• Title/Summary/Keyword: hazardous heavy metals

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The Characteristics of Sludge Landfill Site in Nanjido (난지도 하수슬러지 매립지의 슬러지 성상분석)

  • Namkoong, Wan;Hwang, Seon Suk;Kim, Chul Soo;Yeun, Bum Han;Ryu, Bum Su
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.2
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    • pp.47-53
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    • 1996
  • This study was carried out to estimate the amount and the characteristics of sewage sludge disposed of in the Nanjido sludge landfill site. Boring test was conducted to estimated the landfill volume and to get sludge samples to be analyzed. Total analysis and leaching test were performed to find the characteristics of sewage sludge. The Nanjido sludge landfill site had the surface area of $50,000m^2$ and the average depth of 15m. The estimated sludge volume was 600,000ton. Sewage sludge in Nanjido sludge landfill site was very stable. Results of total analysis of heavy metals indicated that the sludge could be classified as a non-hazardous waste according to the California state regulation. The sludge also could be used as compost based on compost quality criteria of foreign countries. Results of Korea Extraction Procedure showed that sewage sludge in Nanjido sludge landfill site was not a hazardous waste.

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Analysis of Non-compliance of Food Utensils, Containers, and Packages in Foreign Countries During 2011-2019 (2011-2019년 식품용 기구 및 용기·포장의 제외국 부적합 정보 분석)

  • Cho, Seung Yong;Lee, Ye Yeon;Cho, Sanggoo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.27 no.3
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    • pp.141-147
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    • 2021
  • The foreign trends of noncompliance occurring frequently in food contact materials during the period of 2011-2019 was investigated by analyzing the food safety risk information DB in the National Food Safety Information Service (NFSI). A total of 2,042 cases of noncompliance of food utensils, containers, and packages were classified into 5 violation categories; administrative procedures, manufacturing and processing standards, residues and migration standards, labeling and advertising, and quality standards. This was again subcategorized according to non-compliance causative factors. The non-compliances in residues and migration standards comprised the largest proportion (76.4%) of the violative categories. The number of noncompliance information collected in 2011 was 88 cases and increased to 373 cases in 2019. A 72.8% of the non-compliance case was identified to be products of 4 countries (China 64.2%, Germany 4.0%, Japan 3.2%, and Taiwan 3.1%), those produce large quantities of containers and packaging products. During the period of 2011-2019, the number of illegal use of hazardous materials and illegal recycling of waste synthetic resins has decreased to less than one a year since 2014. On the other hand, after 2016, inconsistency of heat-resisting temperature labeling (Taiwan), non-compliance in paper container's strength standards, violation of printing standards, and the risk of consumer injury while using the products were newly reported due to the strengthening of consumer safety protection regulations. Migration of hazardous substances in synthetic polymer products such as heavy metals, melamine and formaldehyde in melamine tableware, primary aromatic amines which are colorant components in kitchenware such as ladles and spatulas, and phthalate plasticizers have been continuously reported with high frequency.

Monitoring of hazardous heavy metals in circulated collagen products in Korea (유통 콜라겐 제품 중 유해중금속 함량 모니터링)

  • Ji-Eun, Kim;Beom-Ho, Kim;Kyung-A, Kim;Dae-Hwan, Kim;Young-Ju, Choi;Hyo-Jung, Kang;Ji-Hyeon, Min;Myung-Jin, Lee
    • Journal of Food Hygiene and Safety
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    • v.37 no.6
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    • pp.394-399
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    • 2022
  • This study was conducted to estimate hazardous heavy metal content, including lead (Pb), cadmium (Cd), arsenic (As) and mercury (Hg) in 120 collagen products currently marketed in Korea. Hg concentration was analyzed by a gold amalgamation method using a mercury analyzer, while concentrations of Pb, Cd, and As were analyzed by ICP-OES. The average Pb concentration was 0.097 mg/kg. For comparison, respective average concentrations were 0.108 mg/kg, 0.084 mg/kg, 0.131 mg/kg, and 0.149 mg/kg in functional health foods, other processed products, beverages, and fruit/vegetable processed products. The average concentration of Cd was 0.026 mg/kg. All products in which Cd was detected were functional health foods. The average concentration of As was 0.097 mg/kg, with respective average concentrations of 0.091 mg/kg, 0.133 mg/kg, and 0.086 mg/kg in functional health foods, other processed products, and fruit/vegetable processed products. The average Hg concentration was 0.0025 mg/kg, with respective average concentrations of 0.0012 mg/kg, 0.0028 mg/kg, 0.0013 mg/kg, and 0.0031 mg/kg in functional health foods, other processed products, fruit/vegetable processed products, and candies respectively. Heavy metal levels in beverages and candy products with set heavy metal standards were below the set standards. Even products without regulatory standards were found to be relatively safe compared with heavy metal standards set for domestic and foreign foods.

A Study on the Characteristic Trace of Water Quality Pollutants in the Industrial Wastewater (업종별 산업폐수의 수질오염물질 배출 특성)

  • Park, Sun Ku;Kim, Sung Soo;Ko, Oh Suk
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.141-150
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    • 1999
  • Twenty organic chemical substances, tetrachloroethylene, toluene, ethylbenzene, p-xylene, m-xylene, isopropyl benzene, stylene, bromobenzene, 1,3,5-trimethylbenzene, 2-chlorotoluene 1,2,4-trimethylbenzene, p-isopropyltoluene, 4-chlorotoluene, n-butylbenzene, 1,2,4-trichlorobenzene, naphthalene, tert-butylbenzene, sec-butylbenzene, phenol, isopropyl benzene hydroperoxide were isolated from untreated and treated wastewater collected at 76 companys of 9 types industry in the basin of Young San River. Their organic compounds were elucidated by Gas Chromatography/Mass Spectrometry (GC/MS) and by comparison with each standard reagents. Especially, phenol compound is detected from effluent water but not detected from plant wastewater in the chemical industry. Heavy metal, which are Cr, Mn, Cu, Zn, Cd, Pb, As, Al and Fe, are contained in the plant wastewater of all industry, Fe, Al of them is more detected than the other metals in plant wastewater. Cr, Cd, Pb, As is contained much in plant wastewater of electricity and electron, metal molding industry. Nine metals is nearely treated when plant wastewater is treated, and then the concentration of each other metals is detected below water quality standard or not detected by using AA.

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Adsorption of Chromium by Heat-treated Microporous Carbon (열처리 다공성탄소를 통한 크롬(Cr+6)흡착)

  • You, Sang-Hee;Kim, Hak-Soo;Kim, Hak-Hee
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.631-636
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    • 1997
  • This study was conducted to increase the adorption capacity of microporous carbon which is widely used as an adsorbent. After increasing the adsorption capacity of microporous carbon by heat-treatment, chromium($Cr^{+6}$) solution, which is the one of hazardous heavy metals, was selectively adsorbed on microporous carbon. Optimum temperature range for the heat-treatment of microporous carbon was $340{\sim}350^{\circ}C$, and the average specific surface area was measured as $1380m^2/g$ by BET (Brunauer-Emmett-Teller) method. The weight loss was about 10 percents during the heating to optimum temperature. However, It became a qualitative adsorbent due to a larger specific surface area. Removal of chromium($Cr^{+6}$) in solution by heat-treated microporous carbon was successfully carried out.

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Decontamination Performance Assessment for the Plasma Arc Vitrification pilot plant on the basis of Trial Burn Results(I) - Decontamination Characteristics for Hazardous Metal, Radioactive surrogate and Radioactive Tracer in Off-gas (시험연소결과에 근거한 플라즈바 아크방식 유리화 시험 설비의 제염성능 평가(I) - 배기가스중의 유해중금속, 방사성핵종 모의물질 및 방사성핵종 제염특성 -)

  • Chae, Gyung-Sun;Park, Youn-Hwan;Min, Byong-Yun;Chang, Jae-Ock;Park, Jun-Yong;Jeong, Weon-Ik;Moon, Byung-Sik
    • Journal of Radiation Protection and Research
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    • v.25 no.2
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    • pp.99-107
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    • 2000
  • Through the results of off-gas analysis at 3 sampling points in Plasma Arc Melting vitrification pilot plant, it was evaluated the partitioning of spiked materials in off-gas and the decontamination characteristic of off-gas treatment system. Spiked materials are hazard_us heavy metals(Pb, Cd, Hg), radioactive surrogate(Co, Cs) and radioactive materials($^{60}Co,\;^{137}Cs$). Through the Trial burn tests, Decontamination factor of spiked materials in off-gas treatment system is calculated.

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Micellar Enhanced Ultrafiltration Using PEO-PPO-PEO Block Copolymer (PEO-PPO-PEO 블록공중합체를 사용한 마이셀 증진 한외여과법 (유해유기물의 가용화 및 분리특성))

  • 최영국;이동진;김정훈;김동권;이수복
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.83-86
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    • 1998
  • 1. Introduction : Low molecular harmful organics such as 1-naphthol and phenol are widely used in industries, and pose serious environmental problems. Wastewater containing low molecular harmful organics may be ejected from various sources including metal-plating industries, circuit-board manufacturing process, photographic and photo-processing industries, refineries and metal-tailing leachate. The pollution of nation harbors, waterways and ground water resources with these organics has reached critical portions, and might also give hazardous influence on human health. Micellar enhanced ultrafiltration(MEUF) is a recently developed process to remove dissolved organics and/or heavy metals present in small or trace quantities from aqueous solution. In this system, the fatal defect is leakage of surfactants especially at low concentration below CMC(critical micelle concentration), which becomes a secondary pollution. Our group proposed to use biosurfactant and polymeric micelle to solve problems mentioned above. In this study we investigated a modified MEUF using PEO-PPO-PEO (polyethyleneoxide-polypropyleneoxide-polyethyleneoxide) block copolymers for the removal of organic solutes such as 1-naphthol and phenol from aqueous wastewater. We proposed PEO-PPO-PEO block copolymers as new surfactants for forming micelles in MEUF, and investigated the solubilization characteristics and efficiency for the removal of 1-naphthol and phenol. PEO-PPO-PEO block copolymers are, environmentally mild and safe as biosurfactants.

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Variation of hazardous substances in sewage ecotoxicological assessment (하수 원수내 유해물질 변화에 따른 생태독성평가)

  • Seo, Byong-Won;Lee, Ju-Hwa;Lee, Yong-Hoon;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.5
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    • pp.603-610
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    • 2013
  • According to industrialization, increased toxic chemicals discharge has been causing water pollution. Especially domestic sewage is a major source of water pollution. Sixty percent of the total wastewater discharged is domestic sewage. Self-purification capacity of rivers and streams is drastically reduced by the emission of domestic sewage, industrial wastewater and livestock wastewater. Although domestic sewage is managed by implementing standards and regulations, toxicity effect of domestic sewage to humans and the environment is not yet clearly understood. In this study, by using daphnia magna, the ecotoxicity of domestic swage was assessed. Cl, Cu, Pb, COD, T-N, DO, pH and residual chlorine were investigated as background concentrations. The experiments were conducted with water samples obtained from three local sewage treatment plants. The experiment results indicated that higher level of toxicity corresponds to the higher pollution concentrations. The higher level of combinations of background concentrations such as heavy metals leads to the worse ecotoxicity. Especially, the Cu concentration affects the TU value.

Bacterial quality evaluation on the shellfish-producing area along the south coast of Korea and suitability for the consumption of shellfish products therein

  • Mok, Jong Soo;Shim, Kil Bo;Kwon, Ji Young;Kim, Poong Ho
    • Fisheries and Aquatic Sciences
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    • v.21 no.12
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    • pp.36.1-36.11
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    • 2018
  • Background: To confirm whether shellfish are suitable for consumption, the quality of seawater and shellfish in shellfish-producing areas must be assessed regularly. This study was conducted to evaluate the bacterial quality on the Changseon area, containing a designated shellfish-producing area, in Korea during 2011-2013. Result: Even though many inland pollutants near the area were identified, they showed no significant impact on the designated area and the shellfish therein. The concentrations of fecal bacteria in all the seawater and mussel samples from the designated area during the harvesting season were within the standards of various countries. Pathogenic bacteria were not detected in any of the mussel samples. In our previous study, the hazardous metal levels in all the mussels from the same area were also within the limits of different countries. Conclusion: The mussel products in this area are suitable for consumption based on fecal pollution, pathogenic bacteria, and also heavy metals.

Comparative Analysis of Nutrients and Hazardous Substances in Locusta Migratoria from Host Plants (기주식물별 풀무치의 영양성분 및 유해물질 비교분석)

  • Kim, Sun Young;Kwak, Kyu-Won;Kim, Eunsun;Park, Kwanho;Kim, Nang Hee;Song, Myung-Ha;Kim, Yong-Soon;Yoon, Hyung Joo
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.253-262
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    • 2020
  • BACKGROUND: It has been reported that the nutritional composition of Locusta migratoria (Orthoptera: Acrididae) changes nutrients depending on the host plants. In this study, to confirm whether Locusta migratoria is an edible insect, the nutrients and harmful substances such as heavy metals and pathogens were analyzed and compared according to corn (LC) or wheat (LW) as host plants. METHODS AND RESULTS: All experimental methods mainly referred to AOAC (2004). The content of crude protein per dry weight was 77.3% in (LW), 1.1 times higher than 69.8% in LC. Crude fat was 6.5% in LW, 2.2 times less than LC 14.3%. Alpha-linolenic acid, which has the highest content among unsaturated fatty acids, was 1.2 times higher in LC (39.9%) than LW (32.5%). As a result of analysis of harmful substances by LC and LW, lead and cadmium among heavy metals were at levels suitable for heavy metal standards of edible insects, and arsenic was not detected in both groups. E. coli and Salmonella spp. were not detected in both groups. CONCLUSION: When comparing the overall nutrients composition of LW and LC, it was confirmed nutrients are different depending on the host plants, and the safety was proved.