• 폴리머
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• 제33권5호
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• pp.485-489
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• 2009

중수소화 폴리스티렌-폴리에틸렌옥사이드 이중블록공중합체(dPS-PEO)로 형성된 미셀의 구조에 대한 온도 의존성을 소각중성자산란(SANS)을 이용하여 조사하였다. SANS 데이터는 코어-쉘 모델의 form factor와 hard-sphere structure factor를 결합하여 분석하였으며, 산란 곡선 맞춤을 이용하여 미셀 응집수와 코로나 반경을 구하였다. 온도가 $25^{\circ}C$에서 $45^{\circ}C$로 증가함에 따라서 미셀 응집수는 229에서 240으로 변화하였으며, 이로 인해 코어 반경이 증가하였다. 그러나, 미셀의 쉘 두께는 6.2 nm에서 5.8 nm로 감소하였다. 이러한 구조적 변화는 온도 증가에 따라서 PEO 블록의 소수성이 증가함으로써 코로나 내의 친수성 그룹 당 수화 부피가 감소하였기 때문이다.

• Tribology and Lubricants
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• 제36권6호
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• pp.378-384
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• 2020

The friction surfaces of mechanical parts are heat-treated or coated with hard materials to minimize wear. Increasing the hardness is a very useful way to reduce abrasive wear. The general Brinell hardness test, which is widely used for metallic materials, is not suitable because it hardly shows any change in hardness when coated with thin films. In this study, we propose a basis for the application of the new Brinell hardness test method to the coated friction surface. An indentation analysis of the rigid sphere and elastic-perfectly plastic materials is performed using a commercial finite element analysis software. The results indicate that their loadto-diameter ratio is the same; the Brinell hardness test method can be applied even when the indenter diameter is on the micrometer scale. In the case of hard coating, it is difficult to calculate Brinell hardness using the diameter of the indentation, but the study revealed, for the first time, that it can be calculated using the depth of the indentation regardless of coating. The change in hardness owing to thin film coating over a wide load range implies that the hardness evaluation method is appropriate. Additional studies on various properties related to the substrate and coating material are required to apply the proposed method.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집E
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• pp.643-648
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• 2001

The direct simulation Monte Carlo(DSMC) method is applied to investigate steady and unsteady flow fields of a single-stage disk-type drag pump. Two different kinds of pumps are considered: the first one is a rotor-rotor combination, and the second one is a rotor-stator combination. The pumping channels are cut on a rotor and stator. The rotor and stator have 10 Archimedes' spiral blades, respectively. In the present DSMC method, the variable hard sphere model is used as a molecular model, and the no time counter method is employed as a collision sampling technique. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies. The DSMC results are in good agreement with the experimental data.

• Elastomers and Composites
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• 제11권2호
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• pp.113-121
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• 1976

Fundamental and specific properties of the tennis ball on rubber ball body are surveyed to match the quality of the tennis ball now on applied in the tennis game, 1. Much dose of filler of non-crystalline or flat form applied to rubber compounding than general procedure and over vulcanization is found excellent in the resistant to gas permeability. 2. Flat curing improved characteristics of the ball on the homogenous rebounds when applied on the specified concrete surface. 3. Satisfactory adhesive power is found with Desmodur R and standard rubber recipe in case of applying on the under-vulcanizate of half sphere. 4. The stable gas-generating compounds of sodiun nitrate, ammonium chloride, water and sodium carbonate, anhydorus help controlling of optimum internal over-pressure in the tall.

• 대한기계학회논문집B
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• 제26권10호
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• pp.1394-1405
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• 2002

The performance of micro-actuators utilizing radiometric forces are studied numerically. The Knudsen number based on gas density and characteristic dimension is varied from near-continuum to highly rarefied conditions. Direct simulation Monte Carlo(DSMC) calculations have been performed to estimate the performance of the micro-actuators. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.

• Journal of Mechanical Science and Technology
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• 제17권11호
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• pp.1638-1649
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• 2003

A study is made on the characterization of damage tolerance by spherical indentation in hardly coated layer structure with modest elastic modulus mismatch. A hard silicon nitride is prepared for the coating material and silicon nitride with 5wt% of boron nitride composites for underlayer. Hot pressing to eliminate the effect of interface delamination during the fracture makes strong interfacial bonding. The elastic modulus mismatch between the layers is not only large enough to suppress the surface crack initiation from the coating layer but sufficiently small to prevent the initiation of radial crack from the interface. The strength degradation of the layer structure after sphere contact indentation does not significantly occur, while the degradation of silicon nitride-boron nitride composite is critical at a high load and high number of contacts.

• 한국소음진동공학회논문집
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• 제20권6호
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• pp.521-527
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• 2010

This article presents a method to calculate the sound radiation of transmission gearbox housing by using Helmholtz integral. Rayleigh integral is used to verify the method. Half-space radiation is considered because the actual gearbox housing is on hard place like concrete. For optimization, orthogonal array is used as a fractional factorial design method. Sound Radiation is calculated with simple source like plate and sphere shape, then actual gearbox BEM model is applied to the method.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.207-208
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• 2006

Here, we discuss various thermodynamic factors that affect the design of nanomaterials based on block copolymers. It is well known that the ordering behavior is determined by composition, chain size N, and the ubiquitous Flory. However, the recent discovery of ordering upon heating, immisibility loops, and baroplasticity addresses a clear need for further microscopic interpretation of such. in order to help to design nanomaterials at aimed purposes. Employing a perturbed hard sphere chain model, the molecular factors such as self and cross-interactions, free space distribution, and directional interactions are incorporated in. It is shown that not only typical ordering phenomena, but also the recent observations just mentioned are all described through this unified way.

• Nuclear Engineering and Technology
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• 제6권3호
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• pp.171-182
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• 1974

시간상관 함수를 일반화된 동력학적 수력학에 의해 기술하는 방법을 이용하여 단순 유체내에서의 소리의 산포를 분석 검토하였다. 소리의 산포에 대한 전단응력의 음의 산포에 영향을 액체알곤과 희석 경구형깨스에 대해 검토하였다. 액체알곤의 경우에는 광범위한 파수영역에 걸쳐 이론적으로 예언된 산포는 전단응력 이완상관과 구조상관의 복합된 영향을 나타내었다. 희석개스에 대한 결과는 전단응력이완을 포함시킨 이론이 나비어-스토크스 이론보다 정성적으로 우수함을 보였다.

• 대한화학회지
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• 제25권5호
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• pp.291-299
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• 1981

용액중에서 화학반응을 설명하기 위하여 한개의 대표적인 입자의 반복적 충돌현상까지 고려한 동역학적인 이론을 경구모델을 사용하여 연구하였다. 반응성을 지닌 대표적인 입자의 상공간 밀도의 시간상관함수가 만족시키는 동역학방정식을 유도하였고 이로부터 비활성 용매 S중에서 일어나는 A + B ${\rightleftharpoons$ C + D 형태의 가역반응에 관계되는 반응속도 계수의 인자를 투영연산자방법으로 구하였다.