• Title/Summary/Keyword: heavy metal distribution

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Vertical Distribution of Heavy Metals in Paddy Soil Adjacent to Lead and Zinc Mining Sites and Their Relation to Soil Characteristics (연.아연 금속광산 주변 농경지 토양중 중금속의 수직분포와 토양특성과의 관계)

  • 이민효;유홍일;서윤수
    • Journal of the Korean Society of Groundwater Environment
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    • v.1 no.2
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    • pp.80-84
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    • 1994
  • The objective of this study was to find out the relationships between the vertical distribution of heavy metals in paddy soils and some soil characteristics. One hundred eight soil samples were collected by soil depths from 27 points of paddy fields in the vicinity of lead-zinc mining sites, and heavy metal contents and the physico-chemical characteristics of the soils were analysed. The results obtained were summarized as follows; 1) Distribution of heavy metals (Cd, Cu, Pb, Zn and As) by soil depths were ranged 42-51% in 0- 15 cm, 21-29% in 15- 30 cm, 12- 17% in 30-60 cm and 11-14% in 6o-100 cm. 2) The distribution of As by soil depth showed clear difference between sandy loam and loam, while that of Cd, Cu, Pb and Zn did not show any difference between these textures. 3) Distribution of Cd, Cu, Pb, Zn and As by different soil depths showed significantly negative correlation with soil pH value but they showed significantly positive correlation with soil organic matter content. 4) Cadmium, copper, lead, and zinc in soil had tendency to be highly correlated in each soil depth. Especially, high correlation was shown at the depth of 0- 15 cm, 30-60 cm and 60-100 cm for Pb and Zn, and 0-15 cm for Cd and Zn. Arsenic in soil was not correlated with these heavy metals.

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Concentration of Heavy Metal and Alteration of Reproductive and Histological Biomarker of Mytilus galloprovincialis in Gamak Bay of the Southern Coast of Korea (한국 남해안 가막만에서 채집된 지중해담치, Mytilus galloprovincialis의 체내 중금속 농도와 생식 및 조직학적 지표 변화)

  • Jeon, Mi Ae;Kang, Ju Chan;Lee, Jung Sick
    • The Korean Journal of Malacology
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    • v.29 no.1
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    • pp.33-41
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    • 2013
  • This study investigated concentration of metal ions, intersexuality and histological alterations of digestive gland in Mytilus galloprovincialis. Samples were collected from two areas of Gamak Bay in May, 2010. The concentration of metal ions showed that Al ($366.5{\pm}249.7$ mg/kg) was highest and Zn ($179.5{\pm}67.8$ mg/kg) was second high concentration. Co ($1.0{\pm}0.2$ mg/kg) was lowest. The intersexuality was 26.4% and males (38.8%) was higher than the females (12.9%). Intersex type was observed four types. Destruction of digestive tubule epithelium was highest among other biomarker in digestive gland. Distribution of basophilic cell and lipofuscin was 6.1% and 1.5%, respectively.

Distribution of Cadmium, Copper, Lead, and Zinc in Paddy Soils around an Old zinc Mine (가학광산 주변 논토양의 카드뮴, 구리, 납 및 아연 함량 분포)

  • Yoo, Sun-Ho;Ro, Kwang-Jun;Lee, Sang-Mo;Park, Moo-Eon;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.4
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    • pp.424-431
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    • 1996
  • This study was carried out to provide information for establishing counter measures of soil pollution through analysis of Cd. Cu, Pb, and Zn in paddy soils and brown rice. Cadmium, Cu, Pb, and Zn contents in soils were analyzed and distribution maps for these heavy metals were prepared. Heavy metal contents in brown rice were also measured. Average contents of Cd, Cu, Pb, and Zn in surface paddy soils extracted with 0.1 N HCl were 7.4, 35.8, 98.9, and $118.8mg\;kg^{-1}$, respectively. These were 9 times (Cu) to 50 times (Cd) higher than the background level of heavy metals in unpolluted paddy soils in Korea. The contents of Pb and Zn were lower than those measured in 1980, whereas Cd content did not decrease. The levels of heavy metal contamination in paddy soils may not affect growth or yield of rice plant, however, Cd contents indicated a level of serious concern to humans. The average contents of Cd, Cu, Pb, and Zn in brown rice were 0.38, 2.38, 1.31 and $22.31mg\;kg^{-1}$, respectively.

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Emission Characteristics of PMs and Heavy Metals from Industrial Hazardous Waste Incinerators (산업 폐기물 소각시설의 입자상 물질 및 중금속의 배출특성)

  • 유종익;이성준;김기헌;장하나;석정희;석광설;홍지형;김병화;서용칠
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.3
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    • pp.213-221
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    • 2002
  • The emission characteristics of particulate matter (PMs) and heavy metals from hazardous industrial wast incinerators were investigated. The particle size distribution (PSD) of PM-10 showed different patterns for two tripes of incinerators; stoker and rotary kiln. However both types showed bimodal form at inlet of air pollution control devices (APCD) and each peak (mode) is located at smaller than 1 ${\mu}{\textrm}{m}$ and near 10 ${\mu}{\textrm}{m}$. It could explain the growth of fine PM by nucleation/coagulation/condensation of metal vapors for fine mode. The PSD of PM-10 after APCD was also influenced by APCD types that had different collection mechanism, and both electrostatic precipitator and bag filter showed less collection efficiency for particles ranged from 0.2 to 0.4 ${\mu}{\textrm}{m}$ and led to a mode in the range of 0.2 to 0.8 ${\mu}{\textrm}{m}$. However the hag filter showed two modes of PSD, while the electrostatic precipitator had one peak. The PMs and heavy metals emission factors, the representative value of emission quantity for sources, for tested facilities were developed. The emission factor of uncontrolled total PM and PM-10 were 14.7 and 7.05 kg/ton waste, respectively. The emission factors from this study were a little bit different with those from US EPA AP-42. It may thus be appropriate to use these results in the course of developing national emission factors.

중금속으로 오염된 사격장토의 동전기 정화 -실내 파일롯 실험 중심으로-

  • 한상재;김병일;이정철;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.69-72
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    • 2003
  • The purpose of this study is the development of hybrid horizontal electrokinetic(EK) remediation system on rifle range soil under unsaturated conditions. In order to remediate soil polluted by multi-species heavy metals, in pi]of scale, a series of EK remediation tests are carried out. PVC and PDB(Plastic Drain Board) electrode systems that connected with the power supply of constant voltage and vacuum pressure of 0.5kgf/$\textrm{cm}^2$ are installed, The test results showed that the pH distribution in the sample is below 8, which is maintained until the test is finished, because of the injection of flushing solution. The final concentration, which is normalized by initial concentration, is ranged about 50 to 90%.

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Macroinvertebrate Community Structure along Environmental Conditions in Ponds of Urban Parks, Korea

  • Kim, Myoung-Chul;Chun, Dong-Jun;Ro, Tae-Ho
    • Korean Journal of Ecology and Environment
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    • v.41 no.2
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    • pp.198-205
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    • 2008
  • Benthic macroinvertebrates were examined to elucidate community structures of a set of 9 shallow ponds from a total of 6 parks located in Seoul metropolitan area, Korea. The result showed that macroinvertebrates were diverse and abundant, and aquatic macrophyte provide habitat diversities in ponds. The differences among benthic macroinvertebrate community compositions seemed to be attributed to local biotic and abiotic interactions. We surveyed benthic macroinvertebrate, biotic (macrophyte), abiotic (turbidity, nutrient concentrations, conductivity, heavy metal concentration) and morphometric (area, depth) of the lentic systems. Generally, the benthic macroinvertebrates were dominated by Cloeon dipterum or Coenagrion sp.. Distribution of the aquatic macrophyte community was correlated with the species composition of macroinvertebrates. The result demonstrated a significant and positive relationship between habitat quality and macroinvertebrate composition.

Heavy Metal Contamination in Surface Sediments from Masan and Jinhae Bay, Southeast Coast of Korea (남해 동부해역 임해공단 연안퇴적물의 중금속 오염: 마산만 및 진해만)

  • Cho, Yeong-Gil;Lee, Chang-Bok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.4
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    • pp.302-313
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    • 2012
  • Concentrations of selected heavy metals (Al, Fe, Mn, Cr, Cu, Ni, Zn, Pb, As and Cd) in surface sediments from 96 sites in Masan and Jinhae Bay were studied in order to understand metal contamination. Results show that the surface sediments were mainly enriched by Cu (18-294 ppm), Zn (67-568 ppm), Pb (10-120 ppm) and Cd (0.2-3.5 ppm). The coastal zone of Masan Bay was significantly more contaminated than the non-coastal zone, and spatial distribution pattern suggested additional sources of heavy metal input in the coastal area. The enrichment ratio and geoaccumulation index ($I_{geo}$) have been calculated and the relative contamination levels assessed in the study area. The enrichment ratios of Cu, Zn, Pb and Cd in Masan Bay have been observed to be relatively high. $I_{geo}$ results reveal that the study area is not contaminated with respect to Fe, Mn, Cr and Ni; moderately to strongly contaminated with Cu, Zn and Pb; and strongly to strong contaminated with Cd. The high contents of Cu, Zn, Pb and Cd in the study area result from anthropogenic activities in the catchment area. Based on the eight different sediment quality guideline values from USA (ERL, ERM), Canada (TEL, PEL), Australia/New Zealand (ISQG-high, ISQG-low) and Hong Kong (ISQV-low, ISQV-high), sediment quality of Masan and Jinhae Bay was also assessed and characterized.

Sediment Quality Assessment for Heavy Metals in Streams Around the Shihwa Lake (시화호 유역 하천 퇴적물에서의 중금속 오염도 평가에 관한 연구)

  • Jeong, Hyeryeong;Kim, Kyung-Tae;Kim, Eun-Soo;Ra, Kongtae;Lee, Seung-Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.1
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    • pp.25-36
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    • 2016
  • Heavy metals in the stream sediments around Shihwa Lake were studied not only to investigate the characteristics of spacio-temporal distribution but also to assess the pollution degree and ecological risk using various pollution indices. Among metals, Zn had the highest values (1,311 mg/kg) and Hg showed the lowest value (0.261 mg/kg). The order of mean concentrations (mg/kg) of metals was Zn>Cu>Pb>Cr>Ni>Co>As>Cd>Hg in stream sediments around Shihwa Lake. Metal concentrations showed different pollution pattern with industrial region, indicating that these metals originated from different sources and industrial region had higher metal concentration than rural/urban regions. The results of geoaccumulation index (Igeo) showed that the stream sediments were significantly polluted with Cd, Cu, Zn and Pb, indicating moderately to highly polluted by these metals. According to PLI consideration, industrial region was more seriously polluted by metals whereas an rural/urban region was not polluted. About 85% of sampling site for Cr, Ni, Cu, Zn and Pb from industrial regions were exceeded the PEL values. The mPELQ and SQI values derived from PEL of industrial region were classified as 'highly toxic' and 'very poor' and metal pollution level tend to be worse in wet season. This indicates that the industrial activities and stromwater runoff represents an important sources of heavy metals around Shihwa Lake.

Physiochemical Characteristics and Heavy Metal in the Surface Sediments of Marine Shellfish Farming Waters in Anjung Bay, Korea (안정만 패류양식해역의 표층퇴적물의 지화학적특성과 중금속 함량)

  • Jeong, Woo-Geon;Cho, Sang-Man;Lee, Sang-Jun
    • The Korean Journal of Malacology
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    • v.30 no.4
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    • pp.421-428
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    • 2014
  • Total 20 surface sediments were collected in Anjung bay to investigate the physicochemical environment and heavy metal contents. The physicochemical investigation ranged from 6.41% to 11.68% (average $9.52{\pm}1.28%$) for ignition loss (IL), from 17.99 mg/g to 43.84 mg/g (average $27.53{\pm}6.39mg/g$) for chemical oxygen demand (COD), and from 0.05 mg/g to 0.61 mg/g (average $0.17{\pm}0.14mg/g$) for acid volatile sulfide (AVS) with significant correlation between water content (W/C) and COD. A contour of spatial distribution indicated higher organic pollution at the bottom of ascidian, Stylea clava, cultural waters. Most of metals contents was not exceeded the NOAA's effect range-low (ERL). Estimated enrichment factor (EF) ranging 0.96-1.12 indicated that the sediment environment of the studied waters was relatively pristine from heavy metal pollution in spite of increased vessel traffics, so far.