• 제목/요약/키워드: hard metals

검색결과 117건 처리시간 0.045초

Evaluation of Mechanical Properties and Microstructural Behavior of Sintered WC-7.5wt%Co and WC-12wt%Co Cemented Carbides

  • Raihanuzzaman, Rumman Md.;Song, Jun-U;Tak, Byeong-Jin;Hong, Hyeon-Seon;Hong, Sun-Jik
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 한국재료학회 2011년도 춘계학술발표대회
    • /
    • pp.58.1-58.1
    • /
    • 2011
  • WC-Co and other similar cemented carbides have been widely used as hard materials in industrial cutting tools and as mould metals; and a number of techniques have been applied to improve its microstructural characteristics, hardness and ear resistance. Cobalt is used primarily to facilitate liquid phase sintering and acts as a matrix, i.e. a cementing phase between WC grains. A uniform distribution of metal phase in a ceramic is beneficial for improved mechanical properties of the composite. WC-Co, starting from initial powders, is vastly used for a variety of machining, cutting, drilling, and other applications because of its unique combination of high strength, high hardness, high toughness, and moderate modulus of elasticity, especially with fine grained WC and finely distributed cobalt. In this study, that started with two different compositions of initial powders, WC-7.5wt%Co and WC-12wt%Co with initial powder size being 1~3 ${\mu}m$, magnetic pulsed compaction followed by subsequent vacuum sintering were carried out to produce consolidated preforms. Magnetic Pulsed Compaction (MPC), a very short duration (~600 ${\mu}s$), high pressure (~4 Gpa), high-density preform molding method was used with varied pressure between 0.5 and 3.0 Gpa, in order to reach an initial high density that would help improve the sintering behavior. For both compositions and varied MPC pressure, before and after sintering, changes in microstructural behavior and mechanical properties were analyzed. With proper combination of MPC pressure and sintering, samples were obtained with better mechanical properties, densification and microstructural behavior, and considerably improved than other conventional processes.

  • PDF

Utilization of Waste Mn-ferrite for Treating Heavy Metals in Wastewater (Mn-ferrite의 중금속 흡착특성-폐 페라이트의 중금속폐수 처리 활용 가능성)

  • 이상훈;윤창주;이희란
    • Economic and Environmental Geology
    • /
    • 제36권5호
    • /
    • pp.381-385
    • /
    • 2003
  • We investigated possible application of waste ferrite in treating Cd and Pb in wastewater. Adsorption of Cd and Pb on Mn-Ferrite are influenced by several controlling factors such as contact time, heavy metal concentrations, pH and temperature. Both Cd and Pb achieved adsorption equilibrium within 5 minutes. Based upon this kinetic data, 24 hours of contact time was allowed for other experiment. The adsorption of Cd and Pb was high at high pH and high ion concentrations. The reaction was also affected by temperature. Adsorption isotherms fits well with the Freundlich isotherm equation. pH is the main controlling factor in Cd, Pb adsorption on the Mn-ferrite. Cd showed S type adsorption curve while Pb showed sorption edges, depending on the Pb concentrations.

Investigation on Etch Characteristics of FePt Magnetic Thin Films Using a $CH_4$/Ar Plasma

  • Kim, Eun-Ho;Lee, Hwa-Won;Lee, Tae-Young;Chung, Chee-Won
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
    • /
    • pp.167-167
    • /
    • 2011
  • Magnetic random access memory (MRAM) is one of the prospective semiconductor memories for next generation. It has the excellent features including nonvolatility, fast access time, unlimited read/write endurance, low operating voltage, and high storage density. MRAM consists of magnetic tunnel junction (MTJ) stack and complementary metal-oxide semiconductor (CMOS). The MTJ stack is composed of various magnetic materials, metals, and a tunneling barrier layer. For the successful realization of high density MRAM, the etching process of magnetic materials should be developed. Among various magnetic materials, FePt has been used for pinned layer of MTJ stack. The previous etch study of FePt magnetic thin films was carried out using $CH_4/O_2/NH_3$. It reported only the etch characteristics with respect to the variation of RF bias powers. In this study, the etch characteristics of FePt thin films have been investigated using an inductively coupled plasma reactive ion etcher in various etch chemistries containing $CH_4$/Ar and $CH_4/O_2/Ar$ gas mixes. TiN thin film was employed as a hard mask. FePt thin films are etched by varying the gas concentration. The etch characteristics have been investigated in terms of etch rate, etch selectivity and etch profile. Furthermore, x-ray photoelectron spectroscopy is applied to elucidate the etch mechanism of FePt thin films in $CH_4$/Ar and $CH_4/O_2/Ar$ chemistries.

  • PDF

Tensile and impact toughness properties of various regions of dissimilar joints of nuclear grade steels

  • Karthick, K.;Malarvizhi, S.;Balasubramanian, V.;Krishnan, S.A.;Sasikala, G.;Albert, Shaju K.
    • Nuclear Engineering and Technology
    • /
    • 제50권1호
    • /
    • pp.116-125
    • /
    • 2018
  • Modified 9Cr-1Mo ferritic steel is a preferred material for steam generators in nuclear power plants for their creep strength and good corrosion resistance. Austenitic stainless steels, such as type 316LN, are used in the high temperature segments such as reactor pressure vessels and primary piping systems. So, the dissimilar joints between these materials are inevitable. In this investigation, dissimilar joints were fabricated by the Shielded Metal Arc Welding (SMAW) process with Inconel 82/182 filler metals. The notch tensile properties and Charpy V-notch impact toughness properties of various regions of dissimilar metal weld joints (DMWJs) were evaluated as per the standards. The microhardness distribution across the DMWJs was recorded. Microstructural features of different regions were characterized by optical and scanning electron microscopy. Inhomogeneous notch tensile properties were observed across the DMWJs. Impact toughness values of various regions of the DMWJs were slightly higher than the prescribed value. Formation of a carbon-enriched hard zone at the interface between the ferritic steel and the buttering material enhanced the notch tensile properties of the heat-affected-zone (HAZ) of P91. The complex microstructure developed at the interfaces of the DMWJs was the reason for inhomogeneous mechanical properties.

Etch Characteristics of MgO Thin Films in Cl2/Ar, CH3OH/Ar, and CH4/Ar Plasmas

  • Lee, Il Hoon;Lee, Tea Young;Chung, Chee Won
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.387-387
    • /
    • 2013
  • Currently, the flash memory and the dynamic random access memory (DRAM) have been used in a variety of applications. However, the downsizing of devices and the increasing density of recording medias are now in progress. So there are many demands for development of new semiconductor memory for next generation. Magnetic random access memory (MRAM) is one of the prospective semiconductor memories with excellent features including non-volatility, fast access time, unlimited read/write endurance, low operating voltage, and high storage density. MRAM is composed of magnetic tunnel junction (MTJ) stack and complementary metal-oxide semiconductor (CMOS). The MTJ stack consists of various magnetic materials, metals, and a tunneling barrier layer. Recently, MgO thin films have attracted a great attention as the prominent candidates for a tunneling barrier layer in the MTJ stack instead of the conventional Al2O3 films, because it has low Gibbs energy, low dielectric constant and high tunneling magnetoresistance value. For the successful etching of high density MRAM, the etching characteristics of MgO thin films as a tunneling barrier layer should be developed. In this study, the etch characteristics of MgO thin films have been investigated in various gas mixes using an inductively coupled plasma reactive ion etching (ICPRIE). The Cl2/Ar, CH3OH/Ar, and CH4/Ar gas mix were employed to find an optimized etching gas for MgO thin film etching. TiN thin films were employed as a hard mask to increase the etch selectivity. The etch rates were obtained using surface profilometer and etch profiles were observed by using the field emission scanning electron microscopy (FESEM).

  • PDF

The Numerical Analysis of Two-Dimensional Electrokinetic Remediation Characteristics Dependent on Electrode Configurations (전극배치에 따른 2차원적 동전기 정화 특성의 수치해석)

  • Kim, Soo Sam;Han, Sang Jae;Kim, Byung Ill
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • 제26권5C호
    • /
    • pp.291-301
    • /
    • 2006
  • In this study the characteristics of electrokinetic remediation, which is dependent on a various electrode configuration, was predicted from 2-D numerical analysis program (HERO-2D). Based on the predicted results for one dimensional and two dimensional electrode configurations, the optimized electrode configuration was determined by analyzing remediation efficiency, consumed electric power, installation cost of electrode and so on. When proposed electrode configurations were applied for in-situ remediation of the soils contaminated by heavy metals, the electrode configuration of high remediation efficiency should be chosen in case the high removal effect would be required, and one dimensional electrode configuration should be chosen in case the hard field works would be expected. Because the rectangular electrode configuration is better than others for consumed electric power, remediation efficiency per unit power, installation cost of electrode and so on, it can obtain the best results for the cost reduction.

Effects of Passivation Thin Films on the Optical Properties of the Green Organic Light Emitting Diodes (페시베이션 박막이 녹색 유기발광다이오드의 광학특성에 미치는 영향)

  • Mun, Sae Chan;Lee, Sang Hee;Park, Byung Min;Pyee, Jaeho;Chang, Ho Jung
    • Journal of the Microelectronics and Packaging Society
    • /
    • 제23권1호
    • /
    • pp.11-15
    • /
    • 2016
  • The organic light emitting diodes (OLEDs) have been studied as large flexible displays, light source and hard wares of internet of things. However, OLEDs show some drawbacks in terms of external environments due to the low work function of the metals and the reactive organic materials. In particular, the operation functions of the OLEDs tend to deteriorate rapidly by exposing the oxygen and moisture. So as to prevent it, domestic and overseas studies underway in various method such as ALD, PVD, CVD. But it has complex process and high cost. Therefore In order to protect devices from the external environments, it is important to develop the passivation thin films of low-cost and simple process which can prevent the devices from the penetration of the oxygen and moistures. In this study, to improve the reliability, passivation thin films were coated onto the green OLEDs by spin coating method and investigated the changes of the optical properties of the prepared devices at various doping concentrations of sodium alginate (SA). The passivation solutions were synthesized by using polyvinyl alcohol (PVA) host material with a dopant of SA which were added with the amounts of 10, 20 and 40 wt% into the PVA. As a result, the best barrier properties of the OLEDs were obtained for the samples with 40 wt% SA. Finally, the passivation films can be optimized by using the mixture solution of PVA and SA materials.

The relation of structural transition, thermal and electrical stability deintercalation of Li- CICs(II) : For Li-EaGDICs and Li-EGDICs (Li-CICs의 Deintercalation에 따른 구조변이와 열적, 전기적 안정성과의 관계(II) : Li-EaGDICs와 Li-EGDICs에 관하여)

  • Oh, Won-Chun;Park, Chung-Oh;Back, Dae-Jin;Ko, Young-Shin
    • Analytical Science and Technology
    • /
    • 제9권1호
    • /
    • pp.43-51
    • /
    • 1996
  • We have discussed on the deintercalation process of Li-EaGICs and Li-EGICs synthesized under pressure and temperature by spontaneous oxidation reaction of those compounds based on the results of X-ray diffraction, thermal analysis and electrical specific resistivity analysis. According to the results of the X-ray analysis for the intercalation process, we have found that the stage 1 for Li-EaGICs and Li-EGICs were not completly formed, but their lower stages were formed mainly. And from this results of the deintercalation process, we have found that the deintercalation process did not occur any more after 4 weeks, and the Li-EGDICs have more residual lithium metals than LiEaGDICs between the graphite interlayers. According to the thermal decomposition analysis, Li-two compounds had included very hard exothermic reaction. And we have found that these compounds did not occrurred deintercalation reaction above $400^{\circ}C$. According to the results of the electrical specific resistivity measurements, Li-EGDICs have relatively lower electrical specific resistivity than Li-EaGDICs, and Li-EaGDICs showed a formation of the ideal curve. From these results, we can suggest that Li-EaGDICs have a better properties as an anode material secondary than Li-EGICs.

  • PDF

The Study on living Art and Costumes Culture of the Middle-Age Europe (중세유럽의 생활미술과 복식문화에 관한 연구)

  • 이순홍
    • Journal of the Korean Society of Costume
    • /
    • 제35권
    • /
    • pp.17-44
    • /
    • 1997
  • Medieval European practical art and style of costume is studied through referring to the literatures. The type of clothing that was seen on tapestries arts and crafts paintings and wall paintings and appeared in the architecture such as church. There were symbolic aspects of color motifs at this period and some restraints for clothing according to the social class, It was a period that draped garments due to the War of Crusades is appeared. Be-cause the medieval taste and decorative character is not only 'formative art' but also the taste beyoud 'mode' and atomsphere of that times it could be seen the strong reflec-tion of customs in the clothing of that times which is shown in works of art. 1) The purpose of Christian art which was found in mosaics stained glasses wall pain-tings and statues of architecture was not just the revival of natural phenomena but visuali-zation of sacred and invisible things. It was valuable to understandin of the spiritual through the sense organ It was a monumental art that was combined with decorative func-tion and role of the Bible. It revealed what was about the religious spiritual miracle, 2) In the medieval European painting characteristic and beautiful creativity was the basis of an argument. Both "Worship of East-ern" that is painted ion a parchment and "Cor-onation of Charles VI" were described decor-ation motifs on the edge of buildings geo-metric patterns and others with outstanding skill. there were precise technologic skill of architect and glassmen and lots of patience of craftsmen. " The Labour of the Months" and the scene of"A Trial at the Court" is also de-scribed elaborately. 3) Tapestry was developed in France Ger-many Swiss at the 14th century. Religionary and historical themes unicorn lady bird flowering plants and others were major motifs. It was very important as decorative wall coverings and as practical door arch and bed hangings. It was made through patient hard work with simple technique and it was con-sidered as an art for practical use. Tapestry was what everyone wish to have. It is reckoned for the item of the best gift. The royalty and nobility ordered and used custom-made tapestries. Sometimes the subject of motifs consisted of series which were deeply related to living 4) Decorative arts and crafts was the art that used materials such as precious metals jewels and others and that accorded with the luxurious and gorgeous taste of the royalty and nobility. Christian considered splendid and beautiful color of light as a symbol of glory. They used also for church appliances, There were metal crafts wood crafts textile crafts and others, As was stated above the costume appeared on the arts and crafts for living revealed the process of changes saw how the politic econ-omic and social organizations were developed.and social organizations were developed.

  • PDF