• Title/Summary/Keyword: heat of hydration heat

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Study on Temperature History and Compressive Strength of Mock-up Concrete Considering Seasonal Change (매스콘크리트의 계절에 따른 온도이력과 압축강도에 관한 실험)

  • Kim Young-Joo;Gong Min-Ho;Kim Kwang-Ki;Yang Dong-Il;Pack Moo-Young;Jung Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.11a
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    • pp.89-92
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    • 2005
  • Our country has experienced variations in temperature as belong to the area of the continental climate that shows four significant seasons. These occur quality of construction. As the hydration of cement processes, the strength of concrete is developed. In order to improve the quality of concrete, various conditions including temperature and humidity should be maintained appropriately and concrete itself should be cured sufficiently This paper is basic experiment for estimating influence of strength by seasonal mock-up concrete's heat of hydration and estimate relationship of compressive strength development by curing temperature. And show basic document as quality control.

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A Study on Sodium Sulfate Activited the Hydration Properties of Fly Ash-cement Paste (황산염나트륨 자극제를 사용한 플라이 애쉬 혼입 시멘트 페이스트의 초기 수화 특성에 관한 기초적 연구)

  • Wang, Zihao;Sun, Yang;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.129-130
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    • 2021
  • In order to solve the problem of low early-age compressive strength of high volume fly ash concrete. This paper studies the effect of 2% sodium sulfate (Na2SO4) as a chemical activator on the paste with 40% fly ash content and a water-binder ratio of 0.30. The results indicate that the addition of Na2SO4 can effectively improve the early-age compressive strength of the fly ash-cement system, and the strength improvement rate on the first day reached nearly 70%. In addition, calorimetric analysis reveals that the incorporation of Na2SO4 promotes the early hydration of cement and fly ash, increases the cumulative hydration heat and delays the heat peak of the aluminum phase.

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Hydration Characteristics of Cement Paste Added Liquid and Neutralized Red Mud (액상 및 중화 레드머드를 첨가한 시멘트 페이스트의 수화특성)

  • Kang, Hye Ju;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.104-105
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    • 2020
  • Red mud is a highly alkaline waste by-product of the aluminum industry. Although recycling of red mud is being actively researched, a feasible technological solution has not been found yet. In this study, we propose that neutralization of red mud alkalinity could assist in its use as a construction material. Neutralized red mud ( pH 6-8) was prepared by adding sulfuric acid to liquefied red mud (pH 10-12). After adding liquid and neutralized red mud to the cement paste, the heat of hydration was measured. As a result of the experiment, the calorific value of the cement paste with liquid red mud was lowered and delayed compared to the cement paste with neutralized red mud.

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Experimental Study on the Development of High-Performance Concrete (고성능 콘크리트 개발에 관한 실험적 연구 제 1보 : 고미분말 슬래그 혼합시멘트의 물성)

  • 구자술;이영진;김남호;정재동
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.45-50
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    • 1993
  • This paper describes some results of various tests which were carried out with varying the fineness of salg from 6000 to 10000$\textrm{cm}^2$/g and the slag content in cement from 30 to 50wt% for the perpose of utilizing finely ground blast-furnace slag as an ingredient for high-performance concrete. Test for heat of hydration, microstructural and hydration characteristics in paste, and fluidity and compressive strength in mortar were carried out. From these test results, it was found that, by properly determining the content and fineness of the slag, it is possible to manufacture high-performance concrete that has low heat of hydration, high early strength development, fine pore size and a highly densified microstructure.

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Early Hydration of Ticalcium Silicate(I) (Tricalcium Silicate의 초기수화반응(I))

  • 오희갑;최상흘
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.35-40
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    • 1986
  • The early hydration of tri-calcium silicate $(C_3S)$ with different cooling conditions was studied by varing water/solid ratio and atmosphere. The cooling condition and water/solid ratio affected to the second peak of heat liberation but it had no correlation to the induction period. The $Ca^{2+}$ concentration in the aqueous solution was maximized at the starting point of the second peak of heat liberation but in the $CO_2$ exsistence the $Ca^{2+}$ concentration was low and $SiO_2$ con-centration was increased. The hydration rate of $C_3S$ was so accelerated that the induction period could not appear in the $CO_2$ exsistence.

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Mock-up Test on the Reduction of Hydration Heat of Mass Concrete for Transfer Girder (전이보 매스콘크리트의 수화열 저감에 관한 Mock-up 실험)

  • Yoon Seob;Hwang Yin Seong;Baik Byung Hoon;Han Cheon Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.707-710
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    • 2004
  • This paper reported the results of mock-up test on mass concrete for transfer girder using setting time difference of super retarding agent(SRA). According to test results, two mock-up structures were made. Plain concrete without placing layer reached maximum temperature after 24hours since placement and caused surface hydration cracks at top section. However, concrete with placing layer reached maximum temperature after 72hours and surface temperature was higher than center temperature, which did not cause surface crack. After form removing, no crack was observed at side surface of plain concrete, while concrete using SRA at mid section had surface scaling and settling crack. According to coring results, concrete with placing layer had a penetration crack from top section to bottom section. Therefore, the setting time difference method to reduce hydration heat will have difficulty in applying the mass concrete for transfer girder.

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Lateral Behavior of Abutment Piles in Full Integral Bridge During 7 Days in Response to Hydration Heat and Drying Shrinkage (수화열과 건조수축에 의한 7일간의 완전 일체식 교량 교대 말뚝기초의 횡방향 거동)

  • ;;;;Thomas A. Bolte
    • Journal of the Korean Geotechnical Society
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    • v.19 no.6
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    • pp.127-149
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    • 2003
  • The bridge tested was 3 spans 90m-long PSC beam concrete bridge with a stub-type abutment which had a skew of 60$^{\circ}$ about the axis of bridge. A cement concrete was placed at the superstructural slab of the bridge. Inclinometers and straingauges were installed at piles as well. During 7 days-curing of superstructural slab, the pile behavior in response to hydration heat and drying shrinkage of the slab was monitored. Then monitored values were compared with the horizontal movement obtained from the HACOM program and the calculated lateral behavior obtained from the nonlinear p-y curves of pile. As a result, lateral behavior of H-piles by the field measurement occurred due to the influence of hydration heat and drying shrinkage obtained during curing of superstructural concrete. The lateral displacements by hydration heat and drying shrinkage were 2.2mmand 1.4mm respectively. It was observed as well that the inflection point of lateral displacement of pile was shown at 1.3m down from footing base. It means that the horizontal movement of stub abutment did not behave as the fixed head condition of a pile but behave as a similar condition. The measured bending stress did not show the same behavior as the fixed head condition of pile but showed a similar condition. The increment of maximum bending stress obtained from the nonlinear p-y curves of pile was about 300(kgf/$\textrm{km}^2$) and was 2 times larger than measured values regardless of installation places of straingauges. Meanwhile, lateral load, maximum lateral displacement, maximum bending stress and maximum bending moment of pile showed a linear behavior as curing of superstructural concrete slab.

Evaluation of Hydration Heat of Mass Concrete with Capsulated Slurry PCM and FEM Study for Analyzing Thermal Crack (캡슐형 슬러리 PCM을 혼입한 매스콘크리트의 수화열 평가 및 온도균열 FEM 해석에 관한 연구)

  • Park, ChangGun;Kim, Bo-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.379-388
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    • 2014
  • The purpose of this study is to investigate the effect of capsulated slurry phase change material (PCM) on the thermal crack in mass concrete by experimental work and FEM analysis. In this study, three conditions of samples were prepared for evaluating the level of hydration heat, i.e., a material condition, a cement paste condition and a concrete condition. Also, a compressive strength test was conducted for FEM inverse analysis. Based on the results of the experiment, exothermic function coefficients of concrete with encapsulated slurry PCM were deducted by the inverse analysis. After that, they applied to FEM analysis of the mass scale concrete structures. From the results of this experiment, $31^{\circ}C$ capsulated slurry PCM had no super cooling phenomenon in the material condition. In the cement condition, hydration heat decreased by 34.61J when PCM of 1g was mixed. In the concrete condition, PCM of 6% was deducted as the best level in hydration heat absorption. In FEM inverse analysis, rate coefficient of reaction gradually decreased when PCM mixing ratio increased. But, temperature-rise coefficient increased when PCM mixing ratio exceeded 6%. For the inversed exothermic function coefficients applying to large scale concrete structures, a thermal cracking index increased by 0.05 when PCM of 1% was mixed.

Models for Hydration Heat Development and Mechanical Properties of Ultra High Performance Concrete (초고성능 콘크리트의 수화발열 및 역학적 특성 모델)

  • Cha, Soo-Won;Kim, Ki-Hyun;Kim, Sung-Wook;Park, Jung-Jun;Bae, Sung-Geun
    • Journal of the Korea Concrete Institute
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    • v.22 no.3
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    • pp.389-397
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    • 2010
  • Concrete has excellent mechanical properties, high durability, and economical advantages over other construction materials. Nevertheless, it is not an easy task to apply concrete to long span bridges. That's because concrete has a low strength to weight ratio. Ultra high performance concrete (UHPC) has a very high strength and hence it allows use of relatively small section for the same design load. Thus UHPC is a promising material to be utilized in the construction of long span bridges. However, there is a possibility of crack generation during the curing process due to the high binder ratio of UHPC and a consequent large amount of hydration heat. In this study, adiabatic temperature rise and mechanical properties were modeled for the stress analysis due to hydration heat. Adiabatic temperature rise curve of UHPC was modeled superposing 2-parameter model and S-shaped function, and the Arrhenius constant was determined using the concept of equivalent time. The results are verified by the mock-up test measuring the temperature development due to the hydration of UHPC. In addition, models for mechanical properties such as elastic modulus, tensile strength and compressive strength were developed based on the test results from conventional load test and ultrasonic pulse velocity measurement.

A Comparative Study on Strength Development, Chloride Diffusivity and Adiabatic Temperature Rise of Marine Concrete Depending on Binder Type (결합재 종류에 따른 해양 콘크리트의 강도 발현, 염화물 확산 및 단열온도 상승 특성에 대한 비교 연구)

  • Bae, Jun-Young;Cho, Sung-Hyun;Shin, Kyung-Joon;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.411-418
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    • 2013
  • Recently, in order to reduce a damage of chloride attack and hydration heat in marine concrete structures, blended cement in mixing the marine concrete is widely used. Long term strength development is distinct in concrete with blended cement and it also has excellent resistance to chloride attack and reduction of hydration heat. However, blended cement has a characteristic of relatively low compressive strength in early age of 28 days. On the other hand, a high level of compressive strength is required in the Standard Specification for marine concrete mix design. Such concrete mix design satisfying Standard Specification is effective to chloride attack but disadvantageous for hydration heat reduction due to large quantity of binder. In this study, the material properties of marine concrete considering water-binder ratio and binder type are experimentally investigated. Through the research results, compressive strength in blended cement at the age of 56 days is similar although it has smaller compressive strength at the age of 28 days compared with result of OPC (ordinary portland cement). Even though blended cement has a large water-binder ratio and small unit of binder content, chloride ion diffusion coefficient is still small and hydration heat is also found to be reduced. For meeting the required compressive strength in Standard Specification for marine concrete at 28 days, the increased unit content of binder is needed but the increased hydration heat is also expected.