• Macromolecular Research
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• v.10 no.6
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• pp.365-368
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• 2002

Thermoplastic polyurethanes (TPUs) with different hard segment length has been prepared from a fixed molar ratio of poly(tetramethylene ether glycol), 4,4'-diphenylmethane diisocyanate, and 1,4-butanediol by different polymerization procedures. Results reveal that the on-set temperature of endotherms ( $T_{cc}$ ) due to the crystallization of hard segments by cooling the TPUs from melt and the peak temperature of endotherms due to the melting of hard segments ( $T_{mh}$ ) by heating the TPUs increased and levelled off with increasing the hard segment length of TPUs. It has also been observed that soft segment glass transition temperature ( $T_{gs}$ ) of TPU decreased slightly with increasing the hard segment length, which explains less mixing of soft segments and hard segments. In tensile measurement of TPUs, strain hardening is observed with increasing the hard segment length, which is attributed to the strain induced crystallization of soft segments.

• Proceedings of the Korean Fiber Society Conference
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• 1998.10a
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• pp.33-36
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• 1998

Segmented block copolyetheresters defined as copolymers having sequences of alternating polyester hard blocks and polyether soft blocks create labile physical cross-links upon crystallization of hard polyester blocks Since the nature of the physical interlocking is a crystallite formed exclusively from the crystallizable hard segment, the hard segment content (HSC) and hard segment length (HSL) will play an important role in determining the properties such as mechanical property and dynamic mechanical property. (omitted)

• Fibers and Polymers
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• v.7 no.4
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• pp.367-371
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• 2006

Thermal properties of copolyetherester/silica nanocomposites were examined by using DSC and TGA. The segmented block copolyetheresters with various hard segment structures and hard segment contents (HSC) were synthesized and their silica nanocomposite films were prepared by solution casting method. The nano-sized fumed silica particles were found to act as a nucleating agent of the copolyetheresters. The nanocomposites always showed reduced degree of supercooling or faster crystallization than the corresponding copolyetheresters. The nanocomposites also showed increased hard segment crystallinity except HSC 35 sample which had short hard segment length. In case of 2GT [poly(ethylene terephthalate)] copolyetheresters, which were not developed commercially because of their low crystallization rate, the hard segment crystallinity increased considerably. The copolyetherester/silica nanocomposites showed better thermal stability than copolyetheresters.

• Textile Coloration and Finishing
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• v.5 no.4
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• pp.60-66
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• 1993

Aqueous polyurethane(PU) anionomer dispersions were prepared from isophorone diisocyanate (IPDI), polytetramethylene adipate glycol(PTAd) and dimethylol propionic acid(DMPA) as potential anionic centers. The effects of polyol molecular weight(Mn) on the state of dispersion, thermal, mechanical, and viscoelastic properties and swelling of emulsion cast film were determined. With increasing Mn of PTAd, particle size of emulsion and soft segment T$_{g}$ decreased, and solvent swell, emulsion viscosity, and hard segment $T_{g}$ increased. Tensile strength showed minimum with PTAd 1000, and elongation at break generally increased with the Mn of PTAd. These results were possibly nterpreted in terms of soft segment-hard segment phase separation and crystallization of high molecular weight PTAd.

• Proceedings of the Korean Society of Rheology Conference
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• 2003.05a
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• pp.61-64
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• 2003

• Elastomers and Composites
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• v.34 no.4
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• pp.285-291
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• 1999

Effects of catalysts on network structure, hard segment length and distribution of polyurethane foams in the absence of catalysts were investigated. CFC free all MDI-based poly urethane foams were prepared from poly(ethylene adipate)glycol, 4,4'-diphenylmethane diisocyanate, and water. Amino catalysts used were 1,4-diazabicyclo[2,2,2]octane(DABCO), N, N,N',N'-tetramethyl--hexane-1,6-diamine(MR), bis(2-methylamino ethyl)ether(ET), 1,8-diazabicyclo-[5,4,0]-undecene-7(DBU). Dibutyltindilaurate(DBTL) as control was also used. Hard segment components of polyurethane foams were obtained by a selective degradation of polyester chains with 0.01N KOH-methanol solution. The PUFs with DBU catalyst contained more amount of isocyanurate components than other PUFs. On the other hand, the PUFs with ET, MR, DBTL catalysts contained more amount of allophanate and biuret component than the other PUFs.

• Korean Journal of Cleft Lip And Palate
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• v.15 no.2
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• pp.89-96
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• 2012

Le Fort 1 osteotomy or maxillary advancement with distraction osteogenesis (DO) is main treatment strategy for cleft palate patients with maxillary hypoplasia. Maxillary DO allows greater maxillary advancement within physiological limit than Le Fort 1 osteotomy. Moreover, it is better for velopharyngeal function. However, there is a greater tendency for an increase in nasal sound when maxilla is advanced excessively. Therefore, the advancement of anterior maxillary segment using DO has been utilized. It offers advantages such as an increase in the length of the palate, a prevention of the change in palatopharyngeal depth, and a preservation of the velopharyngeal function. Moreover, it will obliterate the necessity of bone graft, and it prevents the occurrence of oronasal or oroantral fistula. Finally, it stimulates the regeneration of the soft and hard tissue of alveolus, and subsequently makes possible to place implant.

• Journal of the Korean Society of Clothing and Textiles
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• v.19 no.5
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• pp.826-841
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• 1995

This study is concerned with the functional utility of movement in sleeve from an ergonomic viewpoint. Experiments were carried out which include 43 upper extremity segments, 21 motions and 35 female subjects. The major conclusions of the study are. 1. The expansion rate of upper extremity was higher in length than in circumference mesurements. The amounts of expansion were, especially high (more than 60mm) for inner arm length, axillary arm circumference, and outer arm length. Therefore, a lot of ease is necessary for these parts. On the other hand, armhole circumference, forearm circumference, and wrist circumference had low rates of expansion. The sleeve cap length was also contracted in all motions. 2. The expansion rate and the range of expansion and contraction were higher in the upper arm than in the forearm. The main points of expansion were the axillary and elbow parts. The segment of maximum expansi (rate of 44.8%) was Iii of axillary parts. As the body surface expands mainly in some segments, it is desirable to allow ease to the main segments of expansion. 3. In a basic sleeve, necessary ease was lacking in the measurements for outer arm length and axillary arm circumference, while it was too large in armhole circumference, forearm circumference, wrist circumference, and sleeve cap length. Therefore, a basic sleeve is inadequate as a functional sleeve for hard work in point of functional utility of movement. Wider application of these findings would lead to an improvement in the comfort of workers.

• Journal of Fashion Business
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• v.21 no.4
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• pp.116-126
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• 2017

This study applied a segmented hard shell design on knee protectors for children with the objective of increasing mobility. The prototype of the hard shell that does not correspond to movement of the body among components of the knee protector was developed. Surface modeling was conducted based on 3D knee data to enhance comfort through optimized fit on the knee joint where the hard shell would be worn. For this, previous studies on changes in skin near the knee joint during knee flexion were reviewed to establish basic segmental lines. The basic design included six segments, and the number of segments was used as the design variable by increasing or decreasing it to 0, 3, 6, 9, and 14 segments. A prototype was produced from 3D printing with TPU material, worn for wearing assessment. Results revealed fewer numbers of segments resulting in less fit with the body, while actual appearance was stable. Meanwhile, the number of proper segments improved better fit with the body during movement. The wearing assessment revealed the amount of gap reflects change in skin length depending on movement. Assessment results demonstrated basic segment design, S6 with 6 segments, had the best design and most optimized fit. Findings in this study can provide key data for designing knee protection products for children.

• Journal of the Korean Society of Clothing and Textiles
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• v.33 no.7
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• pp.1109-1120
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• 2009

This study develops a fitted torso type basic pattern for men by utilizing 3D body scan data. Recent fashion trends are reflected in the development of the pattern. The subjects were 15 men in their 20's, who wear size 95 (M size). Body scan data was obtained through a 3D whole body scanner (WB4, Cyberware, USA), and a body surface development figure for developing male fitted torso type basic pattern was attained through the use of Rapid Form 2006 as well as Auto CAD 2006 programs. The results are as follows: A body surface development figure through body surface segment method showed high exactitude in an error range of 100$\pm$1%. In addition, it occurred in an error range of 100:1:3% because of the hard scanning conditions in the incline of the shoulder and armpit areas. However, the body surface development figure as well as the direct measurement results can be used as basic data for the given patternmaking since the error range falls into 100$\pm$3%. Dart amounts obtained from the average cross section were center back 2.2cm (24.3%), back armpit point 3.8cm (41.8%), front armpit point 3.0cm (33.9%). As shown the jacket pattern, the biggest dart amount was portioned out at the back armpit point. The drafting equations for the development pattern acquired are as follows; Full width=C/2+5cm, back length=height/4-1cm, armhole depth=(C/10+12cm)+3cm, back width=2C/10+2cm, front width=2C/10. The development pattern was a fitted torso basic pattern that was composed of 3 pieces, so it would be very useful in developing shirt or jacket patterns. According to the results of the evaluation of the developed pattern appearance, it obtained higher scores of over 3.5 points in almost items, meaning that the developed pattern is appropriate for a male fitted torso type basic pattern. It suggests a possibility of patternmaking from a body surface development figure in 2-D to prototype.