• Title/Summary/Keyword: high manganese alloy

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Corrosion Behavior of a High-Manganese Austenitic Alloy in Pure Zinc Bath

  • Yi, Zhang;Liu, Junyou;Wu, Chunjing
    • Corrosion Science and Technology
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    • v.9 no.2
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    • pp.98-103
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    • 2010
  • In order to further reduce the cost without reducing the corrosion resistance, a high-manganese austenitic alloy for sink roll or stabilizer roll in continuous hot-dip coating lines was developed. A systematic study of corrosion behavior of the high-manganese austenitic alloy in pure zinc bath at $490^{\circ}C$ was carried out. The results shows that, the high-manganese austenitic alloy shows better corrosion resistance than 316L steel. The corrosion rate of the high-manganese austenitic alloy in pure zinc bath is calculated to be approximately $6.42{\times}10^{-4}g{\cdot}cm^{-2}{\cdot}h^{-1}$, while the 316L is $1.54{\times}10^{-3}g{\cdot}cm^{-2}{\cdot}h^{-1}$. The high-manganese austenitic alloy forms a three-phase intermetallic compound layer morphology containing ${\Gamma$}, ${\delta}$ and ${\zeta}$ phases, while the 316L is almost ${\zeta}$ phase. The ${\Gamma}$ and ${\delta}$ phases of the high-manganese austenitic alloy contain about 8.5 wt% Cr, the existence of Cr improve the stabilization of phases, which slow down the reaction of Fe and Zn, improve the corrosion resistance of the high-manganese austenitic alloy. So substitute the nickel with the manganese to manufacture the high-manganese austenitic alloy of low cost is feasible.

Study of the Distillation of Ferromanganese Alloy Melts at Reduced Pressure (훼로 망간 합금철 용탕의 감압 증류에 관한 연구)

  • Hong, Seong-Hun;Jeon, Byoung-Hyuk;You, Byung-Don;Kim, Jong-Deok;Jang, Pill-Yong;Kang, Soo-Chang;Geum, Chang-Hun
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.154-162
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    • 2010
  • A fundamental study of the distillation behavior of ferromanganese alloy melts was carried out at 1773 K and 0.1333 kPa (=1 Torr). During the distillation of ferromanganese alloy melts under reduced pressure, manganese vaporizes preferentially to phosphorus and other solute elements. High purity manganese metal with a very low content of solute elements can be obtained by distillation of ferromanganese alloy melts. The evaporation of manganese is suppressed as the carbon content of ferromanganese alloy melt increases due to the decrease of activity and vapor pressure of the manganese. When the carbon content of ferromanganese alloy melt is high, melt droplets are ejected from the bath, especially in the early stages of the distillation, and the solute elements in the splashed droplets contaminate the condensed material. The ejection of melt droplets is presumed to be caused by the increase of melting temperature and viscosity of the surface layer of melt due to the enrichment of solute elements such as carbon and iron.

Fatigue Strength Assessment of High Manganese Steel for LNG CCS (LNG CCS적용을 위한 고망간강의 극저온 피로성능 평가)

  • Lee, Jin-Sung;Kim, Kyung-Su;Kim, Yooil;Yu, Chang-Hyuk;Park, Jooil;Kang, Bong-Ho
    • Journal of the Society of Naval Architects of Korea
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    • v.51 no.3
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    • pp.246-253
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    • 2014
  • Liquid natural gas is stored and transported inside cargo tank which is made of specially designed cryogenic materials such as 9% Ni steel, Al5083-O alloy and SUS304 and so on. The materials have to keep excellent ductile characteristics under the cryogenic environment, down to -163oC, in order to avoid the catastrophic sudden brittle fracture during the operation condition. High manganese steel is considered to be the promising alternative material that can replace the commonly used materials mentioned above owing to its cost effectiveness. In line with this industrial need, the mechanical properties of the high manganese steel under both room and cryogenic environment were investigated in this study focused on its tensile and fatigue behavior. In terms of the tensile strength, the ultimate tensile strength of the base material of the high manganese steel was comparable to the existing cryogenic materials, but it turned out to be undermatched one when welding is involved in. The fatigue strength of the high manganese steel under room temperature was as good as other cryogenic materials, but under cryogenic environment, slightly less than others though better than Al 5083-O alloy.

The Properties of Aluminium Alloy Powder for Aluminothermy Process with $Mn_3O_4$ Waste Dust ($Mn_3O_4$ 분진의 Al 테르밋 반응용 Al 합금분말의 특성)

  • Kim, Youn-Che;Song, Youn-Jun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.71-77
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    • 2013
  • Aluminium powder as reductant in aluminothermy process needs a fine particle size under 200 mesh, but it is not easy economically to make that because of its high ductility and powder production cost. In order to reduce the production cost of fine aluminum powder as reductant of $Mn_3O_4$ waste dust, therefore, the properties of aluminium alloy powder were investigated. Aluminium alloy ingot containing large amount of manganese can be crushed easily because of its intermetallic compounds having brittle properties. The manganese is also main element in ferro-manganese. We can obtain economically Al-15%Mn alloy powder by mechanical comminution process. And the result of thermite reaction using Al-15% Mn alloy powder instead of pure Al powder showed the fact that can be obtained the ferro-manganese which have a high purity in case of using pure aluminium powder as reductant. The recovery of manganese from $Mn_3O_4$ waste dust with Al-15%Mn alloy powder was higher level of about 70% than about 65% in case of using aluminium powder, that is due to lower spatter loss.

Joint technology between Manganese crossing and rail by Flash Butt Welding (망간크로싱과 레일의 플래시버트 용접 기술 개발)

  • Kwon Ho Jin;Kim Soon Chul;Choi In Suk;Lee Bo Young
    • Proceedings of the KSR Conference
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    • 2003.10b
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    • pp.163-169
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    • 2003
  • In order to develop domestic railway technology, it is necessary that manufacturing technology of turnout should be kept up with update level, because turnout is the core component of high speed railway. Manganese crossing made of high manganese alloy steel is a important component of turnout. So far, this could not have been welded with rail steel due to metallic problem in Korea. However, joint technology hereunder between manganese crossing and rail by using Flash Butt Welding which is developed by Kangwon Railtech Co., Ltd is the state of the art and enable to realize rail continuousness in turnout section, speed up train velocity, reduce maintenance cost, and enhance riding quality.

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Friction and Wear Properties of High Manganese Steel in Brake Friction Material for Passenger Cars (자동차용 브레이크 마찰재에서 고망간강의 마찰 및 마모특성)

  • Jung, Kwangki;Lee, Sang Woo;Kwon, Sungwook;Song, Myungsuk
    • Tribology and Lubricants
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    • v.36 no.2
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    • pp.88-95
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    • 2020
  • In this study, we investigate the mechanical properties of high manganese steel, and the friction and wear characteristics of brake friction material containing this steel, for passenger car application, with the aim of replacing copper and copper alloys whose usage is expected to be restricted in the future. These steels are prepared using a vacuum induction melting furnace to produce binary and ternary alloys. The hardness and tensile strength of the high manganese steel decrease and the elongation increases with increase in manganese content. This material exhibits high values of hardness, tensile strength, and elongation; these properties are similar to those of 7-3 brass used in conventional friction materials. We fabricate high manganese steel fibers to prepare test pad specimens, and evaluate the friction and wear characteristics by simulating various braking conditions using a 1/5 scale dynamometer. The brake pad material is found to have excellent friction stability in comparison with conventional friction materials that use 7-3 brass fibers; particularly, the friction stability at high temperature is significantly improved. Additionally, we evaluate the wear using a wear test method that simulates the braking conditions in Europe. It is found that the amount of wear of the brake pad is the same as that in the case of the conventional friction material, and that the amount of wear of the cast iron disc is reduced by approximately 10. The high manganese steel is expected to be useful in the development of eco-friendly, copper-free friction material.

A Study on Making of High-Purity Ferro-manganese from $Mn_3O_4$ Waste Dust ($Mn_3O_4$ 분진으로부터 고순도 훼로망간 제조에 관한 연구)

  • Kim, Youn-Che;Song, Young-Jun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.135-139
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    • 2011
  • In order to make high-purity ferro-manganese from $Mn_3O_4$ waste dust, the application of aluminothermite process to the reduction of the waste dust was investigated. The mixture from $Mn_3O_4$ dust as metallic source and Al metal powder as the reductant ignited, and reduced with an extremely intense exothermic reaction. The rapid propagation of the aluminothermite reaction occurred spontaneously and stably by ignition of the mixture. The Manganese having some alloy elements emerged as liquids due to the high temperatures reached up to about $2,500^{\circ}C$ and separated from the liquid by their differences of specific gravity. The result of thermite reaction showed the fact that can be obtained high purity ferro-manganese which have over about 90% of manganese content and lower impurities such as C, P, S than those of KS D3712 specification. The recovery of manganese from $Mn_3O_4$ dust was lower level of about 65% than about 75% from manganese ore by electric furnace process, that is due to spatter loss because of its extremely intense thermite reaction. But it will be improved by the process designed to provide CaO as the cooler or to use the Al metal powder having larger particle size distribution.

Effects of Ni and Si on the Matrix Structure and Graphite Formation in Fe-12Mn-3.5C Alloy (Fe-12Mn-3.5C 계주철(系鑄鐵)에서 기지조직(基地組織)과 흑연석출(黑鉛析出)에 미치는 Ni 및 Si 의 영향)

  • Ra, Hyong-Yong;Son, Won-Tak
    • Journal of Korea Foundry Society
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    • v.3 no.3
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    • pp.174-180
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    • 1983
  • The matrix changes and graphite formation in high manganese cast iron (Fe-12Mn-3.5C) are studied with increasing nickel and silicon content. Also, the decomposition of carbides and graphite precipitation are studied by adequate heat treatment.The results obtained in this work are as follows. 1. In high manganese cast iron, fine flakes graphite appeared by adding 5 wt% nickel and A-type flakes graphite can be obtained by adding 7 wt% nickel. 2. Nodular graphite are obtained by graphite spheroidizing treatment with same melt. 3. In high manganese cast iron containing 7 wt% nickel, full austenitic matrix with nodular graphite can be achieved by water quenching after 10 hours' solution heat treatment at $1050^{\circ}C$ in case of containing 2.0 wt% silicon, and 6 hours' at the same temperature in case of containing 2.5 wt% silicon.

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Influence of Strain Rate on Tensile Properties and Dynamic Strain Aging of an Fe-24.5Mn-4Cr-0.45C Alloy (변형률 속도에 따른 Fe-24.5Mn-4Cr-0.45C 합금의 인장 특성과 동적 변형시효)

  • Lee, Seung-Yong;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.281-286
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    • 2016
  • In the present study, the tensile properties and dynamic strain aging of an Fe-24.5Mn-4Cr-0.45C alloy were investigated in terms of strain rate. During tensile testing at room temperature, all the stress-strain curves exhibited serrated plastic flows related to dynamic strain aging, regardless of the strain rate. Serration appeared right after yield stress at lower strain rates, while it was hardly observed at high strain rates. On the other hand, strain-rate sensitivity, indicating a general relationship between flow stress and strain rate at constant strain and temperature, changed from positive to negative as the strain increased. The negative strain-rate sensitivity can be explained by the Portevin Le Chatelier effect, which is associated with dynamic strain aging and is dependent on the strain rate because it is very likely that the dynamic strain aging phenomenon in high-manganese steels is involved in the interaction between moving dislocations and point-defect complexes.

Electrical Properties of Cu/Mn Alloy Resistor with Low Resistance and Thermal Stability (낮은 저항과 열안정성을 가지는 Cu/Mn 합금저항의 전기적 특성)

  • Kim, Eun Min;Kim, Sung Chul;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.365-369
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    • 2016
  • In this paper, we fabricated Cu/Mn alloy shunt resistor with low resistance and thermal stability for use of mobile electronic devices. We designed metal alloy composed of copper (Cu) and manganese (Mn) to embody in low resistance and low TCR which are conflict each other. Cu allows high electrical conductivity and Mn serves thermal stability in this Cu/Mn alloy system. We confirmed the elemental composition of the designed metal alloy system by using energy dispersive X-ray (EDX) analysis. We obtained low resistance below $10m{\Omega}$ and low temperature coefficient of resistance (TCR) below $100ppm/^{\circ}C$ from the designed Cu/Mn alloy resistor. And in order to minimize resistance change caused by alternative frequency on circuit, shape design of the metal alloy wire is performed by rolling process. Finally, we conclude that design of the metal alloy system was successfully done by alloying Cu and 3 wt% of Mn, and the Cu/Mn alloy resistor has low resistance and thermal stability.