• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.459-460
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• 2008

Zinc oxide micro rods were fabricated using as chemical bath deposition ok photolithography. Vertically aligned Zinc Oxide rod array as grown by chemical bath deposition method on Zinc Oxide template layer. The ZnO template layer was deposited on glass and the pattering was made by standard photolithography technique. The selective growth of ZnO micro rods were achieved with the masked ZnO template layer substrate. The fabricated ZnO micro rods were found to be single crystalline and have grown along hexagonal c-axis direction of (0002) which is same as the preferred growth orientation of ZnO template layer. The ZnO micro-rod array structure was implemented as a window layer in Cu(InGa)Se2 solar cell and its effect on photovoltaic efficiency was examined.

• 한국분말재료학회지
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• 제6권4호
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• pp.307-313
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• 1999

The effect of carbon content on the shape of WC grains dispersed in the Co-rich matrix during liquid phase sintering of WC-35%Co hard metals has been determined. The shape of WC grains was observed using SEM stereography after removing cobalt matrix with boiling hydrochloric acid solution. The WC grains changed from hexagonal to trigonal prism as the carbon content increased in the two-phase region of(WC + $\beta$ - Co), while the morphology of WC grains changed from trigonal to hexagonal shape as the carbon content decreased. The morphology of WC grains changes reversibly along with carbon loss or carbon pick-up. Morphology change of WC grains is attributed to crystal structure of WC, which has an asymmetric array of carbon atoms. There are two types of prismatic planes having different numbers of broken W-C bonds in WC grains. It is scrutinized that as the carbon content increases, the high energy prism planes grow fast and the crystals change from hexagonal to trigonal shape. On the other hand, when the carbon content decreases, the high energy prism planes are dissolved accompanying split of (100) plane into (101) and (101) planes.

• 한국세라믹학회지
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• 제40권8호
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• pp.784-790
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• 2003

본 논문은 세라믹재료가 강화재로써 보강된 복합재료가 횡방향의 단축인장하중을 받는 경우, 복합재료의 변형, 재료내 발생되는 손상의 특징, 및 응력-변형률 특성에 관한 컴퓨터 해석결과이다. 해석은 SiC/Ti 시스템을 대상으로 하였으며, 특성은 강화재의 배열형태, 강화재/기지 계면에서의 결합유무, 강화재의 부피분율변화에 대하여 각기 해석되었다. 계면에서 강한 결합이 있는 복합재와는 달리, 약한 결합의 복합재는 인장하중에 의하여 세라믹/기지 계면에서 분리가 발생되었다. 이 분리는 전체 복합재의 강성을 감소시키며, 세라믹 강화재의 부피분율이 증가할수록 탄성계수 및 횡방향 평균응력의 최종크기를 나타내는 한계응력의 크기감소로 나타났다. 계면결합이 강한 경우는 세라믹 부피분율이 증가할수록 사각형 배열보다는 육각형배열의 복합재에서 다소 큰 증가율로 나타났다. 그러나, 계면결합이 약한 경우는 세라믹 부피분율이 증가할수록 사각형 배열보다는 육각형배열의 복합재에서 상대적으로 큰 감소율로 해석되었다. 본 연구의 해석결과는 알려진 문헌의 결과와 잘 일치하였다.

• 한국전기전자재료학회논문지
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• 제23권3호
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• pp.222-227
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• 2010

ZnO nanorods array have been grown on the seed crystal coated Si(100) substrate by hydrothermal method. The growth, structural and optical properties of ZnO nanorods array were investigated with a variation of precursor concentration from 0.01 M to 0.04 M. The array density of grown ZnO nanorods per same area was increased with increasing the concentration of precursor solution. Vertically aligned ZnO nanorods with hexagonal wurtzite structure have highly preferred c-axis orientation along (002) lattice plane. Especially, ZnO nanorods array developed from 0.04 M precursor solution showed a diameter of about 85 nm and length of 1.2 {\mu}m$ without any crystallographic defects. The photoluminescence spectra of ZnO nanorods from heavier precursor concentration exhibited stronger UV emission around 380 nm corresponding with near-band-edge emission.

• 한국재료학회지
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• 제21권2호
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• pp.111-114
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• 2011

As a growth-template of ZnO nanorods (NR), a hexagonal $\beta-Ni(OH)_2$ nanosheet (NS) was synthesized with the low temperature hydrothermal process and its microstructure was investigated using a high resolution scanning electron microscope and transmission electron microscope. Zinc nitrate hexahydrate was hydrolyzed by hexamethylenetetramine with the same mole ratio and various temperatures, growth times and total concentrations. The optimum hydrothermal processing condition for the best crystallinity of hexagonal $\beta-Ni(OH)_2$ NS was determined to be with 3.5 mM at $95^{\circ}C$ for 2 h. The prepared $Ni(OH)_2$ NSs were two dimensionally arrayed on a substrate using an air-water interface tapping method, and the quality of the array was evaluated using an X-ray diffractometer. Because of the similarity of the lattice parameter of the (0001) plane between ZnO (wurzite a = 0.325 nm, c = 0.521 nm) and hexagonal $\beta-Ni(OH)_2$ (brucite a = 0.313 nm, c = 0.461 nm) on the synthesized hexagonal $\beta-Ni(OH)_2$ NS, ZnO NRs were successfully grown without seeds. At 35 mM of divalent Zn ion, the entire hexagonal $\beta-Ni(OH)_2$ NSs were covered with ZnO NRs, and this result implies the possibility that ZnO NR can be grown epitaxially on hexagonal $\beta-Ni(OH)_2$ NS by a soluble process. After the thermal annealing process, $\beta-Ni(OH)_2$ changed into NiO, which has the property of a p-type semiconductor, and then ZnO and NiO formed a p-n junction for a large area light emitting diode.

• Journal of the Optical Society of Korea
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• 제19권3호
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• pp.265-271
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• 2015

We propose a reactive mesogen (RM) lens array to obtain good focusing behavior along with a short focal plane, where the focusing behavior is switchable according to the polarization state of incident light. Polarization-dependent focusing behavior is obtained using a planoconvex RM microlens array on a planoconcave isotropic lens template. Even though the sagitta of our RM lens is high, to obtain the short focal length, the RM layer can be aligned well by introducing a top-down alignment effect, using a nanogrooved template. The optical noise due to the $moir{\acute{e}}$ effect generated by the nanogrooves on the surface of the planoconvex RM layer can be removed simply by overcoating a thin RM layer, which is self-aligned by the geometric surface effect, without an additional alignment process. We demonstrate a hexagonal-packed RM lens array that has a very high fill factor and symmetric phase profile, for an ideal lens.

• 한국재료학회지
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• 제21권12호
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• pp.697-702
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• 2011

Two-dimensional (2D) nano patterns including a two-dimensional Bravais lattice were fabricated by laser interference lithography using a two step exposure process. After the first exposure, the substrate itself was rotated by a certain angle, $90^{\circ}$ for a square or rectangular lattice, $75^{\circ}$ for an oblique lattice, and $60^{\circ}$ for a hexagonal lattice, and the $90^{\circ}$ and laser incident angle changed for rectangular and the $45^{\circ}$ and laser incident angle changed for a centered rectangular; we then carried out a second exposure process to form 2D bravais lattices. The band structure of five different 2D nano patterns was simulated by a beam propagation program. The presence of the band-gap effect was shown in an oblique and hexagonal structure. The oblique latticed ZnO nano-photonic crystal array had a pseudo-bandgap at a frequency of 0.337-0.375, 0.575-0.596 and 0.858-0.870. The hexagonal latticed ZnO nano-crystallite array had a pseudo-bandgap at a frequency of 0.335-0.384 and 0.585-0.645. The ZnO nano structure with an oblique and hexagonal structure was grown through the patterned opening window area by a hydrothermal method. The morphology of 2D nano patterns and ZnO nano structures were investigated by atomic force microscopy and scanning electron microscopy. The diameter of the opening window was approximately 250 nm. The height and width of ZnO nano-photonic crystals were 380 nm and 250 nm, respectively.

• 한국전기전자재료학회논문지
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• 제22권8호
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• pp.682-688
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• 2009

A periodic away of zinc oxide(ZnO) micro-rods as fabricated by using chemical bath deposition and photo-lithography. Vertically aligned ZnO micro-rods array was successfully grown by chemical bath deposition method on ZnO seed layer. The ZnO seed layer was deposited on glass and the patterning was made by standard photo-lithography technique. The selective growth of ZnO micro-rods as achieved with the masked ZnO seed layer. The fabricated ZnO micro rods were found to be single crystalline and have grown along hexagonal c-axis direction of (0002) which is same as the preferred growth orientation of ZnO seed layer.

• 한국항공우주학회지
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• 제34권10호
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• pp.24-31
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• 2006

본 논문에서는 유연수지 복합재료에 대하여 기하학적 비선형해석을 수행하였다. 실제 랜덤한 섬유배열을 사각배열과 육각배열로 가정하고 각각에 대해 단위구조를 정의하였다. 다양한 하중상태를 수치적으로 모사하여 단위구조해석을 통해 전체 구조물의 응력-변형률 선도를 예측하였고 이로부터 등가물성치를 계산하였다. 해석시 유연수지의 초탄성 성질을 정의하기 위해 Mooney-Rivlin모델을 사용하였다. 계산결과, 유연수지 복합재료 구조물은 변형률 증가에 따라 비선형의 응력-변형률 관계를 보였다. 비선형성은 횡방향 하중 상태에서 더욱 두드러지게 나타났으며, 이 경우 복합재 단면의 섬유배열 형태에 따라 상당한 차이를 보여주었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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• pp.922-925
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• 2003

The interest of self-organization materials that have uniform and regular structure in nano scale has been grown due to their utilization in various fields of nanotechnology. An attractive candidate among these materials is anodic aluminum oxide film, which are formed by anodization of aluminum in an appropriate acid solution. The anodic aluminum oxide film has a highly ordered porous structure with very uniform and nearly parallel pores that can be organized in an almost precise close-packed hexagonal structure. In this study, we attempt to make Au dot arrays, which were fabricated using anodic aluminum oxide film as an evaporation mask. The Au dot arrays have a uniform sized dots and spacing to its neighbors and the average diameter of Au dots is about 60 nm corresponding to them of the mask.