• 제목/요약/키워드: hard carbon

검색결과 220건 처리시간 0.033초

패키지형 탄소섬유복합재 가공시스템 개발 (Development of Manufacturing System Package for CFRP Machining)

  • 김효영;김태곤;이석우;윤한솔;경대수;최인휴;최현;고종민
    • 한국정밀공학회지
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    • 제33권6호
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    • pp.431-438
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    • 2016
  • Recently, concerns about the environment are becoming more important because of global warming and the exhaustion of earth's resources. In the aviation and automobile industries, the application of light materials is increasingly important for eco-friendly and effective. Carbon Fiber Reinforced Plastics is a composite material which great formability and the high strength of carbon fiber. CFRP, which is both light and strong, is hard to manufacture. In addition, CFRP machining has a high chance of defects. This research discusses the development of a manufacturing system package for CFRP machining. It involving CFRP Drilling/Water-jet Manufacturing Machines, Inspection/Post-processing Systems, CNC platform for an EtherCAT servo Communication, Flexible Manufacturing Systems and CFRP machining Processes.

스테인리스강 STS 316L과 탄소강 A516-70의 이종금속 GTA 용접부 특성에 대한 연구 (A Study of Characteristics on the Dissimilar Metals (STS 316L - Carbon Steel: ASTM A516-70) Welds made with GTAW)

  • 김세철;신태우;문인준;장복수;고진현
    • Journal of Welding and Joining
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    • 제33권4호
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    • pp.37-43
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    • 2015
  • Characteristics of dissimilar metal welds between STS 316L and carbon steel ASTM A516 Gr.70 made with GTAW have been evaluated in terms of microstructure, ferrite content, chemical analysis, hardness and corrosion resistance. Three heat inputs of 9.00, 11.25, 13.00kJ/cm were employed to make joints of dissimilar metals with ER309 wire. Based on microstructural examination, the amount of vermicular type of ${\delta}$-ferrite was increased with increasing heat input due to the increase of Creq/Nieq in the second layer of welds. Based on the EDX analysis of weld metals, Cr and Ni content in the 2nd layer increased while those content in the first layer of welds decreased with heat inputs. Cellular solidification mode in the 1st layer and dendritic solidification mode in the 2nd layer due to different cooling rates were prevailed, respectively. Heat affected zone which formed hard microstructure showed higher hardness than the weld metal. The salt spray test of dissimilar metals weld joints showed that the carbon steel surfaces only corroded. The weight loss rate due to corrosion increased up to 100hours but it decreased above 100 hours. There was little difference in the weight loss caused by corrosion regardless of heat inputs.

활성탄의 세공구조와 Acetone Vapor 흡착특성의 상관관계 (Correlations Between Pore Structure of Activated Carbon and Adsorption Characteristics of Acetone Vapor)

  • 이송우;배상규;권준호;나영수;안창덕;윤영삼;송승구
    • 대한환경공학회지
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    • 제27권6호
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    • pp.620-625
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    • 2005
  • 연속식 흡착장치를 사용하여 활성탄의 세공구조와 아세톤 중기의 흡착특성과의 상관관계를 고찰하였다. 실험에서 비교한 활성탄 중 젠체 세공구조에서 직경 $10{\AA}$ 이하의 세공이 가장 많이 발달한 Takeda의 ACT 활성탄이 가장 긴 파과시간을 가지고 있었다. 평형흡착량은 파과시간에는 비례했지만, BET 비표면적에는 비례한다고 볼 수 없었기 때문에 BET 비표면적 만으로 흡착능을 평가하는 것은 어려웠다. 누적표면적과 평형흡착량과의 상관관계는 $10{\AA}$ 이하에서 가장 컸고, 세공범위가 클수록 감소했다.

극저온 $CO_2$ 세정공정을 위한 거친표면 위 미세입자의 점착특성 연구 (A Study of Minute Particles' Adhesion on a Rough Surface for a Cryogenic $CO_2$ Cleaning Process)

  • 석종원;이성훈;김필기
    • 반도체디스플레이기술학회지
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    • 제9권1호
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    • pp.5-10
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    • 2010
  • Among a variety of cleaning processes, the cryogenic carbon dioxide ($CO_2$) cleaning has merits because it is highly efficient in removing very fine particles, innoxious to humans and does not produce residuals after the cleaning, which enables us to extend its area of coverage in the semi-conductor fabrication society. However, the cryogenic carbon dioxide cleaning method has some technical research issues in aspect to particles' adhesion and removal. To resolve these issues, performing an analysis for the identification of particle adhesion mechanism is needed. In this study, a research was performed by a theoretical approach. To this end, we extended the G-T (Greenwood-Tripp) model by applying the JKR (Johnson-Kendall-Roberts) and Lennard-Jones potential theories and the statistical characteristics of rough surface to investigate and identify the contact, adhesion and deformation mechanisms of soft or hard particles on the rough substrate. The statistical characteristics of the rough surface were taken into account through the employment of the normal probability distribution function of the asperity peaks on the substrate surface. The effects of surface roughness on the pull-off force for these particles were examined and discussed.

Hydrocarbon Plasma of a Low-Pressure Arc Discharge for Deposition of Highly-Adhesive Hydrogenated DLC Films

  • Chun, Hui-Gon;Oskomov, Konstantin V.;Sochugov, Nikolay S.;Lee, Jing-Hyuk;You, Yong-Zoo;Cho, Tong-Yul
    • 반도체디스플레이기술학회지
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    • 제2권1호
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    • pp.1-5
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    • 2003
  • Plasma generator based on non-self-sustained low-pressure arc discharge has been examined as a tool for deposition of highly-adhesive hydrogenated amorphous diamond-like carbon(DLC) films. Since the discharge is stable in wide range of gas pressures and currents, this plasma source makes possible to realize both plasma-immersion ion implantation(PIII) and plasma-immersion ion deposition(PIID) in a unified vacuum cycle. The plasma parameters were measured as functions of discharge current. Discharge and substrate bias voltage parameters have been determined for the PIII and PIID modes. For PIID it has been demonstrated that hard and well-adherent DLC coating are produced at 200-500 eV energies per deposited carbon atom. The growth rates of DLC films in this case are about 200-300 nm/h. It was also shown that short(∼60$\mu\textrm{s}$) high-voltage(> 1kV) substrate bias pulses are the most favorable for achieving high hardness and good adhesion of DLC, as well as for reducing of residual intrinsic stress are.

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벌크흑연 제조를 위한 결합재로 이용되는 콜타르 핏치 및 페놀수지의 열처리에 의한 결정성 변화 (Crystallinity Changes Heat Treatment of Coal Tar Pitch and Phenol Resin used as a Binder for Bulk Graphite Manufacturing)

  • 이상민;이현용;이상혜;노재승
    • 공업화학
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    • 제32권2호
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    • pp.174-179
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    • 2021
  • 인조흑연 제조용 바인더로 주로 이용되는 콜타르 핏치와 페놀 레진은 soft carbon 및 hard carbon의 초기 탄소화합물 구조에 차이가 있다. 따라서 탄화 온도에 따른 열분해 거동, 미세조직, 결정성의 변화 과정도 다를 것으로 예상할 수 있다. 본 연구에서는 콜타르 핏치 및 페놀 레진의 열분해 거동, 미세조직, 결정성 변화에 관하여 비교 분석하였다. 콜타르 핏치는 액상을 경유한 탄화 과정을 거치며, 탄화 온도가 증가함에 따라 미세조직이 점차 변화되는 것을 확인할 수 있었다. 탄화 온도가 증가함에 따라 콜타르 핏치 및 페놀 레진 모두 결정성은 증가하는 경향을 나타냈지만, 콜타르 핏치는 미세조직이 급변하는 500 및 600 ℃ 구간에서 결정성도 급격히 변화는 것을 확인할 수 있었다. 또한 미세조직과 결정성은 서로 밀접한 연관성이 있었다.

배가스로부터에틸렌 회수를 위한 활성탄과 CMS 흡착탑의 흡착거동 특성 (Adsorption Dynamics of Activated Carbon and Carbon Molecular Sieve Beds for Ethylene Recovery)

  • 윤기용;전필립;우은지;;이창하
    • Korean Chemical Engineering Research
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    • 제50권3호
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    • pp.527-534
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    • 2012
  • FCC 연료가스로부터 에틸렌 회수를 위한 흡착공정을 개발을 위하여 활성탄(AC)과 탄소분자체(CMS)로 충진된 흡착탑의 흡착 동특성을 비교하였다. FCC 연료가스로는 6성분($CH_4/C_2H_4/C_2H_6/C_3H_6/N_2/H_2$,32:15:14:2:12:25 vol.%) 혼합가스를 이용하였으며, 흡착탑의 흡착 및 탈착파과 실험을 실시하였다. 활성탄 흡착탑의 경우 파과는 $H_2$ < $N_2$ < $CH_4$ < $C_2H_4$ < $C_2H_6$ 순서로 나왔으며, CMS 흡착탑의 경우는 $H_2$< $CH_4$ < $N_2$ < $C_2H_6$ < $C_2H_4$ 순서를 보였다. CMS 흡착탑은 활성탄 흡착탑보다 성능이 나쁘나, 속도분리의 특성으로 $CH_4$$N_2$뿐만 아니라 활성탄에서 제거하기 어려운 $C_2H_6$ 이상의 성분들을 흡착단계에서 제거할 수 있다. 흡착탑의 재생은 감압과정만으로는 두 흡착제 충진탑에서 충분히 재생되기 어려우며, 진공재생이 필요하다. 따라서 CMS를 이용하는 흡착공정은 전처리 공정으로 설계하고, 활성탄을 이용하는 흡착공정을 주요 분리기로 설계하는 압력진공순환식 흡착공정(PVSA)이 에틸렌 회수에 제안될 수 있다.

Synthesis of Uniformly Doped Ge Nanowires with Carbon Sheath

  • 김태헌;장야무진;최순형;서영민;이종철;황동훈;김대원;최윤정;황성우;황동목
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.289-289
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    • 2013
  • While there are plenty of studies on synthesizing semiconducting germanium nanowires (Ge NWs) by vapor-liquid-solid (VLS) process, it is difficult to inject dopants into them with uniform dopants distribution due to vapor-solid (VS) deposition. In particular, as precursors and dopants such as germane ($GeH_4$), phosphine ($PH_3$) or diborane ($B_2H_6$) incorporate through sidewall of nanowire, it is hard to obtain the structural and electrical uniformity of Ge NWs. Moreover, the drastic tapered structure of Ge NWs is observed when it is synthesized at high temperature over $400^{\circ}C$ because of excessive VS deposition. In 2006, Emanuel Tutuc et al. demonstrated Ge NW pn junction using p-type shell as depleted layer. However, it could not be prevented from undesirable VS deposition and it still kept the tapered structures of Ge NWs as a result. Herein, we adopt $C_2H_2$ gas in order to passivate Ge NWs with carbon sheath, which makes the entire Ge NWs uniform at even higher temperature over $450^{\circ}C$. We can also synthesize non-tapered and uniformly doped Ge NWs, restricting incorporation of excess germanium on the surface. The Ge NWs with carbon sheath are grown via VLS process on a $Si/SiO_2$ substrate coated 2 nm Au film. Thin Au film is thermally evaporated on a $Si/SiO_2$ substrate. The NW is grown flowing $GeH_4$, HCl, $C_2H_2$ and PH3 for n-type, $B_2H_6$ for p-type at a total pressure of 15 Torr and temperatures of $480{\sim}500^{\circ}C$. Scanning electron microscopy (SEM) reveals clear surface of the Ge NWs synthesized at $500^{\circ}C$. Raman spectroscopy peaked at about ~300 $cm^{-1}$ indicates it is comprised of single crystalline germanium in the core of Ge NWs and it is proved to be covered by thin amorphous carbon by two peaks of 1330 $cm^{-1}$ (D-band) and 1590 $cm^{-1}$ (G-band). Furthermore, the electrical performances of Ge NWs doped with boron and phosphorus are measured by field effect transistor (FET) and they shows typical curves of p-type and n-type FET. It is expected to have general potentials for development of logic devices and solar cells using p-type and n-type Ge NWs with carbon sheath.

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실리콘 유무기 하이브리드 코팅을 이용한 CNT 투명전도필름의 내구성 증진에 관한 연구

  • 하인호;신권우;한종훈;서문석;김선민;조진우;이철승
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.414-414
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    • 2012
  • 차세대 플렉시블 디스플레이 소재로서, 탄소나노뷰브(CNT) 기반의 투명전도막은 기존의 ITO 박막보다 우수한 유연성을 갖기 때문에 많은 관심을 모으고 있다. 특히 낮은 저항과 투과도를 유지하면서 투명 전도막의 내구성을 향상시키는 연구는 상업화에 가장 필요한 연구 분야이다. 본 연구에서는 다층벽 탄소나노튜브(MWCNT)를 이용하여 제작된 투명 전도막의 내구성을 개선하기 위하여 오버 코팅을 통한 물성 개선을 연구하였다. 투명전도막은 PET기판 위에 스프레이 방식을 이용하여 균일하게 코팅하였다. 오버 코팅 물질로는 실리콘계 유무기하이브리드 투명하드 코팅을 적용하였다. 연구결과 오버 코팅층과 CNT 코팅층과의 젖음성이 물성 향상에 가장 많은 영향을 끼치는 것을 관찰하였고, 특히 젖음성이 증가할수록 투과도와 전기전도도가 향상되는 것을 확인하였다. 또한 고온 고습 환경에서 240시간 이상 내구성 테스트 결과, 저항률 변화가 1.1 이하인 것을 확인하였다.

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Screening and Production of Manganese Peroxidase from Fusarium sp. on Residue Materials

  • Huy, Nguyen Duc;Tien, Nguyen Thi Thanh;Huyen, Le Thi;Quang, Hoang Tan;Tung, Truong Quy;Luong, Nguyen Ngoc;Park, Seung-Moon
    • Mycobiology
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    • 제45권1호
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    • pp.52-56
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    • 2017
  • In this study, we report the manganese peroxidase production ability from a Fusarium sp. strain using an inexpensive medium of agriculture residues of either rice straw or wood chips as carbon source. The highest manganese peroxidase activity on rice straw medium and on wood chips was 1.76 U/mL by day 9 and 1.91 U/mL by day 12, respectively.