• Title/Summary/Keyword: heat of hydration heat

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A Study for Controlling Early-age Temperature Rise of the Concrete Pavement by Shadow Tent in Hot Weather Construction (차광막를 이용한 하절기 콘크리트포장의 초기온도 관리 방안연구)

  • Joh, Young-Oh;Kim, Hyung-Bae;Suh, Young-Chan;Ann, Sung-Soon
    • International Journal of Highway Engineering
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    • v.6 no.4 s.22
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    • pp.75-89
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    • 2004
  • Long term performance of concrete pavement significantly depends on the given construction and environmental condition. It means that random cracks and extreme crack width due to inappropriate quality control at the early age might lead to decreasing the pavement service life. The temperature and moisture during the construction, cement and aggregate types, curing condition are major components to affect the quality of the concrete pavement at the early age. First of all, the high temperature differential, that is made by increasing air temperature and the heat of cement hydration, is known as the major contributor to severe cracks. In this study, tent covering was used for controlling temperature of the concrete slab. The field measurement data indicates that the effect of the tent covering is very significant to decrease possibilities of random crack occurrence and curling stress and enhance the long-term concrete strength. HIPERPAV(High PERformance PAVing software), a program predicting the strength and stress of an earty-age concrete pavement (72 hour after placement), is used for simulating the effects of tent covering. The HIPERPAVE results showed that the section with the tent covering has higher reliability than the section without the tent covering by 22.5%. In details, reliability is increased 72.5% (without the tent covering) to 95% (with the tent covering).

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The Feasibility Study for Utilization of Blended Cement as a Activator of Bottom Ash from Circulating Fluidized Bed Combuster Boiler (순환유동층 보일러 바텀애시의 혼합시멘트 자극제 활용을 위한 타당성 연구)

  • Park, JongTak;Jung, Gwon Soo;Kang, Chang Ho;Oh, Hongseob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.255-262
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    • 2020
  • Blended cement with fly ash and bottom ash from Circulating Fluidized Bed Combustor boiler(CFBC) burned at a low temperature, can be high heat of hydration and abnormal setting caused by higher volumn contents of Fe2O3, free-CaO, SO3. In this study, the ground CFBC bottom ash powder mixed with blast furnace slag was used as substitute activator of gypsum and recycled iron slag was produced from mix and pulverized by ball mill to increase the recycling rate. The effect on compressive strength of cements with the mixture of original and hydrated bottom ash mixtures with BFS with small water, respectively, was analyzed, and it was found that the hydrated bottom ash activator was more effective in initial strength development. To improve the initial strength of blended cement, an activator mixed with a blast furnace slag and bottom ash mixing ratio of 5:95 and 10:90, respectively, the slag cement by about 6%, and it was analyzed to develop an initial strength similar to gypsum as a conventional activator.

Durability Characteristics of Ternary Cement Matrix Using Ferronickel Slag According to the Alkali-Activators (알칼리 활성화제 종류별 페로니켈슬래그를 사용한 3성분계 시멘트 경화체의 내구특성)

  • Cho, Won-Jung;Park, Eon-Sang;Jung, Ho-Seop;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.190-197
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    • 2020
  • This paper evaluates the mechanical properties and durability of cement matrix blended with mineral admixtures and ferronickel slag(FNS) powder which is an industrial b y-product during ferronickel smelting process. The hydration heat, pore structure, compressive strength, length change, rapid chloride penetration test(RCPT), and freezing and thawing resistance of ternary blended cement matrix were investigated and compared with ordinary portland cement matrix. The result showed that the compressive strength of ternary blended cement matrix using ferronickel slag powder and mineral mixture was low in strength compared to the reference concrete, but recovered to a certain extent by using alkali activator. Length change of cement mortar using FNS powder have shown less shrinkage occurs than the reference specimen. In addition, irrespective of using the alkali-activators, all ternary mix are indicative of the 'very low' range for chloride ion penetrability according to the ASTM C 1202, and the freeze-thaw resistance also showed excellent results.

Evaluation of the Properties of an Environment-Friendly De-icing Agent Based on Industrial By-Products (산업부산물을 활용한 친환경제설제의 특성평가)

  • Heo, Hyung-Seok;Lee, Byung-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.132-139
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    • 2017
  • A huge amount of de-icing agent is sprayed during winter to promote traffic safety in cold regions, and the quantity of de-icing agent sprayed has increased each year. The main ingredients in commonly used de-icing agents are chlorides, such as calcium chloride($CaCl_2$) and sodium chloride(NaCl). While calcium chloride is mostly used in Korea and sodium chloride is usually used in the U.S. and Japan, all de-icing agents include chloride ions. The chlorides included in sprayed calcium chloride-based de-icing agents have severe adverse effects, including the corrosion of reinforcing steels through salt damage by infiltrating into road structures, reduced structural performance of pavement or damage to bridge structures, and surface scaling, in combination with freezing damage in winter, as well as water pollution. In addition, the deterioration of paved concrete road surface that occurs after the use of calcium chloride-based de-icing agent accelerates the development of visual problems with traffic structures. Therefore, the present study was performed to prepare an environment-friendly liquid de-icing agent through a reaction between waste organic acids and calcium-based by-products, which are industrial by-products, and to analyze the properties of the de-icing agent in order to evaluate its applicability to road facilities.

Evaluation for Applicability of Reinforced Concrete Structure with Domestic Pond Ash (국산 매립회 골재를 사용한 콘크리트 구조물의 적용성 평가)

  • Lee, Bong-Chun;Jung, Sang-Hwa;Chae, Sung-Tae;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.23 no.5
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    • pp.541-550
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    • 2011
  • Many researches have been performed on concrete with fly ash and bottom ash. However researches on concrete with pond ash (PA) and its application to RC (Reinforced Concrete) structure are limitedly carried out. This paper presents an applicability of PA concrete in construction of real size structure. Referring to the previous study, 2 domestic PA samples with normal performance are selected and 2 replacement ratios (25% and 50%) to fine aggregate are considered for 5 PA concrete structures consisting of column, slab, and wall. In order to evaluate the property of fresh concrete, several tests including air content, slump, and setting time are performed. Using cored out samples from hardened PA concrete structure, tests for strength, resistance to carbonation and chloride penetration are carried out and compared with control samples. Additionally, tests for rebound hardness, drying shrinkage, and hydration heat are performed for PA concrete structure. The test results showed that PA concrete has reasonable strength and durability performances compared to those of normal concrete. Therefore, its potential application to RC structure is promising. The PA aggregate can be more actively used for RC structures with better quality control for content of fly ash, bottom ash, and unburned carbon.

The CH3CHO Removal Characteristics of Lightweight Aggregate Concrete with TiO2 Spreaded by Low Temperature Firing using Sol-gel Method (Sol-gel법으로 이산화티탄(TiO2)을 저온소성 도포시킨 경량골재콘크리트의 아세트알데히드(CH3CHO) 제거 특성)

  • Lee, Seung Han;Yeo, In Dong;Jung, Yong Wook;Jang, Suk Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.2A
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    • pp.129-136
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    • 2011
  • Recently studies on functional concrete with a photocatalytic material such as $TiO_2$ have actively been carried out in order to remove air pollutants. The absorbtion of $TiO_2$ from those studies is applied by it being directly mixed into concrete or by suspension coated on the surface. When it comes to the effectiveness, the former process is less than that of the latter compared with the $TiO_2$ use. As a result, the direct coating of $TiO_2$ on materials' surface is more used for effectiveness. The Surface spread of it needs to have a more than $400^{\circ}C$ heat treat done to stimulate the activation and adhesion of photocatalysis. Heat treat consequently leads hydration products in concrete to be dehydrated and shrunk and is the cause of cracking. The study produces $TiO_2$ used Sol-gel method which enables it to be coated with a low temperature treat, applies it to pearlite using Lightweight Aggregate Concrete fixed with a low temperature treat and evaluates the spread performance of it. In addition to this, the size of pearlite is divided into two types: One is 2.5 mm to 5.0 mm and the other is more than 5.0 mm for the benefit of finding out the removal characteristics of $CH_3CHO$ whether they are affected by pearlite size, mixing method and ratio with $TiO_2$ and elapsed time. The result of this experiment shows that although $TiO_2$ produced by Sol-gel method is treated with 120 temperature, it maintains a high spread rate on the XRF(X ray Florescence) quantitative analysis which ranks $TiO_2$ 38 percent, $SiO_2$ 29 percent and CaO 18 percent. In the size of perlite from 2.5 mm to 5.0 mm, the removal characteristic of $CH_3CHO$ from a low temperature heated Lightweight concrete appears 20 percent higher when $TiO_2$ with Sol-gel method is spreaded on the 7 percent of surface. In other words, the removal rate is 94 percent compared with the 72 percent where $TiO_2$ is mixed in 10 percent surface. In more than 5.0 mm sized perlite, the removal rate of $CH_3CHO$, when $TiO_2$ is mixed with 10 percent, is 69 percent, which is similar with that of the previous case. It suggests that the size of pearlite has little effects on the removal rate of $CH_3CHO$. In terms of Elapsed time, the removal characteristic seems apparent at the early stage, where the average removal rate for the first 10 hours takes up 84 percent compared with that of 20 hours.

An Experimental Study on the Required Performances of Roof Concrete Placed in the In-ground LNG Storage Tank (지하식 LNG 저장탱크의 지붕 콘크리트의 요구성능에 관한 실험적 연구)

  • Kwon, Yeong-Ho
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.339-345
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    • 2013
  • This study is to derive from the required performances and the optimum mix proportion of the roof concrete placed in the in-ground LNG storage tank with a capacity of 200000 $m^3$, and propose the actual data for site concrete work. The concrete placing work without sliding and segregation in the fresh concrete condition is very important because the slope of domed roof is varied in the large range by its curvature. Also the control of hydration heat and the strength development at test ages are classified with massive section about 1.4 m thick and considered to the pre-stressing work and removal of air support after concrete placing work. Considering above condition, slump range is selected $100{\pm}25$ mm under the slope $20^{\circ}$ and $150{\pm}25$ mm over the slope $20^{\circ}$ s until 60 minutes of elapsed time. Also, the roof concrete is satisfied with compressive strength range including design strength at 91 days (30 MPa), pre-stressing work at 7 days (10 MPa), air support removal work at 21 days (14 MPa). Replacement ratio of limestone powder is determined by confined water ratio test and main design factors include water-cement ratio (W/C), sand-aggregate ratio and dosage of admixture. As test results, the optimum mix proportion of the roof concrete used low heat cement is as followings. 1) Replacement ratio of limestone powder 25% by confined water ratio test 2) Water-cement ratio 57.8% 3) Sand-aggregate ratio 42.0%. Also, test results for the adiabatic temperature rising test is satisfied with its criteria and shown the lower value compared to preceding storage tank (TK-13, 14). These required performances and the optimum mix proportion is to apply the actual construction work.

Crack and Time Effect on Chloride Diffusion Coefficient in Nuclear Power Plant Concrete with 1 Year Curing Period (1년 양생된 고강도 원전 콘크리트의 염화물 확산에 대한 균열 및 시간효과)

  • Chun, Ju-Hyun;Ryu, Hwa-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.83-90
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    • 2017
  • Concrete structure for nuclear power plant is mass concrete structure with large wall depth and easily permits cracking in early age due to hydration heat and drying shrinkage. It always needs cooling water so that usually located near to sea shore. The crack on concrete surface permits rapid chloride intrusion and also causes more rapid corrosion in the steel. In the study, the effect of age and crack width on chloride diffusion is evaluated for the concrete for nuclear power plant with 6000 psi strength. For the work, various crack widths with 0.0~1.4 mm are induced and accelerated diffusion test is performed for concrete with 56 days, 180days, and 365 days. With increasing crack width over 1.0mm, diffusion coefficient is enlarged to 2.7~3.1 times and significant reduction of diffusion is evaluated due to age effect. Furthermore, apparent diffusion coefficient and surface chloride content are evaluated for the concrete with various crack width exposed to atmospheric zone with salt spraying at the age of 180 days. The results are also analyzed with those from accelerated diffusion test.

A Study on Analysis Technique for Chloride Penetration in Cracked Concrete under Combined Deterioration (복합열화에 노출된 균열부 콘크리트 내의 염화물 침투 해석 기법에 대한 연구)

  • Kwon, Seung-Jun;Song, Ha-Won;Byun, Keun-Joo
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.359-366
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    • 2007
  • Recently, analysis researches on durability are focused on chloride attack and carbonation due to increased social and engineering significance. Generally, chloride penetration and carbonation occur simultaneously except for in submerged condition and chloride behavior in carbonated concrete is evaluated to be different from that in normal concrete. Furthermore, if unavoidable crack occurs in concrete, it influences not only single attack but also coupled deterioration more severely. This is a study on analysis technique with system dynamics for chloride penetration in concrete structures exposed to coupled chloride attack and carbonation through chloride diffusion, permeation, and carbonation reaction. For the purpose, a modeling for chloride behavior considering diffusion and permeation is performed through previous models for early-aged concrete such as MCHHM (multi component hydration heat model) and MPSFM (micro pore structure formation). Then model for combined deterioration is developed considering changed characteristics such as pore distribution, saturation and dissociation of bound chloride content under carbonation. The developed model is verified through comparison with previous experimental data. Additionally, simulation for combined deterioration in cracked concrete is carried out through utilizing previously developed models for chloride penetration and carbonation in cracked concrete. From the simulated results, CCTZ (chloride-carbonation transition zone) for evaluating combined deterioration is proposed. It is numerically verified that concrete with slag has better resistance to combined deterioration than concrete with OPC in sound and cracked concrete.

A Study on the Engineering Property and Durability of Recycled Concrete with Replacement Ratio of Recycled Fine Aggregate and Fly-ash (재생잔골재 및 플라이애시 대체율에 따른 재생콘크리트의 공학적 특성 및 내구성능에 관한 연구)

  • Kim, Moo-Han;Kim, Gyu-Yong;Kim, Jae-Whan;Cho, Bong-Suk;Kim, Young-Sun;Moon, Hyung-Jae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.89-97
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    • 2005
  • Recently, for the problem solution of demand and supply imbalance of fine aggregate due to the shortage of natural fine aggregate resource and the environment regulation on sea sand extraction in the construction field, the studies for the application of recycled fine aggregate using waste concrete are being progressed versatilely. On the other hand, the treatment of fly-ashes that of industrial by-product originated in the steam power plant is discussed by the continuous increasing of origination quantities. In the ease of using fly-ash, advantages are the improvement of workability, viscosity and long-time strength, and the reduction of hydration heat under the early ages, as the admixtures for concrete, but the studies for the application of fly-ash as recycled concrete admixtures are inadequacy. There fore, in this study, through investigating the properties of fresh, hardened and durability according to the replacement of recycled fine aggregate and fly-ash, it is intended to propose the fundamental data for structural application of recycled concrete using recycled fine aggregate and fly-ash. As the result of this study, they arc shown that the engineering properties and durability, in the case of replacement ratio 100% of recycled fine aggregate, arc similar to those of concrete using natural fine aggregate, so it is considered that recycled fine aggregate could be used as the fine aggregate for concrete. Also, the performances of recycled concrete are improved by replacing fly-ash.

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