• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.4
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• pp.618-624
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• 1989

Ultrasonically induced bubble formation in thermoplastic matrix was investigated experimentally and theoretically. polystyrene was saturated with nitrogen under the pressure of 0.2 to 3.45 MPa in a pressure chamber, followed by pressure release and ultrasonic bubble nucleation. Zinc stearate was added to polystyrene as the nucleating agent to induce heterogeneous nucleation. Various mixture of low density polyethylene and polyethylene wax was also saturated with the gas. The foamed specimens with or without ultrasonically induced bubble nucleation was modeled by modifying the classical nucleation theory. The rate of ultrasonic nucleation was predicted for homogeneous and heterogeneous nucleation at a conical cavity. This study showed that the heterogeneous and heterogeneous nucleation at a conical cavity. This study showed that the heterogeneous nucleation must be employed for ultrasonic production of bubbles in a viscous fluid and the homogeneous nucleation for ultrasonic production of bubbles in a low viscosity fluid.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.6
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• pp.813-822
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• 1998

The microexplosion of a slurry droplet was considered to be caused by the shell formation and the following pressure build-up in the shell which would be promoted by the suppression of evaporation, subsequent superheating and heterogeneous nucleation of liquid carrier. To closely investigate the pressure build-up and the heterogeneous nucleation, a numerical model was introduced by considering the internal temperature distributions with the shell formation, suppression of evaporation and pressure build-up inside. The microexplosion time was estimated by postulating the limit of superheat for heterogeneous nucleation. The simulation yielded a reasonably good agreement with experimental results for Al/n-heptane slurry droplets under various solid loadings.

• Nuclear Engineering and Technology
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• v.38 no.2
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• pp.175-184
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• 2006

Boiling and flashing are driven by the same physics for nucleation, bubble growth, departure etc. An adequate model of boiling has to describe the flashing too. The subject of this paper is to prove this uniqueness of the elementary physics driving the both processes.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.1885-1890
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• 2008

3-D heterogeneous nucleation was simulated by classical molecular dynamics (MD), where the Lennard-Jones (LJ) gas and solid cluster-seed molecules have argon and aluminum properties, respectively. There are three shapes of cluster-seeds, cube, rod, and sphere, and three classes of masses and the simulation took place under nine supersaturation ratios, making a total of 81 calculations. Results show that the dimension of the cluster-seed highly affects the rates of cluster development. In order to analyze heterogeneous nucleation above and below the critical supersaturation ratio, growth rate and liquefaction rate were separately defined to supplement the investigation. Design of experiments (DOE) was used for analysis which displayed that the shape and mass of the cluster-seed are prominent for the growth rate, while the supersaturation ratio is most significant followed by the mass for liquefaction rate. The significance of the supersaturation ratio for overall liquefaction suggests that thermal diffusion is more dominant than mass interactions for this system.

• Applied Microscopy
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• v.43 no.3
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• pp.122-126
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• 2013

The heterogeneous nucleation of the ${\Theta}^{\prime}$ phase on nanoscale precipitates has been investigated using a combination of three-dimensional atom probe tomography and high-resolution transmission electron microscopy. Two types of ${\Theta}^{\prime}$ phases were observed, namely small (~2 nm thick) cylindrical precipitates and larger (~100 nm) globular precipitates and both appear to be heterogeneously nucleated on the nanoscale precipitates. The composition and crystal structure of precipitates were directly analyzed by combination of two advanced characterization techniques.

• Particle and aerosol research
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• v.5 no.4
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• pp.171-178
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• 2009

$PM_{2.5}$ is one of critical air pollutants due to its high absorbability of heavy metallic fumes, PAH and bacillary micro organisms. Such a fine particulate matter is often formed through various nucleation processes including condensation. This study attempts to find the nucleation behaviors of $PM_{2.5}$ arisen from coal power stations using a classical heterogeneous Fletcher's theory. The numerical simulation by C-language could approximate the nucleation process of $PM_{2.5}$ from water vapor, of which approach revealed the required energy for embryo formation and embryo size and nucleation rate. As a result of the calculation, it was found that wetting agents could affect the particle nucleation in vapor condensation. In particular, critical contact angle relates closely with the vapor saturation. Particle condensation could be reduced by lowering the angles. The wetting agents aid to decrease the contact angle and surface tensions, thereby may contribute to save the formation energy.

• Fibers and Polymers
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• v.4 no.3
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• pp.102-106
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• 2003

Crystallization behaviour of blends of different MFI isotactic polypropylenes (PP), and blends of PP with carbon nanofibre have been investigated by DSC and polarizing optical microscope. Both higher MFI PP component and the carbon nanofibre in the blend influence the nucleation activity of the melt during non-isothermal crystallization. In presence of carbon nanofibre, the sherulitic growth rate is highly disturbed. The calculation of nucleation activity indicates that carbon nanofibres act as active substrate for heterogeneous nucleation.

• Journal of the Korean Ceramic Society
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• v.38 no.11
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• pp.1030-1036
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• 2001

Hydroxyapatite[COL] nanocomposite was prepared through coprecipitation process. The chemical bond formation between HAP and COL was confirmed by diffusive reflectance FT-IR and TEM observation. Higher concentration of COL in the preparation induced tiny nanocrystalline composite particles, but lower concentration of COL contributed to form the well developed HAP particles. From TEM observation and ED(Electron Diffraction) pattern the embedded HAP nanoparticles were oriented along the c-axis of COL fiber. In an aqueous system of constant [Ca$\^$2+/] and [PO$_4$$\^$3-/], quantity of soluble COL matrix was doing an important role of controlling the heterogeneous nucleation site for the formation of HAP nanocrystals. Higher concentration of COL will provide more nucleation sites for Ca$\^$2+/ and so the concentration of calcium ions for the total number of active nucleation sites will be getting relatively dilute.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05b
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• pp.241-246
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• 1996

An analytical model to calculate rate of vapor generation due to heterogeneous wall nucleation in flashing flow is developed. In the present model, an important parameter of the vapor generation term, i.e. nucleation site density is calculated by integrating its probability distribution function with respect to active cavity radius. The limits of integration are minimum and maximum active cavity radii, and these are formulated using an active cavity model for nucleate boiling. This formulation, therefore. can statistically account for the effect of surface specific thermo-physical and geometric conditions on the vapor generation rate and flashing inception. For verifying the adequacy of the present model, steady state two-fluid and the bubble transport equations are solved with applicable constitutive equations. The applicable region of the bubble transport equation is also extended to churn-turbulent flow regime to predict interfacial area concentration at high void fraction. Predicted results in terms of axial pressure and void fraction profiles along the channels are compared with experimental data of Super Moby Dick and BNL Reasonable agreements have been achieved and this shows the applicability of the present model to flashing flow analysis.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.12
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• pp.1576-1585
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• 1997

The microexplosive combustion of a slurry droplet was investigated experimentally. The microexplosion has been approximately considered to be caused by pressure build-up in the shell and to be promoted by heterogeneous nucleation of liquid carrier, which is due to the suppression of evaporation and subsequent superheating of liquid carrier. To closely investigate the pressure build-up and the heterogeneous nucleation, the experiments were conducted in an electric combustor, of which temperature was controllable (400 K-900 K). And the effects of two aligned droplets on the interactive combustion and microexplosion were found in a hot post region of a flat flame burner. Transient internal temperature distributions for slurry droplets were measured. And the shell formation and the microexplosion of suspended A1/JP-8 and Al/n-heptane slurry droplets were examined with various surfactant concentrations (0.5-5 wt%) and solid loadings (10-50 wt.%). The microexplosion time of binary array of droplets was found to be less than that of the isolated droplet due to radiative interaction between droplets.