts required over 10% of process oil. To obtain the HMPSAs having low viscosity which can be applied by a spraying type applicator, secondary polymer having relatively low crystallinity was required. And, tackifier having high molecular weight attributed to increasing the cohesive strength of me-PO based HMPSAs.

Preparation of Magnetic Chitosan Microsphere Particles (나노 크기의 마그네타이트 입자를 이용한 자성 키토산 미소구체의 제조)

  • Ko, Sang-Gil;Cho, Jun-Hee;Ahn, Yang-Kyu;Song, Ki-Chang;Choi, Eun-Jung
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.66-70
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    • 2006
  • Magnetite nanoparticles, which have been extensively used in many fields, were encapsulated with a natural polymer, chitosan, to improve their biocompatibility. We have synthesized magnetite $(Fe_3C_4)$ nanoparticles using chemical coprecipitation technique with sodium oleate as surfactant. Nanoparticle size can be varied from 1.2 to 7.4nm by controlling the sodium oleate concentration. Magnetite phase nanoparticles could be observed from X-ray diffraction. Magnetic colloid suspensions containing particles with sodium oleate and chitosan have been prepared. High magnetic property chitosan-microsphere particles were prepared from oleate-coated magnetite suspension using spray method. The surftce, and tile morphology of the magnetic chitosan microsphere particles were characterized using optical microscope and scanning electron microscope. Magnetic hysteresis measurement were performed using a superconducting quantum interference device (SQUID) magnetometer at room temperature to investigate the magnetic properties of the chitosan microspheres including magnetite nanoparticles. The SQUID measurements revealed superparamagnetism of nanoparticles.

A Study for the Fire Hazard Evaluation through the Fire Simulation of an Apartment Fire Accident (아파트 화재 사례 전산모사를 통한 화재위험성 평가에 관한 연구)

  • Jeon, Heung-Kyun;Choi, Young-Sang;Choo, Hong-Lok
    • Fire Science and Engineering
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    • v.24 no.4
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    • pp.69-78
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    • 2010
  • In this study, Fire Hazards were evaluated through computer simulation using FDS program for an apartment fire accident. The results of fire simulation showed that the maximum heat release rate in the case of no sprinklers activation was 7,700 kW which was about 16 times of that in the case of sprinklers activation, 497 kW and there was a very high fire hazard due to the backdraft phenomenon when the door of fire room was forced to open. Regarding the hazard time of fire room temperature and detection time of detectors, available evacuation time was 32.5 seconds of minimum to 53.5 seconds of maximum. In the case of sprinklers activation, fire hazard in the apartment was showed to be very low due to the fire control by the spray cooling of sprinklers. This study shows that what a important function for fire safety is the activations of fire sprinkler system and emergency alarm system and what a large loss can cause if these systems don’t activate in fire accidents.

Microstructure and Liquid Al Erosion Property of Tribaloy T-800 Coating Material Manufactured by Laser Cladding Process (Laser Cladding 공정으로 제조된 Tribaloy T-800 코팅 소재의 미세조직 및 용융 Al 침식 특성)

  • Kim, Kyoung-Wook;Ham, Gi-Su;Park, Sun-Hong;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.210-218
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    • 2020
  • A T-800 (Co-Mo-Cr) coating material is fabricated using Co-Mo-Cr powder feedstock and laser cladding. The microstructure and melted Al erosion properties of the laser-cladded T-800 coating material are investigated. The Al erosion properties of the HVOF-sprayed MoB-CoCr and bulk T-800 material are also examined and compared with the laser-cladded T-800 coating material. Co and lave phases (Co2MoCr and Co3Mo2Si) are detected in both the laser-cladded T-800 coating and the bulk T-800 materials. However, the sizes of the lave phases are measured as 7.9 ㎛ and 60.6 ㎛ for the laser-cladded and bulk T-800 materials, respectively. After the Al erosion tests, the erosion layer thicknesses of the three materials are measured as 91.50 ㎛ (HVOF MoB-CoCr coating), 204.83 ㎛ (laser cladded T-800), and 226.33 ㎛ (bulk T-800). In the HVOF MoB-CoCr coating material, coarse cracks and delamination of the coating layer are observed. On the other hand, no cracks or local delamination of the coating layer are detected in the laser T-800 material even after the Al erosion test. Based on the above results, the authors discuss the appropriate material and process that could replace conventional bulk T-800 materials used as molten Al pots.