• 제목/요약/키워드: heat of formation

검색결과 1,686건 처리시간 0.035초

착상을 고려한 극저온 질소-대기 열교환기의 해석 (Analysis of a Cryogenic Nitrogen-Ambient Air Heat Exchanger Including Frost Formation)

  • 최권일;장호명
    • 설비공학논문집
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    • 제12권9호
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    • pp.825-834
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    • 2000
  • A heat exchanger analysis is performed to investigate the heating characteristics of cryogenic nitrogen by ambient air for the purpose of cryogenic automotive propulsion. The heat exchanger is a concentric triple-passage for supercritical nitrogen, and the radial fins are attached on the outermost tube for the crossflow of ambient air. The temperature distribution is calculated for the nitrogen along the passage, including the real gas properties of nitrogen, the fluid convections and the conductions through the tube walls and the fins. Since the wall temperature of the outer (ambient side) tube is very low in most cases, a heavy frost can be formed on the surface, affecting the heat exchange performance. By the method of the similarity between the heat and the mass transfer of moist air, the frost growth and the time-dependent effectiveness of the heat exchanger are calculated for various operating conditions. It is concluded that the frost formation can augment the heating of nitrogen during the initial period because of the latent heat, then gradually degrades the heat exchange because of the increased thermal resistance. Practical design issues are discussed for the flow rate of nitrogen, the velocity and humidity of ambient air, and the sizes of the fin.

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전열특성을 이용한 가스하이드레이트 인공제조 성능향상에 대한 실험적 연구 (An Experimental Study on the Heat Transfer Characteristics to Enhance the Artificial Hydrate Formation Performance)

  • 신창훈;박승수;권옥배;신광식;최양미;이정환
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.515-518
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    • 2007
  • Gas hydrates are ice-like crystalline compounds that form under low temperature and elevated pressure conditions. Recently, gas hydrates present a novel means for natural gas storage and transportation with potential applications in a wide variety of areas. An important property of hydrates that makes them attractive for use in gas storage and transportation is their very high gas-to-sol id ratio. In addition to the high gas content, gas hydrates are remarkably stable. The main barrier to development of gas hydrate technology is the lack of an effective mass production method of gas hydrate in solid form. In this study, some performance comparison among several cases classified by different volume sizes of solution were carried to identify the characteristics due to the volume increment. And it is found that one of the main reasons disturbing hydrate formation is related to the lack of cooling heat transfer due to the volume increase of the solution. So, three kinds of heat transfer plates which have different shapes and cross sectional areas were made and tested for the performance comparison following to the shape and area of each plate. Finally it is clarified that the heat transfer is one of the major factors effecting hydrate formation performance and the installation of heat transfer plate can enhance the formation performance especially not in terms of the quantity but the speed.

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강원도 정선군 운치리 얼음골의 여름철 결빙현상에 관한 연구 (On Study of Summertime Ice Formation in the Ice Valley at Unchiri, Gangwon-Province)

  • 전병일
    • 한국환경과학회지
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    • 제11권9호
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    • pp.857-863
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    • 2002
  • The meteorological elements were measured to investigate cause of summertime ice formation at Unchiri, Gangwon Province. The cause of freezing at valley was conformed as adiabatic expansion theory, latent heat of evaporation, natural convective theory, cold air remain theory, and convective freezing theory according to former study. However nither theory produced a satisfactory explanation. This studying area is not valley but ridge, and underground water surface exists at below than freezing height. wintertime temperature drop and summertime cold air spouting were explain as natural convective theory, generation of water drop on the rock was explained as cooling theory by air expansion, and ice formation on the rock was explained as adiabatic expansion theory. In conclusion, formation of ice valley at Unchiri was formed by natural convective theory, adiabatic expansion theory, and latent heat of evaporation successively.

엔진 물통로 내부 벽면 스케일 축적이 LPG 엔진의 열적 내구성에 미치는 영향에 대한 연구 (A Study on Effect of Scale Formation in Water Jacket on Thermal Durability in LPG Engine)

  • 류택용;신승용;최재권
    • 한국자동차공학회논문집
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    • 제9권3호
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    • pp.42-50
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    • 2001
  • In this paper, the effects of scale formation in engine water jacket upon the thermal durability of engine itself and its component parts were studied. To understand the effect of quality of water, a full load engine endurance test for 50 hours was carried out with not-treated underground water. The followings were found through the tested engine inspection after the endurance test; 1-2 mm thick scale formation in the engine water jacket, valve seat wear, piston top land scuffing, piston pin stick, and cylinder bore scuffing in siamese area. In order to understand the causes of above test results, the heat rejection rate to coolant, the metal surface temperature of combustion chamber, and the oil and exhaust gas temperatures were measured and analyzed. The scale formed in the engine water jacket played a role as thermal insulator. The scale formed in the engine reduced the heat rejection rate to coolant and it caused to increase the metal surface temperature. The reduced heat rejection rate to coolant increased the heat rejection rate to oil and exhaust gas and increased the oil and exhaust gas temperature. Also, the reasons of valve seat wear, piston top land scuffing and cylinder bore scuffing, and piston pin stick quantitatively analyzed in this paper.

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고분자전해질 연료전지에서 전기화학반응 열생성에 의한 열전달특성 (Heat transport characteristics by heat generation of electrochemical reactions in proton exchange membrane fuel cell)

  • 조선아;이필형;한상석;황상순
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.3377-3382
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    • 2007
  • In proton exchange membrane fuel cell, the heat is generated at the catalyst layer as result of exothermic electrochemical reaction. This heat increases temperature of gas diffusion layer and membrane whose conductivity is very sensitive to humidity, function of temperature. So it is very important to analysis heat transfer through fuel cell to maintain temperature at specified range. In this paper numerical simulation was done including reversible, irreversible, ionic resistance, water formation loss to source term of energy equation. Results show that irreversible and water formation loss contributes mainly to energy source term and as current density increases, all of energy source terms become increased and Nusselt number is increased as results of more heat generation. Particularly irreversible loss is found to be predominant among the all energy source and water formation at cathode channel influences the temperature distribution of fuel cell greatly.

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CH4/Air 예혼합화염의 하류영역에서 체류시간 및 열손실에 의한 NOx의 생성특성 (The Effect of Residence Time and Heat Loss on NOx Formation Characteristics in the Downstream Region of CH4/Air Premixed Flame)

  • 황철홍;현승호;탁영조;이창언
    • 대한기계학회논문집B
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    • 제31권1호
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    • pp.99-108
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    • 2007
  • In this study, the NOx formation characteristics of one-dimensional $CH_4$/Air premixed flame using detailed-kinetic chemistry are examined numerically. The combustor length and the amount of heat loss are varied to investigate the effect of residence time and heat loss on the NOx formation in a post-flame region. In the flame region, NO is mainly produced by the Prompt NO mechanism including $N_2$O-intermediate NO mechanism over all equivalence ratios. However, thermal NO mechanism is more important than Prompt NO mechanism in the post-flame region. In the case of adiabatic condition, the increase of combustor length causes the remarkable increase of NO emission at the exit due to the increase of residence time. On the other hand, NO reaches the equilibrium state in the vicinity of flame region, considering radiation and conduction heat losses. Furthermore the NO, in the case of $\phi$=1.2, is gradually reduced in the downstream region as the heat loss is increased. From these results, it can be concluded that the controls of residence time and heat loss in a combustor should be recognized as an important NOx reduction technology.

소형 슬러시 제조기의 전열현상에 관한 연구 (Heat Transfer Characteristics of Small Slush Maker)

  • 김도영;김내현;오왕규;최용민;변호원
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 하계학술발표대회 논문집
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    • pp.346-350
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    • 2008
  • Tests were conducted to obtain heat transfer coefficients during slush formation from 10% sucrose solution. The slush was made by scraping the ice formed on the cylinder. Cold brine was supplied inside of the cylinder to cool the outer surface. Below a certain brine temperature, which was $5^{\circ}C$ in this study, the solution was supercooled, and suddenly turned into ice. The super-cooling increases as the brine temperature increased. During slush formation, the heat transfer coefficient oscillated significantly, due to periodic removal of ice chunk form the surface. The average heat transfer coefficient during slush formation was approximately twice of that obtained during single phase cooling. The heat transfer coefficient was also affected by the brine temperature with increasing heat transfer coefficient at lower brine temperature.

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Laminar Flamelet Model을 이용한 비예혼합 난류제트화염의 연소과정 및 NO 생성 해석 (Laminar Flamelet Modeling of Combustion Processes and NO Formation in Nonpremixed Turbulent Jet Flames)

  • 김성구;김후중;김용모
    • 한국연소학회지
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    • 제4권2호
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    • pp.51-62
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    • 1999
  • NOx formation in turbulent flames is strongly coupled with temperature, superequilibrium concentration of O radical, and residence time. This implies that in order to accurately predict NO level, it is necessary to develop sophisticated models able to account for the complex turbulent combustion processes including turbulence/chemistry interaction and radiative heat transfer. The present study numerically investigates the turbulent nonpremixed hydrogen jet flames using the laminar flamelet model. Flamelet library is constructed by solving the modified Peters equations and the turbulent combustion model is extended to nonadiabatic flame by introducing the enthalpy defect. The effects of turbulent fluctuation are taken into account by the presumed joint PDFs for mixture fraction, scalar dissipation rate, and enthalpy defect. The predictive capability of the present model has been validated against the detailed experimental data. Effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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초기재령 콘크리트의 세공구조 형성 및 발영특성에 관한 미시역학적 모델 (Micromechanics based Models for Pore-Sructure Formation and Hydration Heat in Early-Age Concrete)

  • 조호진;박상순;송하원;변근주
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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    • pp.123-128
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    • 1999
  • Recently, as a performance based design concept is introduced, assurance of expected performances on serviceability and safety in the whole span of life is exactly requested. So, quantitative assessments about durability related properties of concrete in early-age long term are come to necessary, Especially in early age, deterioration which affects long-term durability performance can be occurred by hydration heat and shrinkage, so development of reasonable hydration heat model which can simulate early age behavior is necessary. The micor-pore structure formation property also affects shrinkage behavior in early age and carbonations and chloride ion penetration characteristic in long term, So, for the quantitative assessment on durability performance of concrete, modelings of early age concrete based on hydration process and micor-pore structure formation characteristics are important. In this paper, a micromechanics based hydration heat evolution model is adopted and a quantitative model which can simulate micro-pore structure development is also verified with experimental results. The models can be used effectively to simulate the early-age behavior of concrete composed of different mix proportions.

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