• Carbon letters
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• v.2 no.1
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• pp.1-8
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• 2001

Exfoliated graphite was found to sorb selectively a large amount of heavy oil, about 80 g of heavy oil floating on water per 1 g of exfoliated graphite, which is highly possible to be applied to recovering spilled heavy oil. Sorption capacity, selectivity and kinetics of exfoliated graphite were reviewed. The possibility of recovery of heavy oil from exfoliated graphite and recycling of both recovered heavy oil and exfoliated graphite was also discussed. Its sorption performance was compared with other materials which were reported to show sorption of heavy oil.

• Journal of Korean Society of Water and Wastewater
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• v.12 no.2
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• pp.31-41
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• 1998

As the leakage of crude oil from tankers breaks out frequently, it caused a serious problem for ocean pollution and calls for developing treatments to handle the leaked crude oil and mitigate the pollution. Thus it is required to develop new purification technolgies and appropriate treatment systems which have sufficient treatment capability in order to cope with the anticipated ocean pollution. In this experiment, A and B type heavy oils were used to make the emulsion of both water containing heavy oil and sea-water containing heavy oil. The following are the main results from this study ; 1. When A and B type heavy oils were added to the original sea-water and treatedin the homogrenizer respectively, the particle of oil beacame smaller in both cases. Under the same condition, while the initial oil density of sea-water containing B-heavy oil is higher than of emulsion with A-heavy oil, the particle of A-heavy oil is finer than that of B-heavy oil. 2. When A and B type heavy oils were added to distilled water and treated in the homogenizer respectively, the particle was more dispersed and finer than that in the case of sea-water in both cases. In this result, the water containing oil formed more stable emulsion than the sea-water containing oil. 3. In this experiment, all emulsions showed oil in water types. 4. Since the oil particle is larger in the sea-water than in the distillated water, interms of elimination of oil, it is thought to be more important to give Membrane treatment after implementing sandfilter, activity carbon, coagulation-sedimentation and floating separation as pre-treatment.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.6
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• pp.471-481
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• 2005

Heavy crudes (bitumen) are extremely viscous and contain high concentrations of asphaltene, resins, nitrogen and sulfur containing heteroaromatics and several metals, particularly nickel and vanadium. These properties of heavy crude oil present serious operational problems in heavy oil production and downstream processing. There are vast deposits of heavy crude oils in many parts of the world. In fact, these reserves are estimated at more than seven times the known remaining reserves of conventional crude oils. It has been proven that reserves of conventional crude oil are being depleted, thus there is a growing interest in the utilization of these vast resources of unconventional oils to produce refined fuels and petrochemicals by upgrading. Presently, the methods used for reducing viscosity and upgradation is cost intensive, less selective and environmentally reactive. Biological processing of heavy crudes may provide an ecofriendly alternative or complementary process with less severe process conditions and higher selectivity to specific reactions to upgrade heavy crude oil. This review describes the prospects and strengths of biological processes for upgrading of heavy crude oil.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.1-10
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• 2000

An experimental study regarding the effect of emulsions on RO is presented. Heavy oil was added to the sea water and the distilled water separately and treated for 30 minutes by a homogenizer to make emulsions. For the case of the sea water without heavy oil the permeate decreased from the beginning of the experiment. Chloride and conductivity increased with time, due to the fouling occurring as the suspended solids in the sea water accumulated on the membrane surface. Rejection rate of salt was 99.6~99.7%. As for the sea water containing heavy oil, the permeate decreased slowly from the beginning of the experiment. This result was the same for the case of the sea water only. However. chloride and conductivity increased significantly when heavy oil was added. In the second experiment with sea water containing heavy oil, the operation time of RO was reduced considerably. With addition of oil, the chloride increased greatly, while the permeate reduced comparatively. In the experiment where emulsion of $0.3{\sim}0.8mg/{\ell}$ was supplied to RO. oil concentration was about 10ppb in the permeate at the end of the experiment. In case of the distilled water containing heavy oil. the conductivity increased. However. the permeate reduced to 30% compared to the case of the sea water containing heavy oil. The case of sea water containing heavy oil showed an opposite result, but the effect of the addition of oil on RO was significant. Oil caused fouling of the RO and the contamination of the whole system, and as the result the system could not be operated properly. As a result the membrane capacity, the amount and water quality of permeate deteriorated significantly.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.1
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• pp.88-92
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• 2006

This study is intended to check the flame temperature to raise in burning grade C heavy fuel oil and emulsion fuel oil in a boiler and to measure the concentration of Dry Shoot(DS) and Soluble Organic Fraction(SOF) after collecting the Particulate Matters (PM). The flames temperature in boiler was measured by burning grade C heavy oil and oil-water emulsion (C heavy oil $70\%\;and\;30\%$ of water) Combustion characteristics of two fuels was also compared by trapping particulate matters (PM) in exhaust gas and measuring the generated quantities of DS and SOF in fuel gas.

• Journal of Advanced Marine Engineering and Technology
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• v.7 no.2
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• pp.15-21
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• 1983

Preparing for treatment and management of the emulsified fuel oil which will be generalized henceforth, this paper is an attempt to examine the viscosity-temperature characteristics of emulsified heavy fuel oil which is mixed with water and emulsifier in various mixture ratio by mechanical mixer. The experimental results are summarized as follows: 1. The viscosity-temperature characteristics of the emulsified C & B grade heavy fuel oil mixed with water of same or less weight, is changed according to log.log(v+0.6)=b-3.8log T. 2. The emulsifier has to be added to the emulsified A grade heavy fuel oil mixed with water of same or less weight, because it is instable. Especially if the emulsifier is sodium stearate, it is added more than 0.3% of the weight of oil and water. 3. In the emulsified A grade heavy fuel oil mixed with water and emulsifier, the higher the ratio of water addition becomes, the higher the viscosity is and the more the viscosity-temperature slope decreases. But the higher the ratio of emulsifier addition is, the more the viscosity-temperature slope increases. In this case, the linearity of viscosity-temperature characteristic curve is poorer than that of B and C grade heavy fuel oil. 4. In the emulsified A grade heavy fuel oil mixed with emulsifier of 0.3% or less, the emulsion type is O/W type when water addition ratio is 40%, but it is W/O type when it is 10%, 20%, 30% and 50%.

• Proceedings of the Korean Professional Engineer Association Conference
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• 1984.12a
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• pp.84-91
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• 1984

Heavy Residual Fuel oils is a mixture of reduced crude from crude unit, bottom products from vacuum and/or catalytic cracking unit with distillate to meet the specification and generally used as Heavy Fuel Oil for large combustion engines, boilers, etc…. But this study was made to investigate Heavy Residual Fuel oils for using as industrial raw material and resulted the following possibilties as valuable raw material as well as Heavy Fuel Oil. 1) Production of straight asphalt through vacuum distillation unit. 2) Using straight asphalt from vacuum distillation unit for manufacturing of Blown Asphalts, Cut Back Asphalts, Emulsified Asphalts and Asphalt Compound, etc…. 3) Using waxy oil side streams for manufacturing of raw oil to be Lube Oil base stocks through solvent dewaxing. 4) Production of lube base oils from dewaxed raw oil through chemical treatments. 5) Manufacturing of paraffine wax from slack wax to be produced as by product of dewaxing process.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.4
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• pp.83-90
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• 2019

In this study, the characteristics of the SRF (Solid Refuse Fuel) prepared by blending each of the additives (citrus peel, waste wood, coal) in the heavy oil fly ash, evaluating the heavy oil fly ash recyclability. Recycling SRFs were fabricated by pellet extruding method after blending the heavy oil fly ash and additives based on 30% moisture content. As a result, the formability of the SRFs was excellent under condition of blending heavy oil fly ash with coal or citrus peel and the highest calorific value was 4,274 kcal/kg at heavy oil fly ash mixed with coal. Therefore, the formability and calorific value were improved when the heavy oil fly ash was mixed with coal(20 wt%) at 30% moisture content. From these results, the applicability of SRFs with additives was confirmed by using the heavy oil fly ash from J thermal power plant.

• Journal of Biosystems Engineering
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• v.24 no.2
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• pp.107-114
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• 1999

To find the best combustion conditions in the heavy oil burner kinetic viscosity of heavy oil A, B and C at different temperature range, from 40 to 140$^{\circ}C$, and the droplet sizes of the heavy oils at different temperature and pump pressure were measured. And, combustion characteristics were investigated under the different conditions : two different heavy oil and three different oil temperature. At temperature of 70, 100, 130$^{\circ}C$ the kinetic viscosity of heavy oil A and B are 7.9, 5.7, 4.3 and 30.4, 13.7, 7.9cSt, respectively. The greatest and smallest viscosity were 7,455 cSt at C oil on 27$^{\circ}C$ and 4.26cSt at A oil on 140$^{\circ}C$. The magnitude of viscosity difference between at 100$^{\circ}C$ and 140$^{\circ}C$ under 6 cSt in cases of A and B oil, but more than 30cST on C oil. Of the droplet sizes, the biggest and smallest droplet size in A oil were 98$\mu\textrm{m}$ at oil temperature of 130$^{\circ}C$(4.3cSt), pump pressure of 1.57MPa and 72$\mu\textrm{m}$ at 70$^{\circ}C$(7.9cSt), 2.35MPa, respectively. It appeared that as spraying pressure increased the droplet size decreased, however, no distinct differences were found in the effects of kinetic viscosity on the droplet sizes of the test range. The best combustion performance was observed when droplet size, spraying pressure and oil temperature were 73$\mu\textrm{m}$, 2.35MPa and 70$^{\circ}C$ producing CO2 of 13.1%, CO of 13ppm and flue gas temperature of 250$^{\circ}C$ in A oil combustion For B oil, it was100$^{\circ}C$, 2.35MPa, 52$\mu\textrm{m}$, producing CO2 of 10ppm and flue gas temperature of 260$^{\circ}C$. In general, it appeared that better combustion results were observed in the smaller droplets produced burner condition.

• Journal of the Korean Society of Industry Convergence
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• v.21 no.6
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• pp.355-360
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• 2018

The product developed in this study is a ceramic catalyst filter for 1 ton heavy-oil boiler that can simultaneously process dust and nitrogen oxides. This has been developed for simultaneous processing of nitrogen oxides and dust at high efficiency of hot exhaust gas (approximately $300^{\circ}C$) generated after burning 1 ton heavy oil boiler. Ceramic catalytic filters for 1 tonne heavy-duty glass display are technologies that remove 90% of dust and 85% or more of nitrogen oxides. This is an improved new technology to integrate exhaust ventilation and desiccation devices into one, thereby reducing the production process and improving the economy. To this end, the performance test of the catalytic filter for heavy oil boilers was carried out, and the durability of the PLC circuit was constructed.