• Journal of the Korean earth science society
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• v.23 no.5
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• pp.424-435
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• 2002

This study analyzes the surface ozone and meteorological data in Daegu for a period from 1997 to 1999. It also investigates the meteorological characteristics of high ozone episodes. For this study the high ozone episode has been defined as a daily maximum ozone concentration higher than 100ppb in at least one station among six air quality monitoring stations in Daegu, Korea. The frequency of episodes is 13 days. The frequency is the highest in May and September. The average value of daily maximum ozone concentration is 81.6ppb, and 8-hour average ozone concentration is 58.6ppb for the high episodes. This shows that ozone pollution is continuous and wide-ranging in Daegu. The daily maximum ozone concentration is positively correlated to solar radiation and daily maximum temperature, but negatively correlated to relative humidity, wind speed and cloud amount. The maximal correlation coefficient to solar radiation is 0.45. The differences between high ozone episode day's daily mean meteorological value and monthly mean value are +1.58hPa for sea level pressure, +3.45${\circ}$C for maximum temperature, -5.69% for relative humidity, -0.46ms$^{-1}$ for wind speed, -1.79 for cloud amount, and +3.97MJm$^{-2}$ for solar radiation, respectively. This shows that strong solar radiation, low wind speed and no precipitation between 0700${\sim}$1100LST are favorite conditions for high ozone episodes. It is related to the morning stagnant condition.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.6
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• pp.607-623
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• 2000

Major trends of ozone concentration variations in Korea were investigated by using observation data from around 100 stations for the period of 1991∼1997. In addition, important regulating those variations were inferred. Three measures such as the number of days exceeding 80ppb, the 95th percentile of daily maxima, and the annual average concentration were used for the analysis of multi-scale ozone concentration variations. Three areas in the southwest (Sosan, Mokpo, and Cheju) of which monitoring has been operated since 1995 showed the highest annual average concentrations over; this was noted because of the high annual average in the Yosu area in the early 1990s. Large increases in annual average concentrations were observed along the relatively cleaner areas connecting Kangnung and Kwangju(northeast to southwest), in contrast to polluted areas connecting Seoul and Pusan(northeast to southeast). Both the number of exceedance days and the daily maximum concentration were nearly constant in the Greater Seoul Area in spite of interannual flucturations associated with year-to-year changes in air temperature. Within the Greater Seoul Area, all three measures usually showed the same trend; they decreased in the middle and west and increased in the east and northeast. All three measures including the number of exceedance days increased largely at Sillim where the average concentration was high but no exceedance days were recorded in the early 1999s, Nationwide ozone concentration variations appear to be determined by the competitive influence of long-range transport and local urban emissions, Within the city including the Greater Seoul Area, changes in emission which accompany changes in population and in the number if vehicles ( in the process of urban development) were found to be important components of ozone concentration variations.

• Journal of Environmental Science International
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• v.19 no.3
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• pp.269-279
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• 2010

The relative contributions of physical and chemical processes to the production of ozone ($O_3$) were evaluated based on an integrated process rate (IPR) analysis using the MM5/CMAQ in a downtown (i.e., Yangsan_U) and suburban area (i.e., Ungsang) on high ozone days during spring and summer in 2006 (28 April and 8 August 2006). The IPR includes a horizontal advection (HADV) and diffusion (HDIF), a vertical advection (ZADV) and diffusion (VDlF), a dry deposition (DDEP), and a chemistry (CHEM). The VDIF in Yangsan_U was found to be the most dominant contributor (29.5% in spring and 32.1% in summer) to high $O_3$ concentrations, followed by the HADV and ZADV. In contrast, the contributions of the HADV (40.3% in spring and 32.3% in summer) in Ungsang were significantly higher than those of VDIF and ZADV. Moreover, $O_3$ production due to the chemical effect in the two areas (especially in Ungsang) during summer was found to be moderately higher than that during spring.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.31-34
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• 2004

Feasibility of electrokinetic(EK)-Fenton process and Ozone chemical oxidation were investigated for tile removal of organic contaminants and heavy metals from the contaminated soil. In EK-Fenton process, accumulated electroosmotic flow(EOF) was 80 L for 26 days. Removal efficiency of TPH, As, and Ni were 61%, 36%, and 47%, respectively. The concentration of As was high near the anode due to the transport of anionic As toward the anode, while the concentration of Ni was high near the cathode by the movement of cationic Ni to the cathode. Field scale application of in-situ ozonation was carried out for removal of TPH in 3-D test cell (3 m$\times$2 m$\times$2 m). After 25 days of ozone injection, more than 80% of removal rate was observed through the test cell.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.2
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• pp.159-173
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• 1999

Based on air quality monitoring data('89~'97) operated by the Department of Environment, we provide various fundamental statistics for ground ozone. The purpose of this paper are to review the national ambient ozone standard, to study spatial distribution of ozone. Since we, in Korea, calculate average ozone level, to examine the occurrences of ozone level 3 times a day (1~8, 9~16, 17~24 hours), the method does not seem to be scientifically sound comparing to a running average method adapted by the USEPA. When we counted the number of cases with 8-h average O3 level exceeding 60ppb(8-h average standard in Korea)and 80 ppb (that in the U.S.A) and also when we calculated 8-hour average ozone level based on th US method, some regions were classified as non-attainment areas. Especially in Seoul, results of spatial distribution analysis showed that high level ozone over 80 ppb was observed at Kuui-Dong and Pangi-Dong in the eastern part and at Ssangmun-Dong in the northeastern part. Also, occurrences of ozone episode defined as number of days then ozone level exceeding 80 ppb for 3 consecutive hours were extensively reviewed in this paper.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.2
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• pp.161-176
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• 2010

We examined high ozone episodes observed during the intensive measurement periods (11 May~21 June and 30 July~11 August 2009) in the Gulf of Gwangyang. During that period, there were a few events (or days) in which 1 hr averaged ozone concentrations were greater than 100 ppbv. The analysis of ozone budget and photochemical characteristics related to the ozone production was carried out using a photochemical box model. Ozone sensitivity to $NO_x$ and VOCs was also examined in the study area during the measurement period. Diurnal variation of ozone during the episodes was similar to that of odd hydrogen radicals ($HO_2,CH_3O_2$, and $RO_2$), suggesting significant correlation with photochemical production of ozone during the episodes. In general, ozone concentration in the study area during the measurement period was sensitive to VOCs, whereas ozone was sensitive to $NO_x$ under certain conditions. Ozone sensitivity assessment using a radical budget analysis and $NO_x$/VOCs-control strategy was consistent with that using indicator species ($H_2O_2/HNO_3$ ratio).

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.2
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• pp.215-224
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• 2004

We report the high concentration episodes for PM$_{10}$, SO$_2$, NO$_2$, and $O_3$ in many urban areas Korea during 2002. The high concentration episodes are identified based on the National Ambient Air Quality Standards and the observations obtained from the Regional Air Monitoring Network composed of approximately 160 air pollution monitoring stations located in a number of major or big cities in South Korea including Seoul, Pusan, Daegu, and Incheon cities. The results show that the twenty cases of high concentration episodes in 2002 consists of both ozone warning episodes (6 cases) and high PM$_{10}$ concentration cases (14 cases), and one half of the latter are found to occur in association with the Yellow Sand (Asian Dust) phenomena. The most outstanding characteristics of the reported episodes are the excessively high levels of maximum PM$_{10}$ concentrations during the Yellow Sand period (i.e., exceeding 3,000$\mu\textrm{g}$/㎥ in April, 2002) and their variable occurrence frequencies across seasons. The high ozone concentration episode days are mainly resulting from both the high photochemical reactions and poor ventilations. The high PM$_{10}$ concentration days during non Yellow Sand periods, however, mostly occurred under the influence of synoptic meteorological conditions such as stagnant or slowly passing high pressure centers, and consequently prevailing weak wind speeds over the Korean peninsula. The overall results of our study thus suggest the importance of both synoptic and local meteorological factors for high concentration levels in the major and/or big cities in Korea.n Korea.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.6
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• pp.545-554
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• 1998

The diurnal variation of O3 concentration shows two peaks, the first peak at noontime and the secondary peak at night. In order to show why the secondary peak, high nocturnal O3 concentration, occurs without sunlight which is a essential factor of a photochemical response, the O3 concentration, several weather elements and synoptic weather map were used for June∼September at 1995, 1996. The mean concentration of high nocturnal O3 concentration days is higher by 5.4 ppb than that of low nocturnal O3 concentration days. The nocturnal O3 concentration is higher than that of diurnal O3 concentration during high nocturnal O3 concentration days, at July, 1995 and June, 1996. The high nocturnal O3 concentration is related to low air pressure, high cloud cover and high wind speed. The correlation coefficient, r. between nocturnal O3 concentration and wind speed, pressure and cloud cover is 0.387, -0.218, and 0.194, respeftiviely. It is interesting that the O3 concentration increases at Pusan when the typhoon passes by. The same result showed at Taegu when the typhoon FAYE passed by. According to the analysis of nocturnal O3 concentration for June∼September at 1995 and 1996, it seems that the high nocturnal O3 concentration relates to the trough and cyclones passing by Pusan.

• Journal of Environmental Science International
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• v.17 no.7
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• pp.743-753
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• 2008

Gwangyang Bay is often severely confronted by photochemical pollutants due to its location and dense emissions. It is located in a basin on the south coast of the Korean peninsula and is crossed by a remarkable cluster of hills and mountains of a small horizontal scale that forms a channel. Clearly, the air flow field has a great influence on the dispersion of air pollutants. The characteristics of the wind flow patterns have an important effect on the dispersion of pollutants emitted. In these situations, the distribution of the ozone concentration is extremely complicated because of the superposition of circulations of the air flow fields, especially in complex coastal region. In this study, we examined the distribution of the high level ozone on Gwangyang Bay particularly during the episode day (for 5 years). Among these days, A high level ozone was induced by the development of a sea/land breeze local circulation system, as well as by an anabatic/catabatic flow from the mountains and valley with weakening of the synoptic wind. High level ozone distribution pattern(6 types) on Gwangyang bay is analyzed and the comparison of each pattern reveals substantial localized differences in intensity and distribution of ozone concentration from the site coherence and UPA analysis of ozone concentration. The observed VOC concentration had much difference in concentrations and daily variations between Jungdong and Samil.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.172-175
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• 2003

Field scale application of in-situ ozonation were carried out for remediation of variably saturated soils contaminated with diesel fuel with 3 dimensional test cell (3m$\times$2m$\times$2m). After 20 days of ozone injection, more than 90% of removal rate was observed through the 3-D test cell. This result might be caused by uniform distribution, relatively low oxidant demand, and low water content of soils, as well as high oxidation potential of ozone. However, less than 50 % of injected ozone was monitored through the 3-D test cell even after 20 days of injection.