• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.133.2-133.2
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• 2010

Fischer-Tropsch synthesis (FTS) was carried out in heat-exchanger typed reactor with cobalt metallic foam catalyst. Considering the heat and mass transfer limitations in the cobalt catalyst, a Co-foam catalyst with an inner metallic foam frame and an outer cobalt catalyst was developed. The Co-foam catalyst was highly selective toward liquid hydrocarbon production and the liquid hydrocarbon productivity at $203^{\circ}C$ reached to $52.5ml/(kg_{cat}{\cdot}h)$, which was higher than that obtained by the Co-pellet. Furthermore, the heat-exchanger typed reactor was developed to efficiently control the highly exothermic reaction heat. The reaction heat generated in the FTS reaction on the cobalt active site was easily transferred to reactor wall by the metallic foam in the catalyst and the transferred reaction heat was directly removed by the hot oil which circulated the wall side of the heat-exchanger typed reactor.

• Journal of the Korean Wood Science and Technology
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• v.45 no.2
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• pp.195-201
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• 2017

This study was conducted to evaluate the resistance of heat-treated wood using the catalyst to decay caused by fungi for sapwood and heartwood of two tree species, Korean red pine (Pinus densiflora) and Japanese larch (Larix kaempferi), respectively. Wood samples were immersed for 10 min in sulfuric acid (7.5%) and then heat-treated at $130^{\circ}C$ for 90 min. Fomitopsis palustris, a brown-rot fungus, was used to examine the decay resistance of Korean red pine and Japanese larch wood. Weight and density of wood from the all conditions increased after heat treatment using the catalyst. Weight loss after decay resistance test was also dropped with a heat treatment. The lowest weight loss indicated at heat-treated heartwood of Japanese larch. Heat treatment using the catalyst effectively increased the resistance of wood to decay caused by fungi.

• Journal of the Korean Society of Propulsion Engineers
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• v.18 no.5
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• pp.95-100
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• 2014

In hypersonic aircraft, increase of aerodynamic heat and engine heat leads heat loads in airframe. It could lead structural change of aircraft's component and malfunctioning. Endothermic fuels are liquid hydrocarbon fuels which are able to absorb the heat load by undergoing endothermic reactions. In this study, exo-tetrahydrodicyclopentadiene was selected as a model endothermic fuel and experiments on endothermic properties were investigated with pore structure controlled zeolite catalyst using metal deposition. We secured the catalyst that had better endothermic performance than commercial catalyst. The object of this study is inspect catalyst properties which have effect on heat absorption improvement. Synthetic catalyst could be applied to system that use exo-THDCP as endothermic fuel instead of other commercial catalyst.

• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.645-648
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• 2017

A catalyst for promoting the commercialization of N-phenylamleimide (PMI), a compound used to strengthen the heat resistance of ABS resins and also completely imported, was developed. N-phenylmaleamic acid (PMA) was first quantitatively obtained through the reaction of maleic anhydride and aniline. A catalyst was then investigated for obtaining PMI. Zinc acetate/$Et_3N$, composite catalyst, showed better performance than a single acid catalyst. By using the developed composite catalyst, PMI could be synthesized with the yield and purity of 90% and 99.3%, respectively without any further purification processes.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.9-16
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• 2004

Close-coupled catalyst (CCC) can reduce the engine cold-start emissions by utilizing the energy in the exhaust gas. However, in case the engine is operated at high engine speed and load condition, the catalytic converter may be damaged and eventually deactivated by thermal aging. Excess fuel is sometimes supplied intentionally to lower the exhaust gas temperature avoiding the thermal aging. This sacrifices the fuel economy and exhaust emissions. This paper describes the results of an exhaust heat exchanger to lower the exhaust gas temperature mainly under high load conditions. The heat exchanger was installed between the exhaust manifold and the inlet of close-coupled catalytic converter. The exhaust heat exchanger successfully decreased the exhaust gas temperature, which eliminated the requirement of fuel enrichment under high load conditions. However, the cooling of the exhaust gas through the heat exchanger may cause the deterioration of exhaust emissions at cold start due to the increment of catalyst light-off time.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.6
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• pp.822-829
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• 1997

A catalytic burner was studied which can be used as a heater operated in medium temperature. Noble metal catalysts (Pd/NiO) were used, which were supported on alumina wash coated honeycomb. The maximum heat-resisting temperature of the catalyst is about 900.deg. C. Combustion efficiency of the catalytic burner reached more than 99.5 % at the excess air ratio above 1.25.NOx emissions were lower than 1.0 ppm at all operation conditions. The operation condition for a stable catalytic combustion was obtained. It was dependent on the catalyst thickness. The 30 mm thick catalyst showed the widest stable catalytic combustion region. Stable catalytic combustion region of 30 mm thick catalyst was the operation condition of excess air ratio 1.25 - 1.75 and heat flux 7 - 14 kcal/h center dot cm$^{2}$.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.181-186
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• 2004

Catalytic combustion is one of the suitable methods which is applicable to micro heat source due to high energy density and no flame quenching. And hydrogen can be oxidized at room temperature with platinum catalyst. So hydrogen-fueled micro catalytic combustor with platinum catalyst can be good and easy-handling heat source for another micro devices. In this work we focused on general catalytic combustion characteristics of hydrogen-air premixed gas in 10mm scale catalytic combustor for the further application to micro scale. Platinum was coated on dense ceramic monolith which can be installed in simple-structured catalytic combustor. We investigated the effect of flow rate, heat loss and platinum percentage in catalyst-coated monolith on catalytic combustion performance by temperature distribution in the combustor. By those results we confirmed catalytic reactivity and estimated reaction area. And we simulated micro scale catalytic reaction by sliced monolith. The results of this work will be important design factors for micro scale catalytic combustor.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.4
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• pp.179-189
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• 1997

Among aftertreatment devices which reduce exhaust gas of diesel engine, diesel oxidation catalyst(DOC) with high reduction efficiency for gaseous matter and particulate matter is now studied actively. In this study, a transient one-dimensional model developed to simulate the thermal and conversion characteristics of adiabatic monolithic converters operating under warm up conditions is presented. This model takes into account the gas solid heat and mass transfer, axial heat conduction, chemical reactions and the related heat release. The model has been used to analyze the transient response of an axisymmetric catalytic converter during a warm-up as a function of catalyst design parameters and operation conditions in order to observe their effects on the lightoff behaviour. The experimental test was carried out 2400 cc light diesel engine with DOC.

• Journal of the Korean Society of Combustion
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• v.5 no.1
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• pp.1-6
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• 2000

Surface reaction occurs at a certain surface temperature when a catalyst is heated up in a reactive mixture. If homogeneous ignition does not occur, a steady state is observed because the heat produced by the surface reaction is balanced with the heat loss caused by convection, conduction and radiation. The present paper treats the effects of pressure on the surface temperature at the steady state. Hydrogen and oxygen are used as reactants and nitrogen as an inert gas. A spherical platinum catalyst of 1.5 mm in diameter is sustained in the chamber with two wires of 0.1 mm in diameter. As results, there exists a maximum steady temperature at a certain relative hydrogen concentration which increases with total pressure. At the steady state, it can be approximated that the heat release is estimated by the mass transfer considering the effect of natural convection. The experimental results are explained qualitatively by the approximation.

• Journal of Hydrogen and New Energy
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• v.31 no.2
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• pp.202-209
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• 2020

In methanol steam reforming, commercial catalysts in the form of pellets are mainly used, but there are limitations to directly apply them to underwater weapon systems that require shock resistance and heat transfer characteristics. In this study, to overcome this problem, a multi-layer cup structure (MLCS) was applied to support a pellet type catalyst. The characteristics of pellet catalyst supported by MLCS and the pellet catalyst supported by conventional structure (CS) were compared by the reforming experiment. In the case of MLCS, a high methanol conversion rate was shown in the temperature range 200 to 300℃ relative to the CS manufactured with the same catalyst weight as MLCS. CS shown similar characteristics to MLCS when it manufactured in the same volume as MLCS by adding an additional 67% of the catalyst. In conclusions, MLCS can not only reduce catalyst usage by improving heat transfer characteristics, but also support pellet catalyst in multiple layers, thus improving shock resistance characteristics.