• Journal of the Architectural Institute of Korea Structure & Construction
• /
• v.34 no.3
• /
• pp.37-42
• /
• 2018

The use of fly ash in construction materials is increasing worldwide due the various advantages of using it, such as to produce durable concrete, or to use less cement and thus lower carbon dioxide emissions. The quality of fly ash is often determined by loss on ignition value (LOI), where an upper limit of LOI is set in each country for quality control purpose. However, due to many reasons, production of high LOI fly ash is increasing that cannot be utilized in concrete, ending up in landfill. In this study, the effect of fly ash use in cementitious materials on nitrogen oxides adsorption is examined. In particular, the effect of using high LOI, and thus high carbon content fly ash on nitrogen oxides adsorption is investigated. The results suggest that the higher carbon content fly ash is related to higher nitrogen dioxide adsorption, although normal fly ash was also more effective in nitrogen dioxide adsorption than ordinary portland cement. Also, higher replacement rate of up to 40% of fly ash is beneficial for nitrogen dioxide adsorption. These results demonstrate that high carbon fly ash can be used as construction materials in an environmentally friendly way where strength requirement is low and where nitrogen oxides emissions are high.

• Resources Recycling
• /
• v.12 no.2
• /
• pp.45-53
• /
• 2003

In 2001, Korea produced a total of 4.91 million metric tons of fly ash, approximately 63.3% of which was recycled. Almost all of the recycled fly ash are used in concrete mixtures and cement industry. Therefore, in order to develop a new usage to increase the utilization of the fly ash, conductive induction was used in this research rather than triboelectrostatic. By applying conductive induction, we could verify the possibility of obtaining high purity fly ash below 1%LOI and high carbon fly ash over 70%LOI from raw fly ash. In this test, the potential difference between the two electrodes was conducted by changing the range of 8 to 16 kV.

• Analytical Science and Technology
• /
• v.15 no.6
• /
• pp.567-573
• /
• 2002

The most important and largest commercial outlet of fly ash in Korea is a replacement material of Portland cement in concrete industry. The high level of unburned carbon in ash brings about some malfunctions in concrete. Therefore, fly ash is refined to improve the quality as a concrete additive. In this process, a lot of the residual carbon is produced, and discarded now. In the present study, to find out a valuable outlet of the enriched carbon samples, the basic morphology of residual carbon in fly ash from Boryung power plant was investigated. The unburned carbon characterization included shape, size measurement, and chemical analysis was examined using scanning electron microscope (SEM) and energy dispersive X-ray spectrometer (EDX).

• Korean Journal of Materials Research
• /
• v.27 no.2
• /
• pp.76-81
• /
• 2017

Recently, there have been many efforts to establish suitable processes for recycling fly ash, which is produced in thermal power plants and which poses serious environmental problems. Use of fly ash as a major ingredient of ceramic tiles can increase fly ash utilization, as well as reduce the cost of raw materials in ceramic tile production. In this study, the effects of fly ash addition on ceramic tile properties such as bending strength, water absorption and porosity were investigated. A manufacturing process of ceramic tile was developed for utilization of fly ash with high carbon content. In this approach, it is important to hold the ceramic tiles at a temperature that is sufficient for carbon oxidation, before the pores supplying oxygen to the inside of the ceramic tile are sealed. Ceramic wall tiles were manufactured with 0-40wt% of fly ash addition. The water absorption and porosity of the fired body were slightly changed with increasing fly ash content up to 30wt% and decreased with greater amounts of fly ash addition. The bending strength of ceramic tile including 10wt% fly ash increased, reaching a level comparable to that of ceramic tile without fly ash.

• Journal of the Korean Ceramic Society
• /
• v.50 no.1
• /
• pp.18-24
• /
• 2013

This study was conducted to recycle fly ash containing an abundance of CaO generated from combustion in a circulating layer as a carbon storage medium. The study utilized XRD, TG-DTA and XRF analyses during the hydration of fly ash and identified calcium substances within fly ash that could be used in a carbonation process. $Ca^{2+}$ ions in the calcium substances were easily converted to hydrates. A carbonation experiment was done, which used the method of $CO_2$ gas injection to produce suspensions by mixing fly ash with distilled water. The results were analyzed using TG-DTA, XRD, and pH meter measurements. The study was able to verify that the reaction was completed at a $CO_2$ flow rate of 300cc/min approximately 30 minutes after an injection into a solution with a solid-liquid ratio of 1 : 10 of fly ash and distilled water. Moreover, the stirring time of the suspensions did not influence the reaction, and the reaction time was found to diminish as the portion of the fly ash became smaller. Thus, this study produced carbon storage fly ash having a $CO_2$ storage rate of about 71% through the utilization of the CaO content contained within fly ash.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.05a
• /
• pp.640-643
• /
• 2004

Synthetic lightweight aggregates are manufactured with recycled plastic and fly ash with 12 percent carbon. Nominal maximum-size aggregates of 9.5mm were produced with fly ash contents of 0 percent, 35 percent, and 80 percent by total mass of the aggregate. An expanded day lightweight aggregate and a normal-weight aggregate were used as comparison. Mechanical properties of the concrete determined included density, compressive strength, elastic modulus, and splitting tensile strength. Compressive and tensile strengths were lower for the synthetic aggregates; however, comparable fracture properties were obtained. Relatively low compressive modulus of elasticity was found for concretes with the synthetic lightweight aggregate, although high ductility was also obtained. As fly ash content of the synthetic lightweight aggregate increased, all properties of the concrete were improved.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2023.05a
• /
• pp.295-296
• /
• 2023

This study evaluated the compressive strength after making mortar with low cement composition for carbon-neutral steam curing to respond to climate change. Blast furnace slag, fly ash, and ultra-high powder fly ash were used as substitutes for cement. The cement substitute was used at 40% of the mass of cement, and after steam curing, the compressive strength was measured on the 1st, 3rd, 7th and 28th days of age. As a result of the experiment, at the age of 1 day, the mixture using only cement showed the highest strength, but from the 3rd day, the specimen using ultra-high powder showed a high strength development rate, followed by blast furnace slag and fly ash.

• Advances in concrete construction
• /
• v.6 no.4
• /
• pp.407-422
• /
• 2018

The study evaluates properties of brick having coal ash and explores the possibility of utilization of coal bottom ash and coal fly ash as an alternative raw material in the production of coal ash bricks. Lower cement content was used in the investigations to attain appropriate strength and prohibit high carbon content that is cause of environmental pollution. The samples use up to 7% of cement whereas sand was replaced with bottom ash. Bricks were tested for compressive strength, modulus of rupture, ultrasonic pulse velocity (UPV), water absorption and durability. The results showed mix proportions of bottom ash, fly ash and cement as 1:1:0.15 i.e., M-15 achieved optimum values. The coal ash bricks were well bonded with mortar and could be feasible alternative to conventional bricks thus can contribute towards sustainable development.

• Magazine of the Korea Concrete Institute
• /
• v.3 no.3
• /
• pp.101-110
• /
• 1991

Results of an experimental study on the manufacture, the mechanical properties and watertightness of pitch - based carbon fiber reinforced fly ash. cement composites are presented in this paper. The carbon fiber reinforced fly ash. cement composites using early strength cement silica powder and a small amount of stylene butadiene rubber latex are prepared with carbon fiber, foaming agents and mixing conditions. As a result, the mechanical and physical properties such as compressive , tensile and flexural strengths, watertightness and drying shrinkage of lightweight carbon fiber reinforced fly ash cement composites are Improved by using a samll amount of stylene butadiene rubber latex. Also, the manufacturing pnx:ess technology of carbon fiber reinforced fly ash . cement composItes is developed. The development and applications of precast products of lightweight carbon fiber remforced cement composites are expected in the near future.

• Journal of the Korean Ceramic Society
• /
• v.49 no.2
• /
• pp.185-190
• /
• 2012

The purpose of this study was to examine a possibility that fly ash could be used as raw material for carbonation by conducting the experiment on magnetic separation and hydration of fly ash that contained a large amount of CaO composite. Wet magnetic separation experiment was performed to remove the component of magnetic substance that contained fly ash, which aimed at increasing the content of CaO in the non-magnetic domain. The selected fly ash was used for hydration experiment before the TG-DTA, XRF and XRD analyses were made to confirm the Ca component that could be carbonated. Then, the fly ash was turned to a hydrate that was favorable to dissociation of $Ca^{2+}$ ion. As a result, the magnetic separation enabled detecting the content of CaO component by up to 61 wt% in the non-magnetic domain. Since the hydrate was confirmed, it is believed that the fly ash can be used as raw material for carbonation.