• Title/Summary/Keyword: high resolution spectrum

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Metal-insulator Transition in $(Sr_{0.75},\;La_{0.25})TiO_3$ Ultra-thin Films

  • Choi, Jae-Du;Choi, Eui-Young;Lee, Yun-Sang;Lee, Jai-Chan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.19.2-19.2
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    • 2011
  • The $(Sr_{0.75},\;La_{0.25})TiO_3$ (SLTO) ultra-thin films with various thicknesses have been grown on Ti-O terminated $SrTiO_3$(100) substrate using Laser-Molecular Beam Epitaxy (Laser MBE). By monitoring the in-situ specular spot intensity oscillation of reflection high energy electron diffraction (RHEED), we controlled the layer-by-layer film growth. The film structure and topography were verified by atomic force microscopy (AFM) and high resolution thin film x-ray diffraction by the synchrotron x-ray radiation. We have also investigated the electronic band structure using x-ray absorption spectroscopy (XAS). The ultra thin SLTO film exhibits thickness driven metal-insulator transition around 8 unit cell thickness when the film thickness progressively reduced to 2 unit cell. The SLTO thin films with an insulating character showed band splitting in Ti $L_3-L_2$ edge XAS spectrum which is attributed to Ti 3d band splitting. This narrow d band splitting could drive the metal-insulator transition along with Anderson Localization. In optical conductivity, we have found the spectral weight transfer from coherent part to incoherent part when the film thickness was reduced. This result indicates the possibility of enhanced electron correlation in ultra thin films.

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Influence of Quantum well Thickness Fluctuation on Optical Properties of InGaN/GaN Multi Quantum well Structure Grown by PA-MBE

  • Woo, Hyeonseok;Kim, Jongmin;Cho, Sangeun;Jo, Yongcheol;Roh, Cheong Hyun;Kim, Hyungsang;Hahn, Cheol-Koo;Im, Hyunsik
    • Applied Science and Convergence Technology
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    • v.26 no.3
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    • pp.52-54
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    • 2017
  • An InGaN/GaN multiple quantum well (MQW) structure is grown on a GaN/sapphire template using a plasma-assisted molecular beam epitaxy (PA-MBE). The fluctuation of the quantum well thickness formed from roughly-grown InGaN layer results in a disordered photoluminescence (PL) spectrum. The surface morphologies of the InGaN layers with various In compositions are investigated by reflection high energy electron diffraction (RHEED) and atomic force microscopy (AFM). A blurred InGaN/GaN hetero-interface and the non-uniform QW size is confirmed by high resolution transmission electron microscopy (HR-TEM). Inhomogeneity of the quantum confinement results in a degradation of the quantum efficiency even though the InGaN layer has a uniform In composition.

Uranium Enrichment Determination Using a New Analysis Code for the U XKα Region: HyperGam-U

  • Kim, Junhyuck;Choi, Hee-Dong;Park, Jongho
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.778-784
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    • 2016
  • HyperGam-U was recently developed to determine uranium enrichment based on ${\gamma}$- and X-ray spectroscopy analysis. The $XK_{\alpha}$ region of the uranium spectrum contains 13 peaks for $^{235}U$ and $^{238}U$ and is used mainly for analysis. To describe the X-ray peaks, a Lorentzian broadened shape function was used, and methods were developed to reduce the number of fitting parameters for decomposing the strongly overlapping peaks using channel-energy, energy-width, and energy-efficiency calibration functions. For validation, eight certified reference material uranium samples covering uranium enrichments from 1% to 99% were measured using a high-resolution planar high-purity germanium detector and analyzed using the HyperGam-U code. When corrections for the attenuation and true coincidence summing were performed for the detection geometry in this experiment, the goodness of fit was improved by a few percent. The enrichment bias in this study did not exceed 2% compared with the certified values for all measured samples.

Acquisition of High Resolution Images and its Application using Synchrotron Radiation Imaging System (방사광 X-선을 이용한 고해상도 영상획득과 응용)

  • 홍순일;김희중;정해조;홍진오;정하규;김동욱;제정호;김보라;유형식
    • Progress in Medical Physics
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    • v.12 no.1
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    • pp.51-58
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    • 2001
  • Synchrotron radiation (SR) has several advantages over convetional x-rays, including its phase, collimation, and high flux. A synchrotron radiation beamline 5C1 at Pohang Light Source (PLS) was recently built for imaging applications. We have shown that a SR imaging system is useful in imaging microscopic structures. SR with broad-band energy spectrum were adjusted to an object by Si wafers and their energy were approximately ranging from 6 keV to 30 keV. SR were passed through an object and finally transformed into visible lights by CdWO$_4$ scintillator screen. The visible lights which were reflected at an angle of 90 degrees by gold plated mirror were detected by a CCD camera and the image data were acquired using image acquisition system. A high-resolution phantom, capacitor, adult tooth, child tooth, cancerous breast tissue, and mouse lumbar vertebra were imaged with SR imaging system. The Objects were rotated within the field of view of the CCD detector, and their projection image data were obtained at 250 steps over 180 degrees rotation. Image reconstructions were carried out in a PC by using IDLTM(Research systems, Inc., US) program. The spatial resolution of the images acquired by the SR imaging system was measured with a high-resolution chart manufactured for several micrometer resolution. The specimens were also imaged with conventional x-ray radiography system to compare the image quality of radiography obtained with the SR imaging system. The results showed more structural details and high contrast images with SR imaging system than conventional x-ray radiography system. The SR imaging system may have a potential for imaging in biological researches, material applications, and clinical radiography.

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Probing Atomic Structure of Quarternary Aluminosilicate Glasses using Solid-state NMR (다성분계 현무암질 비정질 규산염의 원자 구조에 대한 고상핵자기 공명 분광분석연구)

  • Park, Sun-Young;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.4
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    • pp.343-352
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    • 2009
  • High-resolution Solid-state NMR provides element specific and quantitative information and also resolves, otherwise overlapping atomic configurations in multi-component non-crystalline silicates. Here we report the preliminary results on the effect of composition on the structure of CMAS (CaO-MgO-$Al_2O_3-SiO_2$) silicate glasses, as a model system for basaltic magmas, using the high-resolution 1D and 2D solid-state NMR. The $^{27}Al$ MAS NMR spectra for the CMAS silicate glasses show that four-coordinated Al is predominant, demonstrating that $Al^{3+}$ is network forming cation. The peak position moves toward lower frequency about 4.7 ppm with increasing $X_{MgO}$ due to an increase in $Q^4$(4Si) fraction with increasing Si content, indicating that Al are surrounded only by bridging oxygen. $^{17}O$ MAS NMR spectra for $CaAl_2SiO_6$ and $CaMgSi_2O_6$ glasses qualitatively suggest that NBO fraction in the former is smaller than that in $CaMgSi_2O_6$ glasses. As $^{17}O$ 3QMAS NMR spectrum of model quaternary aluminosilicate glass resolved distinct bridging and non-bridging oxygen environments, atomic structure for natural magmas can also be potentially probed using high-resolution 3QMAS NMR.

Structure and Photoreaction of Photoactive Yellow Protein

  • Imamoto, Yasushi;Harigai, Miki;Shimizu, Nobutaka;Kamikubo, Hironari;Yamazaki, Yoichi;Kataoka, Mikio
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.126-129
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    • 2002
  • The chromophore/protein interactions in the photocycle intermediates of photoactive yel- low protein (PYP) were probed by site-directed mutagenesis. The absorption spectra of L- intermediates produced from E46Q, T50V, and R52Q mutants were calculated using the absorption spectra of dark states and difference absorption spectra between L-intermediates and dark states, and compared with that of PYP$\_$L/. The absorption spectrum of R52Q$\_$L/ agreed with that of PYP$\_$L/, but those of E46Q$\_$L/ and T50V$\_$L/ were red-shifted. The effect of these mutations on the absorption spectrum for L-intermediate was comparable to that for the dark state, suggesting that the interaction around the phe-nolic oxygen of the chromophore is conserved in PYP$\_$L/ unlike the crystal structure. On the other hand, we have reported that the absorption spectra of Y 42F$\_$M/, T50V $\_$M/, and R52Q$\_$M/ agreed with that of PYP$\_$M/, but that of E46Q$\_$M/ was red-shifted, suggesting that the hydrogen bond of the chromophore with Glu46 is conserved but that with Tyr42 is broken in PYP$\_$M/. These results suggest that the chromophore inter-acts with Glu46 throughout the photocycle, but never directly interacts with Arg52. This model con- flicts with some of the structural model of PYP intermediates proposed based on the high-resolution X -ray crystallography.

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Quality Evaluation of Wind Vectors from UHF Wind Profiler using Radiosonde Measurements (라디오존데 관측자료를 이용한 UHF 윈드프로파일러 바람관측자료의 품질평가)

  • Kim, Kwang-Ho;Kim, Min-Seong;Seo, Seong-Woon;Kim, Park-Sa;Kang, Dong-Hwan;Kwon, Byung Hyuk
    • Journal of Environmental Science International
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    • v.24 no.1
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    • pp.133-150
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    • 2015
  • Wind profiler provides vertical profiles of three-dimensional wind vectors with high spatiotemporal resolution. The wind vectors is useful to analyze severe weather phenomena and to validate the various products from numerical weather prediction model. However, the wind measurements are not immune to ground clutter, bird, insect, and aircraft. Therefore, quality of wind vectors from wind profiler must be quantitatively evaluated prior to its application. In this study, wind vectors from UHF wind profiler at Ganwon Regional Meteorological Administration was quantitatively evaluated using 27 radiosonde measurements that were launched every two or three hours according to rainfall intensity during Intensive Observation Period (IOP) from June to July 2013. In comparison between two measurements, wind vectors from wind profiler was relatively underestimated. In addition, the accuracy and quality of wind vectors from wind profiler decrease with increasing beam height. The accuracy and quality of the wind vectors for rainy periods during IOP were higher than for the clear-air measurements. The moderate rainfall intensity lead to multi-peaks in Doppler spectrum. It results in overestimation of vertical air motion, whereas wind vectors from wind profilers shows good agreement with those from radiosonde measurements for light rainfall intensity.

A Study on Analysis of Beat Spectra in a Radar System (레이다 시스템에서의 비트 스펙트럼 분석에 관한 연구)

  • Lee, Jong-Gil
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.10
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    • pp.2187-2193
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    • 2010
  • A specific radar system can be implemented more easily using the frequency modulated continuous wave comparing with the pulse Doppler radar. It also has the advantage of LPI (low probability of interception) because of the low power and wide bandwidth characteristics. These radars are usually used to cover the short range area and to obtain the high resolution measurements of the target range and velocity information. The transmitted waveform is used in the mixer to demodulate the received echo signal and the resulting beat signal can be obtained. This beat signal is analyzed using the FFT method for the purpose of clutter removal, detection of a target, extraction of velocity and range information, etc. However, for the case of short signal acquisition time, this FFT method can cause the serious leakage effect which disables the detection of weaker echo signals masked by strong side lobes of the clutter. Therefore, in this paper, the weighting window method is analyzed to suppress the strong side lobes while maintaining the proper main lobe width. Also, the results of FFT beat spectrum analysis are shown under various environments.

A Study of Rotor Fault Detection for the Induction Motor Using Axial Leakage Magnetic Flux (축방향 누설자속 측정에 의한 유도전동기의 회전자 결함검출에 관한 연구)

  • Shin, Dae-Cheul;Kim, Young-Hwan
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.1
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    • pp.132-137
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    • 2006
  • The second part of paper related rotor failure is to evaluate that the axial magnetic flux measurement could be used as a tool of the condition monitoring system for the induction motor and to develope the diagnostic algorithm for the various fault in the electric motors. The magnetic leakage flux signal is captured by the flux coil located at the end of motor without the disturbance of the operation. And the signal is analyzed both time and frequency domain to detect the failure of the motor. Specific signature can be described in tin and frequency domain for each fault of the motor. The experimental test found that the rotor failures - broken rotor bar, broken end ing and rotor eccentricity, could be detected from the spectrum with high resolution. The method of detecting the rotor fault was found by analysing the specific frequency and the sideband of the rotor bar pass frequency from axial leakage flux spectrum. In addition the optimal flux coil and measuring equipment for the axial leakage flux measurement was verified and the diagnostic method for the detection of the rotor related failure was developed.

A Prediction of Infrared Spectrum of Rocket Plume with Considering Soot Particles (Soot 입자를 고려한 로켓 플룸의 적외선 스펙트럼 예측)

  • Jo, Sung Min;Nam, Hyun Jae;Kim, Duk Hyun;Kwon, Oh Joon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.4
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    • pp.24-36
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    • 2015
  • In the present study, numerical predictions of infrared spectrum of rocket plume with considering effect of particles based on approximation theories were performed by using a line-by-line radiation model with radiation databases. The high-resolution radiation databases were used to predict thermal emission spectra of gas molecules within the rocket plume regime. The particles were modeled as soot particles by using 1st term approximation of Mie theory and Rayleigh approximation. The reliability of modeled effect of soot particles using the two approximation theories was verified, and the spectral radiance of rocket plume was predicted based on the verification. The results were improved in the short wavelength range by considering the effect of soot particles.