• 제목/요약/키워드: heat of formation

검색결과 1,689건 처리시간 0.033초

Effect of Flue Gas Heat Recovery on Plume Formation and Dispersion

  • Wu, Shi Chang;Jo, Young Min;Park, Young Koo
    • 한국입자에어로졸학회지
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    • 제8권4호
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    • pp.161-172
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    • 2012
  • Three-dimensional numerical simulation using a computational fluid dynamics (CFD) was carried out in order to investigate the formation and dispersion of the plume discharged from the stack of a thermal power station. The simulation was based on the standard ${\kappa}{\sim}{\varepsilon}$ turbulence model and a finite-volume method. Warm and moist exhaust from a power plant stack forms a visible plume as entering the cold ambient air. In the simulation, moisture content, emission velocity and temperature of the flue gas, air temperature and wind speed were dealt with the main parameters to analyze the properties of the plume composed mainly of water vapor. As a result of the simulation, the plume could be more apparent in cold winter due to a big difference of latent heat capacity. At no wind condition, the white plume rises 120 m upward from the top of the stack, and expands to 40 m around from the stack in cold winter after flue gas heat recovery. The influencing distance of relative humidity will be about 100 m to 400 m downstream from the stack with a cross wind effect. The decrease of flue gas temperature by heat recovery of thermal energy facilitates the formation of the plume and restrains its dispersion. Wind speed with vertical distribution affects the plume dispersion as well as the density.

11 wt% 크롬이 함유된 Ti 첨가 페라이트스테인리스강의 입계부식에 미치는 규소의 영향 (Effect of Silicon on Intergranular Corrosion Resistance of Ti-stabilized 11 wt% Cr Ferritic Stainless Steels)

  • 현영민;김희산
    • Corrosion Science and Technology
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    • 제12권6호
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    • pp.265-273
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    • 2013
  • Ti-stabilized 11 wt% Cr ferritic stainless steels (FSSs) for automotive exhaust systems have been experienced intergranular corrosion (IC) in some heat-affected zone (HAZ). The effects of sensitizing heat-treatment and silicon on IC were studied. Time-Temperature-Sensitization (TTS) curves showed that sensitization to IC was observed at the steels heat-treated at the temperature lower than $650^{\circ}C$ and that silicon improved IC resistance. The sensitization was explained by chromium depletion theory, where chromium is depleted by precipitation of chromium carbide during sensitizing heat-treatment. It was confirmed with the results from the analysis of precipitates as well as the thermodynamical prediction of stable phases. In addition, the role of silicon on IC was explained with the stabilization of grain boundary. In other words, silicon promoted the formation of the grain boundaries with low energy where precipitation was suppressed and consequently, the formation of Cr-depleted zone was retarded. The effect of silicon on the formation of grain boundaries with low energy was proved by the analysis of coincidence site lattice (CSL) grain boundary, which is a typical grain boundary with low energy.

판형 열교환기를 이용한 과냉각수용액에서 유동과냉도 및 냉각속도가 연속제빙에 미치는 영향 (Influence of the Supercooling Degree and Cooling Rate on a Continuous Ice Formation by a Supercooled Aqueous Solution in Flow Using a Plate Heat Exchanger)

  • 이동규;백종현;홍희기;강채동
    • 설비공학논문집
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    • 제19권9호
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    • pp.647-653
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    • 2007
  • In dynamic ice storage system(DISS), ice slurry is formed not only from solution freezing by mechanical removing parts but also supercooled solution. However, in order to perform continuous ice formation in the system without mechanical moving parts, supercooled aqueous solution should be formed stable through cooling heat exchanger and be dissolved uniformly in storage tank. In previous study, the time of ice slurry increased as the pressure of the cooling heat exchanger(PHX) increased. In this study, a cooling experiment of an ethylene glycol 7mass% solution was performed with various inlet temperature of the PHX, which has constant brine inlet temperature of $-7^{\circ}C$. The temperature in the storage tank maintained to freezing point of the solution. At results, the time of ice slurry formation increased as the supercooling degree decreased and the cooling rate increased.

용융 금속의 고화층 증가가 자연대류 열전달에 미치는 영향 (Effect of Crust Increase on Natural Convection Heat Transfer in the Molten Metal Pool)

  • 박래준;최상민;김상백;김희동
    • 대한기계학회논문집B
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    • 제23권2호
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    • pp.226-233
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    • 1999
  • An experimental study has been performed on natural convection heat transfer with a rapid crust formation in the molten metal pool of a low Prandtl number fluid. Two types of steady state tests, a low and high geometric aspect ratio cases in the molten metal pool, were performed. The crust thickness by solidification was measured 88 a function of boundary surface temperatures. The experimental results on the relationship between the Nusselt number and Rayleigh number In the molten metal pool with a crust formation were compared with existing correlations. The experimental study has shown that the bottom surface temperature of the molten metal layer, in all experiments. is the major influential parameter in the crust formation, duo to the natural convection flow. The Nusselt number of the case without a crust formation in the molten metal pool is greater than that of the case with the crust formation at the same Rayleigh number. The present experimental results on the relationship between the Nusselt number and Rayleigh number In the molten metal pool match well with Globe and Dropkin's correlation. From the experimental results, a now correlation between the Nusslet number and Rayleigh number in the molten metal pool with the crust formation was developed as $Nu=0.0923(Ra)^{0.302}$ ($2{\times}10^4< Ra<2{\times}10^7$).

어닐링처리에 따른 니켈 도금한 하이브리드 동판의 집합조직 및 기계적 특성평가 (Evaluation of Texture and Mechanical Property on Annealing Condition of Ni-Plated Hybrid Cu Sheet)

  • 이정일;이주호;조경원;김건남;김강범;장태순;박노진
    • 열처리공학회지
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    • 제21권3호
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    • pp.144-149
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    • 2008
  • It has been reported that copper and copper alloys have a large anisotropy of functional properties such as electrical, thermal and mechanical properties, which means that the texture of polycrystalline alloy should be considered to achieve better properties. In this study, the determination of grain growth orientation and texture formation in the cold-rolled, heat-treated and Ni-plated hybrid copper sheets was investigated. Grain growth direction and texture formation were analyzed by the X-ray pole figure. The influence of texture on the mechanical properties could be quantitatively confirmed by the results from the orientation distribution function and the tensile test. The heat-treated texture in the cold-rolled hybrid copper sheet is also investigated and discussed.

Mechanism of intragranular ferrite formation in heat-affected zone of titanium killed steel

  • Terasaki, Hidenori;Komizo, Yu-Ichi
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2009년 추계학술발표대회
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    • pp.197-201
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    • 2009
  • A lot of work is carried out concerning to acicular ferrite formation in the weld metal of high strength and low-alloy steel. Those results are suggesting that oxides that contain titanium elements provides nucleation site of intragranular ferrite, referred as acicular ferrite. Thus, when intragranular ferrite is expected to form in heat-affected zone, oxide containing titanium element should be formed in the steel. However, normal steel is deoxidized by using aluminum element (Al-killed steel) with little oxygen content. It means almost oxygen is deoxidized with aluminum elements. In the present work, in order to form the acicular ferrite in the heat affected zone, with the same concept in the case of weld metal, the steel deoxidized with titanium element (titanium killed-steel) is prepared and the acicular ferrite formation is observed in detail by using laser-conforcal microscopy technique. The confocal technique makes it possible that the morphological change along the phase transformation from austenite to ferrite is in-situ tracked. Thus, the inclusion that stimulated the ferrite nucleation could be directly selected from the observed images, in the HAZ of the Ti-killed steel. The chemical composition of the selected inclusion is analyzed and the nucleation potential is discussed by changing the nucleation site with boron element. The potency for the ferrite nucleation is summarized and the existence of effective and ineffective manganese sulfide for nucleation is made clear.

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스케일 층의 생성 및 성장을 고려한 가열로 내 슬랩의 승온 특성 해석에 관한 연구 (A Numerical Study on the Slab Heating Characteristics in a Reheating Furnace with the Formation and Growth of Scale on the Slab Surface)

  • 이동은;장정현;김종민;홍동진;박해두;박윤범;김만영
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.109-112
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    • 2008
  • In this work, a mathematical heat transfer model of a walking-beam type reheating furnace that can predict the formation and growth of the scale layer, which is produced due to oxidative reaction between the furnace oxidizing atmosphere and the steel surface in the reheating furnace, has been developed. The model can also predict the heat flux distribution within the furnace and the temperature distribution in the slab and scale throughout the reheating furnace process by considering the heat exchange between the slab and its surroundings in the furnace, including radiant heat transfer among the slabs, the skids, the hot gases and the furnace wall as well as the gas convection heat transfer in the furnace. Using the model developed in this work, the effects of the scale layer on the heat transfer characteristics and temperature behavior of the slab is investigated. A comparison is also made between the predictions of the present model and the data from an in situ measurement in the furnace, and a reasonable agreement is founded.

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비예혼합 수소-공기 난류제트화염내의 NOx 생성특성 예측 (Prediction of NOx Formation Characteristics in Turbulent Nonpremixed Hydrogen-Air Jet Flames)

  • 김성구;김용모;안국영;오군섭
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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    • pp.165-170
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    • 1998
  • Turbulent nonpremixed $H_2$-air jet flames are numerically investigated using the joint PDF model. The reaction progress variable is derived by assuming the radicals 0, H, and OH to be in partial equilibrium and additional species $HO_2$ and $H_2O_2$ in steady state. The model is extended to npnadiabatic flame by introducing additional variable for the transport of enthalpy and radiative source term is calculated using a local, geometry independent model. In terms of flame structure and NO formation, the predicted results are favorably agreed with experimental data. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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광기록에 이용되는 Te-based Mediao에 대한 열적 해석 (The Thermal Analysis of Te-based media for Optica1 Recording)

  • 천석표;이성준;이현용;정홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.123-126
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    • 1994
  • We discussed the thermal analysis for recording media with the variation of the laser pulse duration and the power and the temperature distribution for the optimized Te-based antireflection structure by using the computer calculations. If the radial diffusion of heat is negligible, we can calculate the maximum temperature at the spot center in recording layer by Simple Method, and the temperature profile considering the specific heat and the latent heat by Numerical Method. As a result, the effect of the heat sinking which acted as a loss for the hole formation can be minimized by introducing the pulse of the hole formation duration( $\tau$ ) shorter than the thermal time constant( $\tau$$\sub$D/) of dielectric layer. This requirments can be satisfied as using the dielectric thickness of the 7nd ART condition or the dielectric materials with low thermal diffusivity.

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광기록에 이용되는 Te-based media에 대한 열적 해석 (The thermal analysis of te-based media for the optical recording)

  • 이성준;천석표;이현용;정홍배
    • E2M - 전기 전자와 첨단 소재
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    • 제8권1호
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    • pp.64-70
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    • 1995
  • We discussed the thermal analysis for a recording media with the variation of the laser pulse duration, the laser power and the temperature distribution in order to optimize the Te-based antireflection structure from the computer calculations. In the case that the radial heat diffusion is negligible, we can calculate the maximum temperature of the recording layer at the center of the spot by the Simple Model. The temperature profile of the recording layer is obtained from the Numerical Model by considering the total specific heat and the latent heat. As a result, the effect of the heat sinking acting as a thermal loss for the hole formation could be minimized by introducing the pulse with the hole formation duration(.tau.) below the thermal time constant(.tau.$_{D}$) of a dielectric layer. These requirments can be satisfied by using the dielectric thickness of the 2nd ART(Anti-Reflection Trilayer) condition or the dielectric materials with a low thermal diffusivity.y.

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