• Title/Summary/Keyword: hazardous materials facilities

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On-site Investigation of Hazardous Substances in Floor Dust of Several Primary Schools (일부 초등학교 바닥 먼지내 포함하고 있는 유해물질 성분에 대한 현장 평가)

  • Kim, Ki Youn;Kim, Hyeon Tae;Lee, Kwon Seob
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.478-483
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    • 2014
  • Objectives: The main objective of this study is to assess the levels of hazardous substances in floor dust in primary schools located in the city of Busan in Korea. Materials and Methods: An on-site investigation of three primary schools was performed between April and May 2013. The hazardous substances measured in this study were 14 heavy metals (Cu, Fe, Pb, Mn, Ni, Zn, Cr, Cd, As, Al, Sn, Co, Mo and Si) and the biological agents were bacteria, fungi and endotoxin). Results: Among the heavy metals, Cd, Co, Pb and Cr were not detected in the floor dust from the three primary schools. The mean levels of other heavy metals were as follows: $20({\pm}10)ng/cm^2$ for As, $30({\pm}20)ng/cm^2$ for Al, $5({\pm}4)ng/cm^2$ for Sn, $20({\pm}20)ng/cm^2$ for Mo, $1,340({\pm}620)ng/cm^2$ for Si, $110({\pm}100)ng/cm^2$ for Cu, $240({\pm}50)ng/cm^2$ for Fe, $30({\pm}30)ng/cm^2$ for Mn, $10({\pm}10)ng/cm^2$ for Ni, and $50({\pm}30)ng/cm^2$ for Zn. It was found that mean concentrations of bacteria, fungi and endotoxin in the floor dust of primary schools were $4.7{\time}10^7({\pm}2.2{\time}10^7)cfu/cm^2$, $6.3{\time}10^6({\pm}6.4{\time}10^6)cfu/cm^2$, and $8,140({\pm}5,801)EU/cm^2$, respectively. The predominant species identified in the floor dust of the primary schools were Pseudomonas spp. for bacteria and Penicillium spp.,Cladosporidium spp.,and Aspergillus spp. for fungi, which would be somewhat similar to the microbial distribution pattern of other general environments. Conclusions: Based on the results obtained from this study, the levels of heavy metals, microbes and endotoxin distributed in the floor dust of primary school were higher than those reported for other general facilities. Thus, preventive measures should be prepared for the health care of children.

A Case Study of Risk Assessments and Safety Measures in a PCB Manufacturing Process (인쇄회로기판 제조 공정에서 위험성평가와 안전조치 적용 사례 연구)

  • Lee, Young Man;Lee, Inseok
    • Journal of the Korean Society of Safety
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    • v.37 no.4
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    • pp.120-128
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    • 2022
  • Printed circuit boards (PCBs) are a basic component in the electronics industry and are widely used in nearly all electronic products, such as mobile phones, tablet computers, and digital cameras, as well as in electric equipment. PCB manufacturing involves the use of many chemicals and chemical processes and therefore has more risks than other manufacturing sectors. This study aims to identify the causes of possible accidents during PCB manufacturing through risk assessment, develop and implement safety measures, and evaluate the effectiveness of these measures. Note that the safety measures developed to mitigate the risks of a certain process were also implemented for other similar processes. The risk assessments conducted over seven years, from 2015 to 2021, at a PCB manufacturing company identified 361 hazardous processes. Between 2016 and 2019, 41-56 hazardous processes were identified per year; such processes decreased to fewer than 20 per year after 2020. Application of the risk assessment results to the improvement of the hazardous processes with the similar characteristics seems to be effective in decreasing the risks. Equipment-related factors such as lack of appropriate maintenance, low work standards, and defective protection devices were responsible for 59.8% of all possible accidents. Because PCB manufacturing involves many chemicals, skin contact with hazardous substances, electric shock, fire, and explosion were the most common types of possible accidents (81.7%). In total, 505 safety measures were implemented, including 157 related to purchase and improvement of equipment and devices for safety (31.1%), 147 related to the installation/modification of fire prevention facilities (29.1%), and 69 related to the use of standard electrical appliances (13.7%). Risk assessment conducted after implementing the safety measures showed that these measures significantly decreased risk; 247 processes (68.4%) had a risk level of 3, corresponding to "very low," and 114 processes (31.6%) showed a risk level of 4, corresponding to "low." In particular, risk assessment of 104 processes with risk scores of 12 and 10 other processes with risk score of 16 showed that the risk decreased to 4 after implementing the safety measures. Thus, implementing these measures in similar manufacturing sectors that involve chemical processes can mitigate risk.

Health Risk Assessment for Artificial Turf Playgrounds in School Athletic Facilities: Multi-route Exposure Estimation for Use Patterns

  • Kim, Ho-Hyun;Lim, Young-Wook;Kim, Sun-Duk;Yeo, In-Young;Shin, Dong-Chun;Yang, Ji-Yeon
    • Asian Journal of Atmospheric Environment
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    • v.6 no.3
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    • pp.206-221
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    • 2012
  • Hazardous chemicals can be released from artificial turf used in some school playgrounds. To distinguish between Health risk assessment (HRA) exposure scenarios for this study, the ratio of elementary, middle and high schools was considered before final selection. Considering exposure pathways (inhalational, oral and dermal), media and materials were examined, targeting hazardous chemicals released from artificial turf playground-related products. Upon evaluation, the quantity of infill chips was shown to exceed the domestic product content standard (90 mg/kg) at eight (16%) out of 50 schools. PAHs were shown to exceed standards (10 mg/kg) at two (4%) out of the 50 schools. The excess cancer risk (ECR) of carcinogens was shown to be $1{\times}10^{-6}$ in most users for the worst exposure scenario. In children with pica, who represented the most extreme exposure group, the ECR was expected to be as high as $1{\times}10^{-4}$, showing the low risk level of carcinogens. The hazard index (HI) for individual chemicals was shown to be low, at around 0.1 or less, except for children with pica, according to the mean exposure scenario of artificial turf playground exposure. However, the HI was shown to exceed 1.0 in children with pica. Therefore, no direct health risk was found in using artificial turf playgrounds and urethane flooring tracks for the mean exposure scenario, except in children with pica.

Study on Establishment of management standards of Chemistry laboratory handling harzadous substances and improvement of system (유해·위험물질 취급 화학실험실 관리 기준 정립 및 체계 개선에 관한 연구)

  • Cho, Nam-Joon;Lee, Man-Soo
    • Journal of the Korea Safety Management & Science
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    • v.18 no.4
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    • pp.57-72
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    • 2016
  • There are more than 30,000 chemical substances handled in domestic university laboratories. Among them, hazardous materials are selected and managed as designated substances by the standards of 19 Ministries and 16 Acts. However, domestic safety-related laws and regulations are used to manage industrial risk factors based on industrial activities. In case of installing a university chemical laboratory in accordance with the installation standards applicable to general workplaces. It is not suitable to use as a laboratory installation standard that can be applied to a chemical laboratory installed at a university such as a problem occurs in applying to a university using a small quantity of dangerous substances in a small amount. In order to establish the laboratory structure and facility standards that are appropriate for the laboratory characteristics and apply systematic laboratory safety, the National Security Administration shall apply the special handling standard of chemical experiment to places where handling less than 30 times the designated quantity of chemical substances for chemical experiments. On August 2, 2016, the regulations for the enforcement of the Dangerous Goods Safety Management Act and the standards for the structure and facilities of the university chemical laboratory were enacted. In this study, we investigated the domestic chemical substances laws and regulations to determine the chemical substances that are over-regulated in the relevant laws, and define them as substances against accidents. The management criteria for the substances were analyzed. The R value for the designation of the designated quantity by the concept of the space in the management standard was calculated.

A Study on Optimal Ventilation Design for Gas Boxes Installed in Semiconductor Manufacturing Equipment Handling Flammable Liquids (인화성 가스를 취급하는 반도체 제조장비에 설치된 가스박스 최적 환기 설계에 대한 연구)

  • Gyu Sun Cho;Sang Ryung Kim;Won Baek Yang
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.63-69
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    • 2023
  • Although Korea is the world's No. 1 semiconductor producing country, most studies are conducted with risk assessment for simple material risks due to the closedness of the site for industrial protection. In terms of industrial safety, a monitoring system such as a gas detector to determine the leakage of hazardous substances has been established, but research on effectively discharging harmful gastritis substances in case of leakage has only recently begun. Semiconductor manufacturing facilities (gas boxes) where a large amount of flammable materials are handled are currently being safety managed by using a gas detector and blocking the air inlet. It is difficult to dilute in a short time in case of leakage of flammable substances. Therefore, in this study, based on various criteria, the size of the duct according to the size of the gas box is determined and the appropriate size of the air inlet is studied to minimize the exhaust performance requirement without exposing hazardous chemicals to the outside in the event of a flammable leak. We want to do an optimal exhaust design.

Suggestion of Physicochemical Characteristics and Safety Management in the Waste Containing Nanomaterials from Engineered Nano-materials Manufacturing Plants and Waste Treatment Facilities (산업용제조시설과 폐기물처리시설에서 발생된 나노폐기물의 물리화학적 특성 및 안전관리방안 제시)

  • Kim, Woo-Il;Yeon, Jin-Mo;Cho, Na-Hyeon;Kim, Yong-Jun;Um, Nam-Il;Kim, Ki-Heon;Lee, Young-Kee
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.670-682
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    • 2018
  • Engineered nanomaterials (ENMs) can be released to humans and the environment through the generation of waste containing engineered nanomaterials (WCNMs) and the use and disposal of nano-products. Nanoparticles can also be introduced intentionally or unintentionally into waste streams. This study examined WCNMs in domestic industries, and target nanomaterials, such as silicon dioxide, titanium oxide, zinc oxide, nano silver, and carbon nanotubes (CNTs), were selected. We tested 48 samples, such as dust, sludge, ash, and by-products from manufacturing facilities and waste treatment facilities. We analyzed leaching and content concentrations for heavy metals and hazardous constituents of the waste. Chemical compositions were also measured by XRD and XRF, and the unique properties of nano-waste were identified by using a particle size distribution analyzer and TEM. The dust and sludge generated from manufacturing facilities and the use of nanomaterials showed higher concentrations of metals such as lead, arsenic, chromium, barium, and zinc. Oiled cloths from facilities using nano silver revealed high concentrations of copper, and the leaching concentrations of copper and lead in fly ash were higher than those in bottom ash. In XRF measurements at the facilities, we detected compounds such as silicon dioxide, sulfur trioxide, calcium oxide, titanium dioxide, and zinc oxide. We found several chemicals such as calcium oxide and silicon dioxide in the bottom ash of waste incinerators.

Study on the Establishment of a Safety Allowance Level of Disastrous and Hazardous Facilities in Large Cities (대도시 위해.위험시설에 대한 안전도 수용기준 정립에 관한 연구)

  • 고재선;윤명오
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.84-92
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    • 2001
  • In today's world, rise in the establishment of social infrastructure resulting from population saturation in large cities has led to more extensive and frequent use of chemical materials on facilities. A result, unexpected and serious accidents, hazards, contingencies and disasters are more prevalent than ever. Such phenomenon calls for more devoted and concerted efforts towards finding ways to reduce the safety hazards that are seen to take place more often than before with the increase in the number of facilities that are prone to bring disaster and hazard coupled with the conventional safety problems that continue to exist even today. In developed countries, such challenge is addressed by various appropriate countermeasures drawn up by local professional committees on industrial facilities, whose members conduct offsite and onsite evaluation un the potential industrial disasters and its seriousness and provide their advice thereof. Against this backdrop, this study aims at identifying a comprehensive safety allowance level (safety acceptable level) when imposing limitation on the development of conventional or new facilities, for the fur pose of establishing a safety allowance level of disastrous and dangerous facilities in Korea. This is done by assessing and applying the level of danger each individual is exposed to in a randomly selected region (disastrous and dangerous areas in Seoul) based on probability of quantitative hazards, as well as simulation and calculation methods which include: i) social disaster evaluation method applying Quantified Risk Assessment of Health & Safety Executive of UK and Matrix of Risk of Evaluated Sources of Hazard; ii) Fault Tree or Event Tree Analysis and etc.

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Development of Risk Representation System for Chemical Plane (화학공장의 위험도 표현 시스템 개발)

  • Ko Jae Wook;Lee Jung Woo;Lim Dong Ho
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.28-33
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    • 2005
  • Because chemical industrial facilities deal with large amount of hazardous materials, the damage affect to off-site as well as on-site when an accident occurs. So it is necessary to develop a Risk Representation System for effective control and response to major accidents. In this study a Risk Representation System(S/W) was developed to help analyzing actual risk and to set an alternative that can reduce the analyzed risk by drawing the level of individual plant's risk on a digital map network.

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Offsite Risk Assessment on Toxic Release (독성물질 저장설비의 사고시 사업장외에 미치는 영향평가)

  • Park, Kyoshik
    • Journal of the Korean Institute of Gas
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    • v.21 no.3
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    • pp.9-16
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    • 2017
  • Toxic release is one of the most interested area in evaluating consequence to the vicinity of industry facilities handling hazardous materials. Chloric acid production facility is selected and toxic release is evaluated to assess the risk impacted to its off-site. Accident scenarios were listed using process safety information. The scenarios having effect to the off-site were selected and assessed further according to guideline provided by Korea government. Worst case and alternative scenarios including other interested scenarios were evaluated using ALOHA. Each evaluated scenario was assessed further considering countermeasures. The results showed that the facility handling chloric acid is safe enough and needed no further protections at the moment.

A Study on the Explosion Hazardous Area in the Secondary Leakage of Vapor Phase Materials Based on the Test Results and the Leak Rate According to SEMI S6 in the Semiconductor Industry (반도체 산업의 SEMI S6에 따른 실험결과 및 누출률을 기준으로 한 증기 상 물질의 2차 누출 시 폭발위험장소에 관한 연구)

  • Kim, Sang Ryung;Lim, Keun Young;Yang, Won Baek;Rhim, Jong Guk
    • Journal of the Korean Institute of Gas
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    • v.24 no.2
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    • pp.15-21
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    • 2020
  • Currently, in KS C IEC 60079-10-1, the leakage hole radius of secondary leakage is expressed as a recommendation. Underestimation of leak hole size can lead to underestimation of the calculated values for leak rates, and conservative calculations of leak hole sizes, which are considered for safety reasons, can be overestimated, resulting in an overestimated risk range. This too should be avoided. Therefore, a careful and balanced approach is necessary when estimating the size of leaking holes.Based on this logic, this study examines the stability by grasping the concentration inside the gas box when leaking dangerous substances as a result of experiments based on SEMI S6, an international safety standard applied in the semiconductor industry and The scope of explosion hazardous area was determined by applying the formula of KS C IEC 60079-10-1 according to SEMI F15 leak rate criteria and SEMI S6 leak rate criteria. Based on this, we will examine whether the exhaust performance needs to be improved as an alternative to FAB facilities that are difficult to apply to explosion hazards such as semiconductor industry.