• Title/Summary/Keyword: high current density

Search Result 2,273, Processing Time 0.037 seconds

Characterization of manganese oxide supercapacitors using carbon cloth (Carbon Cloth을 이용한 이산화망간 슈퍼커패시터 특성 연구)

  • Lee, Seung Jin;Kim, Chihoon;Ji, Taeksoo
    • Journal of Digital Contents Society
    • /
    • v.18 no.6
    • /
    • pp.1199-1205
    • /
    • 2017
  • Global energy consumption is rapidly increasing yearly due to drastic industrial advances, requiring the development of new energy storage devices. For this reason, supercapacitors with fast charge-discharge, long life cycle and high power density is getting attention, and have been considered as one of the potential energy storage systems. In this research, we developed a supercapacitor that consists of amorphous manganese oxide($MnO_2$) electrodes deposited onto carbon cloth substrates using the hydrothermal method. The Fe-doped amorphous $MnO_2$ samples were characterized by X-ray diffraction(XRD), Energy Dispersive X-ray spectroscopy(EDX), as well as scanning electron microscopy(SEM). The electrochemical analysis of the prepared samples were performed using cyclic voltammetry and galvanostatic charge-discharge measurements in 1M $Na_2SO_4$ electrolyte. The test results demonstrate that the supercapacitor based on the Fe-doped amorphous $MnO_2$ electrodes has a specific capacitance as high as 163F/g at 1A/g current density, and good cycling stability of 87.34% capacitance retention up to 1000 cycles.

Fundamental Study about Bottom-Clinging Rate in Free Floating Larva by Infiltration Flow in Tidal (조석의 침투류에 의한 패류 유생의 착저 (着底) 효과에 관한 기초적 연구)

  • Back, Sang-Ho;Park, Kwang-Jae;Park, Young-Je;Cheon, Jun-Je;Cho, Kee-Chae;Kim, Yi-Un
    • The Korean Journal of Malacology
    • /
    • v.25 no.2
    • /
    • pp.97-103
    • /
    • 2009
  • It is a research that free floating larva of Ruditapes philippinarum in compliance with infiltration flow of tidal accumulation and bottom-clinging system in high density also, It is a precondition this for the continuous augmentation of Ruditapes philippinarum resources. So in flow field of tidal the free floating larva produced the infiltration water tank that can possibly bottom-clinging and experiment the water tank which uses free floating larva, It evaluates that the acceleration effect of free floating larva by infiltration in objective. As a result, 1) The experiment on free floating larva's bottom sediment grain diameter came to be high recording as bottom-clinging rate at the static water field and even biologically it selects bottom-clinging substrate it will be able to confirm. 2) About occurrence of infiltration flow field is in case of that: the drift of a current 10cm/s, bottom sediment grain 1.21mm infiltration flow 0.3cm/s increase of 3~5 times was confirmed. 3) From free floating larva of Ruditapes philippinarum the choice of bottom sediment grain diameter depends in the biological factor and form the flow field the bottom-clinging acceleration effect was controled over physical stable condition. 4) In case of density of Ruditapes philippinarum free floating larva of sea area, bottom sediment grain diameter, flow condition which are very cleanly in the research that possibly could conjecture the free floating larva's bottom-clinging rate.

  • PDF

A 3D ground penetrating radar imaging of the heavy rainfall-induced deformation around a river levee: a case study of Ara River, Saitama, Japan (폭우에 의해 발생된 강 제방 주변 변형의 3차원 GPR 영상화: 일본 사이타마현의 아라강에 대한 현장적용사례)

  • Yokota, Toshiyuki;Inazaki, Tomio;Shinagawa, Shunsuke;Ueda, Takumi
    • Geophysics and Geophysical Exploration
    • /
    • v.12 no.1
    • /
    • pp.49-55
    • /
    • 2009
  • This paper describes a three-dimensional ground penetrating radar (GPR) survey carried out around a levee of the Ara River in Saitama, Japan, where deformation of the ground was observed after heavy rainfall associated with the typhoon of September 2007. The high-density 3D GPR survey was conducted as a series of closely adjacent four directional sets of 2D surveys at an area surrounding vertical cracks on the paved road caused by deformations induced by heavy rain. The survey directions of the 2D surveys were 0, 90, 45, and -45 degrees with respect to the paved road and the intervals between lines were less than 0.5 m. The 3D subsurface structure was accurately imaged by the result of data processing using Kirchhoff-type 3D migration. As a result, locations and vertical continuities of the heavy rainfall induced cracks in the paved road were clearly imaged. This will be a great help in considering the generation mechanisms of the cracks. Moreover, the current risk of a secondary disaster was found to be low, as no air-filled cavities were detected by the 3D GPR survey.

Structural and Electrical Properties of Amorphous 2Ti4O12 Thin Films Grown on TiN Substrate (TiN 기판 위에 성장시킨 비정질 BaSm2Ti4O12 박막의 구조 및 전기적 특성 연구)

  • Park, Yong-Jun;Paik, Jong-Hoo;Lee, Young-Jin;Jeong, Young-Hun;Nahm, Sahn
    • Korean Journal of Materials Research
    • /
    • v.18 no.4
    • /
    • pp.169-174
    • /
    • 2008
  • The structural and electrical properties of amorphous $BaSm_2Ti_4O_{12}$ (BSmT) films on a $TiN/SiO_2/Si$ substrate deposited using a RF magnetron sputtering method were investigated. The deposition of BSmT films was carried out at $300^{\circ}C$ in a mixed oxygen and argon ($O_2$ : Ar = 1 : 4) atmosphere with a total pressure of 8.0 mTorr. In particular, a 45 nm-thick amorphous BSmT film exhibited a high capacitance density and low dissipation factor of $7.60\;fF/{\mu}m2$ and 1.3%, respectively, with a dielectric constant of 38 at 100 kHz. Its capacitance showed very little change, even in GHz ranges from 1.0 GHz to 6.0 GHz. The quality factor of the BSmT film was as high as 67 at 6 GHz. The leakage current density of the BSmT film was also very low, at approximately $5.11\;nA/cm^2$ at 2 V; its conduction mechanism was explained by the the Poole-Frenkel emission. The quadratic voltage coefficient of capacitance of the BSmT film was approximately $698\;ppm/V^2$, which is higher than the required value (<$100\;ppm/V^2$) for RF application. This could be reduced by improving the process condition. The temperature coefficient of capacitance of the film was low at nearly $296\;ppm/^{\circ}C$ at 100 kHz. Therefore, amorphous BSmT grown on a TiN substrate is a viable candidate material for a metal-insulator-metal capacitor.

Facile Chemical Growth of Cu(OH)2 Thin Film Electrodes for High Performance Supercapacitors (간단한 화학적 합성을 통한 고성능 슈퍼캐패시터용 수산화 구리 전극)

  • Patil, U.M.;Nam, Min Sik;Shinde, N.M.;Jun, Seong Chan
    • KEPCO Journal on Electric Power and Energy
    • /
    • v.1 no.1
    • /
    • pp.175-180
    • /
    • 2015
  • A facile soft chemical synthesis route is used to grow nano-buds of copper hydroxide [$Cu(OH)_2$] thin films on stainless steel substrate[SS]. Besides different chemical methods for synthesis of $Cu(OH)_2$ nanostructure, the chemical bath deposition (CBD) is attractive for its simplicity and environment friendly condition. The structural, morphological, and electro-chemical properties of $Cu(OH)_2$ thin films are studied by means of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) measurement techniques. The results showed that, facile chemical synthesis route allows to form the polycrystalline, granular nano-buds of $Cu(OH)_2$ thin films. The electrochemical properties of $Cu(OH)_2$ thin films are studied in an aqueous 1 M KOH electrolyte using cyclic voltammetry. The sample exhibited supercapacitive behavior with $340Fg^{-1}$ specific capacitance. Moreover, electrochemical capacitive measurements of $Cu(OH)_2/SS$ electrode exhibit a high specific energy and power density about ${\sim}83Wh\;kg^{-1}$ and ${\sim}3.1kW\;kg^{-1}$, respectively, at $1mA\;cm^{-2}$ current density. The superior electrochemical properties of copper hydroxide ($Cu(OH)_2/SS$) electrode with nano-buds like structure mutually improves pseudocapacitive performance. This work evokes scalable chemical synthesis with the enhanced supercapacitive performance of $Cu(OH)_2/SS$ electrode in energy storage devices.

GPS-based monitoring and modeling of the ionosphere and its applications for high accuracy correction in China

  • Yunbin, Yuan;Jikun, Ou;Xingliang, Huo;Debao, Wen;Genyou, Liu;Yanji, Chai;Renggui, Yang;Xiaowen, Luo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
    • /
    • v.2
    • /
    • pp.203-208
    • /
    • 2006
  • The main research conducted previously on GPS ionosphere in China is first introduced. Besides, the current investigations include as follows: (1) GPS-based spatial environmental, especially the ionosphere, monitoring, modeling and analysis, including ground/space-based GPS ionosphere electron density (IED) through occultation/tomography technologies with GPS data from global/regional network, development of a GNSS-based platform for imaging ionosphere and atmosphere (GPFIIA), and preliminary test results through performing the first 3D imaging for the IED over China, (2) The atmospheric and ionospheric modeling for GPS-based surveying, navigation and orbit determination, involving high precisely ionospheric TEC modeling for phase-based long/median range network RTK system for achieving CM-level real time positioning, next generation GNSS broadcast ionospheric time-delay algorithm required for higher correction accuracy, and orbit determination for Low-Earth-orbiter satellites using single frequency GPS receivers, and (3) Research products in applications for national significant projects: GPS-based ionospheric effects modeling for precise positioning and orbit determination applied to China's manned space-engineering, including spatial robot navigation and control and international space station intersection and docking required for related national significant projects.

  • PDF

Binderless Consolidation of Fine Poly-Si Powders for the Application as Photovoltaic Feedstock (태양전지(太陽電池) 원재료(原材料)로 사용(使用)하기 위한 폴리실리콘 미세분말(微細粉末)의 무점결제(無粘結劑) 성형(成形))

  • Shin, Je-Sik;Kim, Dae-Suk;Kim, Ki-Young;Shon, In-Jin;Moon, Byung-Moon
    • Resources Recycling
    • /
    • v.18 no.1
    • /
    • pp.38-43
    • /
    • 2009
  • In this study, binderless consolidation processes of ultra foe Si powder, by-products of making high purity poly-Si in the current method, were systematically investigated for use as economical solar-grade feedstock. The average diameter of the silicon powder was $7.8{\mu}m$. The main contaminants of the fine silicon powder were $SiO_2$ type oxide and humidity. The chemical pretreatment using the HF solution was observed to be effective for the improvement of the compactability of the silicon powder and the density ratio and the strength of the silicon powder compacts. The yield of the binder-free consolidation process increased by 20% under a vacuum condition. In as-received state, the silicon powder were not pure enough to be used as solar grade feed-stock material. After the dry chemical treatments, a sufficiently high purity above solar-grade was able to be achieved.

Spatio-Temporal Variations of Harmful Algal Blooms in the South Sea of Korea

  • Kim, Dae-Hyun;Denny, Widhiyanuriyawan;Min, Seung-Hwan;Lee, Dong-In;Yoon, Hong-Joo
    • Korean Journal of Remote Sensing
    • /
    • v.25 no.6
    • /
    • pp.475-486
    • /
    • 2009
  • Harmful algal blooms (HAB) caused by the dominant species Cochlodinium polykrikoides (C. polykrikoides) appear in the South Sea of Korea and are particularly present in summer and fall seasons. Environmental factors such as water temperature, weather conditions (air temperature, cloud cover, sunshine, precipitation and wind) influence on the initiation and subsequent development of HAB. The purpose of this research was to study spatial and temporal variations of HAB in the Yeosu area using environmental (oceanic and meteorological) and satellite data. Chlorophyll-a concentrations were calculated using Sea-viewing Wide Field-of-view Sensor (SeaWiFS) images by an Ocean Chlorophyll 4 (OC4) algorithm, and HAB were estimated using the Red tide index Chlorophyll Algorithm (RCA). We also used the surface velocity of sequential satellite images applying the Maximum Cross Correlation method to detect chlorophyll-a movement. The results showed that the water temperature during HAB occurrences in August 2002-2008 was $19.4-30.2^{\circ}C$. In terms of the frequency of the mean of cell density of C. polykrikoides, the cell density of the HAB found at low (<300 cells/ml), medium (300-1000 cells/ml), and high (>1000 cells/ml) levels were 27.01%, 37.44%, and 35.55%, respectively. Meteorological data for 2002-2008 showed that the mean air temperature, precipitation, wind speed and direction, and sunshine duration were $22.39^{\circ}C$, 6.54 mm/day, 3.98 m/s (southwesterly), and 1-11.7 h, respectively. Our results suggest that HAB events in the Yeosu area can be triggered and extended by heavy precipitation and massive movement of HAB from the East China Sea. Satellite images data from July to October 2002-2006 showed that the OC4 algorithm generally estimated high chlorophyll-a concentration ($2-20\;mg/m^3$) throughout the coastal area, whereas the RCA estimated concentrations at $2-10\;mg/m^3$. The surface velocity of chlorophyll-a movement from sequential satellite images revealed the same patterns in the direction of the Tsushima Warm Current.

Electrochemical Properties of Lithium Anode for Thermal Batteries (열전지용 리튬음극의 전기화학적 특성)

  • Im, Chae-Nam;Yoon, Hyun Ki;Ahn, Tae-Young;Yeo, Jae Seong;Ha, Sang Hyeon;Yu, Hye-Ryeon;Baek, Seungsu;Cho, Jang Hyeon
    • Applied Chemistry for Engineering
    • /
    • v.29 no.6
    • /
    • pp.696-702
    • /
    • 2018
  • Recently, the current thermal battery technology needs new materials for electrodes in the power and energy density to meet various space and defense requirements. In this paper, to replace the pellet type Li(Si) anode having limitations of the formability and capacity, electrochemical properties of the lithium anode with high density for thermal batteries were investigated. The lithium anode (Li 17, 15, 13 wt%) was fabricated by mixing the molten lithium and iron powder used as a binder to hold the molten lithium at $500^{\circ}C$. The single cell with 13 wt% lithium showed a stable performance. The 2.06 V (OCV) of the lithium anode was significantly improved compared to 1.93 V (OCV) of the Li(Si) anode. Specific capacities during the first phase of the lithium anode and Li(Si) were 1,632 and $1,181As{\cdot}g^{-1}$, respectively. As a result of the thermal battery performance test at both room and high temperatures, the voltage and operating time of lithium anode thermal batteries were superior to those of using Li(Si) anode thermal batteries. The power and energy densities of Li anode thermal batteries were also remarkably improved.

Development of a new armor unit against high waves (고파랑 대응 신형 소파블록 개발)

  • Park, Young Hyun;Youn, Daeok
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.6
    • /
    • pp.737-743
    • /
    • 2016
  • Coastal hazards such as high waves are expected to increase due to global climate change. Therefore, we investigated new armor unit structures for disaster prevention. Recently, a concrete caisson has been used in many breakwaters against high waves in South Korea, but the demand for concrete armor unit has increased due to the high cost and many installation requirements. Though many new armor units have been developed over the world since Tetrapod in 1950, few have been used due to lack of systematical development. The representative armor units in current use have many advantages, but they cannot be applied to waves higher than 8 m. One of the new armor units developed by the design guide based on recent trend and hydraulic model experiments were conducted. The new armor unit was developed as a single layer due to cost effectiveness. However, the thickness is close to 1.5 times by overlapping the alphabet A and V. It showed higher overtopping compared to a double layer because of the thickness and the high packing density. It has a high interlocking vertically but low horizontally. It shows good stability at 9 m in model testing.