• Title/Summary/Keyword: hard phase

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Development of Cu-CeO2 Catalysts for Selective Oxidation of CO (일산화탄소의 선택적 산화반응을 위한 Cu-CeO2 촉매의 개발)

  • Jung, C.-R.;Han, J.;Yoon, S.P.;Nam, S.-W.;Lim, T.-H.;Hong, S.-A.;Lee, H.-I.
    • Clean Technology
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    • v.8 no.1
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    • pp.53-59
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    • 2002
  • $Cu-CeO_2$ catalysts were prepared by co-precipitation and liquid phase oxidation (CP-LPO) and the prepared catalysts were examined as selective oxidation of carbon monoxide catalysts for the application of fuel cell vehicles. The prepared $Cu-CeO_2$ catalysts showed high reaction activity, but it was hard to find the correlation between the amount of Cu loaded and the reaction activities. As increase of the amount of Cu loaded, the micro pore structure of the catalyst was changed. It is due to the formation of solid solution between Cu and $CeO_2$. During pretreatment, the catalyst formed the solid-solution of Cu-Ce-O, resulting in the improvement of catalytic activity.

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Material Characteristics and Clay Source Interpretation of Joseon (the 15th to 17th Century) Potteries from Ssangyongdong Yongam Site in Cheonan, Korea (천안 쌍용동 용암유적 출토 조선시대 토기의 재료과학적 특성과 원료의 산지해석)

  • Kim, Ran-Hee;Lee, Chan-Hee;Yun, Jung-Hyun
    • Journal of Conservation Science
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    • v.28 no.1
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    • pp.7-20
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    • 2012
  • This study was to identify the material characteristics and provenance of the Joseon (the 15th to 17th century) potteries from Ssangyongdong Yongam site in Cheonan. The pottery samples of the kilns and the workshops (habitation) from the study area have grey or red color with similar matrix but various shapes and different hardness, according to firing temperature. All of the pottery and the workshop soils were very similar patterns with characteristics of occurrences, mineralogy and geochemical evolution trend. But soils from around the site does not correspond with them. So the workshop soil that the fine clay is raw clay for making pottery in Yongam site. Firing temperature of soft-type potteries were presumed to be formed around $900^{\circ}C$ based on phase transition of clay minerals and mica. Hard-type pottery, mullite was detected and plagioclase was not detected by X-ray diffraction analysis, which means that potteries had experienced firing between 1,000 to $1,100^{\circ}C$.

Skin Brightening Effect of Gel Essence Containing High Concentrated-Marine Minerals in Silicon Copolyol Network Film in vivo (고농도의 미네랄을 실리콘 네트워크 필름에 포집한 젤 에센스 제형의 피부 밝기 개선 효과)

  • Kim, Sun-Kyong;Kim, Young-So;Joo, Kyung-Mi;Kim, Eun-Joo;Lee, Ji-Eun;Chae, Byung-Gun;Cho, Jun-Cheol;Han, Sang-Hoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.3
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    • pp.283-288
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    • 2011
  • Since minerals are in ionic forms in aqueous phase (like deep sea water), it is very hard to incorporate concentrated minerals in gel like cosmetic formulations which are generally composed of carbomer or acrylates polymer. In this study, we invented a salt-resistant network formulation made of silicon copolyol. It was found that the network formulation traps minerals (especially from marine) in a mesh-like silicone copolyol structure. Since the mineral-containing formulation makes a very thin film on the skin, minerals could be easily absorbed into stratum corneum. In 6 weeks in vivo test, it was found that the novel mineral formulation increased the amounts of amino acids, major components of natural moisturizing factors (NMFs), as well as levels of minerals. It was also found that the moisture contents and the brightness of the skin increased.

AN EXPERIMENTAL STUDY OF GUIDED BONE REGENERATION OF BONE DEFECTS IN RABBIT USING RUBBER DAM (가토에서 러버댐을 이용한 골결손부의 골조직 유도 재생술에 관한 실험적 연구)

  • Jang, Chang-Dug;Whang, Hie-Seong;Shin, Sang-Hun
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.21 no.2
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    • pp.110-119
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    • 1999
  • The principle of guided tissue regeneration (GTR), as applied to bone healing, is based on the prevention of connective tissue from entering the bony defect during the healing phase. This allows the slower bone producing cells to migrate into and reproduce bone within the defect. The principle of guided tissue regeneration has demonstrated a level of success in regenerating bone defect. Several types of membrane barrier, each one with distinct properties, have been utilized to apply this principle in bone regeneration. The purpose of this study is to introduce and discuss the attributes of rubber dam as a barrier membrane and evaluate whether improved bone regeneration can be achieved by GTR using rubber dam. In the 15 New Zealand white rabbits, full-thickness bone defects on three sites of each rabbit calvaria were made. Non membrane group served as a control and experimental group 1 was covered with rubber dam and group 2 covered with Gore-Tex$^{TM}$ membrane. Macroscopic, radiographic, microscopic examinations were made serially on 1, 2, 3, 6, 12 weeks after operation. The results were as follows: 1. Macroscopically, the control site was collapsed and filled with connective tissue throughout the experimental period. But the defects of experimental groups 1 and 2 were filled with bone-like mass and showed the hard consistency on palpation. 2. Radiographically, the early new bone formation appeared similarly from the host bone in groups 1 and 2. 3. Microscopically, there were much connective tissue at the central part of control site but the defect of group 1 and 2 was filled with the mature bony trabeculae on the 12th week. This results suggest that rubber dam can be effectively used as a barrier membrane for guided bone regeneration.

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On the Analysis of DS/CDMA Multi-hop Packet Radio Network with Auxiliary Markov Transient Matrix. (보조 Markov 천이행렬을 이용한 DS/CDMA 다중도약 패킷무선망 분석)

  • 이정재
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.5
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    • pp.805-814
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    • 1994
  • In this paper, we introduce a new method which is available for analyzing the throughput of the packet radio network by using the auxiliary Markov transient matrix with a failure state and a success state. And we consider the effect of symbol error for the network state(X, R) consisted of the number of transmitting PRU X and receiving PRU R. We examine the packet radio network of a continuous time Markov chain model, and the direct sequence binary phase shift keying CDMA radio channel with hard decision Viterbi decoding and bit-by-bit changing spreading code. For the unslotted distributed multi-hop packet radio network, we assume that the packet error due to a symbol error of radio channel has Poisson process, and the time period of an error occurrence is exponentially distributed. Through the throughputs which are found as a function of radio channel parameters, such as the received signal to noise ratio and chips of spreading code per symbol, and of network parameters, such as the number of PRU and offered traffic rate, it is shown that this composite analysis enables us to combine the Markovian packet radio network model with a coded DS/BPSK CDMA radio channel.

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Application of Emulsion Liquid Membrane to Removal of Fermentation Inhibitors from Simulated Hemicellulosic Hydrolysates (모사 헤미셀룰로오스 가수분해액으로부터 발효 저해물질의 제거를 위해 에멀젼형 액막법의 적용)

  • Lee, Sang Cheol
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.457-462
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    • 2015
  • Hemicellulosic hydrolysates contain not only sugars but also several kinds of ethanol fermentation inhibitory substances such as carboxylic acids, furans and phenolic compounds. In this work, emulsion liquid membrane (ELM) was chosen as a separation technology to remove the inhibitors. A basic simulated hemicellulosic hydrolysate was composed of xylose as sugar, dilute sulfuric acid solution as solvent, and acetic acid as carboxylic acid, and furfural as furan derivative or p-hydroxybenzoic acid(HBA) as phenolic compound was added to the hydrolysate when necessary. Acetic acid and HBA as weak acid could be selectively removed from the hydrolysates in all the ELM systems considered here, but furfural as aldehyde was quite hard to remove. Also, when HBA was added to the basic simulated hemicellulosic hydrolysate, both of acetic acid and HBA in the feed phase could be selectively removed up to 99% in an ELM system with tributyl phosphate as extractant.

BONE HEALING CAPACITY OF THE NEW FLUORIDATED HYDROXYAPATITE IN THE RABBIT CRANIUM DEFECT (가토 두개골 결손부에 이식된 새로운 합성 골이식재의 골치유능력)

  • Rho, Kyu-Seop;Han, Se-Jin;Kim, Chul-Hwan;Kim, Kyung-Wook
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.33 no.5
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    • pp.464-469
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    • 2007
  • The bone graft materials are grossly divided into autogenous bone, allogenic bone, xenogenic bone, and alloplastic material. Among the various allogenic graft materials, hydroxyapatite($Ca_{10}(PO_4)_6(OH)_2$, HA), the main inorganic phase of human hard tissue, is widely used as a repair material for bones. When HA applied to bony defect, however, it may be encapsulated with fibrous tissue and floated in the implanted area by the lack of consolidation. Fluoridated hydroxyapatite($Ca_{10}(PO_4)_6(OH)_2$, FHA), where F- partially replaces the OH- in the hydroxyapatite, is considered as an alternative material for bone repair due to its solubility and biocompatibility. This study was designed to find out the bone healing capacity of FHA newly produced as a nanoscale fiber in the laboratory. We implanted HA and FHA in the rabbit cranium defect and histologically analysed the specimen. The results were as follows. 1. In the 4 weeks, fibrous connective tissue and little bone formation around materials of the experimental group I implanted HA were observed. In the experimental group II implanted FHA, newly formed bone around materials were observed. 2. In the 8 weeks, the amount of newly formed and matured bone of the experimental group II was more than the experimental group I and control group. From the results obtained, we suggest that FHA, newly synthesized, is relatively favorable bone substitute with bioconpatibility and has better bone healing capacity than pure HA.

Effect of Cobalt Oxide on Carbothermal Reduction of Spray Dried Titanium-Cobalt-Oxygen Based Oxide Powder (분무건조법에 의해 제조된 Ti-Co-O계 산화물 분말의 환원/침탄반응에 미치는 코발트 산화물의 영향)

  • Lee, Gil-Geun;Kim, Chan-Young
    • Journal of Powder Materials
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    • v.12 no.5 s.52
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    • pp.336-344
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    • 2005
  • In the present study, the focus is on the effect of cobalt oxide powder in the carbothermal reduction of the titanium-cobalt-oxygen based oxide powder by solid carbon for the optimizing synthesis process of ultra fine TiC/Co composite powder. The titanium-cobalt-oxygen based oxide powder was prepared by the combination of the spray drying and desalting processes using the titanium dioxide powder and cobalt nitrate as the raw materials. The titanium-cobalt-oxygen based oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under flowing argon atmosphere. Changes in the phase structure and thermal gravity of the mixture during carbothermal reduction were analysed using XRD and TGA. Titanium-cobalt-oxygen based oxide powder desalted at $600^{\circ}C$ had a mixture of $TiO_2\;and\;Co_{3}O_4$. And the one desalted at $800^{\circ}C$ had a mixture of $TiO_2\;and\;CoTiO_3$. In the case of the former powder, the reduction of cobalt oxide powder in the titanium-cobalt-oxygen based oxide powder occurred at lower temperature than the latter one. However, the carbothermal reduction of titanium dioxide powder in the titanium-cobalt-oxygen based oxide powder with a mixture of $TiO_2\;and\;Co_{3}O_4$ occurred at higher temperature than the one with a mixture of $TiO_2\;and\;CoTiO_3$. And also, the former powder showed a lower TiC formation ability than the latter one.

Analysis of Standard Cost and the Construction Period Applied TBM Excavation Method (TBM 굴착 공법 적용 구경별 표준 공사비 및 공사기간 분석 연구)

  • Park, Hong Tae
    • Journal of the Society of Disaster Information
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    • v.8 no.4
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    • pp.319-327
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    • 2012
  • This research collected work drilling report of TBM method site developed by WRITH company to TBM equipment company in Germany and analyzed work operating productivity. Based the data analyzed TBM operating productivity, This research derived and presented excavation speed(m/day) by TBM diameter (2.6m, 3.0m, 3.5m, 5.0m, 8.0m) and rock. Also, based on the excavation speed(m/day) by TBM diameter, This research estimated a day direct construction cost and total direct construction costs by applying a direct construction cost which spent on per 1m. Based on hard rock 40.0%, soft rock 30.0%, usually rock 20%, weathered rock 10.0%, TBM boring velocity, m per cost, total construction period shall estimate the construction cost and the construction period by the effective use by diameter when future applying TBM method to the basic planning stages and in the preliminary design phase.

A Design and Implementation of a Timing Analysis Simulator for a Design Space Exploration on a Hybrid Embedded System (Hybrid 내장형 시스템의 설계공간탐색을 위한 시간분석 시뮬레이터의 설계 및 구현)

  • Ahn, Seong-Yong;Shim, Jea-Hong;Lee, Jeong-A
    • The KIPS Transactions:PartA
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    • v.9A no.4
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    • pp.459-466
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    • 2002
  • Modern embedded system employs a hybrid architecture which contains a general micro processor and reconfigurable devices such as FPGAS to retain flexibility and to meet timing constraints. It is a hard and important problem for embedded system designers to explore and find a right system configuration, which is known as design space exploration (DSE). With DES, it is possible to predict a final system configuration during the design phase before physical implementation. In this paper, we implement a timing analysis simulator for a DSE on a hybrid embedded system. The simulator, integrating exiting timing analysis tools for hardware and software, is designed by extending Y-chart approach, which allows quantitative performance analysis by varying design parameters. This timing analysis simulator is expected to reduce design time and costs and be used as a core module of a DSE for a hybrid embedded system.