• Title/Summary/Keyword: heat of sorption

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A Study on the Simplified Presumption Method for the Prediction of Cooling and Heating Performance in a Fresh Air Load Reduction System by Using Geothermal Energy (지열 이용 외기부하 저감시스템의 냉각 및 가열효과 예측 간이추정법에 관한 연구)

  • Son, Won-Tug;Choi, Young-Sik
    • Journal of the Korean Society of Industry Convergence
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    • v.13 no.3
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    • pp.169-181
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    • 2010
  • This paper presents a feasibility study of a fresh air load reduction system by using an underground double floor space. The fresh air is introduced into the double slab space and passes through the opening bored into the footing beam. The air is cooled by the heat exchange with the inside surface of the double slab space in summer, and heated in winter. This system not only reduces sensible heat load of the fresh air by heat exchange with earth but also reduces latent heat load of the fresh air by ad/de-sorption of underground double slab concrete. In this paper, we proposed a simplified presumption method for the prediction of cooling and heating performance in the system. In conclusion the proposed method has been verified by comparing with the calculated value of the numerical analysis model by using nonlinear two-dimension hygroscopic question.

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A Study on the Correlation between Outdoor Air and Outlet Air Temperature in a Fresh Air Load Reduction System by Using Geothermal Energy (지열을 이용한 외기부하저감시스템의 외기온도와 출구온도의 상관관계 분석)

  • Son, Won-Tug;Park, Kyung-Soon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.9
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    • pp.620-627
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    • 2010
  • This paper presents a feasibility study of a fresh air load reduction system by using an underground double floor space. The fresh air is introduced into the double slab space and passes through the opening bored into the footing beam. The air is cooled by the heat exchange with the inside surface of the double slab space in summer, and heated in winter. This system not only reduces sensible heat load of the fresh air by heat exchange with earth but also reduces latent heat load of the fresh air by ad/de-sorption of underground double slab concrete. In this paper, we investigated the correlation between outdoor air temperature and outlet air temperature in the system. In conclusion, from the results of the high correlation we proposed a equation of regression for the outlet air temperature in the system by using linear regression analysis.

Study on Designing and Installation Effect of Fresh Air Load Reduction System by using Underground Double Floor Space - Proposal of Numerical Model coupled Heat and Moisture Simultaneous Transfer in Hygroscopic - (지열을 이용한 공조외기부하저감(空調外氣負荷低減) 시스템의 설계 및 도입 효과에 관한 연구 - 증기 확산지배에 의한 열수분 동시 이동 수치모델의 제안 -)

  • Son, Won-tug;Choi, Young-sik
    • Journal of the Korean Society of Industry Convergence
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    • v.7 no.4
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    • pp.331-340
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    • 2004
  • This paper presents a feasibility study of a fresh air load reduction system by using an underground double floor space. The fresh air is introduced into the double slab space and passes through the opening bored into the footing beam. The air is cooled by the heat exchange with the inside surface of the double slab space in summer, and heated in winter. This system not only reduces sensible heat load of the fresh air by heat exchange with earth but also reduces latent heat load of the fresh air by ad/de-sorption of underground double slab concrete. In this paper, we used a model for evaluation of fresh air latent heat load reduction by hygroscopic of air to earth exchange system taking into account coupled heat and moisture transfer of underground double floor space. In conclusion it shows the validity of the proposed method for a design tool and the quantitative effect of the system.

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Influence of various metal oxides on mechanical and physical properties of heat-cured polymethyl methacrylate denture base resins

  • Asar, Neset Volkan;Albayrak, Hamdi;Korkmaz, Turan;Turkyilmaz, Ilser
    • The Journal of Advanced Prosthodontics
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    • v.5 no.3
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    • pp.241-247
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    • 2013
  • PURPOSE. To evaluate the effect of various metal oxides on impact strength (IS), fracture toughness (FT), water sorption (WSP) and solubility (WSL) of heat-cured acrylic resin. MATERIALS AND METHODS. Fifty acrylic resin specimens were fabricated for each test and divided into five groups. Group 1 was the control group and Group 2, 3, 4 and 5 (test groups) included a mixture of 1% $TiO_2$ and 1% $ZrO_2$, 2% $Al_2O_3$, 2% $TiO_2$, and 2% $ZrO_2$ by volume, respectively. Rectangular unnotched specimens ($50mm{\times}6.0mm{\times}4.0mm$) were fabricated and drop-tower impact testing machine was used to determine IS. For FT, compact test specimens were fabricated and tests were done with a universal testing machine with a cross-head speed of 5 mm/min. For WSP and WSL, disc-shaped specimens were fabricated and tests were performed in accordance to ISO 1567. ANOVA and Kruskal-Wallis tests were used for statistical analyses. RESULTS. IS and FT values were significantly higher and WSP and WSL values were significantly lower in test groups than in control group (P<.05). Group 5 had significantly higher IS and FT values and significantly lower WSP values than other groups (P<.05) and provided 40% and 30% increase in IS and FT, respectively, compared to control group. Significantly lower WSL values were detected for Group 2 and 5 (P<.05). CONCLUSION. Modification of heat-cured acrylic resin with metal oxides, especially with $ZrO_2$, may be useful in preventing denture fractures and undesirable physical changes resulting from oral fluids clinically.

Identification of Sorption Characteristics of Cesium for the Improved Coal Mine Drainage Treated Sludge (CMDS) by the Addition of Na and S (석탄광산배수처리슬러지에 Na와 S를 첨가하여 개량한 흡착제의 세슘 흡착 특성 규명)

  • Soyoung Jeon;Danu Kim;Jeonghyeon Byeon;Daehyun Shin;Minjune Yang;Minhee Lee
    • Economic and Environmental Geology
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    • v.56 no.2
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    • pp.125-138
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    • 2023
  • Most of previous cesium (Cs) sorbents have limitations on the treatment in the large-scale water system having low Cs concentration and high ion strength. In this study, the new Cs sorbent that is eco-friendly and has a high Cs removal efficiency was developed by improving the coal mine drainage treated sludge (hereafter 'CMDS') with the addition of Na and S. The sludge produced through the treatment process for the mine drainage originating from the abandoned coal mine was used as the primary material for developing the new Cs sorbent because of its high Ca and Fe contents. The CMDS was improved by adding Na and S during the heat treatment process (hereafter 'Na-S-CMDS' for the developed sorbent in this study). Laboratory experiments and the sorption model studies were performed to evaluate the Cs sorption capacity and to understand the Cs sorption mechanisms of the Na-S-CMDS. The physicochemical and mineralogical properties of the Na-S-CMDS were also investigated through various analyses, such as XRF, XRD, SEM/EDS, XPS, etc. From results of batch sorption experiments, the Na-S-CMDS showed the fast sorption rate (in equilibrium within few hours) and the very high Cs removal efficiency (> 90.0%) even at the low Cs concentration in solution (< 0.5 mg/L). The experimental results were well fitted to the Langmuir isotherm model, suggesting the mostly monolayer coverage sorption of the Cs on the Na-S-CMDS. The Cs sorption kinetic model studies supported that the Cs sorption tendency of the Na-S-CMDS was similar to the pseudo-second-order model curve and more complicated chemical sorption process could occur rather than the simple physical adsorption. Results of XRF and XRD analyses for the Na-S-CMDS after the Cs sorption showed that the Na content clearly decreased in the Na-S-CMDS and the erdite (NaFeS2·2(H2O)) was disappeared, suggesting that the active ion exchange between Na+ and Cs+ occurred on the Na-S-CMDS during the Cs sorption process. From results of the XPS analysis, the strong interaction between Cs and S in Na-S-CMDS was investigated and the high Cs sorption capacity was resulted from the binding between Cs and S (or S-complex). Results from this study supported that the Na-S-CMDS has an outstanding potential to remove the Cs from radioactive contaminated water systems such as seawater and groundwater, which have high ion strength but low Cs concentration.

PHYSICAL PROPERTIES OF RELINING DENTURE BASE RESINS WITH DIFFERENT POLYMERIZING METHODS (중합방법이 다른 의치상 이장용레진의 물리적 특성)

  • Cho Suck-Kyu;Song Kwang-Yeob;Yoon Soo-Yun;Kim Mun-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.4
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    • pp.386-395
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    • 2002
  • This study would like to measure and compare water sorption and solubility of acrylic resins, with 3 different polymerizing methods, and tensile strength between denture base resin and relining rosins. For this experiment, 3 different acrylic resins were used; heat polymerizing resin: Vertex (Dentmex, Zeist, Holland), autopolymerizing resin: Tokuso Rebase (Tokuyama Corp, Tokyo, Japan), and light curing resin: Mild Rebaron LC(GC Corp, Tokyo, Japan) The results were as follows ; 1. Tokuso Rebase showed the lowest water sorption. followed by Mild Rebaron LC and Vertex. Among resins, there were some signigicant differences (P<0.05). 2. Vertex showed the lowest solubility, followed by Mild Rebaron LC and Tokuso Rcbase. Among resins, there were some signigicant differences (P<0.05). 3. Intact Vertex showed the highest tensile strength, and Mild Rebaron LC had a more tensile strength than Tokuso Rebase. Between Vertex and the other resins, there were some signigicant differences (P<0.05) However, between Mild Rebaron LC and Tokuso Rebase, there was no statistical difference (P>0.05). About 50% of Rebaron LC showed cohesive fracture. 4. Tensile strength has more decreased after thermocycling than before, but there was no statistical difference (P>0.05).

Natural Gas Sorption Using Activated-Carbon with Surface Treatment (활성탄의 표면처리에 의한 천연가스 흡장)

  • Yun, Seok-Min;Kim, Ju-Wan;Im, Ji-Sun;Kim, Shin-Dong;Hong, Ji-Sook;Suh, Jeong-Kwon;Lee, Young-Seak
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.4
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    • pp.434-439
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    • 2006
  • In this study, activated carbon(ACs) have been modified by nitric acid and heat-treatment. The surface and structure properties of ACs were determined by BET surface area, FT-IR pH and acid/base value. The changes in pore structure and surface properties of these modified ACs were correlated with natural gas adsorption which measured by volumetric apparatus at $0^{\circ}C$ and $25^{\circ}C$. The pore textural properties of activated carbon was also characterized by nitrogen adsorption at 77 K. Specific surface area and micropore volume of them were calculated by Langmuir equation and Horvath-Kawazoe method, and chemical properties of surface were measured by FT-IR and titration of acid and base solutions. Pore texture of activated carbons after treatments were not significantly changed. Total acidity increased and basicity of samples decreased. however the basicity increased with heat treatment. The methane adsorption of ACs become different depending on the acid/base value of samples.

A Study on the Simplified Presumption Method for the Prediction of Cooling and Heating Performance in a Fresh Air Load Reduction System by Using Geothermal Energy (지열을 이용한 외기부하저감시스템의 냉각 및 가열효과 예측을 위한 간이추정법에 관한 연구)

  • Son, Won-Tug;Park, Kyung-Soon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.9
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    • pp.628-634
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    • 2010
  • This paper presents a feasibility study of a fresh air load reduction system by using an underground double floor space. The fresh air is introduced into the double slab space and passes through the opening bored into the footing beam. The air is cooled by the heat exchange with the inside surface of the double slab space in summer, and heated in winter. This system not only reduces sensible heat load of the fresh air by heat exchange with earth but also reduces latent heat load of the fresh air by ad/de-sorption of underground double slab concrete. In this paper, we proposed a simplified presumption method for the prediction of cooling and heating performance in the system. In conclusion the proposed method has been verified by comparing with the calculated value of the numerical analysis model by using nonlinear two-dimension hygroscopic question.

An Analysis of the Patents for Heat Pumps (열펌프의 정량적 특허기술 분석에 관한 연구)

  • Choi Jong Min;Kim Yongchan;Cheon Deokwoo;Shin Yun-Hee;Lee Sang Hyuk;Kwak Jae Su
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.9
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    • pp.808-815
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    • 2005
  • A technical analysis was conducted to predict the development trends for heat pump system. This study was based on submitted patents from 1983 to 2002 in Korea, USA, and Japan. The total number of raw data from the registered database was 19,261 and the obtained data to be analyzed through the filtering process was 5,143. Japan's technical development for the heat pump system was more dominant than the other countries. Approximately $54\%$ of the total patents related with the heat pump system was registered by Japan. The number of patents for the heat pump system registered by Korea was very low in 1980's, but it increased rapidly in 1990's. As a result, the number of patents applied by Korea was $21\%$ of all patents. When the patent was categorized into compression, absorption/ad-sorption, and chemical type, the technology of compression type made up over $80\%$ in each country. Approximately $93\%$ of the patents surveyed in this study was developed for air or water source heat pumps because of easy applications compared with other heat sources. The $89\%$ of all patents was applied by companies when applicants were divided into three groups of company, individual, and the others (national institute, university, and so on).