• Journal of the Korean Graphic Arts Communication Society
• /
• v.29 no.1
• /
• pp.35-44
• /
• 2011

For printed electronic paper making which is high leveled dimensional stability. The furnish which is hard wood pulp and soft wood pulp, mixed with hard and soft wood pulp is added sea algae pulp. If sea algae pulp was added 15% contents, paper which is made with hard wood pulp is increased about 28% dimensional stability and soft wood pulp is increased about 32%, dimensional stability and hard wood 30% and soft wood 70% mixed pulp is increased about 40% dimensional stability.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.30 no.3
• /
• pp.57-64
• /
• 2012

When papers each made with sea-algae pulp 1%, 5% and soft, hard wood pulp were aged for 12days. Paper made with soft wood pulp is 30% loss of folding endurance, made with hard wood pulp is 50% loss of folding endurance. On the other, papers each made with 9% sea-algae pulp and soft, hard wood pulp were 18% loss of folding endurance. In the aging test of paper made with different freeness paper made with 300ml CSF, is more effective than 400ml CSF, 500ml CSF.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.45 no.6
• /
• pp.72-77
• /
• 2013

Tissue and paper manufacturing companies have common problems with increasing cost of imported virgin pulp and the restriction of using woods in the forest. Possibility of using bagasse pulp for solving those problems was studied. In order to reduce the production cost and study the dependency on pulps, bagasse pulp has been studied for mixing with Sw-BKP and Hw-BKP. Optimum blending ratio of wood pulps and bagasse pulp to enhance tissue properties were analyzed. Various properties of the hand sheet after blending of wood pulp and bagasse pulp were measured. As results, the bagasse pulp could substitute the hard wood pulp with similar properties of tissue. Therefore, we judged that the bagasse pulp was suitable for replacement of the hardwood pulp.

• Journal of the Korean Graphic Arts Communication Society
• /
• v.18 no.1
• /
• pp.141-155
• /
• 2000

To examine how the difference of molecular weight distribution of cellulase influenced the beating process according to surface pore size of the fiber, high molecular weight enzyme and low one were applied to soft wood pulp, hard wood pulp, cotton linter pulp. Some enzymes with the distribution of low molecular weight penetrated into cellulose in the proportion of surface pore size and the results were negative as like : the low viscosity, decrease of refining Yield, decrease of fine fibers content and so on. But in cotton linter pulp in the small surface area, the fiber softness was increased and it had a positive result that the paper intensity was high. Other enzymes with the distribution of high molecular weight had an enzyme reaction on the most surfaces of cellulose. They were effective in eliminating the fuzz of hydrophile fine fibers and the freeness was increased.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2006.06a
• /
• pp.43-49
• /
• 2006

The surface and pore structure of cellulose fibers have a significant impact on the properties and performance in applications. Cellulase enzymatic hydrolysis of cellulose fibers can result in changes to the surface and pore structure thus providing a useful tool for fiber modification. This research characterizes these changes using various test methods such as fiber dimension, water retention value, hard-to-remove water content, freezing and non-freezing bound water content, polymer adsorption, and crystallinity index. For a high-dosage enzyme treatment (0.10 g/g), the fiber length was significantly decreased and the fibers were 'cut' in the cross direction, not in the axial direction. The swelling capacities as measured by the WRV and HR water content increased for the high-dosage treatment. Three independent measurements (non-freezing bound water, polymer adsorption, and crystallinity index) are in good agreement with the statement that the amorphous regions of cellulose fibers are a more readily available substrate relative to crystalline regions. Based on the experimental results obtained herein, a model was proposed to explain surface and pore structure modification of cellulose fibers via enzymatic treatment.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2006.06b
• /
• pp.331-336
• /
• 2006

The aim of this work was to inhibit the heat-and moisture-induced yellowing of ECF/TCF bleached hard wood kraft pulp (HBKP) retaining hexenuronic acid (HexA). We have already reported that one of the derivatives of HexA, 5-formyl-2-furancarboxylic acid (FFA), causes yellowing of HBKP in acidic paper, and that FFA might polymerize or react with pulp components to form new chromophoric groups (1). In this study, it was shown that the carboxylic base of FFA interacts with that of glucuronic acid or galacturonic acid, resulting in strong yellowing. Therefore, it seems that preventing the reaction of carboxylic bases could be effective in suppressing this yellowing. We have discovered that polycarboxylic acids (for example, citric acid, tartaric acid, etc.) are useful as a yellowing inhibitor.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2006.06b
• /
• pp.257-263
• /
• 2006

This paper examines the physico-chemical properties and structural features of thio lignin and alcohol lignin preparations extracted from fast-growing poplar wood. The lignin preparations were characterized using UV, IR and alkaline nitrobenzene oxidation methods. The yield was higher in thiolignin due to its preparation from wood under drastic alkaline conditions and almost the total amount of alkaline degraded lignin was precipitated except acid soluble lignin. In case of ethanol lignin, structural modifications were comparatively less and form a cream colored lignin more or less similar to its original natural color. The methoxyl values were higher due to syringyl unit present in hard wood lignin in addition to guaicyl unit present in soft wood. The higher values of methoxyl content of isolated lignin revealed that it was built up of high syringyl units. The elementary analysis, methoxyl group and hydroxyl groups were presented by $C_{9}$ formula indicated that it was made up of phenyl propane monomers. Nitrobenzene oxidation of thio lignin and ethanol lignin yield more or less the chromatograms of similar pattern, except difference in relative percentage. The ultra violet spectra of lignins were quite similar, irrespective of the source and method of isolation. Infrared spectroscopy studies of poplar deltoides, thio and ethanol lignin shown different absorption bands which have been utilized for structural investigations.

• Journal of the Korean Wood Science and Technology
• /
• v.46 no.2
• /
• pp.118-124
• /
• 2018

Juglans mandshurica is a fast growing hard species, which is a tree in family of Juglandaceae and has a wide distribution in China, Korea and eastern Russia. Plant materials from J. mandshurica have extensively been used in folk medicines to prevent or cure gastric, esophageal, lung and cardiac cancer. As one chain of our searching for anticomplementary agents from natural sources, two epimeric ellagitannins, [2,3-O-4,4',5,5',6,6',-hexahydroxydiphenoyl (HHDP))-(${\alpha},{\beta}$)-D-glucose] (I) and pedunculagin (II) were purified from 70% acetone extracts of the stem barks of J. mandshurica by Thin Layer Chromatography and Sephadex LH-20 column chromatography approaches. The chemical structures of the isolated compounds were characterized by MS, NMR, and a careful comparation with published literatures. The epimeric ellagitannins I and II exhibited inhibitory properties against a classical pathway of complementary system with 50 % inhibitory concentrations ($IC_{50}$) values of 65.3 and $47.7{\mu}M$, respectively, comparing with riliroside ($IC_{50}=104{\mu}M$) and rosmarinic acid ($IC_{50}=182{\mu}M$), which were used as positive controls. Thus, the work indicated both the two secondary metabolites possess excellent inhibitory activity and might be developed as potential anticomplementary chemicals.

• Journal of Korea Foresty Energy
• /
• v.23 no.1
• /
• pp.45-68
• /
• 2004

The word of lignin is derived from the Latin word 'ligum' meaning wood. Lignin is complex polymer consisting of coniferyl alcohol, sinapyl alcohol and p-coumaryl alcohol unit and has an amorphous, three dimensional network structure which is hard to be hydrolyzed by acid. Lignin is found in the cell wall of plants lignified. The mode of polymerization of these alcohols in the cell wall lead to a heterogeneous branched and cross-linked polymer in which phenyl propane units are linked by carbon-carbon and carbon-oxygen bonds. This polymerization of precursors, p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol to lignin is formed by enzymic dehydrolyzation. The reaction is initiated by an electron transfer which results in the formation of resonance-stabilized phenoxy radical. The combination of these radicals produces a variety of dimers, trimers and oligomers and so on. Lignin research has been divided into basic and practical application field. The basic studies contains biosynthesis, chemical structure, distribution in the cell wall and reactivity by reductants, oxidants and organic solvents. The application research will be approached the reaction of lignin in various pulp making involving pulp bleaching and its effect on pulp qualities. Lignin also will be studied for the production of fine chemicals, polymer products and the conservation into an energy source like petroleum oil because the amount of lignin produced in pulp making process is more than 51,000,000 tons per year in the world. Both basic and application research must lay emphasis on the development for the utilization of lignin and the pulping process. But these researches can not be completed without understanding lignin structure containing functional groups. Therefore, this paper was focused on the review of lignin formulation which has been studied since 1948 in chronological order. This review was based on monomers, dimers, trimers and tetramers of phenyl propane unit structures which were isolated and identified by different methods from various wood.ious wood.

• Journal of Forest and Environmental Science
• /
• v.29 no.1
• /
• pp.1-14
• /
• 2013

Acacia mangium is an evergreen fast-growing tropical tree, which can grow up to 30 m tall and 50 cm thick, under favorable conditions. It is a low-elevation species associated with rain forest margins and disturbed, well-drained acid soils. It is native to Papua, Western Irian Jaya and the Maluku islands in Indonesia, Papua New Guinea and north-eastern Queensland in Australia. Due to its rapid growth and tolerance of very poor soils, A. mangium was introduced into some Asian, African and western hemisphere countries where it is used as a plantation tree. A. mangium has good quality wood traits, such as a comparatively low proportion of parenchymatous cells and vessels, white and hard wood, and high calorific value. Therefore, it is useful for a variety of purposes, such as furniture, cabinets, turnery, floors, particleboard, plywood, veneer, fence posts, firewood, and charcoal. It is also being used in pulp and paper making because it has good pulp traits, with high yields of pulp, quality of kraft, and produces paper with good optical, physical and surface properties. Because there are significant provenance differences in growth rate, stem straightness, heartwood formation and frequency of multiple leaders, the productivity and quality also varies depending upon environmental conditions, so genetic improvement programmes have been undertaken in countries like Australia, India, Indonesia, Malaysia, the Philippines, Taiwan and Thailand. The programme includes provenance identifications and testing, plus tree selection and clonal multiplication, establishment of seed orchards and hybridization. The phenology, reproductive biology, fruit characteristics, silvicultural practices for cultivation, pest and diseases problems, production of improved planting stock, harvesting, wood properties and utilization have been discussed in this paper.