• 한국건설순환자원학회논문집
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• 제9권4호
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• pp.578-584
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• 2021

본 연구에서는 매립회의 유효 활용을 위해 플라이애시(FA)와 매립회(PA) 4종의 수화반응 및 강도발현 특성을 비교 분석하였다. 해수 이동방식에 의해 염소함량 높은 PA는 시멘트 수화반응 촉진으로 FA와 비교하여 응결시간이 촉진되고, 누적 발열량이 증가하였으며, 초기 강도발현이 향상되었다. 그러나 재령 7일 이후 초기 수화물의 급격한 생성으로 활성도 지수 증가율은 감소하였다. 다량의 미연탄소 등 불순물을 함유한 PA는 낮은 수화 반응성으로 응결시간이 지연되고, 전 재령에서 강도가 저하되었다. 담수 이동방식에 의해 염소함량 낮고, 비정질량이 높은 PA는 FA와 유사한 수화반응 및 강도발현 특성을 나타냈다. 열중량 분석결과로 FA와 비슷한 수준의 Ca(OH)₂ 소비량과 포졸란 반응성을 가진 것을 확인하였다. 결과적으로 매립회의 활용성 높이기 위해서는 담수 이동방식의 적용 확대와 강열감량의 관리가 필요할 것으로 분석되었다.

• 한국산업융합학회 논문집
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• 제25권2_2호
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• pp.289-297
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• 2022

Deterioration in durability of structures due to the steel corrosion is difficult to determine whether or not corrosion is initiated and how much propagated, and moreover, repair and maintenance are not easy to deal with. Therefore, preventive treatments can be the best option to avoid the deterioration. Various methods for preventing corrosion of steel, such as electrochemical treatments, anti-corrosion agents and steel surface coatings, are being developed, but economic and environmental aspects make it difficult to apply them to in-situ field. Thus, the purpose of this study was to improve corrosion resistance by using CA-based clinker that are relatively simple and expected to be economically profitable Existing CA-based clinkers had problems such as flash setting and low strength development during the initial hydration process, but in order to solve this problem, CA clinker with low initial reactivity were used as binder in this study. The cement paste used in the experiments was replaced with CA₂ clinker for 0%, 10%, 20%, and 30% in OPC. And the mixture used in the chloride binding test for the extraction of water-soluble chloride was intermixed with Cl- 0.5%, 1%, 2%, and 3% by weight of binder content. To evaluate characteristic of hydration heat evolution, calorimetry analysis was performed and simultaneously chloride binding capacity and acid neutralization capacity were carried out. The identification of hydration products with curing ages was verified by X-ray diffraction analysis. The free chloride extraction test showed that the chlorine ion holding ability improved in order OC 10 > OC 30 > OC 20 > OC 0 and the pH drop resistance test showed that the resistance capability in pH 12 was OC 0 > OA 10 > OA 20 > OA 30. The XRD analyses showed that AFm phase, which can affect the ability to hold chlorine ions, tended to increase when CA₂ was mixed, and that in pH12 the content of calcium hydroxide (Ca(OH)₂), which indicates pH-low resistance, decreased as CA₂ was mixed

• 공업화학
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• 제33권6호
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• pp.588-593
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• 2022

MgO 입자 표면에 첨가된 P₂O₅의 가수분해, 발수성, 그리고 절연 거동에 미치는 영향을 조사하였다. MgO 표면에 첨가된 P₂O₅는 가수분해반응 억제와 발수성을 동시에 나타내기 때문에 독특한 절연거동을 나타내었다. 따라서 절연거동은 MgO의 표면수화반응에 의한 Mg(OH)₂와 OH^-전하 전달비와 친수성에 반비례하였다. 시효에 따른 MgO의 절연성은 표면수화반응, 첨가된 도펀트 종의 밴드갭, 그리고 도펀트의 친수성과 소수성에 강한 영향성과 의존성을 나타내었다. 마지막으로 친수성인 MgO의 표면수화반응을 억제하는 전기절연성을 발현하여 열전달매체 응용분야에서 큰 잠재력을 제공하는 것으로 나타났다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.669-672
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• 2008

본 연구에서는 고로슬래그 미분말을 다량 치환하는 고성능 콘크리트의 가능성을 분석하기 위해, 고로슬래그 미분말의 치환율 변화에 따른 콘크리트의 특성을 분석하였는데, 그 결과를 요약하면 다음과 같다. 먼저, 굳지않은 콘크리트의 특성으로 유동성은 고로슬래그 미분말의 치환율이 증가함에 따라 증가하는 경향을 나타내었고, 공기량은 감소하는 경향을 나타내었으며, 응결시간은 지연되는 것으로 나타났다. 경화콘크리트의 특성으로 고로슬래그 미분말의 치환율이 50%까지 증가하는 조건에서의 압축강도는 초기재령에서 OPC보다 저하 하였지만 재령 28일에서는 OPC와 동등이상의 수준을 나타내었으며, 간이 단열에 의한 온도 상승량은 수화 초기에 치환율이 증가 할수록 감소였으나 후반부에서는 수화가 서서히 진행되어 수화열이 증가하는 것으로 나타났다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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• pp.47-52
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• 2000

Recently, it is very necessary the development of the manufacturing techniques for high strength concrete(HSC) for the large-scale size and good quality of civil structure. But, the manufacture and quality control of HSC of which shrinkage, heat of hydration and workability at construction filed are considered, is very difficult due to its low water-cement ratio and high quantity of unit cement content. In the present study, we tried to know and assess the influences of chemical and physical properties of cement on the material properties of HSC. We analyzed basic properties of 4 kinds of cement whose chemical and physical properties are different each other through various tests such as chemical analysis and mortal test. Also, we performed the assessment of the material properties of HSC for each dement by the test for the conditions of same mix design and similar compressive strength. From the results in the study, the assessment of the important quality factors of cement influencing the properties of HSC may be utilized to quality control of applied cement to manufacture the HSC of high quality.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.731-736
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• 2001

In this thesis, the study on controlling of cracks of concrete box culvert in early ages is presented. The optimum construction method and economical analysis were proposed also through the experiment of the material and field test. As a result of the experiment of the material, using fly ash, CSA expansive agent and BELITE cement(type IV) showed good result in the control of cracks induced by heat of hydration and shrinkage. As a result of construction test analysis, the maintenance time of form system did not show a big difference in controlling of cracks. Control of distribution of reinforcement, spacing of expansion joint and use of BELITE cement showed big differences in the control of cracks in early ages. As a result of economical analysis, control of construction variables before construction can make it possible to reduce the repair expense.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문발표회
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• pp.1-4
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• 2003

Recently, a structure has been larger and higher under the improvement of construction technique. So, a mass concrete constructions that a mat foundation thickness of structure is over 80cm have been many. Also, because of the reason of high strength of concrete, the matter of thermal crack have become an important task to be solved absolutely. tn a cause of a thermal crack occurrence, there are material used, mixture of concrete, construction condition and so forth. In this study, we executed temperature and stress analysis of mat foundation to know the effect of the construction condition on a thermal crack of mat foundation. And we evaluated quantitatively about the occurrence possibility of thermal crack using the hydration heat analysis program. By using of this analysis technique, we will can control skilfully the quality of a mat foundation in advance.

• 한국안전학회지
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• 제16권2호
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• pp.91-96
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• 2001

Theoretical definitions of mixed behavior of PE panel and connote should have preceded to cause a mixed behavior of connote and polyethylene which have different elastic module, one-line expansion coefficients, poison ratios, compressive strengths and tensile strengths. Consequently, changes are analyzed through experiment process to identify the effects on interpretation of mixed behavior on the basis of temperature change of structures, temperature rise of concrete other than PE panel due to hydration heat temperature rise of concrete other than PE panel due to drying and contraction, working of hydrostatic pressure by storage and temperature gradient From the results of interpretation of the analysis, it is concluded that PE panel have slight influences on the change of guess of structures and maintains structural stability compared with concrete structures without PE panel.

• 한국세라믹학회지
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• 제37권5호
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• pp.410-417
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• 2000

In this study the effects of specifics surface area of cement, addition amount of gypsum and substitution ratio of gypsum anhydrite ont he physical properties of cement mortars were investigated by measruements of setting time, flow, compressive strength and hydration heat evolution rate. The results showed that fluidity of mortars was increased by 40 wt.% of maximum flow change with the decreasing specific surface area of cement from 3,500$\textrm{cm}^2$/g to 3,300${\pm}$50$\textrm{cm}^2$/g and affected by the relationship between the cement and balancing between the chemical activityof cement and solubility of calcium sulfate are desirable to prevent the fluidity of concrete from decreasing by high temperature in summer season.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문 발표회
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• pp.1-4
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• 2003

Recently, a structure has been larger and higher under the improvement of construction technique. So, a concrete constructions that a mat foundation thickness of structure is over 80cm have been many. Also, because of the reason high strength concrete, the matter of thermal crack have become an important task to be solved absolutely. In a cause a thermal crack occurrence, there used, mixture of concrete, construction and so forth. In this study, we executed temperature and stress analysis of mat foundation to know the effect the construction condition a thermal crack of mat foundation. And we evaluated quantitatively about the occurrence possibility of thermal crack using the hydration heat analysis program. By using of this analysis technique, will can control skilfully the quality of a mat foundation in advance.