• Title/Summary/Keyword: hazardous

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Comparison of Underwater Drop Characteristics for Hazard Apparatuses on Subsea Cable Using Fluid-Structure Interaction Analysis (유체-구조 연성해석 기반 해저케이블 위해인자의 수중낙하 특성 비교)

  • Jang, Gyung-Ho;Kim, Jeong-Hun;Song, Chang Yong
    • Journal of Ocean Engineering and Technology
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    • v.32 no.5
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    • pp.324-332
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    • 2018
  • It is known that damages to the subsea cables used for electric power transmission between islands and countries, including renewable energy from offshore wind power, current, tides, etc., cost much to restore, which causes social and economic losses. Various types of fishing rigs and anchors have been reported to be the greatest hazards to subsea cables. It is possible to design and construct a suitable protection facility for a subsea cable by precisely estimating the underwater behavior of such hazardous apparatuses. In this study, numerical simulations of the underwater behaviors of various hazardous apparatuses were carried out using fluid-structure interaction (FSI) analysis as a basic study to simulate the actual behavior phenomena of hazardous apparatuses in relation to a subsea cable. In addition, the underwater drop characteristics according to the types of hazardous apparatuses were compared. In order to verify the accuracy of the FSI analysis method used in this study, we compared the test results for underwater drops of a steel ball bearing. Stock anchors, stockless anchors, and rocket piles, which were actually reported to be the cases of damage to subsea cables along the southwest coast of Korea, were considered as the hazardous apparatuses for the numerical simulations. Each hazardous apparatus was generated by a Lagrangian model and coupled with the fluid domain idealized by the Eulerian equation to construct the three-dimensional FSI analysis model. The accuracy of the numerical simulation results was verified by comparing them with the analytical solutions, and the underwater drop characteristics according to the types of hazard apparatuses were compared.

Chemical Accidents Response Information System(CARIS) for the Response of Atmospheric Dispersion Accidents in association with Hazardous Chemicals (유해화학물질 관련 대기오염사고 대응을 위한 화학물질사고대응정보시스템 (CARIS))

  • Kim, Cheol-Hee;Park, C.J.;Park, J.H.;Im, C.S.;Kim, M.S.;Park, C.H.;Chun, K.S.;Na, J.G.
    • Journal of Environmental Impact Assessment
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    • v.12 no.1
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    • pp.23-34
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    • 2003
  • The emergency response modeling system CARIS has been developed at CCSM (Center for Chemical Safety Management), NIER (National Institute of Environmental Research) to track and predict dispersion of hazardous chemicals for the environmental decision support in case of accidents at chemical or petroleum companies in Korea. The main objective of CARIS is to support making decision by rapidly providing the key information on the efficient emergency response of hazardous chemical accidents for effective approaches to risk management. In particular, the integrated modeling system in CARIS consisting of a real-time numerical weather forecasting model and air pollution dispersion model is supplemented for the diffusion forecasts of hazardous chemicals, covering a wide range of scales and applications for atmospheric information. In this paper, we introduced the overview of components of CARIS and described the operational modeling system and its configurations of coupling/integration in CARIS. Some examples of the operational modeling system is presented and discussed for the real-time risk assessments of hazardous chemicals.

A Comparison on Detected Concentrations of LPG Leakage Distribution through Actual Gas Release, CFD (FLACS) and Calculation of Hazardous Areas (가스 누출 실험, CFD 및 거리산출 비교를 통한 LP가스 누출 검지농도 분포에 대한 고찰)

  • Kim, Jeong Hwan;Lee, Min-Kyeong
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.102-109
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    • 2021
  • Recently, an interest in risk calculation methods has been increasing in Korea due to the establishment of classification code for explosive hazardous area on gas facility (KGS CODE GC101), which is based on the international standard of classification of areas - explosive gas atmospheres (IEC 60079-10-1). However, experiments to check for leaks of combustible or toxic gases are very difficult. These experiments can lead to fire, explosion, and toxic poisoning. Therefore, even if someone tries to provide a laboratory for this experiment, it is difficult to install a gas leakage equipment. In this study we find out differences among actual experiments, CFD by using FLACS and calculation based on classification code for explosive hazardous area on gas facility (KGS CODE GC101) by comparing to each other. We develpoed KGS HAC (hazardous area classification) program which based on KGS GC101 for convenience and popularization. As a result, actual gas leak, CFD and KGS HAC are showing slightly different results. The results of dispersion of 1.8 to 2.7 m were shown in the actual experiment, and the CFD and KGS HAC showed a linear increase of about 0.4 to 1 m depending on the increase in a flow rate. In the actual experiment, the application of 3/8" tubes and orifice to take into account the momentum drop resulted in an increase in the hazardous distance of about 1.95 m. Comparing three methods was able to identify similarities between real and CFD, and also similarities and limitations of CFD and KGS HAC. We hope these results will provide a good basis for future experiments and risk calculations.

Simultaneous Determination of 80 Unapproved Compounds using HPLC and LC-MS/MS in Dietary Supplements

  • Kwon, Jeongeun;Shin, Dasom;Kang, Hui-Seung;Suh, Junghyuck;Lee, Gunyoung;Lee, Eunju
    • Mass Spectrometry Letters
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    • v.13 no.3
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    • pp.58-83
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    • 2022
  • We developed analytical methods using high performance chromatography (HPLC) and liquid chromatography tandem mass spectrometry (LC-MS/MS) for the simultaneous determination of 80 unapproved compounds in dietary supplements. The target compounds for analysis were unapproved ingredients (e.g., pharmaceuticals) that have potential adverse effects on consumers owing to accidental misuse, overuse, and interaction with other medication in dietary supplement. Two analytical methods were tested to identify the optimal validation results according to AOAC guideline. As a result, limit of quantification (LOQ) was 0.14-0.5 ㎍ mL-1; linearity (r2) was ≥ 0.99; accuracy (expressed as recovery) was 78.9-114%; precision (relative standard deviation) was ≤ 4.28% in the HPLC method. In the LC-MS/MS method, LOQ was 0.01-2 ng mL-1, linearity (r2) was ≥0.98, accuracy was 71.7-119%; precision was ≤ 12.5%. The developed methods were applied to 51 dietary supplements collected from 2019 to 2021 through MFDS alert system. Based on our previous monitoring study, major compounds were icariin, sibutramine, yohimbine, sildenafil, tadalafil, sennosides (A, B), cascarosides (A, B, C, D), and phenolphthalein. In this study, we re-analyzed samples of detected compounds, and evaluated the statistical difference using Bland-Altman analysis to compare two analytical approaches between HPLC and LC-MS/MS. These results showed a good agreement between two methods that can be used to monitor the unapproved ingredients in dietary supplements. The developed two methods are complementarily suitable for monitoring the adulteration of 80 unapproved compounds in dietary supplements.

Evaluation of analytical methods for several metals and fluoride by certified reference materials (인증표준물질을 이용한 중금속류와 플루오르화물 전처리방법 비교 연구)

  • Jeon, Tae Wan;Chung, David;Shin, Sun Kyoung;Choi, Hun Geun;Chung, Young Hee
    • Analytical Science and Technology
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    • v.19 no.2
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    • pp.172-180
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    • 2006
  • This study was performed to establish new methods for hazardous substances and to develop an analytical method in specified wastes for preventing the environmental pollution caused by hazardous wastes. Therefore, the trends of international management, regulatory criteria, and items of hazardous wastes in various countries were investigated. Based on this study, target priority of new hazardous substances in specified wastes was established. An analytical method was developed using the waste standard reference materials of sludge, oil, bottom ash, etc., which contain the new hazardous substances (Ba, Be, Cr(VI), F, Ni, Sb, Se, and V). A total of 37 waste samples from the representative facilities, which are emitting new hazardous substances, were analyzed.

The Hazardous Components and Prevailing Rate of Sarcopenic Obesity in Younger Women : Based on 2008-2011 Korean National Health and Nutrition Examination Surveys

  • Jongseok Hwang;Chang-Ryeol Lee
    • Journal of The Korean Society of Integrative Medicine
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    • v.12 no.2
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    • pp.1-10
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    • 2024
  • Purpose : Sarcopenic obesity is associated with adverse health consequences in females. Nevertheless, there has been limited research on the hazardous components and prevailing rates of sarcopenic obesity among younger women. This study aimed to identify the hazardous components and prevailing rates of sarcopenic obesity in younger females. Methods : This study utilized data based on 2008~2011 from the Korea National Health and Nutrition Examination Surveys by the centers for disease control and prevention. The analysis was concentrated on a subset of 1,520 women aged between 30 and 39 years of age. The participants answered a questionnaire to gather demographic information. They then underwent a physical examination to measure the human detention variables, which was conducted utilizing bioelectrical impedance analysis. The blood pressure and blood laboratory tests were determined using established laboratory protocols for evaluating blood parameters. Results : This study included 1,520 patients aged 30~39 years old. The mean age of the participants was 34.97 (years)±2.74 and the overall prevailing rate was 1.84 %. The hazard components in human dimensions were the height, weight, body mass index (BMI), waist circumference (WC) and skeletal muscle mass index (SMI). The hazard components in biochemical and blood pressure were high fasting glucose, increased triglyceride, elevated total cholesterol, high systolic blood pressure, and increased diastolic blood pressure with p-values <.05. Conclusion : This study examined the hazardous components and prevailing rates of sarcopenic obesity in younger women living in the community. The results contribute to the current body of knowledge on sarcopenic obesity and shed light on possible hazardous components in a younger female population. Based on these findings, there should be increased health and medical attention towards the prevention, management, and health promotion related to reducing risk factors for sarcopenic obesity in younger women.

A Study on the Suitability Analysis of Tunnel Access Control for Hazardous Materials Transport Vehicles on the Expressway (위험물질 수송차량의 고속도로 터널통행규제 분석 연구)

  • Hong, Jung Yeol;Choi, Yoon Hyuk;Park, Dong Joo
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.17 no.3
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    • pp.18-31
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    • 2018
  • Since accidents of hazardous material transport vehicle on roadways cause severe damage in the form of disaster, foreign countries have long been engaged in systematic management and establishment of relevant laws and policies for the road safety. Recently, over 10-kilometer long tunnel, such as Inje-Yangyang Tunnel and Geumjeongsan Tunnel, has been opened on the expressway and the production of various hazardous materials is increasing with the development of chemical technology. However, road laws related to the safe operation of hazardous materials transport vehicles are still lacking, and policy measures for managing them have not been specified. It is an important task to recognize the risk of accidents of hazardous material transport vehicles and to secure road safety by establishing a management plan for road managers. Therefore, this study analyzed the feasibility of the traffic regulation of expressway tunnel in South Korea and suggested a direction for management. The results of this study can be utilized as the primary data for the revision of law related to hazardous materials transport vehicles on roadways and the derivation of optimal route of hazardous materials transport vehicles.

Dispersal of Hazardous Substance in a City Environment Based on Weather Conditions and Its Risk Assessment at the Pedestrian Level (기상조건에 따른 도시내 위험물질 확산정보와 보행자환경 위험영향평가)

  • Kim, Eun-Ryoung;Lee, Gwang-Jin;Yi, Chaeyeon
    • Journal of Environmental Impact Assessment
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    • v.26 no.4
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    • pp.242-256
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    • 2017
  • In this paper, dispersion scenarios concerning various meteorological conditions and real urban structures were made to estimate the impacts of hazardous substance leakage accidents and to reduce damages. Based on the scenario of the hazardous substance dispersion, the characteristics of the risk in the pedestrian environment were analyzed in Gangnam, Seoul. The scenarios are composed of 48 cases according to the meteorological conditions of wind direction and wind speed. In order to analyze the dispersion characteristics of the hazardous substances, simulations were conducted using a computational fluid dynamic (CFD) model with hydrogen fluoride releases. The validation for the simulated wind was conducted at a specific period, and all the calculated verification indices were within the valid range. As a result of simulated dispersion field at pedestrian level, it was found that the dispersion pattern was influenced by the flow, which was affected by the artificial obstacles. Also, in the case of the weakest wind speed of the inflow, the dispersion of the hazardous substance appeared in the direction of the windward side at the pedestrian level due to the reverse flow occurred at lower layers. Through this study, it can be seen that the artificial structures forming the city have a major impact on the flow formed in urban areas. The proposed approach can be used to simulate the dispersion of the hazardous substances and to assess the risk to pedestrians in the industrial complexes dealing with actual hazardous substances in the future.

Content and leaching characteristics of non-regulated hazardous substances in waste from the paint industry (국내 도료공정 발생 폐기물 중 미규제 중금속류의 배출특성)

  • Jeong, Seong-Kyeong;Kim, Woo-Il;Kang, Young-Yeul;Kim, Dong-Un;Cho, Yoon-A;Shin, Sun-Kyoung;Oh, Gil-Jong
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.387-394
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    • 2011
  • This study was performed to investigate the contents and leaching characteristics of hazardous wastes from the paint industry. In order to establish a hazardous waste list, samples from industrial discharge have been analyzed for 8 non-regulated inorganic hazardous substances (i.e., Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples from a total of 64 workplaces, e.g. manufacture, formulation, supply and use (MFSU) of coatings, adhesives, sealants and printing inks processing, have been chosen and analyzed. Contents and leaching tests for inorganic metal species in samples show that the non-regulated hazardous substances satisfy all the criteria, while quantitative analyses reveal that some samples of the discharged wastes exceeded the criteria proposed by NIER (National Instituted of Environmental Research). In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.

Characteristics of hazardous oil & liquid fuel waste discharged from various industries (폐유 및 액상연료 공정 폐기물에서 무기물질류의 함량특성)

  • Shin, Sun-Kyoung;Jeong, Seong-Kyeong;Kim, Woo-Il;Jeon, Tae-Wan;Kang, Young-Yeul;Yeon, Jin-Mo;Cho, Yoon-A;Kim, Min-Sun
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.276-286
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    • 2013
  • This study was performed to investigate the contents characteristics of hazardous oil wastes and wastes of liquid fuels from different industrial process. In order to establish a hazardous waste list, samples of various industrial discharge have been analyzed for 16 non-regulated inorganic hazardous substances (i.e., Cu, Pb, Cd, CN, Hg, As, T-Cr, $Cr^{6+}$, Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples including waste hydraulic oils, waste engine, gear and lubricating oils, waste insulating and heat transmission oils, bilge oils, oil/water separator contents processing were collected from 37 workplaces and analyzed. We observed that the most of the inorganic substances exceeded the proposed criteria in many samples. Especially the concentration of Sb in heat transmission oil, bilge oil and gear & lubricating oils were ranged from 6 to 419 mg/kg whereas the proposed criteria is 50 mg/kg. The assessment result of hazardous waste in Korea according to the EWC showed that the out of 24 processes, 16 belongs to absolute entry and 8 belongs to mirror entry. In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.