• Journal of Korean Society on Water Environment
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• v.30 no.4
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• pp.403-408
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• 2014

The toxicity of heavy metals (Zn, Pb) and diesel, in single and binary solution was investigated using the photobacterium Vibrio fischeri (Microtox test) as a test organism. In this experiment, the concentration of water soluble fraction of diesel was based on the total petroleum hydrocarbon (TPH). The toxicity of each single compound showed the following $EC_{50}$ (15min): Zn 1.90 mg/L, Pb 0.31 mg/L, TPH 2.09 mg/L. The observed toxicity of binary mixtures increased, depending on the concentration of the mixed substance. The effects were defined as synergistic, antagonistic, or additive, in accordance with the sign of difference between the predicted and observed toxicity at binary mixtures. The interactive effects between zinc and lead were synergistic, on the other hand, antagonistic and additive effects were found in each metal and TPH mixtures on the bioluminescence of V. fischeri.

• Economic and Environmental Geology
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• v.44 no.1
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• pp.83-94
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• 2011

Extra heavy oil reservoirs are distributed over the world but most of them is deposited in the northern part of the Orinoco River in Venezuela, in the area of 5,500 $km^2$, This region, which has been commonly called "the Orinoco Oil Belt", contains estimated 1.3 trillion barrels of original oil-in-place and 250 billion barrels of established reserves. The Venezuela extra heavy oil has an API gravity of less than 10 degree and in situ viscosity of 5,000 cP at reservoir condition. Although the presence of extra heavy oil in the Orinoco Oil Belt has been initially reported in the 1930's, the commercial development using in situ cold production started in the 1990's. The Orinoco heavy oil deposits are clustered into 4 development areas, Boyaco, Junin, Ayachoco, and Carabobo respectively, and they are subdivided into totally 31 production blocks. Nowadays, PDVSA (Petr$\'{o}$leos de Venzuela, S.A.) makes a development of each production block with the international oil companies from more than 20 countries forming a international joint-venture company. The Eastern Venezuela Basin, the Orinoco Oil Belt is included in, is one of the major oil-bearing sedimentary basins in Venezuela and is first formed as a passive margin basin by the Jurassic tectonic plate motion. The major source rock of heavy oil is the late Cretaceous calcareous shale in the central Eastern Venezuela Basin. Hydrocarbon materials migrated an average of 150 km up dip to the southern margin of the basin. During the migration, lighter fractions in the hydrocarbon were removed by biodegradation and the oil changed into heavy and/or extra heavy oil. Miocene Oficina Formation, the main extra heavy oil reservoir, is the unconsolidated sand and shale alternation formed in fluvial-estuarine environment and also has irregularly a large number of the Cenozoic faults induced by basin subsidence and tectonics. Because Oficina Formation has not only complex lithology distribution but also irregular geology structure, geological evolution and characteristics of the reservoirs have to be determined for economical production well design and effective oil recovery. This study introduces geological formation and evolution of the Venezuela extra heavy oil reservoirs and suggest their significant geological characteristics which are (1) thickness and geometry of reservoir pay sands, (2) continuity and thickness of mud beds, (3) geometry of faults, (4) depth and geothermal character of reservoir, (5) in-situ stress field of reservoir, and (6) chemical composition of extra heavy oil. Newly developed exploration techniques, such as 3-D seismic survey and LWD (logging while drilling), can be expected as powerful methods to recognize the geological reservoir characteristics in the Orinoco Oil Belt.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.889-892
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• 2009

A microwave plasma torch at the atmospheric pressure by making use of magnetrons operated at the 2.45 GHz and used in a home microwave oven has been developed. This electrodeless torch can be used to various areas, including industrial, environmental and military applications. Although the microwave plasma torch has many applications, we in the present work focused on the microwave plasma torch operated in pure steam and several applications, which may be used in future and right now. For example, a high-temperature steam microwave plasma torch may have a potential application of the hydrocarbon fuel reforming at one atmospheric pressure. Moreover, the radicals including hydrogen, oxygen and hydroxide molecules are abundantly available in the steam torch, dramatically enhancing the reaction speed. Also, the microwave plasma torch can be used as a high-temperature, large-volume plasma burner by injecting hydrocarbon fuels in gas, liquid, and solid into the plasma flame. Lastly, we briefly report an underway research, which is remediation of soils contaminated with oils, volatile organic compounds, heavy metals, etc.

• Proceedings of the KSR Conference
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• 2007.11a
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• pp.1229-1235
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• 2007

Railway-contaminated soil is categorized by total petroleum hydrocarbon(TPH)-related contamination and heavy-metal contamination. The sources of TPH are diesel and lubricant. In this study, the feasibility of soil washing, chemical oxidation and ultra-sonication were investigated to treat lubricant-contaminated railway soil. tergitol, a non-ionic surfactant, was investigated as a washing agent. However, it is not effective to remove lubricant from soil even though tergitol is most effective washing agent for diesel-contaminated soil. Addition of alcohols with surfactant enhanced slightly washing efficiency of the lubricant-contaminated soil. To remediate railway-contaminated soil, source of pollution should be considered.

• Journal of Surface Science and Engineering
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• v.42 no.3
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• pp.139-144
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• 2009

A microwave plasma torch at the atmospheric pressure by making use of magnetrons operated at the 2.45 GHz and used in a home microwave oven has been developed. This electrodeless torch can be used to various areas, including industrial, environmental and military applications. Although the microwave plasma torch has many applications, we in the present work focused on the microwave plasma torch operated in pure steam and several applications, which may be used in future and right now. For example, a high-temperature steam microwave plasma torch may have a potential application of the hydrocarbon fuel reforming at one atmospheric pressure. Moreover, the radicals including hydrogen, oxygen and hydroxide molecules are abundantly available in the steam torch, dramatically enhancing the reaction speed. Also, the microwave plasma torch can be used as a high-temperature, large-volume plasma burner by injecting hydrocarbon fuels in gas, liquid, and solid into the plasma flame. Finally, we briefly report treatment of soils contaminated with oils, volatile organic compounds, heavy metals, etc., which is an underway research in our group.

• Journal of the korean society of oceanography
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• v.33 no.4
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• pp.168-177
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• 1998

Five and a half months after the Keumdong oil spill accident on the 21$^{st}$ of September 1993, 34 seawater samples and 94 sediment samples were collected from Kwangyang Bay and Namhaedo area to assess its environmental impacts. Hydrocarbon concentration in the seawater ranged from 0.8 to 9.2 ${\mu}$g/1 with an average of 3.3 ${\mu}$g/1. This average value was nearly the same as the value(3.7 ${\mu}$g/1) before the oil spill accident. This suggests that by the early March of 1994 majority of the coastal water in the study area restored to its background hydrocarbon concentration before the oil spill accident. Nutrients, heavy metals and other general environmental parameters of the seawater did not show any aggravated seawater quality compared with the previous records. From the regression analysis of time-course observation of hydrocarbon in the seawater, except the sediment environment, the effect of oil spill on the water column was estimated to last at least 4 months in the study area after the oil spill accident. In the shoreline sediments, oil deposits were, however, still found at the high water marks at several stations, and very high values were found in the west of Namhaedo, ranging from 3.7 to 40.1 mg/g of wet sediment. Gas chromatography of these samples showed a very distinct Bunker C chromatogram identical to the Keumdong oil spill. Hydrocarbons in the subtidal bottom sediments in the study area and the reference stations (YB and CB) ranged from 0.45 to 18.08 ${\mu}$g/g of wet sediment with an average of 3.09 ${\mu}$g/g. West of Namhaedo (Stations Bl2-B33) generally showed much higher values than inner Kwangyang Bay and in Chinju Bay. Chinju Bay generally showed the lowest value among the study area. Subtidal bottom sediments in inner Kwangyang Bay and Chinju Bay seemed to be less affected than west of Namhaedo. Heavy metal concentrations in the sediment were relatively higher in the Kwangyang Bay than in the Chinju Bay. However, metal concentrations in the study area were in general comparable to the reference areas.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.03a
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• pp.330-337
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• 2006

Resistivity cone penetrometer test (RCPT) can be employed at a relatively low cost for delineation of subsurface contamination in situ, and then be supplemented with a minimum confirmatory sampling and laboratory testing program. While the resistivity measurement have potential to investigate the subsurface contamination, resistivity measurements alone will lead to some degree of ambiguity in the results. In this study, capacitance measurement was incorporated into the RCPT to overcome the ambiguity inherent in electrical resistivity measurements for delineating the subsurface contamination. This study is focused on verifying the applicability of resistivity and capacitance measurements on CPT module to provide information on contaminated subsurface by heavy metal and petroleum hydrocarbon. Laboratory model tests were performed to evaluate the sensitivity of the measured resistivity and relative capacitance on the water content and different types of contaminants. Test results show that simultaneous measurement of electrical resistivity and capacitance can give more reliable information on subsurface contamination.

• Journal of Construction Engineering and Project Management
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• v.3 no.2
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• pp.58-65
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• 2013

Earthwork activities are typically performed by heavy duty diesel (HDD) construction equipment that consumes large quantities of diesel fuel use and emits large quantities of pollutants, including nitrogen oxides (NOx), particulate matters (PM), hydrocarbon (HC), carbon monoxide (CO), and carbon dioxide ($CO_2$). This paper presents the framework for a model that can be used to estimate the production rate, activity duration, total fuel use, and total pollutants emissions for earthwork activities. A case study and sensitivity analysis for an excavator performing excavations are presented. The tool is developed by combining the multiple linear regressions (MLR) approach for modeling the productivity with the EPA's NONROAD model. The excavator data from RSMeans Heavy Construction Data were selected to build the productivity model, and emission factors of all type of pollutants from NONROAD model were used to estimate the total fuel use and emissions. The MLR model for the productivity rate can explain 92% of the variability in the data. Based on the model, the fuel use and emissions of excavator increase as the trench depth increase, but as the bucket size increase, the fuel use and emissions decrease.

• Ocean Science Journal
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• v.40 no.2
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• pp.61-66
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• 2005

Benthic amphipod, Grandidierella japonica widely inhabits the Korean coastal waters and is developed as a standard test species for sediment toxicity tests. We exposed G. japonica to various pollutants including 4 kinds of inorganic metals (Ag, Cd, Cu and Hg), tributyltin [TBT], ammonia and 7 polycyclic aromatic hydrocarbon (PAH) compounds (acenaphthene, chrysene, fluoranthene, fluorene, naphthalene, phenanthrene and pyrene) to estimate the no observed effect concentration (NOEC) and the median lethal concentration (LC50) of each pollutant during the 96-hour acute exposure. Among all tested pollutants, TBT was most toxic to G. japonica, and Rg was most toxic among inorganic metals. The toxicity of pyrene to G. japonica was greatest among PAH compounds, followed by fluoranthene, phenanathrene, acenaphthene, fluorene and naphthalene. The toxicity of PAH compounds was closely related to their physico-chemical characteristics such as $K_ow$ and water solubility. G. japonica responded adequately to pollutant concentrations and exposure durations, and the sensitivity of G. japonica to various inorganic and organic pollutants was generally comparable to other amphipods used as standard test species in ecotoxicological studies, indicating this species can be applied in the assessment of environments polluted by various harmful substances.

• Applied Chemistry for Engineering
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• v.24 no.1
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• pp.10-17
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• 2013

Heavy oil residue upgrading process was being used in conventional refinery process. Recently, as the importance of non conventional energy development is growing up, the commercial projects of heavy oil upgrading are getting more active than before. For having competitive business model in the resource competition, non conventional energy development should be considered as an important business strategy. In developing oil sands, extra heavy oil, and shale gas, canadian oil sands and extra heavy oil have great importance in substitution of conventional oil consumption. In oil sands development, the bitumen, which is extracted from oil sands, has great value after upgrading or refining process. Similar process is being used current conventional refinery process. The bitumen is highly viscous hydrocarbon. This bitumen includes impurities which can not be treated in conventional refinery process. As this reason, specified process is needed in bitumen or extra heavy oil upgrading process. Moreover, there will be additional specified facilities in the process of production, transportation and marketing. In oil sands, there are various kinds of commercial upgrading process. Extraction, dilution, coking and cracking method were being used commercially.