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Review on the Recent Membrane Technologies for Pressure Retarded Osmosis (압력지연삼투를 위한 최근 분리막 기술에 관한 총설)

  • Jeon, Sungsu;Patel, Rajkumar;Kim, Jong Hak
    • Membrane Journal
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    • v.31 no.4
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    • pp.253-261
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    • 2021
  • Solutions to water pollution, global warming, and climate change have been currently discussed. Pressure retarded osmosis (PRO) using a difference in salt concentration between two fluids is proposed to meet the demand for clean water and produce eco-friendly energy. Although PRO has been researched continuously, it has not been commercialized yet due to limitations such as lack of technology and the high price of membranes. Meanwhile, the membrane is one of the most significant parts of the PRO engine and salinity gradient power (SGP) technology. Research continues to technologically develop graphene oxide membranes and nanocomposite membranes used in salinity gradient power generation. Studies on efficient membranes, solvents, and solutes are active to enable high energy efficiency of the osmotic heat engine even at low temperatures of waste. Studies have been conducted on reducing internal concentration polarization and increasing power density by using membranes with balanced permeability and selectivity. In this review, dealing with these studies, we discuss the types of PRO membranes, theoretical modeling of technologies through efficient membranes, and other technologies to develop the process efficiency.

Effect on Corrosion Characteristics of SS 400 Steel by Alkali Water pH from Electrolysis of City Water (수돗물의 전기분해에 의해서 생성된 알카리수의 pH가 SS 400강의 부식특성에 미치는 영향)

  • Moon, Kyung-Man;Ryoo, Hae-Jeon;Kim, Yun-Hae;Jeong, Jae-Hyun;Baek, Tae-Sil
    • Journal of Ocean Engineering and Technology
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    • v.31 no.3
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    • pp.248-255
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    • 2017
  • Many rivers and seas have been affected by environmental contamination. Therefore, city water supplies often require a high-degree purification treatment to provide safe drinking water. However, in order to achieve a high-degree purification treatment, a large amount of chlorine has to be added to sterilize city drinking water. The added chlorine reacts chemically with water and forms hypochlorous and chlorine ions. The hypochlorous ionizes with hypochlorous ions and hydrogen ions. As a result, the city water contains a large amount of chlorine ion. As such, when city water is used with domestic boilers, many kinds of heat exchangers, and the engines of vehicle and ships, there are often corrosion problems. In this study, alkali water was electrochemically made by electrolysis of city water, and corrosion properties between alkali and city water were investigated with an electrochemical method. Most of the chlorine ions are thought to not be contained in the alkali water because the alkali water is created in the cathodic chamber with an electrolysis process. In other words, the chlorine ion can be mostly removed by its migration from a cathodic chamber to an anodic chamber. Moreover, the alkali water also contains a large amount of hydroxide ion. The alkali water indicated relatively good corrosion resistance compared to the city water and the city water exhibited a local corrosion pattern due to the chlorine ion created by a high-degree purification treatment. In contrast, the alkali water showed a general corrosion pattern. Consequently, alkali water can be used with cooling water to inhibit local corrosion by chlorine ions in domestic boilers, various heat exchangers and the engine of ships and for structural steel in a marine structure.

Characteristics of hazardous oil & liquid fuel waste discharged from various industries (폐유 및 액상연료 공정 폐기물에서 무기물질류의 함량특성)

  • Shin, Sun-Kyoung;Jeong, Seong-Kyeong;Kim, Woo-Il;Jeon, Tae-Wan;Kang, Young-Yeul;Yeon, Jin-Mo;Cho, Yoon-A;Kim, Min-Sun
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.276-286
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    • 2013
  • This study was performed to investigate the contents characteristics of hazardous oil wastes and wastes of liquid fuels from different industrial process. In order to establish a hazardous waste list, samples of various industrial discharge have been analyzed for 16 non-regulated inorganic hazardous substances (i.e., Cu, Pb, Cd, CN, Hg, As, T-Cr, $Cr^{6+}$, Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples including waste hydraulic oils, waste engine, gear and lubricating oils, waste insulating and heat transmission oils, bilge oils, oil/water separator contents processing were collected from 37 workplaces and analyzed. We observed that the most of the inorganic substances exceeded the proposed criteria in many samples. Especially the concentration of Sb in heat transmission oil, bilge oil and gear & lubricating oils were ranged from 6 to 419 mg/kg whereas the proposed criteria is 50 mg/kg. The assessment result of hazardous waste in Korea according to the EWC showed that the out of 24 processes, 16 belongs to absolute entry and 8 belongs to mirror entry. In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.

Study of spatial temperature distribution during combustion process in a high temperature and pressure constant volume chamber (고온 고압 정적 연소실에서 연소과정에 따른 온도 분포 측정)

  • Kim, Ki-hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.345-350
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    • 2017
  • Downsizing is widely applied to diesel engines in order to improve fuel efficiency and reduce exhaust emissions. Engine sizes are becoming smaller but pressure and temperature inside combustion chambers are increasing. Therefore, research for fuel spray under high pressure and temperature conditions is important. A constant volume chamber which simulates high temperature and pressure likely to be found in diesel engines was developed in this study. Pressure and temperature were increased abruptly because of ignition of the pre-mixture in the constant volume chamber. Then pressure and temperature were gradually decreased due to the heat loss through the chamber wall. Fuel spray occurred when temperature and pressure were reached at the target condition. In this experiment, the temperature condition should be exactly defined to understand the relation between fuel evaporation and ambient temperature. A fast response thermocouple was developed and used to measure the temporal and spatial temperature distribution during the combustion process inside the combustion chamber. In the results, the core temperature was slightly higher than the bulk temperature calculated by the gas equation. Ed-note: do you want to say 'ideal gas equation'? This was attributed to the heat transfer loss through the chamber wall. The vertical temperature deviation was higher than the horizontal temperature deviation by 5% which resulted from the buoyancy effect.

A Study on the Wear Characteristics of Aluminizing Steel ( 1 ) - Wear in Run-in Period on Rolling-Sliding Contact - (알루미나이징 강의 마모특성에 관한 연구 ( 1 ) - Rolling-Sliding 마찰의 초기마모영역을 중심으로 -)

  • 이규용
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.14 no.2
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    • pp.69-78
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    • 1978
  • It is well known that the aluminizing steel is excellent in corrosion resistance and heat resistance. Therefore it has been used as boiler parts, heat exchanger parts and guide rails which are used under comparatively simple conditions. Recently, it has been noticed that aluminizing steel has high resistance to various atmosphere, high temperature oxidation and seawater resistance. So its usage has been extended widely to the production of parts such as intake and exhaust valve of internal combustion engine, turbine blade and pipelines On ships which required such properties. It is considered that aluminium coated steel is excellent in wear resistance because of high hardness on main ingredient FezAIs of Fe-AI alloy layer existed in diffusion coating layer. And it will beused as a new material taking wear resitance with seawater resistance in marine field. However it is difficult to findout any report concering the wear behaviors or properties of alum in izing steel. In this study the experiment was carried out under the condition of rolling-sliding contact using an Amsler-type wear testing machine at 0.80, 0.91, 1. 10, 1. 25% of slip ratio and 55.43, 78.38, 110.85 kg/mm^2 of Hertz's contact stress in run-in period for the purpose of service-ability test of aluminizing steel as a wear resisting material and obtaining the available design data. The followings are the obtained results from the experimen tal study; 1) The 2nd diffusion material has most excellent wear resistance. This material has brought out about 18% decrease of wear weight in a lower friction load level and 40~G decrease in a higher level comparing to the raw material. 2) Satisfactory effect of wear resistivity cannot be much expected in 2nd diffusion specimens. This is considered due to the formation of fine void in the alloy layer near the boundary to the aluminium layer. 3) Fracture on friction surface of aluminizing steel by the rolling-sliding contact is spalling, and spalling crack occurres initially beneath the specimen surface near the boundary in diffusion coating layer.

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FRACTURE TOUGHNESS OF SELF-CURING DENTURE BASE RESINS WITH DIFFERENT POLYMERIZING CONDITIONS (의치상용 자가중합레진의 중합조건에 따른 파괴인성)

  • Jeong Soo-Yang;Kim Ji-Hye;Yang Byung-Deok;Park Ju-Mi;Song Kwang-Yeob
    • The Journal of Korean Academy of Prosthodontics
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    • v.43 no.1
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    • pp.52-60
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    • 2005
  • Purpose. The intent of this study was to evaluate the effects of curing conditions on self-curing denture base resins to find out proper condition in self-curing resin polymerization. Materials and methods, In this study, 3 commercial self-curing denture base resins are used Vertex SC, Tokuso Rebase and Jet Denture Repair Acrylic. After mixing the self curing resin, it was placed in a stainless steel mold(3$\times$6$\times$60mm). The mold containing the resin was placed under the following conditions: in air at 23$^{\circ}C$; or in water at 23$^{\circ}C$; or in water at 23$^{\circ}C$ under pressure(20psi); or in water at 37$^{\circ}C$ under pressure(20psi) or in water at 50$^{\circ}C$ under pressure(20psi) , or in water at 65$^{\circ}C$ under pressure(20psi), respectively. Also heat-curing denture base resin is polymerized according to manufactures' instructions as control. Fracture toughness was measured by a single edge notched beam(SENB) method. Notch about 3mm deep was carved at the center of the long axis of the specimen using a dental diamond disk driven by a dental micro engine. The flexural test was carried out at a crosshead speed 0.5mm/min and fracture surface were observed under measuring microscope. Results and conclusion . The results obtained were summarized as follows : 1. The fracture toughness value of self-curing denture base resins were relatively lower than that of heat-curing denture base resin. 2. In Vertex SC and Jet Denture Repair Acrylic, higher fracture toughness value was observed in the curing environment with pressure but in Tokuso Rebase, low fracture toughness value was observed but there was no statistical difference. 3. Higher fracture toughness value was observed in the curing environment with water than air but there was no statistical difference. 4. Raising the temperature in water showed the increase of fracture toughness.

A Study on the Evaluation of Cabin Thermal Environment and Marine Fuels for Fuel Saving in Summer According to the Improvement of Air Conditioning System - The Case of Training Ship SAENURI - (공조시스템 개선에 따른 하절기 선실 온열환경 평가 및 유류절감에 관한 연구 - 실습선 새누리호를 중심으로 -)

  • Han, Seung-Hun;Kim, Hong-Ryel
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.6
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    • pp.653-662
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    • 2014
  • In this study, Mokpo national maritime university Training ship Centralizes Air Conditioning System was upgraded by installing onboard an Air-cooled Air conditioner. This resulted in the improvement of the performance and operation. This study compared refrigeration performance to former equipment and improving one. And through the actual measurement study about the cabin thermal environment, it will be used as basic data for marine air conditioning design and plan in the future. At same climate condition, when the Centralized Air Conditioning System and an improved air conditioning system operated, cabin temperature was at $24{\sim}28^{\circ}C$, humidity was 55~75 % as comfortable condition, Generator load measurement showed a saving of 48KW in the average load and 8 % in the full load factor. This also resulted in a saving of daily fuel oil consumption(FOC) at around 222 [${\ell}/day$] average. On the other hand, one cadet cabin(Cadet No.21) indicated a higher temperature due to heat transmission of engine room. It found us not to consider installing additional diffuser to reduce the heat transmission.

A Study on the Gaze Flow of Internet Portal Sites Utilizing Eye Tracking (아이트래킹을 활용한 인터넷 포털사이트의 시선 흐름에 관한 연구)

  • Hwang, Mi-Kyung;Kwon, Mahn-Woo;Lee, Sang-Ho;Kim, Chee-Yong
    • Journal of the Korea Convergence Society
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    • v.13 no.2
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    • pp.177-183
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    • 2022
  • This study investigated through eye tracking what gaze path the audience searches through portal sites (Naver, Daum, Zoom, and Nate). As a result of the layout analysis according to the gaze path of the search engine, the four main pages, which can be called to be the gateway to information search, appeared in the form of a Z-shaped layout. The news and search pages of each site use an F-shape, which means that when people's eyes move from top to right in an F-shape, they read while moving their eyes from left to right(LTR), which sequentially moves to the bottom. As a result of analyzing through the heat map, gaze plot, and cluster, which are the visual analysis indicators of eye tracking, the concentration of eyes on the photo and head copy was found the most in the heat map, and it can be said to be of high interest in the information. The flow of gaze flows downward from the top left to the right, and it can be seen that the cluster is most concentrated at the top of the portal site. The website designer should focus on improving the accessibility and readability of the information desired by the user in the layout design, and periodic interface changes are required by investigating and analyzing the tendencies and behavioral patterns of the main users.

Investigation of Autoignition of Propane and n-Butane Blends Using a Rapid Compression Machine

  • Kim, Hyunguk;Yongseob Lim;Kyoungdoug Min;Lee, Daeyup
    • Journal of Mechanical Science and Technology
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    • v.16 no.8
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    • pp.1127-1134
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    • 2002
  • The effects of pressure and temperature on the autoignition of propane and n-butane blends were investigated using a rapid compression machine (RCM) , which is widely used to examine the autoignition characteristics. The RCM was designed to be capable of varying the compression ratio between 5 and 20 and minimize the vortex formation on the cylinder wall using a wedge-shaped crevice. The initial temperature and pressure of the compressed gas were varied in range of 720∼900 K and 1.6∼ 1.8 MPa, respectively, by adjusting the ratio of the specific heat of the mixture by altering the ratio of the non-reactive components (N$_2$, Ar) under a constant effective equivalence ratio (ø$\_$f/= 1.0) The gas temperature after the compression stroke could be obtained from the measured time-pressure record. The results showed a two-stage ignition delay and a Negative Temperature Coefficient (NTC) behavior which were the unique characteristic of the alkane series fuels. As the propane concentration in the blend were increased from 20% and 40% propane, the autoignition delay time increased by approximately 41 % and 55% at 750 K. Numerical reduced kinetic modeling was performed using the Shell model, which introduced some important chemical ideas, represented by the generic species. Several rate coefficients were calibrated based on the experimental results to establish an autoignition model of the propane and n-butane blends. These coefficients can be used to predict the autoignition characteristics in LPG fueled Sl engines.

Change of Mechanical Properties of Injection-Molded Glass-Fiber-Reinforced Plastic (GFRP) According to Temperature and Water Absorption for Vehicle Weight Reduction (차량 경량화를 위한 사출성형 유리섬유강화플라스틱의 온도 및 수분 흡수에 따른 기계적 물성 변화)

  • Chun, Doo-Man;Ahn, Sung-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.2
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    • pp.199-204
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    • 2013
  • Owing to the global energy crisis, studies have strongly focused on realizing energy savings through vehicle weight reduction using light metal alloys or polymer composites. Polymer composites afford many advantages including enabling the fabrication of complex shapes by injection molding, and glass and carbon fibers offer improved mechanical properties. However, the high temperature in an engine room and the high humidity during the rainy season can degrade the mechanical properties of the polymer. In this study, the mechanical properties of injection-molded glass-fiber-reinforced polymer were assessed at a temperature of $85^{\circ}C$ and the maximum moisture absorption conditions. The result showed a 23% reduction in the maximum tensile strength under high temperature, 30% reduction under maximum moisture absorption, and 70% reduction under both heat and moisture conditions. For material selection during the design process, the effects of high temperature and high humidity should be considered.