• 제목/요약/키워드: hard carbon

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炭質陽이온交煥體 製造에 關한 硏究 (Studies on the Cation Exchangers from Coals)

  • 이범순;유인상
    • 대한화학회지
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    • 제4권1호
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    • pp.62-66
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    • 1957
  • With the intention of preparing cation exchangers from the domestic coals, and using these for softening hard water and some other purposes, seven kinds of raw coal were tested and the results are as follows. 1) The following conditions of preparation were given the good results. Reaction time 5 hours Reaction temperature $95^{\circ}$ Concentration of sulfuric acid 98% Amount of sulfuric acid 10 times to the sample (as weight) 2) The raw coals which is rich in fixed carbon and have the fuel ratio 0.8 to 1.0 were suitable, and Kampo lignite has shown the best results. 3) The cation exchangers from coals were able to exchange the cation, both hydrogen and sodium type dynamically and statically, like the synthetic ion exchange resin. The exchange capacities were as follows. Total capacity 1.60 meq/g. Breakthrough capacity 1.30 meq/g. Usable breakthrough capacity 1.20 meq/g National Central Research laboratory

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Fabrication of Hollow Metal Microcapsules with Mesoporous Shell Structure: Application as Efficient Catalysts Recyclable by Simple Magnetic Separation

  • Jang, Da-Young;Jang, Hyung-Gyu;Kim, Gye-Ryung;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • 제32권9호
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    • pp.3274-3280
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    • 2011
  • Monodispersed porous NiO and $Co_3O_4$ microcapsules with a hollow core were synthesized using SBA-16 silica sol and PS as a hard template. The porous hollow microcapsules were characterized by XRD, TEM and $N_2$ adsorption/desorption analysis. After $H_2$ reduction of metal oxide microspheres, they were conducted as an active catalyst in the reduction of chiral butylronitrile and cyanobenzene. The mesoporous metals having a hollow structure showed a higher activity than a nonporous metal powder and an impregnated metal on the carbon support.

마찰가공에 있어서의 분위기 영향에 관한 연구 제 1장

  • 손명완
    • 대한기계학회논문집
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    • 제5권4호
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    • pp.338-346
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    • 1981
  • Honing, lapping, polishing and superfinishing are applied for a precision machining to finish the metal surface, but these precision machining are micro-cutting by hard and micro-abrasive grains. Frictional machining is the new method to finish mirrorlike surface without using those abrasive grains. The frictional machining produces high pressure and high temperature instantly by compressing a tool material against the metal surface in sliding motion. The metal surface is given plastic deformation and plastic flow by the above mentioned frictional motion, but the surface roughness of the metal surface is influenced by physical and chemical reaction in surrounding atmosphere. Therefore, the atmosphere around the metal optimum atmosphere in the frictional machining. The part 1 of the study was performed in liquid atmospheres. Diesel oil, lubricant, grease, lard oil, bean oil and cutting fluid were used as such atmospheres. Medium carbon steel SM 50 C was used as a workpiece and ceramic tip was applied as a frictional tool. The result of the experiment showed characteristic machining conditions to generate the best surface roughness in each atmospheres.

AN ANALYSIS OF THE FACTORS AFFECTING THE HYDRAULIC CONDUCTIVITY AND SWELLING PRESSURE OF KYUNGJU CA-BENTONITE FOR USE AS A CLAY-BASED SEALING MATERIAL FOR A HIGH-LEVEL WASTE REPOSITORY

  • Cho, Won-Jin;Lee, Jae-Owan;Kwon, Sang-Ki
    • Nuclear Engineering and Technology
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    • 제44권1호
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    • pp.89-102
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    • 2012
  • The buffer and backfill are important components of the engineered barrier system in a high-level waste repository, which should be constructed in a hard rock formation at a depth of several hundred meters below the ground surface. The primary function of the buffer and backfill is to seal the underground excavation as a preferred flow path for radionuclide migration from the deposited high-level waste. This study investigates the hydraulic conductivity and swelling pressure of Kyungju Ca-bentonite, which is the candidate material for the buffer and backfill in the Korean reference high-level waste disposal system. The factors that influence the hydraulic conductivity and swelling pressure of the buffer and backfill are analyzed. The factors considered are the dry density, the temperature, the sand content, the salinity and the organic carbon content. The possibility of deterioration in the sealing performance of the buffer and backfill is also assessed.

생체자극으로써의 PRTS 신호의 이용에 관한 연구 (Using Pseudo-Random Ternary Sequence as Physiological Stimulus)

  • 탁계래
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1997년도 추계학술대회
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    • pp.91-94
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    • 1997
  • In this paper, pseudo-random ternary sequence (PRTS) was used to investigate the cardiovascular and respiratory responses to hypoxia and hypercapnia. The actual input or this study was the changes in inhaled oxygen and carbon dioxide concentrations. It is hard to randomly change the concentration within a given breath. Since PRTS has almost the same statistical properties as Gaussian white noise, plus it is physically realizable, PRTS is used for this study. Using PRTS and Volterra kernels by Gram-Schmidt orthogonalization procedure, the cardiovascular and respiratory responses to hypoxia and hypercapnia were analyzed.

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생체재료로의 다이아몬드상 카본 박막의 특성

  • 김동환;김현이;이광렬;김형우;이인섭
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.130-130
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    • 2000
  • 타이타늄(CP Ti)과 타?늄합금은 인체의 골격을 구성하고 있는 물질과 가장 흡사한 물리적 성질과 우수한 생체적합성으로 인해 임플란트용 재료로 많이 사용되고 있으며, 최근에 인공관절이나 치근으로의 사용이 증가하고 있다. 그러나 교합면에서의 취약한 마모특성으로 인해 wear debris에 의한 골 흡수 및 이완 등을 야기하는 문제점으로, 이의 개선에 관한 연구가 활발히 진행되어 왔다. 다이아몬드상 카본 (Diamond-Like-Carbon) 박막은, 다이아몬드와 유사한 높은 경도, 내마모성 그리고 화학적 안정성 등의 매우 우수한 물리화학적 특성을 가지고 있는 박막재료로 고체 윤활박막으로서 hard disk나 VCR head drum의 보호막, 우주항공기의 bearing 재료코팅 등으로의 적용이 최근에 급격히 증가하고 있다. 본 연구에서는 이와 같은 특성을 지닌 다이아몬드상 카본 박막의 생체재료로의 적용을 위해, CP Ti과 Ti-6Al-4V에 13.56MHz를 사용하는 r.f PACVD법으로 DLC를 증착하여 생체적합적 특성을 조사하였다. C6H6 가스를 사용하여 1$\mu\textrm{m}$의 두께로 DLC 박막을 증착하였으며, 기판과의 밀찰력 향상을 위해 Si을 증간층으로 합성하였다. 마모특성은 pin-on-disk type wear tester을 사용하였으며 직경 5mm의 ruby ball로 실험을 수행하였다.

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하드디스크 드라이브에서 슬라이더의 DLC 층 손상에 의한 진동 특성 변화에 관한 연구 (Analysis for flying stability with damaged DLC layer by confined optical energy in TAMR system)

  • 박노철;최종학;임건엽;박경수;박영필
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2014년도 추계학술대회 논문집
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    • pp.984-985
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    • 2014
  • This research investigates to analyze the effect of laser of thermally assisted magnetic recording system on diamond like carbon (DLC) layer of slider. We investigated a damaged DLC layer of slider with laser spot-induced damage and analyze the effect of the damaged DLC layer in slider dynamics. The damaged DLC layer resulted in change of flying height and air bearing stiffness pressure.

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Surface hardening and enhancement of Corrosion Resistance of AISI 310S Austenitic Stainless Steel by Low Temperature Plasma Nitrocarburizing treatment.

  • Lee, Insup
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 추계총회 및 학술대회 논문집
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    • pp.175-177
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    • 2012
  • A corrosion resistance and hard nitrocarburized layer was distinctly formed on 310 austenitic stainless steel substrate by DC plasma nitrocarburizing. Basically, 310L austenitic stainless steel has high chromium and nickel content which is applicable for high temperature applications. In this experiment, plasma nitrocarburizing was performed in a D.C. pulsed plasma ion nitriding system at different temperatures in $H_2-N_2-CH_4$ gas mixtures. After the experiment structural phases, micro-hardness and corrosion resistance were investigated by the optical microscopy, X-ray diffraction, scanning electron microscopy, micro-hardness testing and Potentiodynamic polarization tests. The hardness of the samples was measured by using a Vickers micro hardness tester with the load of 100 g. XRD indicated a single expanded austenite phase was formed at all treatment temperatures. Such a nitrogen and carbon supersaturated layer is precipitation free and possesses a high hardness and good corrosion resistance.

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외기 미세먼지와 탑승객수에 따른 객실 PM10 농도변화 연구 (Study on PM10 levels by the concentration of outdoor aerosols and the number of passengers in railway cabin)

  • 박은영;박덕신;권순박;조영민;김세영;정미영
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2008년도 춘계학술대회 논문집
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    • pp.1816-1820
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    • 2008
  • Indoor air quality in public transportation such as railway, subway and bus is hard to control because of spatial restrict and variation of passenger's number. On January 2007, The Ministry of Environment announced "the guideline of indoor air quality in public transportation" for the concentration managements of particulate matter and carbon dioxide. In this study, we measured the PM10 concentration inside the Mugunghwa-ho passenger cabin and outdoor air and counted passengers. By the statistical analysis using SigmaPlot 2001 and SPSS 13.0, we found that indoor PM10 concentration is significantly affected by outdoor air. It is suggested that the air quality of inflow to the passenger cabin for air exchange must be controlled to support the indoor environment comfortably.

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침탄(浸炭)이 저탄소강(低炭素鋼)의 피로(疲勞)에 미치는 영향(影響) (The Effect of Carburization of the Fatigue of Low Carbon Steel)

  • 강창수;서창민
    • 대한조선학회지
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    • 제10권2호
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    • pp.9-18
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    • 1973
  • The effects of carburization on the fatigue strength and cracks were studied. The fatigue phenomena of the carburized specimens were compared with noncarburized specimens those were either heat-treated or un-treated. The fatigue strength of these specimens were measured by rotating bending fatigue machine. The obtained results indicated that the fatigue strength of carburized specimens were increased ranging from 24-59 % than those of un-treated, and 22-38% than those of heat-treated. The Vickers hardness of carburized were also increased as much as 138-195% than those of un-treated, and 42-125% than those of heat-treated. The microscopic observation of the carburized specimens mostly composed of minute pearlitic structure at hard case exhibited to have more localized slip than those of non-carburized specimens.

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