• Title/Summary/Keyword: heat diffusion

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Hydrophobic Polydimethylsiloxane Thin Films Prepared by Chemical Vapor Deposition: Application in Water Purification (화학적 증기 증착 방법을 통해 제조한 소수성 폴리디메틸실록산 박막: 수처리로의 응용)

  • Han, Sang Wook;Kim, Kwang-Dae;Kim, Ju Hwan;Uhm, Sunghyun;Kim, Young Dok
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.1-7
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    • 2017
  • Polydimethylsiloxane (PDMS) can be deposited on various substrates using chemical vapor deposition process, which results in the formation of PDMS thin films with thickness below 5 nm. PDMS layers can be evenly deposited on surfaces of nanoparticles composed of various chemical compositions such as $SiO_2$, $TiO_2$, ZnO, C, Ni, and NiO, and the PDMS-coated surface becomes completely hydrophobic. These hydrophobic layers are highly resistant towards degradation under acidic and basic environments and UV-exposures. Nanoparticles coated with PDMS can be used in various environmental applications: hydrophobic silica nanoparticles can selectively interact with oil from oil/water mixture, suppressing fast diffusion of spill-oil on water and allowing more facile physical separation of spill-oil from the water. Upon heat-treatments of PDMS-coated $TiO_2$ under vacuum conditions, $TiO_2$ surface becomes completely hydrophilic, accompanying formation oxygen vacancies responsible for visible-light absorption. The post-annealed $PDMS-TiO_2$ shows enhanced photocatalytic activity with respect to the bare $TiO_2$ for decomposition of organic dyes in water under visible light illumination. We show that the simple PDMS-coating process presented here can be useful in a variety of field of environmental science and technology.

Studies on Food Preservation by Controlling Water Activity 1. Measurement of Sorption Isotherm of Dried Filefish Muscle by Equilibration in Dynamic Stream of Conditioned Air (식품보장과 수분활성에 관한 연구 1. 조절기류에 의한 건조말쥐치육의 등온흡습곡선의 측정)

  • HAN Bong-Ho;CHOI Soo-Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.189-193
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    • 1981
  • An apparatus for continuous measurements of sorption isotherm of dried food was manufactured to shorten the time required for equilibration. The apparatus was so designed that the temperature, air velocity and relative humidity in the experimental chamber could be controlled. The use of dynamic stream of conditioned air with a velocity of 0.2m/sec, instead of static atmosphere, allowed a faster equilibration of dried filefish muscle at $25^{\circ}C$. The mean time necessary for the equilibration of dried filefish muscle at the water activity of a given state to a higher water activity was about 45 hours. The monolayer moisture content of dried filefish muscle calculated from BET-equation was 0.092 kg water /kg dry matter at $25^{\circ}C$.

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Antimicrobial Effect of the Submerged Culture of Sparassis crispa in Soybean Curd Whey (순물을 이용한 꽃송이 버섯 균사체 배양액의 항균활성 평가)

  • Lee, Eun Ji;Kim, Ji-Eun;Park, Min-Ju;Park, Dong-Cheol;Lee, Sam-Pin
    • Food Science and Preservation
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    • v.20 no.1
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    • pp.111-120
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    • 2013
  • Sprassis crispa was cultivated using soybean curd whey, and its antimicrobial activities were examined against those of eight microorganisms that were foodborne pathogens or food-poisoning bacteria. The culture broth of soybean curd whey was superior in mycelium content (17.76 g/L) to that of the defined culture broth, and the ${\beta}$-glucan content was about 10.64 percent (w/w). The antimicrobial activities of the culture broth were confirmed against those of B. cereus, St. aureus, L. monocytogenes and S. typhimurium using the paper disk method. The antimicrobial activity was also maintained after the heat treatment and alcalase treatment. The filtrate with less than 3 kDa M.W. also showed the antimicrobial activity against four strains: B. cereus, St. aureus, L. monocytogenes and S. typhimurium. The minimum inhibitory concentration (MIC) was about 1.26 mg/mL in the B. cereus and 12.6 mg/mL in the St. aureus and L. monocytogenes. The S. typhimurium showed a MIC of 62.8 mg/mL. Thus, the culture of Sparassis crispa using soybean curd whey provides a thermally stable antimicrobial agent that can be used as a natural preservative in the biofood industry.

Performance of Hybrid Solar Still Under Operating Conditions (하이브리드 태양열 해수담수기의 운전 조건별 성능실험)

  • Yeo, Se Dong;Lim, Byung Ju;Yu, Sang Seok;Chung, Kyung Yul;Park, Chang Dae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.8
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    • pp.511-519
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    • 2017
  • In this study, we have performed tests to improve the productivity of hybrid solar stills, which can be operated by solar thermal energy and/or waste heat of exhaust gas from electrical generators. The experimental apparatus is a hybrid solar still with a $1m{\times}2m$ collecting area, which consists of a conventional simple solar still and a vertical multi-effect diffusion(MED) section. The experiments were conducted under various operating conditions, with two identical hybrid solar stills, using solar radiation as the energy source. The results of the tests showed that the yield of the hybrid solar still depends on the various operating conditions. Insulation at the side glasses and a lower basin seawater level increased the productivity of the hybrid solar still. Reflecting fins with less than 47% reflectivity unexpectedly decreased the total productivity. However, the various feeding flow rate of the seawater into MED part did not show clear effects on productivity in the tested range.

Design of a Prototype System for Graft-Taking Enhancement of Grafted Seedlings Using Artificial Lighting - Effect of air current speed on the distribution of air temperature and relative humidity in a graft-taking enhancement system (인공광을 이용한 접목표 활착촉진 시스템의 시작품 설계 - 활착촉진 시스템 내의 기온과 상대습도 분포에 미치는 기류속도의 효과)

  • 김용현
    • Journal of Biosystems Engineering
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    • v.25 no.3
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    • pp.213-220
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    • 2000
  • Grafting of fruit-bearing vegetables has been widely used to increase the resistance to soil-borne diseases, to increase the tolerance to low temperature or to soil salinity, to increase the plant vigor, and to extend the duration of economic harvest time. After grafting, it is important to control the environment around grafted seedlings for the robust joining of a scion and rootstock. Usually the shading materials and plastic films are used to keep the high relative humidity and low light intensity in greenhouse or tunnel. It is quite difficult to optimally control the environment for healing and acclimation of grafted seedlings under natural light. So the farmers or growers rely on their experience for the production of grafted seedling with high quality. If artificial light is used as a lighting source for graft-taking of grafted seedlings, the light intensity and photoperiod can be easily controlled. The purpose of this study was to develop a prototype system for the graft-taking enhancement of grafted seedlings using artificial lighting and to investigate the effect of air current speed on the distribution of air temperature and relative humidity in a graft-taking enhancement system. A prototype graft-taking system was consisted by polyurethane panels, air-conditioning unit, system controller and lighting unit. Three band fluorescent lamps (FL20SEX-D/18, Kumho Electric, Inc.) were used as a lighting source. Anemometer (Climomaster 6521, KANOMAX), T-type thermocouples and humidity sensors (CHS-UPS, TDK) were used to measure the air current speed, air temperature and relative humidity in a graft-taking system. In this system, air flow acted as a driving force for the diffusion of heat and water vapor. Air current speed, air temperature and relative humidity controlled by a programmable logic controller (UP750, Yokogawa Electric Co) and an inverter (MOSCON-G3, SAMSUNG) had an even distribution. Distribution of air temperature and relative humidity in a graft-taking enhancement system was fairly affected by air current speed. Air current speed higher than 0.1m/s was required to obtain the even distribution of environmental factors in this system. At low air current speed of 0.1m/s, the evapotranspiration rate of grafted seedlings would be suppressed and thus graft-taking would be enhanced. This system could be used to investigate the effects of air temperature, relative humidity, air current speed and light intensity on the evaportranspiration rate of grafted seedlings.

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Application Potential of Hurdle Technology by Combination of Bacteriocin Produced by Lactobacillus brevis DK25 and Potassium Benzoate (Lactobacillus brevis DK25의 박테리오신과 안식향산칼륨과의 혼용에 의한 Hurdle Technology 적용 가능성)

  • Lim, Sung-Mee
    • Korean Journal of Microbiology
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    • v.47 no.4
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    • pp.364-374
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    • 2011
  • Lactobacillus brevis DK25 isolated from Dongchimi was identified by physiological and biochemical tests and 16S rDNA sequence analysis. Bacteriocin of L. brevis DK25 exhibits inhibitory activity against Enterococcus faecalis and Listeria monocytogenes when using agar well diffusion method. Maximal production of bacteriocin was reached in the beginning of the stationary phase, and inhibitory activity declined after the late stationary phase. This result suggested that bacteriocin was produced in a growth-associated manner. Complete inactivation of bacteriocin activity was observed after treatment with protease, but the activity was stable between pH 4-9 and heat resistant (30 min at $100^{\circ}C$). Bacteriocin showed a concentration-dependent antimicrobial activity against L. monocytogenes KCTC 3569. Moreover, the application experiment showed that combination of bacteriocin (320 AU/ml) with potassium benzoate (0.05%) could significantly reduce the counts of L. monocytogenes KCTC 3569 in mayonnaise during storage at 4 or $25^{\circ}C$ for 10 days. Thus, bacteriocin from L. brevis DK25 may be used for hurdle technology by combination with potassium benzoate in order to increase pathogenic bacteria inactivation in food processing and food safety control.

Mechanical Properties of The CO2 Free Vacuum Carburized in SCM415H (CO2 무 배출 침탄 열처리된 SCM415H 소재의 기계적 성질)

  • Byun, Jae-Hyuk;Ro, Seung-Hoon;Lee, Jong-Hyung;Lee, Chang-Hun;Yang, Seong-Hyeon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.9
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    • pp.971-978
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    • 2012
  • Vacuum carburizing is supposed to be the superior process to the gas carburizing. However, the vacuum carburizing has the stage in which hydrocarbon gas is supplied into the furnace to be pyrolysis, and consequently the stable heat treatment is hard to achieve due to the soot from the hydrocarbon pyrolysis. Recently, many studies have been made which utilize acetylene gas to overcome this defects. In this paper, the carburizing and the diffusion periods have been selected based on the Harris experimental formula, and the mechanical properties of the vacuum carburized specimen have been compared with those of the gas carburized SCM415H specimen to identify the feasibility of the $CO_2$ free vacuum carburizing process. The result showed that the vacuum carburized materials used have no oxidization of the grain boundaries, and show the 29.8% higher effective hardness depth and the acceptable tensile strength.

Hydrogen Electrode Performance with PTFE Bonded Raney Nickel Catalyst for Alkaline Fuel Cell (라니 니켈 촉매에 대한 알칼리형 연료전지용 수소극의 전극특성)

  • Lee, Hong-Ki;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.527-534
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    • 1992
  • Raney nickel was used as catalyst in the hydrogen electrode for an alkaline fuel cell. The hydrogen electrode manufactured with the Raney nickel catalyst which was sintered at $700^{\circ}C$ was found to have the highest electrode performance. Using the Raney nickel powder of average particle size $90{\AA}$ for the electrode, the current density which had been measured was $450mA/cm^2$ at $80^{\circ}C$ using 6N KOH solution as an electrolyte. The effects of PTFE addition were investigated with CO-chemisorption, polarization curves and Tafel slope. CO-chemisorption had shown the optimum value when the Raney nickel was mixed with 5wt% of PTFE, but from the current density and Tafel slope at porous Raney nickel electrode, the appropriate value of PTFE addition was 10wt%. Recommendable Ni and Al portion for Raney nickel was 60 : 40 and loading amount was $0.25g/cm^2$. Also the influence of pressing pressure for manufacturing catalytic layer and for junction with gas diffusion layer was examined. The morphology of catalyst surface was investigated with SEM. The influence of reactivation time and heat-treatment temperature were also studied.

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Effect of Silicone Rubber Content on Thermal Stabilities of EPDM/Silicone Blends (실리콘고무 함량이 EPDM 고무의 열적 안정성에 미치는 영향)

  • Park, Soo-Jin;Kim, Jong-Hak;Joo, Hyeok-Jong;Jin, Fan-Long
    • Elastomers and Composites
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    • v.40 no.4
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    • pp.266-271
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    • 2005
  • In this work, the thermal stability factors, such as the thermal decomposition temperature, decomposition activation energy ($E_d$), and char yield, were measured to investigate the effect of silicone rubber (SR) content on the thermal stabilities of EPDM/SR blends. As a result, the thermal decomposition curve of EPDM/SR blends was similar to the neat EPDM rubber at 10 wt% SR and the thermal decomposition temperature increased above this content. The $E_d$ value of EPDM rubber initially decreased and then was constant above 20 wt% weight losses. The $E_d$ of EPDM/SR blends was higher than that of the neat EPDM rubber and then decreased with increasing the weight loss when the SR content was in the range of 10-20 wt%. Whereas the $E_d$ of the blends was lower than that of the EPDM rubber and then decreased with increasing the weight loss when 30 wt% SR was added. The char yield at $800^{\circ}C$ increased with increasing the SR content, because the decomposition of silane groups in the backbone was capable of forming a silane-rich residue after the initial stage of thermal degradation, which finally prevents further heat transfer and diffusion in the blends.

A study on the smoke control performance of the damper exhaust system at FCEV fire in tunnel for small vehicles (소형차 전용터널 내 수소연료전지차 화재시 집중배기방식의 제연성능에 관한 연구)

  • Hong, Seo-Hee;Baek, Doo-San
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.24 no.6
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    • pp.745-756
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    • 2022
  • The road tunnel is a semi-closed space that is blocked on all sides except the entrance and exit, and in the event of a fire, the smoke of the fire spreads longitudinally due to heat buoyancy caused by the fire and air currents that always exist in the tunnel. To solve this problem, smoke removal facilities are installed in road tunnels to secure a safe evacuation environment by controlling the direction of movement of smoke or directly smoking at fire points. In urban areas, the service level of urban roads decreases due to the increase in traffic due to the increase in population, and as a solution, the construction of underground roads in urban areas is increasing. When a fire occurs during hydrogen leakage through TPRD of a hydrogen fuel cell vehicle (FCEV), the fire intensity depends on the amount of leakage, and the maximum fire intensity depends on the orifice diameter of the TPRD. Considering the TPRD orifice diameter of 1.8 mm, this study analyzed the diffusion distance of fire smoke according to the wind speed of the roadway and the opening interval of the large exhaust port when the maximum fire intensity was 15 MW. As a result, it was analyzed that air flow in the tunnel could be controlled if the wind speed of the road in the tunnel was less than 1.25 m/s, and smoke could be controlled within 200 m from the fire if the damper interval was 50 m and 100 m.