• Title/Summary/Keyword: heating temperature and time

Search Result 1,377, Processing Time 0.029 seconds

Processing and Physicochemical Properties of Collagen from Yellowfin Tuna (Thunnus albacares) Abdominal Skin (황다랑어 복부 껍질을 이용한 콜라겐의 제조 및 물리화학적 특성 해석)

  • Yoo, Sung-Jae;Cho, Sueng-Mock;Woo, Jin-Wook;Kim, Sang-Ho;Han, Yoo-Na;Ahn, Ju-Ryun;Kim, Su-Yeon;Kim, Tae-Wan;Kim, Seon-Bong
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.41 no.6
    • /
    • pp.427-434
    • /
    • 2008
  • Processing of collagen from yellowfin tuna (Thunnus albacares) abdominal skins was optimized by response surface methodology and central composite design. The values of independent variables at optimal conditions were NaOH concentration: 0.5 N, NaOH treatment time: 36.2 hr, pepsin concentration: 1:4.9 ratio (0.245%, w/v), and digestion time: 48.1 hr, respectively. The collagen content estimated under optimal conditions was 33.1%, and the actual experimental collagen content was 32.3%. Physicochemical properties of collagen from yellowfin tuna abdominal skin were investigated by amino acids analysis, SDS-PAGE, FT-IR, viscosity and denaturation temperature. Amino acids content of the collagen was 21.0%. SDS-PAGE pattern of the collagen showed two different $\alpha$-chain (${\alpha}_1$- and ${\alpha}_2$- chain), $\beta$-component and $\gamma$-component. The spectrum of FT-IR of the collagen showed wavenumber at 3,434, 1,650, 1,542 and $1,235\;cm^{-1}$ representing the regions of amide A, I, II and III, respectively. Relative viscosity of the collagen decreased continuously on heating up to $32^{\circ}C$, and the rate of decrease was retarded in the temperature range of $35-50^{\circ}C$. Denaturation temperature (Td) of the collagen solution (0.06%, w/v) was $31^{\circ}C$ and was lower than calf skin collagen ($35^{\circ}C$).

Manufactures of dental casting Co-Cr-Mo based alloys in addition to Sn, Cu and analysis of infrared thermal image for melting process of its alloys (Sn 및 Cu를 첨가한 치과 주조용 Co-Cr-Mo계 합금제조 및 용해과정 분석)

  • Kang, Hoo-Won;Park, Young-Sik;Hwang, In;Lee, Chang-Ho;Heo, Yong;Won, Yong-Gwan
    • Journal of Technologic Dentistry
    • /
    • v.36 no.3
    • /
    • pp.141-147
    • /
    • 2014
  • Purpose: Dental casting #Gr I (Co-25Cr-5Mo-3Sn-1Mn-1Si), #Gr II (Co-25Cr-5Mo-5Cu-1Mn -1Si) and #Gr III (Co-25Cr-5Mo-3Sn-5Cu-1Mn-1Si) master alloys of granule type were manufactured the same as manufacturing processes for dental casting Ni-Cr and Co-Cr-Mo based alloys of ingot type. These alloys were analyzed melting processes with heating time of high frequency induction centrifugal casting machine using infrared thermal image analyzer. Methods: These alloys were manufactured such as; alloy design, the first master alloy manufatured using vacuum arc casting machine, melting metal setting in crucible, melting in VIM, pouring in the mold of bar type, cutting the gate and runner bar and polishing. These alloys were put about 30g/charge in the ceramic crucible of high frequency induction centrifugal casting machine and heat, Infrared thermal image analyzer indicated alloys in the crucible were set and operated. Results: The melting temperatures of these alloys measuring infrared thermal image analyzer were decreased in comparison with remanium$^{(R)}$ GM 800+, vera PDI$^{TM}$, Biosil$^{(R)}$ f, WISIL$^{(R)}$ M type V, Ticonium 2000 alloys of ingot type and vera PDS$^{TM}$(Aabadent, USA), Regalloy alloys of shot type. Conclusion: Co-Cr-Mo based alloy in addition to Sn(#Gr I alloy) were decreased the melting temperature with heating time of high frequency induction centrifugal casting machine using infrared thermal image analyzer.

Deriving the Rate Constants of Coal Char-CO2 Gasification using Pressurized Drop Tube Furnace (가압 DTF를 이용한 석탄 촤-CO2 가스화 반응상수 도출)

  • Sohn, Geun;Ye, Insoo;Ra, Howon;Yoon, Sungmin;Ryu, Changkook
    • Journal of the Korean Society of Combustion
    • /
    • v.22 no.4
    • /
    • pp.19-26
    • /
    • 2017
  • This study investigates the gasification of coal char by $CO_2$ under high pressures in a drop tube furnace(DTF). The rate constants are derived for the shrinking core model using the conventional method based on the set reactor conditions. The computational fluid dynamic(CFD) simulations adopting the rate constants revealed that the carbon conversion was much slower than the experimental results, especially under high temperature and high partial pressure of reactants. Three reasons were identified for the discrepancy: i) shorter reaction time because of the entry region for heating, ii) lower particle temperature by the endothermic reaction, and iii) lower partial pressure of $CO_2$ by its consumption. Therefore, the rate constants were corrected based on the actual reaction conditions of the char. The CFD results updated using the corrected rate constants well matched with the measured values. Such correction of reaction conditions in a DTF is essential in deriving rate constants for any char conversion models by $H_2O$ and $O_2$ as well as $CO_2$.

Effects of Sulfuric Acid on the Synthesis of Highly Pure Calcium Borate in the Boron-Containing Brine and Bittern (붕소함유 염수와 간수로부터 고순도 calcium borate를 합성하는 반응에 황산이 미치는 영향)

  • Seo, Hyo-Jin;Kim, Myoung-Jin
    • Journal of Navigation and Port Research
    • /
    • v.39 no.6
    • /
    • pp.523-528
    • /
    • 2015
  • In this study, we investigated the effects of sulfuric acid on the synthesis of calcium borate in the artificial boron-containing brine (bittern) saturated with calcium hydroxide. For the study, we attempted to synthesize calcium borate under various conditions such as reaction temperature, reaction time, and cooling temperature after heating, and then to examine the recovery and purity of the calcium borate according to the presence or absence of sulfuric acid at each condition. The XRD analysis confirmed that, regardless of the presence of sulfuric acid, the calcium borate ($Ca_2B_2O_5{\cdot}H_2O$) was synthesized, while, in the presence of sulfuric acid, the calcium sulfate ($CaSO_4{\cdot}0.5H_2O$) was produced as a by-product. In all the experiments performed by varying the reaction temperature and time, the recovery and purity of the calcium borate without sulfuric acid were observed higher than those with it. The results indicated that the addition of sulfuric acid increased the solubility of the calcium hydroxide, but the calcium sulfate produced as a by-product could decrease the recovery and purity of the calcium borate by preventing the synthesis. In this study, the artificial boron-containing brine (bittern) (500 mg-B/L) was saturated with calcium hydroxide in the absence of sulfuric acid, and then the solution was heated at $80-105^{\circ}C$ for less than 10 minutes to synthesize the calcium borate. The recovery and purity of calcium borate were measured as high as 80 % and 96 %, respectively.

Application Effects of Biochar Derived from Pruned Stems of Pear Tree on Growth of Crops and Soil Physico-chemical Properties (배 전정지 바이오차 시용이 작물 생육 및 토양이화학성에 미치는 영향)

  • Jang, Jae-Eun;Lim, Gab-June;Park, Jung-Soo;Shim, Jae-Man;Kang, Chang-Sung;Hong, Sun-Seong
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.26 no.4
    • /
    • pp.11-19
    • /
    • 2018
  • This study was conducted to develop the manufacturing method of biochar using pruned stems of pear tree and its application effect on the crop growth and soil physico-chemical properties. In this study, biochar derived from pruned stems of pear tree at heating temperature of $300^{\circ}C$, $500^{\circ}C$ and $700^{\circ}C$ in heating times of 2, 3 and 4 hours, were tested in the changes of their chemical properties during biochar processing. The pH, Exch. K, Exch. Mg and cation exchange capacity (CEC) increased as the pyrolysis temperature increased during the production of biochar, and the change of these properties rapidly occurred at $500^{\circ}C$. However, as the pyrolysis temperature increased, ash content increased and total carbon (T-C), yield decreased. And the change of the properties in response to the heating time was not shown. It was thought that it would be desirable to set the production conditions of biochar at $500^{\circ}C$ for 2 hours in consideration of the change of chemical properties and the ash content and yield. And also, were conducted the experiments to establish manufacturing method of farm-made biochar using drum biochar manufacturing machine and investigate the application effects of biochar on the cultivation of chinese cabbage and tomato. Application of biochar derived from pruned stems of pear tree could enhance pH, organic matter (OM), total carbon (T-C) of soil. On the other hand, soil electrical conductivity (EC), NO3-N were lowered compared to the control which has no application. The bulk density, porosity and aggregate formation of soil were improved by biochar application. The fresh matter yields of chinese cabbage and tomato were significantly increased in proportion to the application rate of biochar. This study demonstrated the effect of the biochar derived from agricultural byproduct to be as a low cost potential soil ameliorant by physico-chemical properties in eco-friendly greenhouse cultivation.

Reaction Rate Analysis of Combustion for Indonesian Coal Char Applied by External/Internal Diffusion (외부 및 내부 확산을 적용한 인도네시아 석탄촤의 연소 반응율 분석)

  • Hwang, Chan-Won;Kim, Ryang-Gyoon;Ryu, Kwang-Il;Wu, Ze-Lin;Jeon, Chung-Hwan
    • Korean Chemical Engineering Research
    • /
    • v.52 no.1
    • /
    • pp.133-140
    • /
    • 2014
  • The experiment was designed to compare the char combustion kinetics of pulverized Indonesia coals commonly utilized in Korea power plants. The reaction rate of coal char has been formulated using the external and internal effectiveness factors to describe the diffusion effect quantitatively. The Random Pore Model (RPM) was used for applying internal specific surface area as a function of carbon conversion ratio. Reaction rate was obtained from reaction time using the Wire Heating Reactor (WHR) which can heat and measure the char particle temperature at the same time. BET and TGA were used to obtain physical properties such as internal specific surface area and structural parameter. Three kinds of Indonesia Sub-bituminous coals "BARAMULTI, ENERGYMAN, AGM" were used in order to derive the activation energy and pre-exponential factor. The results of this study showed that the effect of internal diffusion than that of external diffusion is the dominant as comparison of kinetics was reflected in external and internal effectiveness factors. For three kinds of coal char, finally, activation energy of intrinsic kinetics indicates 110~118 kJ/mol.

Forecasting daily peak load by time series model with temperature and special days effect (기온과 특수일 효과를 고려하여 시계열 모형을 활용한 일별 최대 전력 수요 예측 연구)

  • Lee, Jin Young;Kim, Sahm
    • The Korean Journal of Applied Statistics
    • /
    • v.32 no.1
    • /
    • pp.161-171
    • /
    • 2019
  • Varied methods have been researched continuously because the past as the daily maximum electricity demand expectation has been a crucial task in the nation's electrical supply and demand. Forecasting the daily peak electricity demand accurately can prepare the daily operating program about the generating unit, and contribute the reduction of the consumption of the unnecessary energy source through efficient operating facilities. This method also has the advantage that can prepare anticipatively in the reserve margin reduced problem due to the power consumption superabundant by heating and air conditioning that can estimate the daily peak load. This paper researched a model that can forecast the next day's daily peak load when considering the influence of temperature and weekday, weekend, and holidays in the Seasonal ARIMA, TBATS, Seasonal Reg-ARIMA, and NNETAR model. The results of the forecasting performance test on the model of this paper for a Seasonal Reg-ARIMA model and NNETAR model that can consider the day of the week, and temperature showed better forecasting performance than a model that cannot consider these factors. The forecasting performance of the NNETAR model that utilized the artificial neural network was most outstanding.

Thermal Energy Capacity of Concrete Blocks Subjected to High-Temperature Thermal Cycling (열사이클을 적용한 고온 조건 콘크리트 블록의 열용량 특성)

  • Yang, In-Hwan;Park, Ji-Hun
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.8 no.4
    • /
    • pp.571-580
    • /
    • 2020
  • In this study, an experimental study on storage media for thermal energy storage system was conducted. For thermal energy storage medium, concrete has excellent thermal and mechanical properties and also has various advantages due to its low cost. In addition, the ultra-high strength concrete reinforced by steel fibers exhibits excellent durability against exposure to high temperatures due to its high toughness and high strength characteristics. Moreover, the high thermal conductivity of steel fibers has an advantageous effect on heat storage and heat dissipation. Therefore, to investigate the temperature distribution characteristics of ultra-high-strength concrete, concrete blocks were fabricated and a heating test was performed by applying high-temperature thermal cycles. The heat transfer pipe was buried in the center of the concrete block for heat transfer by heat fluid flow. In order to explore the temperature distribution characteristics according to different shapes of the heat transfer pipe, a round pipe and a longitudinal fin pipe were used. The temperature distribution at the differnent thermal cycles were analyzed, and the thermal energy and the cumulated thermal energy over time were calculated and analyzed for comparison based on test results.

Evaluation of Phase Transition Behavior of Ge2Sb2Te5 Thin Film for Phase Change Random Access Memory (상변환 메모리의 응용을 위한 Ge2Sb2Te5 박막의 상변환 거동 평가)

  • Do, Woo-Hyuk;Kim, Sung-Soon;Bae, Jun-Hyun;Cha, Jun-Ho;Kim, Kyung-Ho;Lee, Young-Kook;Lee, Hong-Lim
    • Journal of the Korean Ceramic Society
    • /
    • v.44 no.1 s.296
    • /
    • pp.18-22
    • /
    • 2007
  • The phase transition behavior of $Ge_2Sb_2Te_5$ (GST) thin film, which is a candidate material of recording layer for phase change random access memory (PRAM), has been evaluated using an in-situ reflectance measurement method. The experimental data have been analyzed by using johnson-mehl-avrami-kolomogorov (JMAK) model. JMAK model can be used only in isothermal state. However, temperature changes with time during the operation of PRAM. To apply JMAK equation to PRAM simulation, it has been assumed that the temperature increases stepwise and isothermally. By using JMAK equation and assumption for the transient state, the phase transition behavior of GST thin film has been predicted under $3^{\circ}C/min$ heating rate in this study. The simulation result agrees well with the experimental results. Therefore, It can be concluded that JMAK equation can be used far the PRAM simulation model.

A study on the burn-in test to accomplish high quality cockpit air of an ultra-sonic aircraft in the early stage of production (생산 초기 초음속 항공기 조종석의 고품질 공기 확보를 위한 burn-in test 연구)

  • Shin, Jae Hyuk;Park, Sung Jae;Seo, Dong Yeon;Jeong, Suheon
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.44 no.10
    • /
    • pp.871-876
    • /
    • 2016
  • Abnormal odor similar with burning smell often appears at the cockpit in the beginning of ultra-sonic aircraft without air filter due to the heating of production materials remained at the bleed air duct. Sources of the odor should be removed by burn-in test before test flight in order to prevent pilot confuses order with emergency such as fire of engine. However, the present method cannot prevent abnormal odor completely at the high altitude flight because maximum temperature of flight is higher than it of burn-in-test. This paper suggests burn-in test improved based on the analysis of thermal conditions of high altitude flight. It is verified that the existing burn-in test cannot cover thermal conditions of high altitude flight due to the discontinuous flow control, high change rate of temperature per unit time and difference between limit temperature of condenser and turbine. In order to overcome the limitations of current methods, the new burn-in test with continuous flow control are suggested. The continuous flow control are achieved by ram air inlet control. The effect of suggested method are verified by ground tests and flight tests. The results show the bleed air temperature can cover the temperature of high altitude flight and prevent abnormal odor at the flight test.