• Journal of the Korean institute of surface engineering
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• v.30 no.4
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• pp.285-297
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• 1997

Finned segment, with which are lined inner wall of the turbine combustors, are subject to severe degradation when they are exposed to a hostile environmment at elevated temperature. To protect the finned segment from this environment and to maintain good mechanical properties of components at high temperature, they are preferred to be coated. The most governing factor for the durability of coatings used in the high temperature is the microstructure of coatings; these are splat from, distibution of microcacks, size and distribution of pores, thickness of coating layer, adhesion between coating layer, and oxidation of band coating. In this study, based on the evaluation of the imported finned segment, new finned segment segment was manufactured with optimum plasma spraying parameters, and their properties were examined. Using $ZrO_2(8wt$Y_2O_3)$,/TEX> powder for ceramic coating and 67Ni-22Cr-10Al-0.5Y mixing powder for bond coating, thickness of ceramic and bond coating layer were varied in order to find optimum condition, the results showed that B2T4(bond coating : 100~250$\mu\textrm{m}$, ceramic coating : 250~300$\mu\textrm{m}$) was the best among the specimens tested. Compared to the imported finned segment, B2T4 has better bond strength, hardness, and isothermal and cyclic oxidation resistance.

• Journal of Environmental Health Sciences
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• v.30 no.2
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• pp.133-139
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• 2004

The objective of this study was to investigate the destruction efficiency and to determine the fundamental parameters of oxidation kinetics under the supercritical water(SCW) condition. Target material was cephradine, toxic and antibiotic material, in the pharmaceutical wastewater. For this purpose, the effect of reaction temperature and oxidant were investigated on the destruction efficiency of cephradine. And the oxidation kinetics of cephradine was derived by using a empirical power-law model. The experiment was carried out in a cylindrical batch reactor made of Hastelloy C-276 which was endurable high temperature and pressure. The destruction efficiency of cephradine increased with increment of the temperature and reaction time. Also the type of oxidants was effected and oxidants(Air and $H_2O$$_2$) were enhanced the destruction efficiency. The global oxidation kinetics for cephradine has led to two rate expressions according to type of oxidant. - In the presence of air oxidant: Rate=k. $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ( $O_2$)$^{0.51}$$\pm$0.05(k=3.27${\times}$$10^{5}$ sec. Ea=63.25 kJ/mole) - In the presence of $H_2O$$_2$ oxidant : Rate=kㆍ $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ($H_2O$$_2$)$^{0.62}$$\pm$0.02(k=2.76${\times}$$10^4$/sec. Ea=47.65 kJ/mole)ole))

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.4
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• pp.525-531
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• 2007

The operating temperature has been increased to improve the efficiency of gas turbine. The most advanced Gas turbine is operated at above $1,500^{\circ}C$. Improvement in material and cooling method permit hot gas path component to run at increased temperature. But, the repair of blades which are developed with advanced manufacture technique is difficult to use normal welding. Most of gas turbine blades are made of precipitation harden nickel base superalloy, which is very hard to weld. Therefore, the employment of welding filler on blade is solid solution nickel base superalloy(Hastelloy X, Inconel 617). In this study, Tensile test in high temperature was conducted on welded GTD111DS with GTD111 to evaluate effect of variation of pre, post treatment. The result of this study showed that the specimen was treated with optimum pre and post treatment(preweld HT($1200^{\circ}C$), Post treatment($1100^{\circ}C$ HIP, $1200^{\circ}C$ + $1100^{\circ}C$ + $800^{\circ}C$ HT) is mush superior.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.790-793
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• 2000

We have fabricated good quality superconducting YBa$_2$Cu$_3$$O_{7-x}$(YBCO) thin films on Hastelloy(Ni-Cr-Mo alloys) metallic substrates with CeO$_2$and BaTiO$_3$buffer layers in-situ by pulsed laser deposition in a multi-target processing chamber. YBCO film with CeO$_2$ single buffer layer shows T$_{c}$ of 71.64 K and the grain size less than 0.1 ${\mu}{\textrm}{m}$. When BaTiO$_3$is used as a single buffer layer, the grain size of YBCO is observed to be larger than that of YBCO/CeO$_2$by 200 times and the transition temperature of the film is enhanced to be about 84 K. CeO$_2$/BaTiO$_3$double buffer layer has been adopted to enhance the superconducting properties, which results in the enhancement of the critical temperature and the critical current density to be about 85 K and 8.4 $\times$ 10$^4$ A/cm$^2$ at 77 K, respectively mainly due to the enlargement of the grain size of YBCO film.ilm.

• Journal of the Korean Society for Nondestructive Testing
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• v.10 no.1
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• pp.47-55
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• 1990

This paper presents experimental results which explore the capability of a CW laser speckle photography for tile measurement of in-plane displacement at high temperature. The serious restrictions on the application of the method seem to be the ambient air turbulence and the change of surface texture caused by the oxidation, as they tend to decorrelate the double exposured speckle patterns. In order to assess only the effect of air turbulence, a ceramics-coated stainless steel plate is heated in air and Ar-laser specklegrams are made with combination of temperature and lateral translation displacement. The slight reduction in visibility of Young's fringes is observed at $1000^{\circ}C$. The analyses of Young's fringes are carried out by a image processing system using a TV-camera and computers, and the result agrees well with the micrometer reading. Futhermore, uncoated stainless steel and Hastelloy X plates are tested and the effect of oxidation is also evaluated. The experimental results demonstrate that a CW laser speckle photography is applicable at temperatures up to $1000^{\circ}C$.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.793-802
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• 2024

In the framework of the European project SAMOSAFER, this numerical study focuses on some thermal aspects of the Emergency Draining Tank (EDT) located underneath the core of a Molten Salt Reactor. In case of an emergency, this tank passively receives the liquid fuel salt and is designed to ensure a subcritical state. An important requirement is that the fuel does not overheat to maintain the EDT Hastelloy container integrity. The present EDT is based upon a group of hexagonal cooling assemblies arranged in a hexagonal grid and cooled down thanks to conduction through the inert salt layer up to an air flow in charge of removing the heat. This numerical thermal study relies on a conjugated heat transfer analysis coupling a Finite Element solid thermal code (SYRTHES) and two instances of a Finite Volume CFD codes (Code_Saturne). Calculations on an initial design suggest that a simple center airpipe flow is likely to not sufficiently cool the device. Alternative solutions have been evaluated. Introduction of fins to enhance the heat transfer do not bring a noticeable improvement regarding maximum temperature reached. However, a solution in which the central pipe air flow is replaced by several cooling channels located closer to the fuel is investigated and suggests a better cooling.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1590-1592
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• 1999

We have fabricated good quality superconducting $YBa_2Cu_3O_{7-{\delta}}$ thin films on Hastelloy(Ni-Cr-Mo alloys) with $CeO_2$ buffer layers by in-situ pulsed laser deposition in a multi-target processing chamber. Using one of electrical properties of YBCO superconducting which the resistance approaches to zero dramatically on transition temperature, we have researched to make power transmission line, we have deposited YBCO thin film on flexible metallic substrate. However, it is difficult to make films on flexible metallic substrates due to both interdiffusion problem between metallic substrate and superconducting layer and non-crystallization of YBCO on amorphous substrate. From early research, two ways-using textured metallic substrate and buffer layer-were proposed to overcome theses difficulties. We have chosen $CeO_2$ as a buffer layer which has cubic structure of $5.41{\AA}$ lattice parameter and only 0.2% of lattice mismatch with $3.82{\AA}$ of a-axis lattice parameter of YBCO on (110) direction of $CeO_2$. In order to enhance the crystallization of YBCO films on metallic substrates we deposited $CeO_2$ buffer layers at varying temperature $700^{\circ}C$ to $800^{\circ}C$ and $O_2$ pressure. By X-ray diffraction, we found that each domination of (200) and (111) orientations were strongly relied upon the deposition temperature in $CeO_2$ layer and the change of the domination of orientation affects the crystallization of YBCO upper layer.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.44-44
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• 2008

GdBCO coated conductor have been fabricated using reactive co-evaporation. The batch type co-deposition system was specially designed and was named EDDC (evaporation using drum in dual chamber) that is possible to deposit superconducting layer with optimum composition ratio of materials at temperature over $700^{\circ}C$ and several mTorr of oxygen. The IBAD-MgO substrate with the architecture of LaMnO3(LMO)/IBAD-MgO/Hastelloy was used for coated conductor. In this study, GdBCO superconducting layer was deposited on IBAD-MgO substrate at optimal oxygen partial pressure (pO2) and deposition temperature. After fabrication of GdBCO coated conductor, critical current density was measured by 4-probe method. Surface morphology and texture of GdBCO coated conductors were analyzed by the SEM and XRD, respectively.

• Progress in Superconductivity
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• v.11 no.2
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• pp.123-127
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• 2010

The properties of buffer layer for thermal and chemical stability in coated conductor is a very important issue. $CeO_2$ has desirable thermal and chemical stability as well as good lattice match. In this study, $CeO_2$ was deposited by electron beam deposition. The MgO(001) single crystal and LMO buffered IBAD substrate(LMO/IBAD-MgO/$Y_2O_3/Al_2O_3$/Hastelloy) were used as substrates, which have $\Delta\phi$ values of ${\sim}8.9^{\circ}$. The epitaxial $CeO_2$ films was deposited with high deposition rate of $12{\sim}16\;{\AA}/sec$. During deposition, the change of oxygen partial pressure(${\rho}O_2$) does not cause change in c-axis texture. In case of $CeO_2$ on MgO single crystal, the substrate temperature was optimized at $750^{\circ}C$ with superior $\Delta\phi$ and $\Delta\omega$ value. Otherwise, In case of LMO buffered IBAD substrate, It was optimized at $650^{\circ}C$ with increasing its deposition thickness of $CeO_2$, which was finally obtained with best $\Delta\phi$ value of $5.5^{\circ}$, $\Delta\omega$ value of $2^{\circ}$ and Ra value of 2.2 nm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.05a
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• pp.9-9
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• 2009

Coated conductor is required to have good critical current property for high efficiency of electric power applications. Until now, long coated conductor does not show high Jc over 3 MA/$cm^2$ in thick superconducting layer because of texture degradation by thick superconducting layer. In this study, in order to overcome this issue, thicker superconducting layer was deposited with optimized conditions to reduce the degradation of critical current density. SmBCO superconducting coated conductor was deposited with 1~3 um of thickness at $750\sim850^{\circ}C$ under 15~20 mTorr of oxygen partial pressure using batch type EDDC( evaporation using drum in dual chamber). The buffered substrate for superconducting layer deposition was used IBAD-MgO template with the architecture of $LaMnO_3/MgO/Y_2O_3/Al_2O_3$/Hastelloy. After fabrication of coated conductor, critical current was measured by 4-prove method under self-magnetic field and 77K. In addition, surface morphology and texture were analyzed by SEM and XRD, respectively. 3 um thick SmBCO coated conductor shows highest $I_C$ values of 638A/cm-w in 1 m long in the world.